DD145273A5 - Verfahren zur herstellung von o-aryl-n-phosphonomethylglycinnitrilen - Google Patents

Verfahren zur herstellung von o-aryl-n-phosphonomethylglycinnitrilen Download PDF

Info

Publication number: DD145273A5
Authority: DD; German Democratic Republic
Prior art keywords: acid; aryl; phosphite; solution; mol
Prior art date: 1976-12-13

Application number

DD77214294A

Other languages

German (de)

English (en)

Inventor

Gerard A Dutra

Original Assignee

Monsanto Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-12-13

Filing date

1977-11-18

Publication date

1980-12-03

1976-12-13 Priority claimed from US05/750,327 external-priority patent/US4067719A/en

1977-11-18 Application filed by Monsanto Co filed Critical Monsanto Co

1980-12-03 Publication of DD145273A5 publication Critical patent/DD145273A5/de

Links

238000004519 manufacturing process Methods 0.000 title 1
-1 methylenedioxy Chemical group 0.000 claims description 44
238000006243 chemical reaction Methods 0.000 claims description 33
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238000000034 method Methods 0.000 claims description 30
150000001875 compounds Chemical class 0.000 claims description 25
239000002253 acid Substances 0.000 claims description 24
125000003118 aryl group Chemical group 0.000 claims description 24
150000003839 salts Chemical class 0.000 claims description 21
238000002360 preparation method Methods 0.000 claims description 16
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238000006460 hydrolysis reaction Methods 0.000 claims description 13
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JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 9
125000004432 carbon atom Chemical group C* 0.000 claims description 9
CTTRIWVSECLRDA-UHFFFAOYSA-N 2-[3,5-bis(cyanomethyl)-1,3,5-triazinan-1-yl]acetonitrile Chemical compound N#CCN1CN(CC#N)CN(CC#N)C1 CTTRIWVSECLRDA-UHFFFAOYSA-N 0.000 claims description 6
DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 claims description 6
230000000694 effects Effects 0.000 claims description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
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239000005909 Kieselgur Substances 0.000 description 1
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
241000209117 Panicum Species 0.000 description 1
235000006443 Panicum miliaceum subsp. miliaceum Nutrition 0.000 description 1
235000009037 Panicum miliaceum subsp. ruderale Nutrition 0.000 description 1
240000000275 Persicaria hydropiper Species 0.000 description 1
235000017337 Persicaria hydropiper Nutrition 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
240000004350 Prunus spinosa Species 0.000 description 1
235000010829 Prunus spinosa Nutrition 0.000 description 1
244000275012 Sesbania cannabina Species 0.000 description 1
235000021536 Sugar beet Nutrition 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000003869 acetamides Chemical class 0.000 description 1
150000008061 acetanilides Chemical class 0.000 description 1
150000001243 acetic acids Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
150000007860 aryl ester derivatives Chemical group 0.000 description 1
229960000892 attapulgite Drugs 0.000 description 1
FXCLIEYDXXVEAI-UHFFFAOYSA-N benzene;dichloromethane Chemical compound ClCCl.C1=CC=CC=C1 FXCLIEYDXXVEAI-UHFFFAOYSA-N 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
150000001559 benzoic acids Chemical class 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
ZUAGNRHSAPEJRW-UHFFFAOYSA-N bis(2-methoxyphenyl) hydrogen phosphite Chemical compound COC1=CC=CC=C1OP(O)OC1=CC=CC=C1OC ZUAGNRHSAPEJRW-UHFFFAOYSA-N 0.000 description 1
PDPQEMNLXUGHNS-UHFFFAOYSA-N bis(3,4-dichlorophenyl) hydrogen phosphite Chemical compound C=1C=C(Cl)C(Cl)=CC=1OP(O)OC1=CC=C(Cl)C(Cl)=C1 PDPQEMNLXUGHNS-UHFFFAOYSA-N 0.000 description 1
WAPALSKUZQDHKX-UHFFFAOYSA-N bis(3-methyl-4-nitrophenyl) hydrogen phosphite Chemical compound C1=C([N+]([O-])=O)C(C)=CC(OP(O)OC=2C=C(C)C(=CC=2)[N+]([O-])=O)=C1 WAPALSKUZQDHKX-UHFFFAOYSA-N 0.000 description 1
VZOSMKZCDPKGHW-UHFFFAOYSA-N bis(3-methylphenyl) hydrogen phosphite Chemical compound CC1=CC=CC(OP(O)OC=2C=C(C)C=CC=2)=C1 VZOSMKZCDPKGHW-UHFFFAOYSA-N 0.000 description 1
ZJRNBGVJGIFZRO-UHFFFAOYSA-N bis(3-nitrophenyl) hydrogen phosphite Chemical compound C=1C=CC([N+]([O-])=O)=CC=1OP(O)OC1=CC=CC([N+]([O-])=O)=C1 ZJRNBGVJGIFZRO-UHFFFAOYSA-N 0.000 description 1
ZOLLZXLIZDRUPF-UHFFFAOYSA-N bis(4-chlorophenyl) hydrogen phosphite Chemical compound C=1C=C(Cl)C=CC=1OP(O)OC1=CC=C(Cl)C=C1 ZOLLZXLIZDRUPF-UHFFFAOYSA-N 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000003940 butylamines Chemical class 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical compound [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 1
150000004657 carbamic acid derivatives Chemical class 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
239000003729 cation exchange resin Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
WORJEOGGNQDSOE-UHFFFAOYSA-N chloroform;methanol Chemical compound OC.ClC(Cl)Cl WORJEOGGNQDSOE-UHFFFAOYSA-N 0.000 description 1
239000004927 clay Substances 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
230000001276 controlling effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
LNZMEOLVTKHUAS-UHFFFAOYSA-N cyclohexane;dichloromethane Chemical compound ClCCl.C1CCCCC1 LNZMEOLVTKHUAS-UHFFFAOYSA-N 0.000 description 1
238000011161 development Methods 0.000 description 1
LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 1
125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
SPCNPOWOBZQWJK-UHFFFAOYSA-N dimethoxy-(2-propan-2-ylsulfanylethylsulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical compound COP(=S)(OC)SCCSC(C)C SPCNPOWOBZQWJK-UHFFFAOYSA-N 0.000 description 1
JNXDHIIQYKMEDV-UHFFFAOYSA-N dinaphthalen-2-yl hydrogen phosphite Chemical compound C1=CC=CC2=CC(OP(OC=3C=C4C=CC=CC4=CC=3)O)=CC=C21 JNXDHIIQYKMEDV-UHFFFAOYSA-N 0.000 description 1
JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
239000000428 dust Substances 0.000 description 1
239000003480 eluent Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
PSLIMVZEAPALCD-UHFFFAOYSA-N ethanol;ethoxyethane Chemical compound CCO.CCOCC PSLIMVZEAPALCD-UHFFFAOYSA-N 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
238000001640 fractional crystallisation Methods 0.000 description 1
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
239000010931 gold Substances 0.000 description 1
229910052737 gold Inorganic materials 0.000 description 1
238000000227 grinding Methods 0.000 description 1
LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
229910000042 hydrogen bromide Inorganic materials 0.000 description 1
229910000039 hydrogen halide Inorganic materials 0.000 description 1
239000012433 hydrogen halide Substances 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000003701 inert diluent Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000003973 irrigation Methods 0.000 description 1
230000002262 irrigation Effects 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229920005610 lignin Polymers 0.000 description 1
125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
239000000391 magnesium silicate Substances 0.000 description 1
235000012243 magnesium silicates Nutrition 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000019713 millet Nutrition 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
235000006408 oxalic acid Nutrition 0.000 description 1
GEVPUGOOGXGPIO-UHFFFAOYSA-N oxalic acid;dihydrate Chemical compound O.O.OC(=O)C(O)=O GEVPUGOOGXGPIO-UHFFFAOYSA-N 0.000 description 1
125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 description 1
229910052625 palygorskite Inorganic materials 0.000 description 1
239000008188 pellet Substances 0.000 description 1
YPJUNDFVDDCYIH-UHFFFAOYSA-N perfluorobutyric acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)F YPJUNDFVDDCYIH-UHFFFAOYSA-N 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
XYQQPUALUKWVRH-UHFFFAOYSA-N phenoxy(phenylsulfanyl)phosphinous acid Chemical compound P(SC1=CC=CC=C1)(OC1=CC=CC=C1)O XYQQPUALUKWVRH-UHFFFAOYSA-N 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003016 phosphoric acids Chemical class 0.000 description 1
230000008635 plant growth Effects 0.000 description 1
229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229940072033 potash Drugs 0.000 description 1
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
235000015320 potassium carbonate Nutrition 0.000 description 1
238000004382 potting Methods 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
239000004576 sand Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
239000011343 solid material Substances 0.000 description 1
238000009331 sowing Methods 0.000 description 1
238000010183 spectrum analysis Methods 0.000 description 1
238000005507 spraying Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000000967 suction filtration Methods 0.000 description 1
239000002426 superphosphate Substances 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical class CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
230000009105 vegetative growth Effects 0.000 description 1
239000011345 viscous material Substances 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4084—Esters with hydroxyaryl compounds
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing heterocyclic radicals
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl

Landscapes

Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Molecular Biology (AREA)
Agronomy & Crop Science (AREA)
Biochemistry (AREA)
Plant Pathology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Cosmetics (AREA)

DD77214294A 1976-12-13 1977-11-18 Verfahren zur herstellung von o-aryl-n-phosphonomethylglycinnitrilen DD145273A5 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US05/750,327 US4067719A (en)	1976-12-13	1976-12-13	O-Aryl N-phosphonomethylglycinonitriles and the herbicidal use thereof
US05/756,521 US4083898A (en)	1976-12-13	1977-01-03	Process for preparing O-aryl, N-phosphonomethylglycinonitriles

Publications (1)

Publication Number	Publication Date
DD145273A5 true DD145273A5 (de)	1980-12-03

Family

ID=27115259

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DD77214294A DD145273A5 (de)	1976-12-13	1977-11-18	Verfahren zur herstellung von o-aryl-n-phosphonomethylglycinnitrilen

Country Status (36)

Country	Link
JP (1)	JPS5373543A (sv)
AR (1)	AR223311A1 (sv)
AT (1)	AT359772B (sv)
AU (1)	AU510196B2 (sv)
BG (2)	BG36634A3 (sv)
BR (1)	BR7707676A (sv)
CA (1)	CA1098529A (sv)
CH (2)	CH636752A5 (sv)
CY (1)	CY1061A (sv)
DD (1)	DD145273A5 (sv)
DE (1)	DE2751631A1 (sv)
DK (1)	DK511677A (sv)
EG (1)	EG12818A (sv)
ES (1)	ES464216A1 (sv)
FI (1)	FI67558C (sv)
FR (1)	FR2373553A1 (sv)
GB (1)	GB1556322A (sv)
GR (1)	GR66150B (sv)
HU (1)	HU184655B (sv)
IE (1)	IE45917B1 (sv)
IL (1)	IL53425A (sv)
IN (1)	IN146347B (sv)
IT (1)	IT1088890B (sv)
KE (1)	KE3045A (sv)
MX (1)	MX4714E (sv)
NL (1)	NL7712653A (sv)
NO (1)	NO151547C (sv)
NZ (1)	NZ185720A (sv)
OA (1)	OA05804A (sv)
PH (2)	PH16387A (sv)
PL (1)	PL113273B1 (sv)
PT (1)	PT67295B (sv)
SE (7)	SE441451B (sv)
TR (1)	TR20178A (sv)
YU (1)	YU275677A (sv)
ZM (1)	ZM8377A1 (sv)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AR027024A1 (es)	1999-12-23	2003-03-12	Basf Ag	Procedimiento para la preparacion de n-fosfonometilglicina
CN110156838A (zh) *	2013-05-14	2019-08-23	北京美倍他药物研究有限公司	磷酸/膦酸衍生物及其医药用途

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1445087A (en) *	1972-11-08	1976-08-04	Ici Ltd	Preparing n-phosphonomethylglycine and nitrile intermediates therefor
JPS5295640A (en) *	1976-02-05	1977-08-11	Nissan Chem Ind Ltd	N-(diphenylphosphonomethyl)aminoacetonitrile
JPS604840B2 (ja) *	1976-11-04	1985-02-06	日産化学工業株式会社	シアノメチルアミノメチルホスホネート誘導体および該誘導体を有効成分とする除草剤

1977
- 1977-11-16 EG EG643/77A patent/EG12818A/xx active
- 1977-11-17 NL NL7712653A patent/NL7712653A/xx not_active Application Discontinuation
- 1977-11-17 ES ES464216A patent/ES464216A1/es not_active Expired
- 1977-11-18 DE DE19772751631 patent/DE2751631A1/de not_active Withdrawn
- 1977-11-18 DK DK511677A patent/DK511677A/da not_active Application Discontinuation
- 1977-11-18 CA CA291,165A patent/CA1098529A/en not_active Expired
- 1977-11-18 ZM ZM7783A patent/ZM8377A1/xx unknown
- 1977-11-18 AU AU30754/77A patent/AU510196B2/en not_active Expired
- 1977-11-18 GR GR54843A patent/GR66150B/el unknown
- 1977-11-18 DD DD77214294A patent/DD145273A5/de unknown
- 1977-11-18 NO NO773959A patent/NO151547C/no unknown
- 1977-11-18 BG BG7839915A patent/BG36634A3/xx unknown
- 1977-11-18 NZ NZ185720A patent/NZ185720A/xx unknown
- 1977-11-18 BG BG7737829A patent/BG28423A3/xx unknown
- 1977-11-18 JP JP13800977A patent/JPS5373543A/ja active Granted
- 1977-11-18 PT PT67295A patent/PT67295B/pt unknown
- 1977-11-18 FI FI773495A patent/FI67558C/fi not_active IP Right Cessation
- 1977-11-18 MX MX776570U patent/MX4714E/es unknown
- 1977-11-18 PL PL1977202250A patent/PL113273B1/pl unknown
- 1977-11-18 FR FR7734834A patent/FR2373553A1/fr active Granted
- 1977-11-18 IL IL53425A patent/IL53425A/xx unknown
- 1977-11-18 GB GB48084/77A patent/GB1556322A/en not_active Expired
- 1977-11-18 AT AT825177A patent/AT359772B/de not_active IP Right Cessation
- 1977-11-18 SE SE7713047A patent/SE441451B/sv not_active IP Right Cessation
- 1977-11-18 IN IN1627/CAL/77A patent/IN146347B/en unknown
- 1977-11-18 CY CY1061A patent/CY1061A/xx unknown
- 1977-11-18 CH CH1411377A patent/CH636752A5/de not_active IP Right Cessation
- 1977-11-18 BR BR7707676A patent/BR7707676A/pt unknown
- 1977-11-18 OA OA56318A patent/OA05804A/xx unknown
- 1977-11-18 YU YU02756/77A patent/YU275677A/xx unknown
- 1977-11-18 PH PH20450A patent/PH16387A/en unknown
- 1977-11-18 HU HU77MO994A patent/HU184655B/hu unknown
- 1977-11-18 IT IT29814/77A patent/IT1088890B/it active
- 1977-11-18 IE IE2354/77A patent/IE45917B1/en unknown
- 1977-11-28 TR TR20178A patent/TR20178A/xx unknown
- 1977-12-12 AR AR270319A patent/AR223311A1/es active
1980
- 1980-04-28 KE KE3045A patent/KE3045A/xx unknown
1982
- 1982-03-30 CH CH196382A patent/CH636885A5/de not_active IP Right Cessation
1983
- 1983-03-30 SE SE8301810A patent/SE8301810D0/sv not_active Application Discontinuation
- 1983-03-30 SE SE8301808A patent/SE8301808L/sv not_active Application Discontinuation
- 1983-03-30 SE SE8301809A patent/SE8301809L/sv not_active Application Discontinuation
- 1983-03-30 SE SE8301805A patent/SE8301805D0/sv not_active Application Discontinuation
- 1983-03-30 SE SE8301807A patent/SE8301807D0/sv not_active Application Discontinuation
- 1983-03-30 SE SE8301806A patent/SE8301806D0/sv not_active Application Discontinuation
- 1983-07-14 PH PH29231A patent/PH18774A/en unknown

Also Published As

Publication number	Publication date
FR2373553A1 (fr)	1978-07-07
IN146347B (sv)	1979-05-05
CY1061A (en)	1980-10-24
AU3075477A (en)	1979-05-24
NO773959L (no)	1978-06-14
EG12818A (en)	1980-07-31
SE8301807L (sv)	1983-03-30
JPS617435B2 (sv)	1986-03-06
FI67558B (fi)	1984-12-31
DE2751631A1 (de)	1978-06-15
KE3045A (en)	1980-07-25
PT67295A (en)	1977-12-01
ES464216A1 (es)	1978-12-16
SE8301810L (sv)	1983-03-30
BG28423A3 (en)	1980-04-15
AR223311A1 (es)	1981-08-14
DK511677A (da)	1978-06-14
NO151547B (no)	1985-01-14
FI773495A (fi)	1978-06-14
FR2373553B1 (sv)	1982-06-25
SE7713047L (sv)	1978-06-14
MX4714E (es)	1982-08-11
SE8301805L (sv)	1983-03-30
PT67295B (en)	1979-04-20
FI67558C (fi)	1985-04-10
PH18774A (en)	1985-09-25
ZM8377A1 (en)	1978-08-21
HU184655B (en)	1984-09-28
PL113273B1 (en)	1980-11-29
IT1088890B (it)	1985-06-10
SE8301806L (sv)	1983-03-30
AT359772B (de)	1980-11-25
NO151547C (no)	1985-05-02
ATA825177A (de)	1980-04-15
CA1098529A (en)	1981-03-31
JPS5373543A (en)	1978-06-30
CH636885A5 (en)	1983-06-30
SE8301809D0 (sv)	1983-03-30
NL7712653A (nl)	1978-06-15
PH16387A (en)	1983-09-19
CH636752A5 (en)	1983-06-30
GR66150B (sv)	1981-01-19
SE8301805D0 (sv)	1983-03-30
SE8301806D0 (sv)	1983-03-30
SE8301807D0 (sv)	1983-03-30
SE441451B (sv)	1985-10-07
IL53425A0 (en)	1978-01-31
NZ185720A (en)	1980-10-08
YU275677A (en)	1983-09-30
BR7707676A (pt)	1978-06-20
IE45917B1 (en)	1982-12-29
SE8301810D0 (sv)	1983-03-30
TR20178A (tr)	1980-09-29
OA05804A (fr)	1981-05-31
IE45917L (en)	1978-06-13
SE8301808D0 (sv)	1983-03-30
SE8301808L (sv)	1983-03-30
IL53425A (en)	1982-11-30
PL202250A1 (pl)	1979-07-16
GB1556322A (en)	1979-11-21
BG36634A3 (en)	1984-12-16
AU510196B2 (en)	1980-06-12
SE8301809L (sv)	1983-03-30

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US4089671A (en)	1978-05-16	N,N'-methylenebis-[O,O-diaryl N-phosphonomethylglycinonitriles]
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US4221583A (en)	1980-09-09	N-Phosphonomethylglycinonitrile and certain derivatives thereof
DE2655910A1 (de)	1977-06-16	Neue dioxolanderivate
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DE2547264A1 (de)	1976-05-06	Mittel zur beeinflussung des pflanzenwachstums
DD145273A5 (de)	1980-12-03	Verfahren zur herstellung von o-aryl-n-phosphonomethylglycinnitrilen
DE2016351A1 (de)	1971-01-21	Phenoxyacetaldehyd athylenacetale, Ver fahren zu ihrer Herstellung und ihre Verwen dung als Herbicide
DE4026027A1 (de)	1992-02-20	Verfahren zur herstellung von aminomethanphosphonsaeure und aminomethyl-phosphinsaeuren
US3489785A (en)	1970-01-13	Pentachlorobenzal cyanhydrine
US3711271A (en)	1973-01-16	Method for controlling algae
DD218268A5 (de)	1985-02-06	Herbizide zusammensetzung
DE68914950T2 (de)	1994-10-13	Aminsalze von 1,4,2-Oxazaphospholidin-2-alkoxy-2-oxid-4-essigsäuren.
AT376224B (de)	1984-10-25	Verfahren zur herstellung neuer o-aryl-nphosphonmethylglycinnitrile bzw. deren sauren und alkalischen salzen
DD251067A5 (de)	1987-11-04	Herbizide zusammensetzung
EP0043801A2 (de)	1982-01-13	Neue 2-substituierte 5-Phenoxy-phenylphosphinsäurederivate mit herbizider Wirksamkeit, Verfahren zur Herstellung derselben, sie enthaltende herbizide Mittel und Verwendung der neuen Wirkstoffe und Mittel
DE2944778A1 (de)	1980-05-14	Verfahren zur herstellung von phosphorsaeureestern und thiophosphorsaeureestern
DE69016602T2 (de)	1995-05-24	Phenoxyalkylamin und Bakterizid für Landwirtschaft und Gartenbau.
DE2706794C2 (de)	1986-09-18	N-(&alpha;-Aminoalkyliden)phosphonamidate, Verfahren zu ihrer Herstellung und diese Verbindungen enthaltende insektizide Zusammensetzungen
EP0273014A2 (de)	1988-06-29	Pflanzenfungizide Mittel enthaltend als Wirstoffe Salze der pyrophosphorigen Säure und ihre Anwendung
DE2451899A1 (de)	1975-05-07	Triazindionverbindungen
US3657358A (en)	1972-04-18	Compounds 2 4 - dichloro - 3 - methoxy-6-nitrophenol 2 6-dichloro - 3 - methoxy-4-nitrophenol and their alkali metal salts
CH638533A5 (en)	1983-09-30	Herbicide