CN105175026B - Flower is oozed in a kind of ink-jet glaze Imitation Rock Porcelain Tiles and preparation method thereof - Google Patents
Flower is oozed in a kind of ink-jet glaze Imitation Rock Porcelain Tiles and preparation method thereof Download PDFInfo
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Abstract
Oozing flower the present invention relates to a kind of ink-jet has glaze Imitation Rock Porcelain Tiles and preparation method thereof, including：1）Prepare ground-coat enamel slurry and clear frit slurry；2）On base substrate, ground-coat enamel slurry is first sprayed, is then dried, then colored ink and penetration-assisting agent are oozed in spraying on ground glaze layer；More than 5 minutes are stood to ensure osmotic effect；3）By step 2）The base substrate of middle preparation is in 800 950 DEG C of biscuitings；4）In step 3）On the middle base substrate through biscuiting, clear frit slurry is first sprayed；5）By step 4）The spray of preparation have clear frit slurry base substrate first burnt till at 1,150 1230 DEG C, then polish, obtain the ink-jet ooze flower have glaze Imitation Rock Porcelain Tiles.Ground glaze layer is penetrated into due to burning till rear ink, therefore the non-resilient module of use is polished after flood clear frit has been thrown and throws ground-coat enamel again at the middle and upper levels, does not also result in local show-through.
Description
Technical field
The present invention relates to architectural pottery technical field, flower is oozed in more particularly to a kind of ink-jet glaze Imitation Rock Porcelain Tiles and its preparation side
Method.
Background technology
At present, pattern permeating tile class product, which mainly has silk screen, roller and drenches starch adhesive ink-jet, oozes flower.Silk screen and roller are more traditional,
But it does not enrich because of decorative colour, and antifouling property is poor, flower is oozed by ink-jet gradually and replaced.Patent publication No. is 102795892A's
Patent application discloses a kind of ink-jet and oozes colored Imitation Rock Porcelain Tiles and its production method, and its technical scheme is that an aspect is drenched on common base substrate
Slurry, ink-jet water and penetration-assisting agent after drying burn till polishing afterwards.Because it uses elastic module to polish, and colored infiltration is oozed in ink-jet
Depth is limited, and what is oozed is deeper, and pattern is more unintelligible, so the depth of polishing is very shallow, surface wave Slippage is obvious.The patent No.
103467103A discloses the production method and ceramic tile of a kind of super spinel ceramics brick of once-firing, and its technical scheme is in common base
Ink-jet after one layer of ground-coat enamel is drenched on body to decorate, then drenches clear frit, burns till polishing.Because the thickness that it drenches clear frit is thicker, it is desirable to 0.4~
0.6mm, burns till rear thickness about 0.3~0.5mm, therefore available non-resilient module polishing so that surface without ripple glaze, it is smooth such as
Mirror.But the thickness of clear frit is thicker in actual production process, the viscosity of glaze is also bigger, and the bubble in glaze layer is difficult to discharge, and causes
Antifouling difference after throwing.And glaze layer thickeies, need again transparent, it is fluxing that it adds a large amount of alkali metal in being formulated, and causes its resistant to chemical etching
Property extreme difference, hardness is not high.Therefore, the field in the urgent need to it is a kind of easily prepare high-quality ink-jet ooze flower have glaze Imitation Rock Porcelain Tiles
Preparation method.
The content of the invention
It is contemplated that overcoming existing ink-jet to ooze flower has the defect of brick face ripple glaze after glaze ceramic brick polishing, and once burn
Super spar chemical resistance is poor, antifouling difference, the defect of difference of hardness etc..Oozing flower the invention provides a kind of ink-jet has glaze Imitation Rock Porcelain Tiles
And preparation method thereof.
Oozing flower the invention provides a kind of ink-jet has the preparation method of glaze Imitation Rock Porcelain Tiles, including：
1) ground-coat enamel slurry and clear frit slurry are prepared, wherein, by weight, ground-coat enamel component includes potassium in ground-coat enamel slurry
20~50 parts of feldspar, 5~30 parts of albite, 3~12 parts of kaolin, 15~30 parts of calcined kaolin, 5~20 parts of quartz, silicic acid
0~8 part of zirconium；By weight, component includes 3~10 parts of potassium feldspar, 30~50 parts of albite, kaolin in clear frit slurry
3~12 parts, 5~15 parts of calcined kaolin, 0~13 part of quartz, 5~15 parts of calcium carbonate, 5~20 parts of wollastonite burns talcum 4~15
Part, 1~5 part of zinc oxide；
2) on base substrate, ground-coat enamel slurry is first sprayed, is then dried, then spraying is oozed colored ink and helped and oozes on ground glaze layer
Agent；More than 5 minutes are stood to ensure osmotic effect；
3) by step 2) in prepare base substrate in 800-950 DEG C of biscuiting；
4) in step 3) on the base substrate through biscuiting, first spray clear frit slurry；
5) by step 4) spray for preparing has the base substrate of clear frit slurry is first to be burnt till at 1150-1230 DEG C, then polishes,
Obtain the ink-jet ooze flower have glaze Imitation Rock Porcelain Tiles.
Because moisture content influences very big to the penetrating power of ink, clear frit can not be directly drenched after spray infiltration ink, therefore adopt
With burning till twice.If directly drenching clear frit after ink-jet, because the diffusion of moisture content, the ink of decorative pattern is horizontal, and longitudinal diffusion adds
Greatly, cause pattern completely unintelligible, and aberration is very serious.
It is preferred that in ground-coat enamel slurry ground-coat enamel component also include 0.1~1 part additive A, 1~5 part of additive B,
Wherein, calculate by percentage to the quality, the composition of additive A is SiO22.01%th, Al2O32.89%th, Fe2O30.03%th, TiO2
93.05%th, CaO 0.03%, MgO 0.09%, K2O 0.02%, Na2O 0.06%, surplus are 1.35% impurity, additive B
Composition be SiO294.41%th, Al2O30.14%th, Fe2O30.05%th, TiO20.05%th, CaO 0.08%,
MgO0.06%, K2O 0.04%, Na2O 0.21%, surplus are 4.59% impurity.
It is preferred that in ground-coat enamel slurry ground-coat enamel component the mesh screen residue 0.8~1.2 of fineness requirement 325, the ratio of ground-coat enamel slurry
1.78~1.87 are weighed, flow velocity 28~40 seconds, usage amount is 450~600g/m2。
It is preferred that when penetration-assisting agent amount is 25%, ink can permeate 0.1~0.6mm depth, ink in ground-coat enamel pulp layer
Discharge rate relation with penetration-assisting agent is ink gray scale plus penetration-assisting agent gray scale is 100%.
It is preferred that step 3) in, the heating rate of biscuiting is 10-20 DEG C/min, and the biscuiting time is 30-50 minutes.
It is preferred that in clear frit clear frit component the mesh screen residue 0.4~0.8 of fineness requirement 325, clear frit slurry
Proportion 1.8~1.85, flow velocity 28~44 seconds, usage amount is 400~550g/m2。
It is preferred that first being sprayed water on base substrate, then spray clear frit slurry, wherein, the consumption of water spray process reclaimed water for 170~
240g/m2。
It is preferred that base substrate is burnt till 45-70 minutes at 1150-1230 DEG C, heating rate is 8-20 DEG C/min.
Have it is preferred that flower is oozed in the ink-jet in glaze Imitation Rock Porcelain Tiles, the thickness of ground-coat enamel is in 0.2~0.3mm, and the thickness of clear frit exists
0.12~0.2mm, ink can permeate 0.1~0.6mm in ground-coat enamel pulp layer.
There are glaze Imitation Rock Porcelain Tiles to be polished using non-resilient module process it is preferred that the ink-jet is oozed into flower, such as use diamond tree
Fat hard grind block is polished.Thickness of cutting is 0,15~0.25mm.
Flower is oozed in the ink-jet prepared present invention also offers a kind of above method glaze Imitation Rock Porcelain Tiles.
Beneficial effects of the present invention：
Ground glaze layer is penetrated into due to burning till rear ink, therefore the non-resilient module of use is polished after flood clear frit has been thrown
Ground-coat enamel is thrown again at the middle and upper levels, is not also resulted in local show-through.Superficial layer after polishing is ground glaze layer, and ground glaze layer is because of its fluxing agent
Few, beginning fusing point is high, therefore exhaust performance is good, and antifouling property is good after polishing, and chemical resistance is strong, the sial content in glaze slip
Height, its Mohs' hardness is also higher than once burning super spar.
Brief description of the drawings
Fig. 1 shows that the ink-jet prepared in an embodiment of the invention oozes flower and has the base substrate sectional view of glaze Imitation Rock Porcelain Tiles；
Fig. 2A, 2B, 2C, which are shown respectively, shows that the ink-jet prepared in an embodiment of the invention oozes flower and has glaze porcelain
Brick polishing before base substrate sectional view, polishing after base substrate sectional view and polishing after full face, the therefrom spray after visible polishing
Ink, which oozes flower, has glaze Imitation Rock Porcelain Tiles light reflection smooth such as mirror；
Fig. 3 A, 3B, 3C, which are shown respectively, shows that the ink-jet of comparative example preparation oozes flower and has the base substrate before glaze ceramic brick polishing to cut
Full face after base substrate sectional view and polishing after face figure, polishing.
Embodiment
The present invention is further illustrated below in conjunction with accompanying drawing and following embodiments, it should be appreciated that accompanying drawing and following embodiments
The present invention is merely to illustrate, is not intended to limit the present invention.
What the present invention was solved is that ink-jet present in prior art oozes colored Imitation Rock Porcelain Tiles external waviness substantially, and Polished crystal tile is antifouling
Difference, chemical resistance is poor, the problem of difference of hardness.Good the invention provides a kind of antifouling property, chemical resistance is strong, hardness
Height, flower is oozed in a kind of ink-jet of surfacing such as mirror manufacture method of glaze Imitation Rock Porcelain Tiles and products thereof.
Oozed the invention provides a kind of ink-jet and spend manufacture method for there are glaze Imitation Rock Porcelain Tiles and products thereof, its technical scheme is as follows：
1：Ooze the preparation of colored Imitation Rock Porcelain Tiles ground-coat enamel：Calcium, magnesium, zinc, barium etc. are added without to coordinate in the color development of infiltration ink, glaze slip
Raw material.Its formula is as follows：20~50 parts of potassium feldspar, 5~30 parts of albite, 3~12 parts of kaolin, 15~30 parts of earth burning, quartz 5
~20 parts, 0~8 part of zirconium silicate, additive A：0.1~1 part, additive B：1~5 part.The chemical composition analysis of additive A is
SiO22.01%th, Al2O32.89%th, Fe2O30.03%th, TiO293.05%th, CaO 0.03%, MgO 0.09%, K2O
0.02%th, Na2O 0.06%, surplus are 1.35% impurity.The chemical composition analysis of additive B is SiO294.41%th, Al2O3
0.14%th, Fe2O30.05%th, TiO20.05%th, CaO 0.08%, MgO 0.06%, K2O 0.04%, Na2It is O0.21%, remaining
Measure as 4.59% impurity.Ground-coat enamel chemical composition analysis is SiO262.2%~69.5%, Al2O316.5%~23%, Fe2O3
0.1%~0.5%, TiO20.2%~0.8%, CaO 0.1%~1%, MgO 0.1%~0.5%, K2O 2.0%~
4.8%th, Na2O 2.0%~4.3%, ZrO 0.5%~5.2%, surplus are 0.5%~4.2% impurity.Ground-coat enamel fineness requirement
325 mesh screen residues 0.8~1.2, proportion 1.78~1.87, flow velocity 28~40 seconds is standby.
2：The preparation and drying of base substrate：Imitation Rock Porcelain Tiles green compact are prepared according to a conventional method and are dried, and moisture control exists after drying
Less than 0.4%.
3：Drench ground-coat enamel：Ground-coat enamel made from step 1 is drenched on green compact in step 2.The ground-coat enamel weight that unit area is drenched
For 450~600g/m2。
4：Dry again：Imitation Rock Porcelain Tiles base substrate made from step 3 is dried again, moisture is controlled below 0.8%.
5：Ink-jet is decorated：By the digital ink-jet machine spray printing designed decorative pattern of Imitation Rock Porcelain Tiles base substrate made from step 4.
Stand 5 minutes or more than 5 minutes and osmotic effect can be ensured；
Colored ink and penetration-assisting agent are oozed in the ink-jet that ink is provided using Ink Corporation on the market.Its provide color be mainly
Brown, yellow, blueness, black.It is mainly characterized by：When the penetration-assisting agent amount oozed in colored ink is 25%, ink is in ground-coat enamel pulp layer
In can permeate 0.1~0.6mm depth, the discharge rate relation of ink and penetration-assisting agent is ink gray scale plus penetration-assisting agent gray scale is
100%.
6：Biscuiting：By Imitation Rock Porcelain Tiles base substrate biscuiting made from step 5, the temperature of biscuiting is in 800~950 DEG C, the heating of biscuiting
Speed is 10-20 DEG C/min, and the biscuiting time is 30-50 minutes.
7：In the preparation of clear frit, clear frit slurry component include 3~10 parts of potassium feldspar, 30~50 parts of albite,
3~12 parts of kaolin, 5~15 parts of calcined kaolin, 0~13 part of quartz, 5~15 parts of calcium carbonate, 5~20 parts of wollastonite burns and slided
4~15 parts of stone, 1~5 part of zinc oxide.Its chemical composition analysis is as follows：SiO242.9%~55.8%, Al2O317.5%~
23%th, Fe2O30.1%~0.5%, TiO20.1%~0.4%, CaO 6.8%~13.1%, MgO 0.8%~3.5%,
K2O1.0%~3.1%, Na2O 3.0%~6.3%, the surpluses of ZnO 1.5%~5.5% are 3.9%~9.2% impurity.It is transparent
The mesh screen residue 0.4~0.8 of fineness requirement 325 of glaze, 1.8~1.85 flow velocity of proportion 28~44 seconds.
8：Water spray：Base substrate made from step 6 is sprayed water, the weight that unit area is sprayed water is 170~240g/m2。
9：Drench clear frit：Clear frit made from step 7 is drenched on biscuiting base substrate, unit area is drenched made from step 8
Clear frit weight be 400~550g/m2。
10：Burn till：Imitation Rock Porcelain Tiles base substrate made from step 9 is burnt till, firing temperature is 1150~1230 DEG C, burns till 45-70
Minute, heating rate is 8-20 DEG C/min, and colored Imitation Rock Porcelain Tiles semi-finished product are oozed in obtained ink-jet, wherein the thickness for burning till rear ground-coat enamel exists
0.2~0.3mm, the thickness of clear frit is in 0.12~0.2mm, and ink can permeate 0.1~0.6mm in ground-coat enamel pulp layer.
11：Polish edging packaging and warehousing：
It is polished using non-resilient module process, such as using the polishing of diamond resin hard grind block.Polishing thickness of cutting is
0,15~0.25mm., the surfacing such as mirror after polishing, no ripple glaze, edging classification after and can packaging and warehousing.
12：Because moisture content influences very big to the penetrating power of ink, clear frit can not be directly drenched after spray infiltration ink, therefore
Using burning till twice.If directly drenching clear frit after ink-jet, because the diffusion of moisture content, the ink of decorative pattern is horizontal, longitudinal diffusion
Increase, cause pattern completely unintelligible, aberration is very serious.
13：Ground glaze layer is penetrated into due to burning till rear ink, therefore uses non-resilient module to be polished and throws flood clear frit
Ground-coat enamel is thrown again at the middle and upper levels after complete, is not also resulted in local show-through.Superficial layer after polishing is ground glaze layer, and ground glaze layer is fluxing because of its
Agent is few, and beginning fusing point is high, therefore exhaust performance is good, and antifouling property is good after polishing, and chemical resistance is strong, the sial content in glaze slip
Height, its Mohs' hardness is also higher than once burning super spar.
Embodiment is enumerated further below to describe the present invention in detail.It will similarly be understood that following examples are served only for this
Invention is further described, it is impossible to be interpreted as limiting the scope of the invention, those skilled in the art is according to this hair
Some nonessential modifications and adaptations that bright the above is made belong to protection scope of the present invention.Following examples are specific
Technological parameter etc. is also only that an example in OK range, i.e. those skilled in the art can be done properly by this paper explanation
In the range of select, and do not really want to be defined in the concrete numerical value of hereafter example.
Embodiment 1
Flower is oozed in a kind of ink-jet manufacture method of glaze Imitation Rock Porcelain Tiles and products thereof
1：Ooze the preparation of colored Imitation Rock Porcelain Tiles ground-coat enamel：Calcium, magnesium, zinc, barium etc. are added without to coordinate in the color development of infiltration ink, glaze slip
Raw material.Its formula is as follows：44 parts of potassium feldspar, 12 parts of albite, 6 parts of kaolin, 22 parts of earth burning, 12 parts of quartz, 4 parts of zirconium silicate,
Additive A：0.5 part, additive B：4 parts.The chemical composition analysis of additive A is SiO22.01%th, Al2O32.89%th, Fe2O3
0.03%th, TiO293.05%th, CaO 0.03%, MgO 0.09%, K2O 0.02%, Na2O0.06%, surplus are 1.35% miscellaneous
Matter.The chemical composition analysis of additive B is SiO294.41%th, Al2O30.14%th, Fe2O30.05%th, TiO20.05%th, CaO
0.08%th, MgO 0.06%, K2O 0.04%, Na2O 0.21%, surplus are 4.59% impurity.Ground-coat enamel chemical composition analysis is
SiO264.88%th, Al2O322.22%th, Fe2O30.26%th, TiO20.65%th, CaO0.49%, MgO 0.12%, K2O
4.20%th, Na2O 3.18%, the surpluses of ZrO 2.53% are 1.05% impurity.Ground-coat enamel fineness is 325 mesh screen residues 0.86, proportion
1.81, flow velocity 32 seconds is standby.
2：The preparation and drying of base substrate：Imitation Rock Porcelain Tiles green compact are prepared according to a conventional method and are dried, and moisture control exists after drying
Less than 0.4%.The composition of base substrate is 15 parts of low temperature sodium sand, 8 parts of low temperature potassium sand, middle 22 parts of temperature potassium sand, 30 parts of high alumina potassium sand, black mud
15 parts, 8 parts of mud washing, 2 parts of black talc.
3：Drench ground-coat enamel：Ground-coat enamel made from step 1 is drenched on green compact in step 2.The ground-coat enamel weight that unit area is drenched
For 580 ± 10g/m2。
4：Dry again：Imitation Rock Porcelain Tiles base substrate made from step 3 is dried again, moisture is controlled below 0.8%.
5：Ink-jet is decorated：By the digital ink-jet machine spray printing designed decorative pattern of Imitation Rock Porcelain Tiles base substrate made from step 4.
Stand 5 minutes or more than 5 minutes and osmotic effect can be ensured；
Colored ink (producer is oozed in the ink-jet that ink is provided using Ink Corporation on the market：Shanghai Mei Gao colorants Co., Ltd) with
And penetration-assisting agent (producer：Shanghai Mei Gao colorants Co., Ltd, model：MET FLUID BS).What it was provided oozes colored ink color master
It to be brown (model：INKMET L253MB1), yellow (model：INKMET L237YB3), blue (model：INKMET
L023CB1), black (model：INKMET L073HB1).It is mainly characterized by：When the penetration-assisting agent amount oozed in colored ink is 25%,
Ink can permeate 0.1~0.6mm depth in ground-coat enamel pulp layer, and the discharge rate relation of ink and penetration-assisting agent adds for ink gray scale to be helped
Penetration enhancer gray scale is 100%.
6：Biscuiting：Step 5 is made into adobe voxel to burn, the temperature of biscuiting is at 890 DEG C, and the biscuiting time is 40 minutes.
7：The preparation of clear frit：Its formula is as follows：11 parts of potassium feldspar, 45 parts of albite, 6 parts of kaolin, calcined kaolin 8
Part, 4 parts of quartz, 10 parts of calcium carbonate, 6 parts of wollastonite burns 6 parts of talcum, 4 parts of zinc oxide.Its chemical composition analysis is as follows：SiO2
50.07%th, Al2O320.08%th, Fe2O30.14%th, TiO20.10%th, CaO9.32%, MgO1.63%, K2O 1.84%,
Na2O 5.08%, the surpluses of ZnO 3.97% are 7.10% impurity.The mesh screen residue 0.57 of fineness 325 of clear frit, proportion 1.80.Stream
Speed 35 seconds.
8：Water spray：Base substrate made from step 7 is sprayed water, the weight that unit area is sprayed water is 200 ± 5g/m2。
9：Drench clear frit：Clear frit made from step 7 is drenched on biscuiting base substrate, unit area is drenched made from step 8
Clear frit weight be 450 ± 10g/m2。
10：Burn till：Imitation Rock Porcelain Tiles base substrate made from step 9 is burnt till, firing temperature is 1185 DEG C, the time is 55 minutes, system
Colored Imitation Rock Porcelain Tiles semi-finished product are oozed in ink-jet, wherein burning till the thickness of rear ground-coat enamel in 0.27~0.29mm, the thickness of clear frit is 0.14
~0.15mm, ink permeates 0.1~0.6mm in ground-coat enamel pulp layer.
11：Polish edging packaging and warehousing：
It is polished using non-resilient module, such as using the polishing of diamond resin hard grind block.It is 0,15 to polish thickness of cutting
~0.25mm.Surfacing such as mirror after polishing, no ripple glaze, edging classification after and can packaging and warehousing.
12：Because moisture content influences very big to the penetrating power of ink, clear frit can not be directly drenched after spray infiltration ink, therefore
Using burning till twice.If directly drenching clear frit after ink-jet, because the diffusion of moisture content, the ink of decorative pattern is horizontal, longitudinal diffusion
Increase, cause pattern completely unintelligible, aberration is very serious.
13：Fig. 1 and Fig. 2A, 2B, 2C respectively illustrate the ink-jet prepared in the present embodiment and ooze the base substrate spent and have glaze Imitation Rock Porcelain Tiles
Sectional view and photo in kind.Ground glaze layer is penetrated into due to burning till rear ink, therefore is polished using non-resilient module by flood
Clear frit throws ground-coat enamel at the middle and upper levels again after having thrown, and does not also result in local show money or valuables one carries unintentionally.Superficial layer after polishing is ground glaze layer, ground glaze layer
Because its fluxing agent is few, beginning fusing point is high, therefore exhaust performance is good, and antifouling property is good after polishing, and chemical resistance is strong, in glaze slip
Sial content is high, and its Mohs' hardness is also higher than once burning super spar.
Embodiment 2
Flower is oozed in a kind of ink-jet manufacture method of glaze Imitation Rock Porcelain Tiles and products thereof
1：Ooze the preparation of colored Imitation Rock Porcelain Tiles ground-coat enamel：Calcium, magnesium, zinc, barium etc. are added without to coordinate in the color development of infiltration ink, glaze slip
Raw material.Its formula is as follows：47 parts of potassium feldspar, 13 parts of albite, 6 parts of kaolin, 21 parts of earth burning, 12 parts of quartz, 5 parts of zirconium silicate,
Additive A：0.5 part, additive B：3 parts.The chemical composition analysis of additive A is SiO22.01%th, Al2O32.89%th, Fe2O3
0.03%th, TiO293.05%th, CaO 0.03%, MgO 0.09%, K2O 0.02%, Na2O0.06%, surplus are 1.35% miscellaneous
Matter.The chemical composition analysis of additive B is SiO294.41%th, Al2O30.14%th, Fe2O30.05%th, TiO20.05%th, CaO
0.08%th, MgO 0.06%, K2O 0.04%, Na2O 0.21%, surplus are 4.59% impurity.Ground-coat enamel chemical composition analysis is
SiO265.54%th, Al2O321.32%th, Fe2O30.29%th, TiO20.66%th, CaO0.51%, MgO 0.10%, K2O
4.78%th, Na2O 3.39%, the surpluses of ZrO 2.53% are 1.21% impurity.Ground-coat enamel fineness is 325 mesh screen residues 0.95, proportion
1.82, flow velocity 34 seconds is standby.
2：The preparation and drying of base substrate：Imitation Rock Porcelain Tiles green compact are prepared according to a conventional method and are dried, and moisture control exists after drying
Less than 0.4%.The composition of base substrate is 15 parts of low temperature sodium sand, 8 parts of low temperature potassium sand, middle 22 parts of temperature potassium sand, 30 parts of high alumina potassium sand, black mud
15 parts, 8 parts of mud washing, 2 parts of black talc.
3：Drench ground-coat enamel：Ground-coat enamel made from step 1 is drenched on green compact in step 2.The ground-coat enamel weight that unit area is drenched
For 590 ± 10g/m2。
4：Dry again：Imitation Rock Porcelain Tiles base substrate made from step 3 is dried again, moisture is controlled below 0.8%.
5：Ink-jet is decorated：By the digital ink-jet machine spray printing designed decorative pattern of Imitation Rock Porcelain Tiles base substrate made from step 4.
Stand 5 minutes or more than 5 minutes and osmotic effect can be ensured.
Colored ink (producer is oozed in the ink-jet that ink is provided using Ink Corporation on the market：Shanghai Mei Gao colorants Co., Ltd) with
And penetration-assisting agent (producer：Shanghai Mei Gao colorants Co., Ltd, model：MET FLUID BS).What it was provided oozes colored ink color master
It to be brown (model：INKMET L253MB1), yellow (model：INKMET L237YB3), blue (model：INKMET
L023CB1), black (model：INKMET L073HB1).It is mainly characterized by：When the penetration-assisting agent amount oozed in colored ink is 25%,
Ink can permeate 0.1~0.6mm depth in ground-coat enamel pulp layer, and the discharge rate relation of ink and penetration-assisting agent adds for ink gray scale to be helped
Penetration enhancer gray scale is 100%.
6：Biscuiting：Step 5 is made into adobe voxel to burn, the temperature of biscuiting is at 870 DEG C, and the biscuiting time is 42 minutes.
7：The preparation of clear frit：Its formula is as follows：13 parts of potassium feldspar, 41 parts of albite, 6 parts of kaolin, calcined kaolin 8
Part, 5 parts of quartz, 8 parts of calcium carbonate, 8 parts of wollastonite burns 7 parts of talcum, 4 parts of zinc oxide.Its chemical composition analysis is as follows：SiO2
51.17%th, Al2O319.57%th, Fe2O30.18%th, TiO20.10%th, CaO8.32%, MgO2.07%, K2O 1.93%,
Na2O 4.88%, the surpluses of ZnO 3.83% are 6.91% impurity.The mesh screen residue 0.62 of fineness 325 of clear frit, proportion 1.83.Stream
Speed 38 seconds.
8：Water spray：Base substrate made from step 7 is sprayed water, the weight that unit area is sprayed water is 200 ± 5g/m2。
9：Drench clear frit：Clear frit made from step 7 is drenched on biscuiting base substrate, unit area is drenched made from step 8
Clear frit weight be 460 ± 10g/m2。
10：Burn till：Imitation Rock Porcelain Tiles base substrate made from step 9 is burnt till, firing temperature is 1195 DEG C, the time is 50 minutes, system
Colored Imitation Rock Porcelain Tiles semi-finished product are oozed in ink-jet, wherein burn till the thickness of rear ground-coat enamel in 0.28~0.3mm, the thickness of clear frit 0.14~
0.15mm, ink permeates 0.1~0.6mm in ground-coat enamel pulp layer..
11：Polish edging packaging and warehousing：
It is polished using non-resilient module, such as using the polishing of diamond resin hard grind block.It is 0,15 to polish thickness of cutting
~0.25mm.Surfacing such as mirror after polishing, no ripple glaze, edging classification after and can packaging and warehousing.
12 influence very big because of moisture content on the penetrating power of ink, can not directly drench clear frit after spray infiltration ink, therefore
Using burning till twice.If directly drenching clear frit after ink-jet, because the diffusion of moisture content, the ink of decorative pattern is horizontal, longitudinal diffusion
Increase, cause pattern completely unintelligible, aberration is very serious.
13：Ground glaze layer is penetrated into due to burning till rear ink, therefore uses non-resilient module to be polished and throws flood clear frit
Ground-coat enamel is thrown again at the middle and upper levels after complete, does not also result in local show money or valuables one carries unintentionally.Superficial layer after polishing is ground glaze layer, and ground glaze layer is fluxing because of its
Agent is few, and beginning fusing point is high, therefore exhaust performance is good, and antifouling property is good after polishing, and chemical resistance is strong, the sial content in glaze slip
Height, its Mohs' hardness is also higher than once burning super spar.
Comparative example 1
Flower is oozed in a kind of ink-jet manufacture method of glaze Imitation Rock Porcelain Tiles and products thereof
1：Ooze the preparation of colored Imitation Rock Porcelain Tiles ground-coat enamel：Calcium, magnesium, zinc, barium etc. are added without to coordinate in the color development of infiltration ink, glaze slip
Raw material.Its formula is as follows：47 parts of potassium feldspar, 13 parts of albite, 6 parts of kaolin, 21 parts of earth burning, 12 parts of quartz, 5 parts of zirconium silicate,
Additive A：0.5 part, additive B：3 parts.The chemical composition analysis of additive A is SiO22.01%th, Al2O32.89%th, Fe2O3
0.03%th, TiO293.05%th, CaO 0.03%, MgO 0.09%, K2O 0.02%, Na2O0.06%, surplus are 1.35% miscellaneous
Matter.The chemical composition analysis of additive B is SiO294.41%th, Al2O30.14%th, Fe2O30.05%th, TiO20.05%th, CaO
0.08%th, MgO 0.06%, K2O 0.04%, Na2O 0.21%, surplus are 4.59% impurity.Ground-coat enamel chemical composition analysis is
SiO265.54%th, Al2O321.32%th, Fe2O30.29%th, TiO20.66%th, CaO0.51%, MgO 0.10%, K2O
4.78%th, Na2O 3.39%, the surpluses of ZrO 2.53% are 1.21% impurity.Ground-coat enamel fineness is 325 mesh screen residues 0.95, proportion
1.82, flow velocity 34 seconds is standby.
2：The preparation and drying of base substrate：Imitation Rock Porcelain Tiles green compact are prepared according to a conventional method and are dried, and moisture control exists after drying
Less than 0.4%.The composition of base substrate is 15 parts of low temperature sodium sand, 8 parts of low temperature potassium sand, middle 22 parts of temperature potassium sand, 30 parts of high alumina potassium sand, black mud
15 parts, 8 parts of mud washing, 2 parts of black talc.
3：Drench ground-coat enamel：Ground-coat enamel made from step 1 is drenched on green compact in step 2.The ground-coat enamel weight that unit area is drenched
For 590 ± 10g/m2。
4：Dry again：Imitation Rock Porcelain Tiles base substrate made from step 3 is dried again, moisture is controlled below 0.8%.
5：Ink-jet is decorated：By the digital ink-jet machine spray printing designed decorative pattern of Imitation Rock Porcelain Tiles base substrate made from step 4.
Stand 5 minutes or more than 5 minutes and osmotic effect can be ensured；
Colored ink (producer is oozed in the ink-jet that ink is provided using Ink Corporation on the market：Shanghai Mei Gao colorants Co., Ltd) with
And penetration-assisting agent (producer：Shanghai Mei Gao colorants Co., Ltd, model：MET FLUID BS).What it was provided oozes colored ink color master
It to be brown (model：INKMET L253MB1), yellow (model：INKMET L237YB3), blue (model：INKMET
L023CB1), black (model：INKMET L073HB1).It is mainly characterized by：When the penetration-assisting agent amount oozed in colored ink is 25%,
Ink can permeate 0.1~0.6mm depth in ground-coat enamel pulp layer, and the discharge rate relation of ink and penetration-assisting agent adds for ink gray scale to be helped
Penetration enhancer gray scale is 100%.
6：The preparation of clear frit：Its formula is as follows：13 parts of potassium feldspar, 41 parts of albite, 6 parts of kaolin, calcined kaolin 8
Part, 5 parts of quartz, 8 parts of calcium carbonate, 8 parts of wollastonite burns 7 parts of talcum, 4 parts of zinc oxide.Its chemical composition analysis is as follows：SiO2
51.17%th, Al2O319.57%th, Fe2O30.18%th, TiO20.10%th, CaO8.32%, MgO2.07%, K2O 1.93%,
Na2O 4.88%, the surpluses of ZnO 3.83% are 6.91% impurity.The mesh screen residue 0.62 of fineness 325 of clear frit, proportion 1.83.Stream
Speed 38 seconds.
7：Drench clear frit：Clear frit made from step 6 is drenched on base substrate, it is saturating that unit area is drenched made from step 5
Bright glaze weight is 460 ± 10g/m2。
8：Burn till：Base substrate made from step 7 is burnt till, firing temperature is 1195 DEG C, and the time is 70 minutes, and obtained ink-jet is oozed
Flower Imitation Rock Porcelain Tiles semi-finished product, wherein burning till the thickness of rear ground-coat enamel in 0.28~0.3mm, the thickness of clear frit is in 0.14~0.15mm.
9：The step of due to eliminating biscuiting after ink-jet, clear frit directly is drenched on the base substrate that ink-jet has been decorated, cause dress
The ink for adoring pattern is horizontal, and longitudinal diffusion is increased, and it is completely unintelligible to burn till rear incrustation pattern, and aberration is serious.Therefore not
Can be using once-firing in this way.
Comparative example 2
Patent No. 103467103A discloses the mode of production and ceramic tile of a kind of super spinel ceramics brick of once-firing, using this
Technical scheme in patent application, prepares ceramic tile, its photo such as Fig. 3 A, 3B, 3C.Because the glaze layer of its clear frit is thicker, use
Non-resilient module surface of polished is smooth such as mirror, no ripple glaze.But its cosolvent is more, the chemical group that cover-coat enamel is formulated in the example one
It is into content (mass percent)：SiO2：55.4, Al2O3：14.1, CaO：7, MgO：4, K2O：1.5, Na2O：3, ZnO：4, BaO：
10.3.Alkali flux content is up to 29.8%, therefore basis《The part of Ceramic Tiles test method the 13rd：Resistance to chemical corrosion
Determine GB T3810.13-2006》During detection, resistance to chemical corrosion is poor.Sial content is low in chemical analysis, Mohs' hardness phase
Should be also relatively low.Each performance comparison is as follows:
The super spar of once-firing：Chemical resistance GLC (V) level, surface portion or whole are changed.Mohs' hardness:
4.0, resistance to soiling:4 grades；
Flower is oozed in the patent ink-jet glaze Imitation Rock Porcelain Tiles：Chemical resistance GHA (V) level, no visible change.Mohs' hardness：
5.5, resistance to soiling：5 grades.
Claims (10)
1. flower is oozed in a kind of ink-jet the preparation method of glaze Imitation Rock Porcelain Tiles, it is characterised in that including：
1）Ground-coat enamel slurry and clear frit slurry are prepared, wherein, by weight, ground-coat enamel component includes potassium feldspar in ground-coat enamel slurry
20 ~ 50 parts, 5 ~ 30 parts of albite, 3 ~ 12 parts of kaolin, 15 ~ 30 parts of calcined kaolin, 5 ~ 20 parts of quartz, 0 ~ 8 part of zirconium silicate；With
Component includes 3 ~ 10 parts of potassium feldspar in weight meter, clear frit slurry, and 30 ~ 50 parts of albite, 3 ~ 12 parts of kaolin, calcining is high
5 ~ 15 parts of ridge soil, 0 ~ 13 part of quartz, 5 ~ 15 parts of calcium carbonate, 5 ~ 20 parts of wollastonite burns 4 ~ 15 parts of talcum, 1 ~ 5 part of zinc oxide；
2）On base substrate, ground-coat enamel slurry is first sprayed, is then dried, then colored ink and penetration-assisting agent are oozed in spraying on ground glaze layer；It is quiet
More than 5 minutes are put to ensure osmotic effect；
3）By step 2）The base substrate of middle preparation is in 800-950 DEG C of biscuiting；
4）In step 3）On the middle base substrate through biscuiting, clear frit slurry is first sprayed；
5）By step 4）The base substrate that the spray of preparation has clear frit slurry is first burnt till at 1150-1230 DEG C, then using non-ballistic
Property module process be polished, the superficial layer after polishing be ground glaze layer, obtain the ink-jet ooze flower have glaze Imitation Rock Porcelain Tiles.
2. preparation method according to claim 1, it is characterised in that the proportion of ground-coat enamel slurry is 1.78 ~ 1.87, usage amount
For 450 ~ 600g/m2。
3. preparation method according to claim 1, it is characterised in that when the penetration-assisting agent amount in colored ink of oozing is 25%, ink
Water can permeate 0.1~0.6mm depth in ground glaze layer.
4. preparation method according to claim 1, it is characterised in that step 3）In, the heating rate of biscuiting is 10-20
DEG C/min, the biscuiting time is 30-50 minutes.
5. preparation method according to claim 1, it is characterised in that the proportion of clear frit slurry is 1.8 ~ 1.85, transparent
The usage amount of glaze slurry is 400 ~ 550g/m2。
6. preparation method according to claim 1, it is characterised in that first sprayed water on the base substrate through biscuiting, then spray transparent
Glaze slurry, wherein, the consumption of water spray process reclaimed water is 170 ~ 240g/m2。
7. preparation method according to claim 1, it is characterised in that base substrate burns till 45-70 points at 1150-1230 DEG C
Clock, heating rate is 8-20 DEG C/min.
8. preparation method according to claim 1, it is characterised in that colored Imitation Rock Porcelain Tiles semi-finished product are oozed in the ink-jet for burning till rear gained
In, the thickness of ground-coat enamel is in 0.2 ~ 0.3mm, and the thickness of clear frit is in 0.12 ~ 0.2mm, and ink penetration depth in ground glaze layer is 0.1
~0.6mm.
9. according to any described preparation method in claim 1-8, it is characterised in that flower is oozed in the ink-jet has glaze Imitation Rock Porcelain Tiles to adopt
Polished with diamond resin hard grind block, polishing thickness of cutting is 0.15 ~ 0.25mm.
10. flower is oozed in the ink-jet that in a kind of claim 1-9 prepared by any methods described glaze Imitation Rock Porcelain Tiles.
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| CN105924233A (en) * | 2016-04-29 | 2016-09-07 | 山东狮子王陶瓷科技有限公司 | Peeling-glaze marble tile and preparation method thereof |
| CN105948823B (en) * | 2016-06-06 | 2019-03-01 | 广东萨米特陶瓷有限公司 | A kind of Ceramic Tiles and production method of slurry containing chromatic colour and infiltration ink formation |
| CN106187212B (en) * | 2016-07-11 | 2019-06-18 | 山东狮子王陶瓷科技有限公司 | The preparation method of entire body Dali stone ceramic tile |
| CN108975892B (en) * | 2018-08-27 | 2021-01-22 | 佛山石湾鹰牌陶瓷有限公司 | Method for preparing ink-jet flower-penetrating jade polished brick and ink-jet flower-penetrating jade polished brick |
| CN109053171B (en) * | 2018-08-27 | 2021-01-26 | 佛山石湾鹰牌陶瓷有限公司 | Unfired brick and inkjet pattern-penetrating jade polished brick |
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| CN110683867B (en) * | 2019-11-22 | 2022-05-03 | 重庆唯美陶瓷有限公司 | Black ink-jet ceramic tile and manufacturing method thereof |
| CN111333324B (en) * | 2020-05-19 | 2020-11-13 | 蒙娜丽莎集团股份有限公司 | Far infrared overglaze and far infrared ceramic tile |
| CN111333433B (en) * | 2020-05-19 | 2020-09-18 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance far-infrared ceramic glazed brick and preparation method thereof |
| CN113979787B (en) * | 2021-11-05 | 2022-12-16 | 蒙娜丽莎集团股份有限公司 | High-wear-resistance pattern-penetrated polished porcelain tile and preparation method thereof |
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| CN104072205B (en) * | 2014-07-11 | 2015-11-25 | 江苏拜富科技有限公司 | A kind of full throwing glaze ceramic and preparation method thereof |
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