CN203568981U - Antiskid glazed tile - Google Patents
Antiskid glazed tile Download PDFInfo
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- CN203568981U CN203568981U CN201320762074.XU CN201320762074U CN203568981U CN 203568981 U CN203568981 U CN 203568981U CN 201320762074 U CN201320762074 U CN 201320762074U CN 203568981 U CN203568981 U CN 203568981U
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- antiskid
- layer
- glaze
- skidding
- glazed tile
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- 210000003298 dental enamel Anatomy 0.000 claims description 7
- 230000000694 effects Effects 0.000 abstract description 26
- 239000011449 brick Substances 0.000 abstract description 12
- 239000000919 ceramic Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 description 18
- 238000010304 firing Methods 0.000 description 14
- 210000003462 vein Anatomy 0.000 description 8
- 239000002994 raw material Substances 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
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- 239000003795 chemical substances by application Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
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- 238000005034 decoration Methods 0.000 description 3
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- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 2
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- 239000003638 chemical reducing agent Substances 0.000 description 2
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- 239000003086 colorant Substances 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
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- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- GTUNMKRGRHOANR-UHFFFAOYSA-N [B].[Ca] Chemical compound [B].[Ca] GTUNMKRGRHOANR-UHFFFAOYSA-N 0.000 description 1
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- -1 after stirring Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
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- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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Abstract
The utility model relates to an antiskid glazed tile, and belongs to building ceramic products. The antiskid glazed tile comprises a green body layer, a printed layer and a transparent overglaze layer and is characterized in that the transparent overglaze layer is provided with antiskid bulges which are 0.1-0.6mm in height, and an interval between the antiskid bulges is less than or equal to 2mm. Compared with the prior art, the antiskid glazed tile provided by the utility model has the advantages that the antiskid effect is better, the antiskid glazed tile is antiskid through the antiskid bulges on the transparent overglaze layer, and compared with a scheme that antiskid grains are stamped on a raw brick, the antiskid glazed tile is larger in antiskid area and better in antiskid effect; glaze is good in quality and does not influence the decorative effect of the printed layer, the transparent overglaze layer has an antiskid effect and can well show the decorative effect of the printed layer, and the dense antiskid bulges on the transparent overglaze layer can make patterns on the printed layer more stereoscopic under the refraction of light.
Description
Technical field
The utility model relates to a kind of architectural pottery product, relates in particular to a kind of ornamental brick with skidproof effect.
Background technology
Ornamental brick is a kind of building material product being widely used.By on adobe surface glazing burn till, obtain abundant decorative effect, and glaze is antifouling, easy to clean, be specially adapted to heavier and more kitchen and the toilet decoration of spot of steam.For stamp series product, can also protect printed layer not to be worn by glaze.But glaze product mostly is plane decoration, and smooth glaze is not anti-skidding, is not suitable for ground paving.For this reason, people by arranging the anti-slip veins with concave convex texture on mould, make the adobe stamping out also have corresponding lines, but after glazing, anti-skidding lines can thicken, this mode can not form intensive anti-skidding projection at brick face, and also easily causes the defects such as disconnected glaze, scarce glaze at the concave convex texture of billet surface.
Summary of the invention
The purpose of this utility model is to propose a kind of anti-skidding glaze face brick, the utility model is by charity one deck granularity≤20 object high temperature clear frit powder on base substrate, high temperature clear frit incomplete fusion when burning till, the softening clinkering each other of frit particle forms transparent cover coat, and because do not have complete melting to sprawl, so can form anti-skidding projection on transparent cover coat, so the more existing ornamental brick of structure has better skidproof effect, be applicable to ground decoration paving, and do not affect the decorative effect that on base substrate, stamp forms.
For reaching this object, the utility model by the following technical solutions: a kind of anti-skidding glaze face brick, it comprises green body layer from the bottom to top, printed layer, transparent cover coat, on wherein said transparent cover coat, having is highly the anti-skidding projection of 0.1mm～0.6mm, described anti-skidding projection spacing≤2mm to each other.In this programme, described anti-skidding projection distance to each other refers to two adjacent anti-skidding protruding spacings.
Preferably, in above-mentioned anti-skidding glaze face brick, anti-skidding projection spacing is to each other 0.2mm～0.5mm.
Impurity in green body layer impacts printed layer when burning till, and preferably, in above-mentioned anti-skidding glaze face brick, also comprises ground glaze layer between green body layer and printed layer.
In order to make manufacturing process more simple, avoid disconnected glaze or scarce glaze defect, in above-mentioned anti-skidding glaze face brick, described green body layer upper surface is plane.
The utility model also provides a kind of method of manufacturing above-mentioned anti-skidding glaze face brick: it comprises the steps:
Step 1): stamp; Select dried ceramic body, on its surface, carry out stamp, form printed layer;
Step 2): charity high temperature clear frit; By particle diameter≤20 object high temperature clear frit particle charity in the billet surface after step 1) stamp;
Step 3: enter klining; Under roller kiln oxidizing atmosphere to step 2) base substrate of charity high temperature clear frit particle burns till, firing temperature is 1150 ℃～1230 ℃, firing period is 80～120 minutes;
Step 4: edging chamfering; After the adobe of burning till until step 3) is cooling, after edging chamfering, can obtain anti-skidding glaze face brick finished product.
Preferably, 1250 ℃ of yield temperature >, the hemispherical temperature scope of above-mentioned high temperature clear frit are identical with firing range described in step 3).In the above conditions, can guarantee high temperature clear frit incomplete fusion effect, make the transparent cover coat and the base substrate that form have good bonding force, can form again the anti-skidding projection of good antiskid effect.
In order to avoid the impact on printed layer of impurity in green body layer, preferably, in aforesaid method, before step 1) stamp, first at billet surface charity one deck milkiness ground-coat enamel.Milkiness ground-coat enamel mainly plays covering effect, whiteness >=80 degree after burning, and it can select zirconium base opaque glaze, also can select phosphorus boron or the heterogeneous opaque glaze of boron calcium.
Because the draft of roller kiln kiln hood blower fan is larger, and step 2) in the high temperature clear frit granularity of charity little, be easy to be sucked away, therefore in step 2) in after charity high temperature clear frit, also comprise the operation of a sprinkling fixing agent.Fixing agent can be fixed on high temperature clear frit on base substrate, and fixing agent can be selected carboxymethyl cellulose aqueous solution etc.
Certainly, can also adopt following scheme to solve because the draft of roller kiln kiln hood blower fan is larger, the problem that high temperature clear frit is sucked away.Can be by step 2) in to use particle diameter≤30 object high temperature clear frit particle be that to add proportion be in 1.6～1.9 transparent slurry, the compound forming after stirring, its cloth is imposed on to the billet surface after step 1) stamp, glaze layer thickness≤the 0.5mm(forming accordingly, burn till formation transparent cover coat thickness also≤0.5mm, if transparent cover coat is blocked up, transparent high-temperature frit particle is difficult to protrude the anti-skidding projection of formation), wherein the mass ratio of high temperature clear frit particle and transparent slurry is 1:1～5.Like this, when step 3) enters klining and becomes, because high temperature clear frit is to be wrapped in glaze layer, therefore can not siphoned away by kiln hood blower fan, glaze melting when burning till, because firing temperature is lower than the yield temperature of high temperature clear frit, so high temperature clear frit can be dispersed on transparent cover coat and form anti-skidding projection after burning.
Here need above high temperature clear frit to do following explanation: at architectural pottery production field, frit refers to a kind of glass state material, and it can be used as the main raw material of glaze, in the field of businessly conventionally the frit being applicable at 1100 ℃ of firing temperatures is called to low temperature frit; The frit that is applicable to 1100 ℃～1250 ℃ of firing temperatures is called middle temperature frit; Be applicable to 1250 ℃ of above frits of firing temperature and be called high temperature frit.The transparence presenting after frit burns till, as the another kind of mode of distinguishing its kind, can see through the clear frit that is called of most of light; The very low lighttight milkiness frit that is called even completely of transmittance; Marginally be called translucent frit.The high temperature clear frit of mentioning in the utility model can be with reference to this section of explanation.
Compared with the existing technology the anti-skidding glaze face brick tool that, the utility model provides has the following advantages:
1, skidproof effect is better.The anti-skidding glaze face brick that the utility model provides is next anti-skidding by have anti-skidding projection on transparent cover coat, and compared to the scheme that adopts punching press anti-slip veins in adobe, friction area is larger, good antiskid effect.
2, glaze quality is good, and on printed layer decorative effect without impact.The utility model adopts transparent cover coat, and when having skidproof effect, transparent cover coat can well present the decorative effect of printed layer, and the intensive anti-skidding projection having is under light refraction effect, can allow printed layer pattern more three-dimensional.
Accompanying drawing explanation
Fig. 1 is the cross section structure schematic diagram in prior art with the ornamental brick of skidproof effect.
Fig. 2 is the cross section structure schematic diagram of the anti-skidding glaze face brick that provides of the utility model embodiment 1.
Fig. 3 is the cross section structure schematic diagram of the anti-skidding glaze face brick that provides of the utility model embodiment 2.
Drawing reference numeral explanation: 101-green body layer; 201-ground glaze layer; 301-printed layer; 401-transparent cover coat.
Embodiment
Below in conjunction with accompanying drawing and by embodiment, further illustrate the technical solution of the utility model.Need to illustrate that accompanying drawing, only for explanation the utility model scheme, not in strict accordance with scale, does not therefore form any restriction of the present utility model, and wherein for needs are described, may have local zooming in or out.
With reference to accompanying drawing 1, accompanying drawing 1 provides the cross section structure schematic diagram of the ornamental brick in prior art with skidproof effect.It provides a kind of ornamental brick with printed layer 301.Here should illustrate, for there is no printed layer, be only that the ornamental brick of glazing in green body layer 101 also can be used as reference.In the feature of these series product, be that the anti-slip veins with concave convex texture is set in green body layer, then after glazing, glaze can rise and fall along with anti-slip veins, with this, reaches anti-skidding object.But because pattern and the degree of depth of anti-slip veins is subject to the thick restriction of glaze, be difficult to play good skidproof effect, and when anti-slip veins is narrower and when darker, easily occur lacking glaze, the defect of the glaze that breaks.The utility model is by adopting particle diameter≤20 object high temperature clear frit particle as the raw material that forms transparent cover coat for this reason, it is (1250 ℃) incomplete fusion under the highest sintering temperature of adobe, the softening liquid phase forming is bonded to each other particle, but not exclusively sprawl, on transparent cover coat, form anti-skidding projection.We are elaborated to the utility model scheme by embodiment 1 and embodiment 2 below.
In addition, for high temperature clear frit, can be by buying and obtain in colour glaze company, the clear frit for example, using in the embodiment providing at the utility model is that Quincy's Caro is bought and obtained than glaze company, the similar frit product of other company also can be realized this programme certainly.In addition, can also be with reference to < < glaze and colorant > > [day] element wood ocean one work; Liu Kedong, Liu Guangyue is translated.-Beijing: China Construction Industry Press, publish in December, 1979.At < < glaze and colorant > > mono-book, be textbook known in this field, component formula wherein and utilize method that Sai Geshi determines glaze or frit formula to know for those skilled in the art.Therefore only need provide firing temperature for those skilled in the art, and the kind of glaze just can find corresponding chemical composition scope in book, and then can determine and specifically fill a prescription and glazing process parameter according to the mineral composition of used raw material.
Embodiment 1
With reference to Fig. 2, in the present embodiment, provide a kind of anti-skidding glaze face brick, it comprises green body layer 101 from the bottom to top, printed layer 301, transparent cover coat 401, wherein on transparent cover coat 401, having is highly the anti-skidding projection of 0.1mm～0.6mm, described anti-skidding projection spacing≤2mm to each other.
This kind of anti-skidding glaze face brick can be prepared as follows:
Select the middle temperature blank raw material that ornamental brick is conventional (to be firing temperature between the blank raw material of 1100 ℃～1250 ℃, with plastic clay, feldspar, sand, additive (additive can include but not limited to softening agent, water reducer etc.) etc., to add water for ball milling and make slurry; Then after deironing, the operation such as old, be delivered to the dry powder of making of spray-drying tower spraying; Again powder is delivered to the impact briquetting of formation system cloth, makes adobe, select in the present embodiment 600 × 600(mm) specification, mould coefficient is 1.09; It is dry that dry kiln is sent in the adobe of making; Dried base substrate is after the cleaning of surface, and stamp forms printed layer; Printing technology can select silk screen, cylinder, ink-jet or above several stamp mode to combine, select in the present embodiment ink-jet printed mode to form printed layer, printing machine is the ink-jet decorating machine of wishing that pottery machine is produced, palm fibre, Huang, indigo plant, brown four chromatic inks that ink is produced for Yi Dajia (esmaglassitaca) company; After stamp, dispense transparent high-temperature frit, particle diameter≤20 order (such formed anti-skidding hill height is 0.1mm～0.6mm) of transparent high-temperature frit, then spray fixing agent, the aqueous solution that is carboxymethyl cellulose by the fixing agent of selecting in the present embodiment; Enter roller kiln oxidizing atmosphere and burn till, firing temperature is 1150 ℃～1230 ℃, and firing period is 80～120 minutes; After goods kiln discharge is cooling, after edging chamfered, can obtain finished product.
The anti-skidding glaze face brick that this programme provides, utilizes high temperature frit incomplete fusion in sintering process, and the softening liquid phase forming is bonded to each other particle, but not exclusively sprawls, and has intensive anti-skidding projection and play anti-skidding effect on transparent cover coat.It is larger that it has friction area, good antiskid effect; And the clear printed layer pattern that presents of energy; In production technique, select conventional mould, without for the extra die sinking of anti-slip veins is set in green body layer 101, more not because anti-slip veins is to each other apart from little, the problems such as the scarce glaze that lines causes occurs while being difficult to stamp and glazing, disconnected glaze.
Embodiment 2
With reference to Fig. 3, in the present embodiment, provide a kind of anti-skidding glaze face brick, it comprises green body layer 101 from the bottom to top, ground glaze layer 201, printed layer 301, transparent cover coat 401, wherein on transparent cover coat 401, having is highly the anti-skidding projection of 0.1mm～0.5mm, described anti-skidding projection spacing≤2mm to each other.
In the present embodiment, select following technique to prepare above-mentioned anti-skidding glaze face brick.
Select the middle temperature blank raw material that ornamental brick is conventional (to be firing temperature between the blank raw material of 1100 ℃～1250 ℃, with plastic clay, feldspar, sand, additive (additive can include but not limited to softening agent, water reducer etc.) etc., to add water for ball milling and make slurry; Then after deironing, the operation such as old, be delivered to the dry powder of making of spray-drying tower spraying; Again powder is delivered to the impact briquetting of formation system cloth, makes adobe, select in the present embodiment 600 × 600(mm) specification, mould coefficient is 1.09; It is dry that dry kiln is sent in the adobe of making; Dried base substrate is after the cleaning of surface, water spray is wetting, then execute ground-coat enamel and form ground glaze layer 201, ground glaze layer thickness is 0.5mm left and right, ground-coat enamel is chosen as the opaque glaze of strong covering power, and its effect is to prevent that the impurity of green body layer 101 from can select the ground-coat enamel of chemical composition in the present embodiment on the impact of printed layer: silicon-dioxide 55.5%～61.5%; Aluminum oxide: 8.5%～11.5%; Ferric oxide :≤0.09%; Calcium oxide: 7.5%～12.5%; Boron oxide: 7.5%～10.5%; Magnesium oxide :≤1.0%; Sodium oxide: 1.0%～2.0%; Zinc oxide: 5.0%～6.0%; Potassium oxide: 9.0%～10.0%; Lithium Oxide 98min :≤1.0%; Anatase type titanium oxide: 0.5%, glazing mode is for drenching glaze, and glaze slip proportion is 1.80,325 mesh screen residues 1～2%, mobility < 100S; Execute after ground-coat enamel stamp again and form printed layer; Printing technology can select silk screen, cylinder, ink-jet or above several stamp mode to combine, select in the present embodiment ink-jet printed mode to form printed layer, printing machine is the ink-jet decorating machine of wishing that pottery machine is produced, palm fibre, Huang, indigo plant, brown four chromatic inks that ink is produced for Yi Dajia (esmaglassitaca) company; After stamp, dispense transparent high-temperature clear frit, particle diameter 30～100 object particles of high temperature transparent high-temperature frit particle account for the more than 90% of total amount, and all the other are the particle below 100 orders; Different from embodiment 1 at the present embodiment 2, selecting above high temperature clear frit to add proportion is in 1.6～1.9 transparent slurry, after stirring, cloth imposes on the billet surface after stamp again, form glaze layer thickness≤0.5mm(accordingly, burn till formation transparent cover coat 401 thickness also≤0.5mm, if transparent cover coat is blocked up, transparent high-temperature frit particle is difficult to protrude the anti-skidding projection of formation), wherein the mass ratio of high temperature clear frit and transparent slurry is 1:1～5; Enter roller kiln oxidizing atmosphere and burn till, firing temperature is 1150 ℃～1230 ℃, and firing period is 80～120 minutes; After goods kiln discharge is cooling, after edging chamfered, can obtain finished product.
By high temperature clear frit powder is added in transparent slurry, can avoid when burning till in the present embodiment, because kiln hood blower fan has been taken out greatly, and make the problem that high temperature clear frit is sucked away.After burning till, high temperature clear frit is dispersed in transparent uniformly, and its projection that does not have complete melting to form has formed the anti-skidding projection on transparent cover coat 401, makes this kind of throwing glazed brick have skidproof effect.In addition, the skidproof effect when anti-skidding projection spacing is to each other 0.2mm～0.5mm is better.
Know-why of the present utility model has below been described in conjunction with specific embodiments.These are described is in order to explain principle of the present utility model, and can not be interpreted as by any way the restriction to the utility model protection domain.Based on explanation herein, those skilled in the art does not need to pay performing creative labour can associate other embodiment of the present utility model, within these modes all will fall into protection domain of the present utility model.
Claims (5)
1. an anti-skidding glaze face brick, it comprises from the bottom to top: green body layer, printed layer, transparent cover coat, is characterized in that, on described transparent cover coat, having is highly the anti-skidding projection of 0.1mm～0.6mm, described anti-skidding projection spacing≤2mm to each other.
2. anti-skidding glaze face brick as claimed in claim 1, is characterized in that, described anti-skidding projection spacing is to each other 0.2mm～0.5mm.
3. anti-skidding glaze face brick as claimed in claim 1 or 2, is characterized in that, between described green body layer and described printed layer, also comprises ground glaze layer.
4. anti-skidding glaze face brick as claimed in claim 1, is characterized in that, described transparent cover-coat enamel layer thickness≤0.5mm.
5. anti-skidding glaze face brick as claimed in claim 3, is characterized in that, described green body layer upper surface is plane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320762074.XU CN203568981U (en) | 2013-11-28 | 2013-11-28 | Antiskid glazed tile |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201320762074.XU CN203568981U (en) | 2013-11-28 | 2013-11-28 | Antiskid glazed tile |
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| CN203568981U true CN203568981U (en) | 2014-04-30 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108545946A (en) * | 2018-06-29 | 2018-09-18 | 佛山石湾鹰牌陶瓷有限公司 | A kind of anti-skid brick and preparation method thereof |
| CN111470774A (en) * | 2020-04-30 | 2020-07-31 | 佛山市三水新明珠建陶工业有限公司 | Production method of microcrystal antiskid ceramic tile |
| CN115196944A (en) * | 2022-07-15 | 2022-10-18 | 佛山市南海凡谷新型材料有限公司 | Transparent opposite-grain through-body ceramic rock plate and preparation method thereof |
-
2013
- 2013-11-28 CN CN201320762074.XU patent/CN203568981U/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108545946A (en) * | 2018-06-29 | 2018-09-18 | 佛山石湾鹰牌陶瓷有限公司 | A kind of anti-skid brick and preparation method thereof |
| CN108545946B (en) * | 2018-06-29 | 2021-04-27 | 佛山石湾鹰牌陶瓷有限公司 | Anti-slip brick and preparation method thereof |
| CN111470774A (en) * | 2020-04-30 | 2020-07-31 | 佛山市三水新明珠建陶工业有限公司 | Production method of microcrystal antiskid ceramic tile |
| CN115196944A (en) * | 2022-07-15 | 2022-10-18 | 佛山市南海凡谷新型材料有限公司 | Transparent opposite-grain through-body ceramic rock plate and preparation method thereof |
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