DE10394353B4 - Verfahren zur Herstellung von an Glycin angereicherten Natriumchloridkristallen mit verbessertem Fluss - Google Patents

Verfahren zur Herstellung von an Glycin angereicherten Natriumchloridkristallen mit verbessertem Fluss Download PDF

Info

Publication number: DE10394353B4
Authority: DE; Germany
Prior art keywords: glycine; salt; saline; saline solution; crystals
Prior art date: 2003-12-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE10394353.6T

Other languages

German (de)

English (en)

Other versions

DE10394353T5 (de

Inventor

Parthasarathi Dastidar

Pushpito Kumar Ghosh

Amza Ballabh

Darshak Rameshbhai Trivedi

Amitava Pramanik

Velayudhan Nair Gopa Kumar

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Council of Scientific and Industrial Research CSIR

Hindustan Unilever Ltd

Original Assignee

Council of Scientific and Industrial Research CSIR

Hindustan Lever Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-12-24

Filing date

2003-12-24

Publication date

2014-09-11

2003-12-24 Application filed by Council of Scientific and Industrial Research CSIR, Hindustan Lever Ltd filed Critical Council of Scientific and Industrial Research CSIR

2006-11-23 Publication of DE10394353T5 publication Critical patent/DE10394353T5/de

2014-09-11 Application granted granted Critical

2014-09-11 Publication of DE10394353B4 publication Critical patent/DE10394353B4/de

2023-12-25 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 title claims abstract description 259
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 title claims abstract description 132
239000004471 Glycine Substances 0.000 title claims abstract description 123
239000013078 crystal Substances 0.000 title claims abstract description 69
239000011780 sodium chloride Substances 0.000 title claims abstract description 55
238000000034 method Methods 0.000 title claims abstract description 46
230000008569 process Effects 0.000 title claims abstract description 29
238000002360 preparation method Methods 0.000 title claims abstract description 7
239000012266 salt solution Substances 0.000 claims abstract description 25
QNRATNLHPGXHMA-XZHTYLCXSA-N (r)-(6-ethoxyquinolin-4-yl)-[(2s,4s,5r)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]methanol;hydrochloride Chemical compound Cl.C([C@H]([C@H](C1)CC)C2)CN1[C@@H]2[C@H](O)C1=CC=NC2=CC=C(OCC)C=C21 QNRATNLHPGXHMA-XZHTYLCXSA-N 0.000 claims abstract description 24
238000001704 evaporation Methods 0.000 claims abstract description 24
230000008020 evaporation Effects 0.000 claims abstract description 22
238000005406 washing Methods 0.000 claims abstract description 22
239000012452 mother liquor Substances 0.000 claims abstract description 16
229920006395 saturated elastomer Polymers 0.000 claims abstract description 13
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 10
-1 dodecahedral Chemical compound 0.000 claims abstract description 8
239000012267 brine Substances 0.000 claims abstract description 5
125000004122 cyclic group Chemical group 0.000 claims abstract description 3
230000008016 vaporization Effects 0.000 claims abstract description 3
150000003839 salts Chemical class 0.000 claims description 76
239000000243 solution Substances 0.000 claims description 8
239000011785 micronutrient Substances 0.000 claims description 6
235000013369 micronutrients Nutrition 0.000 claims description 6
230000002335 preservative effect Effects 0.000 claims description 5
239000003755 preservative agent Substances 0.000 claims description 4
239000004033 plastic Substances 0.000 claims description 3
230000002939 deleterious effect Effects 0.000 claims description 2
235000002639 sodium chloride Nutrition 0.000 description 115
238000004519 manufacturing process Methods 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
238000002425 crystallisation Methods 0.000 description 12
239000003607 modifier Substances 0.000 description 12
230000008025 crystallization Effects 0.000 description 11
230000015572 biosynthetic process Effects 0.000 description 9
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
239000000654 additive Substances 0.000 description 7
235000013305 food Nutrition 0.000 description 6
230000004048 modification Effects 0.000 description 6
238000012986 modification Methods 0.000 description 6
239000000126 substance Substances 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
239000000463 material Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
238000004064 recycling Methods 0.000 description 4
235000011121 sodium hydroxide Nutrition 0.000 description 4
239000000306 component Substances 0.000 description 3
238000003860 storage Methods 0.000 description 3
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
230000008901 benefit Effects 0.000 description 2
UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 2
YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
239000004202 carbamide Substances 0.000 description 2
230000008859 change Effects 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000010411 cooking Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000001914 filtration Methods 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
125000003630 glycyl group Chemical group [H]N([H])C([H])([H])C(*)=O 0.000 description 2
230000005484 gravity Effects 0.000 description 2
150000002825 nitriles Chemical class 0.000 description 2
230000000050 nutritive effect Effects 0.000 description 2
231100000683 possible toxicity Toxicity 0.000 description 2
239000000276 potassium ferrocyanide Substances 0.000 description 2
230000002829 reductive effect Effects 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
239000007787 solid Substances 0.000 description 2
XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
241000238557 Decapoda Species 0.000 description 1
206010013911 Dysgeusia Diseases 0.000 description 1
239000001692 EU approved anti-caking agent Substances 0.000 description 1
241000237536 Mytilus edulis Species 0.000 description 1
239000004111 Potassium silicate Substances 0.000 description 1
229940095054 ammoniac Drugs 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
229940000635 beta-alanine Drugs 0.000 description 1
229960003237 betaine Drugs 0.000 description 1
238000003889 chemical engineering Methods 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000005056 compaction Methods 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
235000013365 dairy product Nutrition 0.000 description 1
210000001787 dendrite Anatomy 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000002050 diffraction method Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000003337 fertilizer Substances 0.000 description 1
235000013312 flour Nutrition 0.000 description 1
235000013373 food additive Nutrition 0.000 description 1
239000002778 food additive Substances 0.000 description 1
235000012041 food component Nutrition 0.000 description 1
239000005428 food component Substances 0.000 description 1
235000003599 food sweetener Nutrition 0.000 description 1
230000036449 good health Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000003317 industrial substance Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000007788 liquid Substances 0.000 description 1
235000010746 mayonnaise Nutrition 0.000 description 1
239000008268 mayonnaise Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000000051 modifying effect Effects 0.000 description 1
235000020638 mussel Nutrition 0.000 description 1
FQTCUKQMGGJRCU-UHFFFAOYSA-N n,n-diacetylacetamide Chemical compound CC(=O)N(C(C)=O)C(C)=O FQTCUKQMGGJRCU-UHFFFAOYSA-N 0.000 description 1
231100000989 no adverse effect Toxicity 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
235000021110 pickles Nutrition 0.000 description 1
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
229910052913 potassium silicate Inorganic materials 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000001953 recrystallisation Methods 0.000 description 1
CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
229940081974 saccharin Drugs 0.000 description 1
235000019204 saccharin Nutrition 0.000 description 1
239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
235000014214 soft drink Nutrition 0.000 description 1
239000011343 solid material Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000019614 sour taste Nutrition 0.000 description 1
239000003765 sweetening agent Substances 0.000 description 1
235000019640 taste Nutrition 0.000 description 1
239000004753 textile Substances 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
- C01D3/06—Preparation by working up brines; seawater or spent lyes
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/26—Preventing the absorption of moisture or caking of the crystals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Seasonings (AREA)
Coloring Foods And Improving Nutritive Qualities (AREA)
Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

DE10394353.6T 2003-12-24 2003-12-24 Verfahren zur Herstellung von an Glycin angereicherten Natriumchloridkristallen mit verbessertem Fluss Expired - Fee Related DE10394353B4 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
PCT/IB2003/006237 WO2005066075A1 (en)	2003-12-24	2003-12-24	Process for production of glycine enriched sodium chloride crystals with improved flow

Publications (2)

Publication Number	Publication Date
DE10394353T5 DE10394353T5 (de)	2006-11-23
DE10394353B4 true DE10394353B4 (de)	2014-09-11

Family

ID=34746632

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE10394353.6T Expired - Fee Related DE10394353B4 (de)	2003-12-24	2003-12-24	Verfahren zur Herstellung von an Glycin angereicherten Natriumchloridkristallen mit verbessertem Fluss

Country Status (9)

Country	Link
JP (1)	JP4805677B2 (pt)
CN (1)	CN1972869B (pt)
BR (1)	BR0318682B1 (pt)
CA (1)	CA2551051C (pt)
DE (1)	DE10394353B4 (pt)
GB (1)	GB2440138B (pt)
IL (1)	IL176542A (pt)
MX (1)	MXPA06007390A (pt)
WO (1)	WO2005066075A1 (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2009087645A1 (en) *	2008-01-07	2009-07-16	Council Of Scientific & Industrial Research	Free flowing 100 - 500 mm size spherical crystals of common salt and process for preparation thereof
GB0807919D0 (pt)	2008-05-01	2008-06-04	Moorlodge Biotech Ventures Ltd
WO2010002712A2 (en)	2008-06-30	2010-01-07	3M Innovative Properties Company	Method of crystallization
US9808030B2 (en)	2011-02-11	2017-11-07	Grain Processing Corporation	Salt composition
CN103373735A (zh) *	2012-04-27	2013-10-30	北京美华盛工程技术有限公司	一种生产具有防结块性质的食品级氯化钠和氯化钾盐的方法
BR112015025834B1 (pt) *	2013-04-10	2021-12-21	Smart Salt Inc	Produto salgado co-cristalizado homogêneo, seus usos e seu método de preparação
US10881123B2 (en) *	2017-10-27	2021-01-05	Frito-Lay North America, Inc.	Crystal morphology for sodium reduction
CN111302362B (zh) *	2020-04-03	2021-05-07	天津科技大学	一种大颗粒球形盐及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3856922A (en) *	1973-11-06	1974-12-24	R Bragdon	Process for preparing substantially non-caking sodium chloride

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH1142064A (ja) *	1997-07-28	1999-02-16	Akou Kasei Kk	高ミネラル食塩組成物
FI110474B (fi) *	1999-01-27	2003-02-14	Modulpo Salts Oy	Ravintofysiologinen suolatuote, sen käyttö ja menetelmä sen valmistamiseksi
JP2001061417A (ja) *	1999-08-25	2001-03-13	Sanei Gen Ffi Inc	粉状物含有組成物
KR100427012B1 (ko) *	2000-01-12	2004-04-30	오성은	순수소금의 제조방법
AU2001269122B2 (en) *	2000-08-14	2004-06-10	Unilever Plc	Granulation process
JP4246407B2 (ja) *	2001-04-27	2009-04-02	キッセイ薬品工業株式会社	液体調味料

2003
- 2003-12-24 WO PCT/IB2003/006237 patent/WO2005066075A1/en active Application Filing
- 2003-12-24 CA CA2551051A patent/CA2551051C/en not_active Expired - Fee Related
- 2003-12-24 GB GB0612958A patent/GB2440138B/en not_active Expired - Fee Related
- 2003-12-24 JP JP2005513078A patent/JP4805677B2/ja not_active Expired - Fee Related
- 2003-12-24 MX MXPA06007390A patent/MXPA06007390A/es active IP Right Grant
- 2003-12-24 BR BRPI0318682-2B1A patent/BR0318682B1/pt active IP Right Grant
- 2003-12-24 DE DE10394353.6T patent/DE10394353B4/de not_active Expired - Fee Related
- 2003-12-24 CN CN2003801109228A patent/CN1972869B/zh not_active Expired - Fee Related
2006
- 2006-06-25 IL IL176542A patent/IL176542A/en not_active IP Right Cessation

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3856922A (en) *	1973-11-06	1974-12-24	R Bragdon	Process for preparing substantially non-caking sodium chloride

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Derwent-abstract zu JP 2001 061 417 A; AN_WPI: 2001263855 und englischsprachige Maschinenübersetzung aus Depatis *
FENIMORE, Charles P; THRAILKILL, Arthur: The Mutual Habit Modification of Sodium Chloride and Dipolar Ions. In: J. Am. Chem. Soc. 1949, Vol. 71, Seiten 2714 - 2717 *
FENIMORE, Charles P; THRAILKILL, Arthur: The Mutual Habit Modification of Sodium Chloride and Dipolar Ions. In: J. Am. Chem. Soc. 1949, Vol. 71, Seiten 2714 – 2717

Also Published As

Publication number	Publication date
CA2551051C (en)	2011-08-02
CN1972869A (zh)	2007-05-30
DE10394353T5 (de)	2006-11-23
JP4805677B2 (ja)	2011-11-02
JP2007527834A (ja)	2007-10-04
AU2003288642A1 (en)	2005-08-12
IL176542A (en)	2010-12-30
WO2005066075A1 (en)	2005-07-21
CN1972869B (zh)	2011-03-30
IL176542A0 (en)	2006-10-05
BR0318682B1 (pt)	2013-07-16
CA2551051A1 (en)	2005-07-21
BR0318682A (pt)	2006-12-12
GB0612958D0 (en)	2006-08-30
GB2440138A (en)	2008-01-23
GB2440138B (en)	2009-04-08
MXPA06007390A (es)	2007-03-23

Legal Events

Date	Code	Title
2011-02-03	8110	Request for examination paragraph 44
2014-04-30	R016	Response to examination communication
2014-05-21	R018	Grant decision by examination section/examining division
2015-06-12	R020	Patent grant now final
2018-07-03	R119	Application deemed withdrawn, or ip right lapsed, due to non-payment of renewal fee

Publication	Publication Date	Title
DE10394353B4 (de)	2014-09-11	Verfahren zur Herstellung von an Glycin angereicherten Natriumchloridkristallen mit verbessertem Fluss
DE1109152B (de)	1961-06-22	Verfahren zur Herstellung von Natriumperborat
DE60029320T2 (de)	2007-07-05	Nichtzusammenbackende natriumchloridkristalle, ein verfahren zu deren herstellung und deren verwendung in einem elektrolyseverfahren
EP1022252B1 (de)	2006-03-22	Verfahren zur Verengung des Kornspektrums von Kalium- und Natriumchloridkristallisaten zur Verbesserung der Rieseleigenschaften
US7220435B2 (en)	2007-05-22	Process for the production of glycine enriched NaCI crystals with improved flow
DE102009018956B4 (de)	2014-02-13	Verfahren zur Herstellung von Kaliumsulfat aus Bittern
DE69216902T2 (de)	1997-08-21	Verfahren zur Kristallisierung von Aspartam
DE68921163T2 (de)	1995-07-20	Isolierung von L-Phenylalanin aus dessen racemischen Mischungen.
DE2506151C3 (de)	1978-03-02	Doppelsalz aus Betain und Natriumchlorid, Verfahren zu seiner Herstellung und seine Verwendung als Würzmittel
DE60202609T2 (de)	2005-12-29	Verfahren zur herstellung von hochreinem feuchtem salz, so erhältliches feuchtes salz und verwendung davon bei einem elektrolyseverfahren
AU2003288642B2 (en)	2008-11-27	Process for the production of glycine enriched sodium chloride crystals with improved flow
WO2005062720A2 (en)	2005-07-14	PROCESS FOR PRODUCTION OF GLYCINE ENRICHED NaCl CRYSTALS WITH IMPROVED FLOW
DE4128607A1 (de)	1992-03-19	Herstellung von kaliumchlorid-kristallen
DE1256649B (de)	1967-12-21	Verfahren zur Reinigung von Polymyxin
DE2151096A1 (de)	1972-05-31	3,4-Dihydroxyphenylalanin-hemihydrochlorid
DE304087C (pt)
DE598368C (de)	1934-06-11	Verfahren zu Herstellung eines streufaehigen, lagerbestaendigen, Ammonsulfat und Ammonnitrat enthaltenden Duengers
AT234266B (de)	1964-06-25	Verfahren zur Behandlung von Insulinkristallen und zur Herstellung von Insulinpräparaten aus diesen Kristallen
DE51224C (de)		Darstellung von Potasche unter gleichzeitiger Gewinnung von Blanc fixe
AT201234B (de)	1958-12-10	Verfahren zur Herstellung von Insulinkristallen ungefähr einheitlicher Größe
AT132690B (de)	1933-04-10	Verfahren zur Herstellung von reinem Calciumhypochlorit.
DE1618492C (de)	1973-02-15	Fruktosegewinnung aus Zucker
DE421470C (de)	1925-11-12	Verfahren zum Auslaugen von sulfathaltigen Nitraterzen
DE1169082B (de)	1964-04-30	Verfahren zur Herstellung von aus Rinder-pankreasdruesen gewonnenen Insulinkristallen mit protrahierter Wirkung
CH156646A (de)	1932-08-15	Verfahren zur Darstellung eines Doppelsalzes des Calciumnitrats mit Kaliumnitrat.