CN1984633B - 含纳米氧化锆填料的牙科组合物 - Google Patents
含纳米氧化锆填料的牙科组合物 Download PDFInfo
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- CN1984633B CN1984633B CN2005800239473A CN200580023947A CN1984633B CN 1984633 B CN1984633 B CN 1984633B CN 2005800239473 A CN2005800239473 A CN 2005800239473A CN 200580023947 A CN200580023947 A CN 200580023947A CN 1984633 B CN1984633 B CN 1984633B
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- compositions
- filler
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/889—Polycarboxylate cements; Glass ionomer cements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/902—Specified use of nanostructure
- Y10S977/904—Specified use of nanostructure for medical, immunological, body treatment, or diagnosis
- Y10S977/919—Dental
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Dental Preparations (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
缩写 | 描述和材料源 |
HEMA | 2-甲基丙烯酸羟乙酯,(Sigma-Aldrich,St.Louis,MO) |
BisGMA | 2,2-双[4-(2-羟基-3-甲基丙烯酰氧基-丙氧基)苯基]丙烷;CAS No.1565-94-2 |
PEGDMA-400 | 二甲基丙烯酸聚乙二醇酯(Sartomer 603;MW约570;Sartomer,Exton,PA) |
Resin A | PEGDMA-400(62wt%)和HEMA(38wt%)的混合物 |
AA∶ITA | 4∶1摩尔比例的丙烯酸∶衣康酸的共聚物,根据US专利5,130,347(Mitra)的实施例3制备,MW(平均)=106,000;多分散性=4.64 |
IEM | 甲基丙烯酸2-异氰酸基乙基酯(Sigma-Aldrich) |
VBCP | 通过使AA:ITA共聚物与足量的IEM反应,将共聚物16mol%的酸基转化为甲基丙烯酸酯侧基得到的聚合物,根据US专利5,130,347实施例11的干聚合物制备进行。 |
GDMA | 二甲基丙烯酸甘油酯(Rohm Tech,Inc.,Malden,MA |
Kayamer PM-2 | 磷酸双(甲基丙烯酰氧乙基)酯(Nippon Kayaku,Japan) |
Ebecryl 1830 | 聚酯六丙烯酸酯树脂(UCB-Radcure Specialties,Brussels,Belgium) |
BHT | 2,6-二叔丁基对甲酚(Sigma-Aldrich) |
DPIPF6 | 二苯基碘鎓六氟磷酸盐(Johnson Matthey,Alpha Aesar Division,Ward Hill,NJ) |
CPQ | 樟脑醌(Sigma-Aldrich) |
MEEAA | 2-[2-(2-甲氧基乙氧基)乙氧基]乙酸(Sigma-Aldrich) |
Zirconia Sol | 含23%固体的含水二氧化锆溶胶,根据US5,037,579(Matchette)描述的方法制备,根据US6,378,981(Zhang等)中描述的Crystallite ParticleSize和Crystal Form Content Test Method确定平均初级离子尺寸为5nm,根据US6,387,981(Zhang等)中描述的Photon Correlation Spectroscopy Test Method,确定平均聚集的离子尺寸为50-60nm |
SILQUEST A-174 | γ-甲基丙烯酰氧丙基三甲氧基硅烷用于填充剂的硅烷处理(Crompton Corporation,Naugatuck,CT) |
SILQUEST A-1230 | PEG硅烷,用于填充剂的硅烷处理(Crompton Corporation) |
AEROSIL R8 12S | 热解二氧化硅填料(Degussa,Germany) |
FillerA(FAS Glass) | 肖特玻璃(产品号No.G 018-117;平均粒子尺寸为1.0μm;Schott Electronic Packaging,GmbH,Landshut,Germany)。如US申请公开2003/0166740(Mitra等)中对填料FAS的描述,对填料进行硅烷处理 |
Filler E(Nanofiller) | 根据US 2003/0181541(Wu等)中的方法制备干粉形式的硅烷处理的非聚集纳米尺寸的氧化硅粒子,。假定Filler E标称的粒子尺寸为与起始的Nalco 2329硅溶胶的尺寸相同,即约75纳米。 |
Filler F(Nanofiller) | 干粉形式的硅烷处理的非聚集纳米尺寸的氧化硅粒子,根据US2003/0181541(Wu等)中填料A的方法制备,不同之处在于使用Nalco 2327代替Nalco 2329。Filler F标称的粒子尺寸假定为与起始的Nalco 2327硅溶胶的尺寸相同,即约20纳米。 |
Filler(实施例1)(纳米氧化锆) | 根据本发明实施例1描述的方法制备的硅烷处理的纳米氧化锆填料。 |
Filler I/Resin A(纳米氧化锆) | 在树脂中含有80wt%填料I的透明糊剂(见实施例1)。 |
Filler K(对比实施例1)(纳米氧化锆) | 根据本发明对比实施例1的方法制备的酸处理的纳米氧化锆填料。 |
Filler K/Resin A(纳米氧化锆) | 在树脂A中含有80wt%填料K的透明有点儿粘性的材料(见对比实施例1)。 |
表1糊剂A组合物 | |||||
组分(重量份) | 糊剂A1 | 糊剂A2 | 糊剂A3 | 糊剂A4 | 糊剂A5 |
HEMA | 3.0 | 3.0 | 6.86 | 6.86 | 5.3 |
PEGDMA-400 | 2.3 | 2.3 | 5.26 | 5.26 | 6.1 |
CPQ | 0.10 | 0.10 | 0.10 | 0.10 | 0.10 |
Filler A(FAS) | 40.0 | 40.0 | 0 | 0 | 60.0 |
Filler F(纳米) | 16.4 | 16.4 | 0 | 0 | 20.0 |
Filler I(硅烷处理的纳米氧化锆) | 29.4 | 0 | 67.3 | 0 | 0 |
Filler K(酸处理的纳米氧化锆) | 0 | 29.4 | 0 | 67.3 | 0 |
DI水 | 8.9 | 8.9 | 20.3 | 20.3 | 9.1 |
总计 | 100 | 100 | 100 | 100 | 100 |
表2糊剂B组合物 | ||
组分(重量份) | 糊剂B1 | 糊剂B2 |
HBMA | 20.15 | 45.5 |
VBCP | 10.85 | 24.5 |
GDMA | 4.6 | 10.38 |
BisGMA | 2.7 | 6.09 |
Kayamer PM-2 | 5.2 | 11.74 |
Ebecryl 1830 | 0.6 | 1.35 |
BHT | 0.01 | 0.01 |
DPIPF6 | 0.20 | 0.45 |
Filler E(纳米) | 53.5 | 0 |
AEROSIL R812S | 1.8 | 0 |
总计 | 100 | 100 |
表3糊剂A+糊剂B组合物 | |||||
实施例2 | 实施例3 | 对比例2 | 对比例3 | 对比例4 | |
组分(重量份) | 糊剂A1+糊剂B1(1.27∶1重量比) | 糊剂A3+糊剂B2(1.27∶1重量比) | 糊剂A2+糊剂B1(1.27∶1重量比) | 糊剂A4+糊剂B2(1.27∶1重量比) | 糊剂A5+糊剂B1(1.27∶1重量比) |
HEMA | 11.82 | 26.77 | 11.82 | 26.77 | 11.82 |
PEGDMA-400 | 3.33 | 7.62 | 3.33 | 7.62 | 3.41 |
VBCP | 4.78 | 10.80 | 4.78 | 10.80 | 4.77 |
GDMA | 2.04 | 4.58 | 2.04 | 4.58 | 2.02 |
BisGMA | 1.19 | 2.69 | 1.19 | 2.69 | 1.19 |
KayamerPM-2 | 2.29 | 5.18 | 2.29 | 5.18 | 2.29 |
CPQ | 0.056 | 0.056 | 0.056 | 0.056 | 0.056 |
Ebecryl1830 | 0.264 | 0.595 | 0.264 | 0.595 | 0.264 |
BHT | 0.0044 | 0.0044 | 0.0044 | 0.0044 | 0.0044 |
DPIPF6 | 0.088 | 0.194 | 0.088 | 0.194 | 0.088 |
Filler A(FAS) | 22.40 | 0 | 22.40 | 0 | 33.51 |
Filler E(纳米) | 23.60 | 0 | 23.60 | 0 | 23.529 |
Filler F(纳米) | 9.19 | 0 | 9.19 | 0 | 11.17 |
Filler I(硅烷处理的) | 13.174 | 30.149 | 0 | 0 | 0 |
Filler K(酸处理的) | 0 | 0 | 13.174 | 30.149 | 0 |
AEROSILR812S | 0.794 | 0 | 0.794 | 0 | 0.792 |
DI水 | 4.985 | 11.37 | 4.985 | 11.37 | 5.082 |
总计 | 100 | 100 | 100 | 100 | 100 |
表4糊剂A+糊剂B组合物—评价结果 | |||||
实施例2 | 实施例3 | 对比例2 | 对比例3 | 对比例4 | |
试验 | 糊剂A1+糊剂B1(1.27∶1重量比) | 糊剂A3+糊剂B2(1.27∶1重量比) | 糊剂A2+糊剂B1(1.27∶1重量比) | 糊剂A4+糊剂B2(1.27∶1重量比) | 糊剂A5+糊剂B1(1.27∶1重量比) |
抗压强度(MPa) | 276 | NT* | NT | NT | NT |
径向拉伸强度(MPa) | 48 | NT | NT | NT | NT |
视觉不透明度 | 0.25 | 0.13 | 0.65 | 0.54 | 0.47 |
射线不透性 | 1.73 | 1.49 | 1.74 | 1.40 | 1.18 |
Claims (10)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/847,782 US7649029B2 (en) | 2004-05-17 | 2004-05-17 | Dental compositions containing nanozirconia fillers |
US10/847,782 | 2004-05-17 | ||
PCT/US2005/010410 WO2005117807A1 (en) | 2004-05-17 | 2005-03-29 | Dental compositions containing nanozirconia fillers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1984633A CN1984633A (zh) | 2007-06-20 |
CN1984633B true CN1984633B (zh) | 2011-06-15 |
Family
ID=34968322
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2005800239473A Expired - Fee Related CN1984633B (zh) | 2004-05-17 | 2005-03-29 | 含纳米氧化锆填料的牙科组合物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7649029B2 (zh) |
EP (1) | EP1771143B1 (zh) |
JP (1) | JP4851454B2 (zh) |
CN (1) | CN1984633B (zh) |
AT (1) | ATE554741T1 (zh) |
AU (1) | AU2005249354B2 (zh) |
CA (1) | CA2567036A1 (zh) |
WO (1) | WO2005117807A1 (zh) |
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---|---|---|---|---|
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EP2133063A1 (en) * | 2008-06-10 | 2009-12-16 | 3M Innovative Properties Company | Initiator system with biphenylene derivates, method of production and use thereof |
CN102056987A (zh) * | 2008-06-11 | 2011-05-11 | 胜技高分子株式会社 | 聚对苯二甲酸丁二醇酯树脂组合物及成型品 |
BRPI0913521A2 (pt) * | 2008-09-04 | 2015-10-13 | 3M Innovative Properties Co | composição dental endurecível e artigo dental |
JP2012504125A (ja) * | 2008-09-30 | 2012-02-16 | スリーエム イノベイティブ プロパティズ カンパニー | 熱変性された鉱物を有する歯科矯正用組成物 |
EP2344107B1 (en) * | 2008-10-15 | 2017-02-08 | 3M Innovative Properties Company | Dental compositions with fluorescent pigment |
RU2472708C2 (ru) * | 2008-10-15 | 2013-01-20 | Зм Инновейтив Пропертиз Компани | Наполнители и композитные материалы с наночастицами диоксида циркония и кремнезема |
CN102209708B (zh) * | 2008-10-22 | 2015-03-11 | 3M创新有限公司 | 包含具有氨基甲酸酯部分的联苯二(甲基)丙烯酸酯单体的牙科用组合物 |
US8790707B2 (en) | 2008-12-11 | 2014-07-29 | 3M Innovative Properties Company | Surface-treated calcium phosphate particles suitable for oral care and dental compositions |
US9296846B2 (en) * | 2008-12-18 | 2016-03-29 | The Trustees Of The University Of Pennsylvania | Porous polymer coating for tooth whitening |
WO2010083035A2 (en) | 2009-01-14 | 2010-07-22 | Corium International, Inc. | Transdermal administration of tamsulosin |
EP2228049B1 (en) * | 2009-03-09 | 2016-11-09 | Dentsply DeTrey GmbH | Dental composition |
US9249283B2 (en) | 2009-04-29 | 2016-02-02 | Tundra Composites, LLC | Reduced density glass bubble polymer composite |
KR20120068009A (ko) | 2009-08-28 | 2012-06-26 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 중합성 이온성 액체 혼합물을 포함하는 조성물 및 물품, 및 경화 방법 |
WO2011031442A2 (en) | 2009-08-28 | 2011-03-17 | 3M Innovative Properties Company | Polymerizable ionic liquid comprising multifunctional cation and antistatic coatings |
US8512464B2 (en) * | 2009-12-02 | 2013-08-20 | 3M Innovative Properties Company | Functionalized zirconia nanoparticles and high index films made therefrom |
EP2515827A2 (en) | 2009-12-22 | 2012-10-31 | 3M Innovative Properties Company | Curable dental compositions and articles comprising polymerizable ionic liquids |
RU2557961C2 (ru) | 2009-12-22 | 2015-07-27 | 3М Инновейтив Пропертиз Компани | Стоматологические композиции, заготовки для стоматологического протезирования и способы |
TWI401263B (zh) * | 2009-12-31 | 2013-07-11 | Far Eastern New Century Corp | 增進聚矽氧水膠潤濕性之共聚物、包含其之聚矽氧水膠組成物及由此製得之眼用物件 |
US9237990B2 (en) | 2010-03-31 | 2016-01-19 | 3M Innovative Properties Company | Polymerizable isocyanurate monomers and dental compositions |
CN102906132B (zh) | 2010-05-18 | 2015-11-25 | 3M创新有限公司 | 包含芳族羧酸根阴离子的可聚合离子液体 |
US8383721B2 (en) | 2010-05-18 | 2013-02-26 | 3M Innovative Properties Company | Polymerizable ionic liquid compositions |
EP2575739A2 (en) | 2010-05-25 | 2013-04-10 | 3M Innovative Properties Company | Method of surface treating inorganic oxide particles, hardenable dental compositions, surface treated particles, and surface treatment compounds |
CN102958466B (zh) * | 2010-06-25 | 2015-07-01 | 松下健康医疗控股株式会社 | 牙科磨削用成型制品及其制造方法 |
US8557893B2 (en) | 2010-09-15 | 2013-10-15 | 3M Innovative Properties Company | Substituted saccharide compounds and dental compositions |
EP2444052A1 (en) | 2010-10-19 | 2012-04-25 | Dentsply DeTrey GmbH | Dental composition |
WO2012064573A2 (en) * | 2010-11-10 | 2012-05-18 | 3M Innovative Properties Company | Adhesive composition suitable for dental uses |
US20120156650A1 (en) * | 2010-12-17 | 2012-06-21 | James R. Glidewell Dental Ceramics, Inc. | Dental crown and a method of fabricating and installing such a dental crown in one patient visit |
US9480540B2 (en) | 2010-12-30 | 2016-11-01 | 3M Innovative Properties Company | Bondable dental assemblies and methods including a compressible material |
WO2012112321A2 (en) | 2011-02-15 | 2012-08-23 | 3M Innovative Properties Company | Dental compositions comprising mixture of isocyanurate monomer and tricyclodecane monomer |
US20120208965A1 (en) | 2011-02-15 | 2012-08-16 | 3M Innovative Properties Company | Addition-fragmentation agents |
US10370322B2 (en) | 2011-02-15 | 2019-08-06 | 3M Innovative Properties Company | Addition-fragmentation agents |
WO2012112350A2 (en) | 2011-02-15 | 2012-08-23 | 3M Innovative Properties Company | Dental compositions comprising ethylenically unsaturated addition-fragmentation agent |
WO2012129143A1 (en) | 2011-03-24 | 2012-09-27 | 3M Innovative Properties Company | Dental adhesive comprising a coated polymeric component |
US8455565B2 (en) | 2011-05-18 | 2013-06-04 | 3M Innovative Properties Company | Disulfide monomers comprising ethylenically unsaturated groups suitable for dental compositions |
US8431626B2 (en) | 2011-05-18 | 2013-04-30 | 3M Innovative Properties Company | Disulfide monomers comprising ethylenically unsaturated norbornyl groups suitable for dental compositions |
WO2012161363A1 (ko) * | 2011-05-26 | 2012-11-29 | (주) 베리콤 | 결정화 글라스-세라믹이 함유된 치과용 복합체 조성물 |
WO2013003396A2 (en) | 2011-06-29 | 2013-01-03 | 3M Innovative Properties Company | Dental compositions comprising a fatty mono(meth)acrylate |
US8653190B2 (en) | 2011-08-08 | 2014-02-18 | 3M Innovative Properties Company | Curable cyclic anhydride copolymer/silicone composition |
WO2013028401A1 (en) | 2011-08-23 | 2013-02-28 | 3M Innovative Properties Company | Addition-fragmentation agents |
JP6077542B2 (ja) | 2011-08-23 | 2017-02-08 | スリーエム イノベイティブ プロパティズ カンパニー | 付加開裂剤を含む歯科用組成物 |
JP6223989B2 (ja) | 2011-11-18 | 2017-11-01 | スリーエム イノベイティブ プロパティズ カンパニー | 感圧性接着剤組成物 |
KR101359073B1 (ko) * | 2012-03-20 | 2014-02-05 | 장성욱 | 지르코니아 분말을 포함하는 치아 충전용 조성물 |
KR102143888B1 (ko) | 2012-11-12 | 2020-08-12 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 부가-단편화제 |
EP2916801B1 (en) | 2012-11-12 | 2017-02-22 | 3M Innovative Properties Company | Dental compositions comprising addition-fragmentation agents |
TWI499429B (zh) * | 2012-11-26 | 2015-09-11 | Univ Nat Taiwan | 牙齒黏合劑及塗層劑 |
WO2014099317A1 (en) | 2012-12-17 | 2014-06-26 | 3M Innovative Properties Company | Addition-fragmentation oligomers |
WO2014126837A2 (en) | 2013-02-12 | 2014-08-21 | Eipi Systems, Inc. | Continuous liquid interphase printing |
KR20150117274A (ko) | 2013-02-12 | 2015-10-19 | 카본3디, 인크. | 3차원 제작을 위한 방법 및 장치 |
EP2976323B1 (en) | 2013-03-20 | 2020-07-15 | 3M Innovative Properties Company | High refractive index addition-fragmentation agents |
WO2014172138A1 (en) | 2013-04-15 | 2014-10-23 | 3M Innovative Properties Company | Dental composition containing high refractive index monomers |
KR20160010493A (ko) | 2013-05-14 | 2016-01-27 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 접착제 조성물 |
EP2803712A1 (en) | 2013-05-17 | 2014-11-19 | 3M Innovative Properties Company | Multilayer Pressure Sensitive Adhesive Assembly |
EP3013582B1 (en) | 2013-06-24 | 2017-11-01 | 3M Innovative Properties Company | Self-wetting adhesive composition |
WO2014209644A1 (en) | 2013-06-24 | 2014-12-31 | 3M Innovative Properties Company | Self-wetting adhesive composition |
JP6410803B2 (ja) | 2013-09-20 | 2018-10-24 | スリーエム イノベイティブ プロパティズ カンパニー | トリチオカーボネート含有付加−開裂剤 |
CN105705112B (zh) | 2013-10-04 | 2018-02-27 | 3M创新有限公司 | 牙科研磨坯料、牙科修复体以及形成牙科研磨坯料的方法 |
CN105683257B (zh) | 2013-10-16 | 2018-02-13 | 3M创新有限公司 | 包含烯丙基二硫化物的加成‑断裂低聚物 |
KR20160122820A (ko) | 2014-02-18 | 2016-10-24 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 고굴절률 기를 갖는 부가-단편화 올리고머 |
WO2015142546A1 (en) | 2014-03-21 | 2015-09-24 | Carbon3D, Inc. | Method and apparatus for three-dimensional fabrication with gas injection through carrier |
US9289360B2 (en) | 2014-04-17 | 2016-03-22 | Dentsply International Inc. | Dental composition |
EP3134250B1 (en) | 2014-04-25 | 2023-11-15 | Carbon, Inc. | Continuous three dimensional fabrication from immiscible liquids |
JP6611801B2 (ja) | 2014-06-20 | 2019-11-27 | カーボン,インコーポレイテッド | 重合性液体の往復運動供給による三次元印刷 |
US10661501B2 (en) | 2014-06-20 | 2020-05-26 | Carbon, Inc. | Three-dimensional printing method using increased light intensity and apparatus therefor |
US10569465B2 (en) | 2014-06-20 | 2020-02-25 | Carbon, Inc. | Three-dimensional printing using tiled light engines |
WO2015200189A1 (en) | 2014-06-23 | 2015-12-30 | Carbon3D, Inc. | Three-dimensional objects produced from materials having multiple mechanisms of hardening |
US11390062B2 (en) | 2014-08-12 | 2022-07-19 | Carbon, Inc. | Three-dimensional printing with supported build plates |
WO2016060845A1 (en) | 2014-10-14 | 2016-04-21 | 3M Innovative Properties Company | Dental articles and methods of using same |
US10350297B2 (en) | 2014-10-31 | 2019-07-16 | 3M Innovative Properties Company | Dental materials and methods |
EP3212153A1 (en) | 2014-10-31 | 2017-09-06 | 3M Innovative Properties Company | Dental materials and methods |
EP3240671B1 (en) | 2014-12-31 | 2020-12-16 | Carbon, Inc. | Three-dimensional printing of objects with breathing orifices |
WO2016112084A1 (en) | 2015-01-06 | 2016-07-14 | Carbon3D, Inc. | Build plate for three dimensional printing having a rough or patterned surface |
WO2016112090A1 (en) | 2015-01-07 | 2016-07-14 | Carbon3D, Inc. | Microfluidic devices and methods of making the same |
EP3245044B1 (en) | 2015-01-13 | 2021-05-05 | Carbon, Inc. | Three-dimensional printing with build plates having surface topologies for increasing permeability and related methods |
WO2016123506A1 (en) | 2015-01-30 | 2016-08-04 | Carbon3D, Inc. | Build plates for continuous liquid interface printing having permeable sheets and related methods, systems and devices |
US11020898B2 (en) | 2015-01-30 | 2021-06-01 | Carbon, Inc. | Build plates for continuous liquid interface printing having permeable base and adhesive for increasing permeability and related methods, systems and devices |
EP3253558B1 (en) | 2015-02-05 | 2020-04-08 | Carbon, Inc. | Method of additive manufacturing by fabrication through multiple zones |
US10479848B2 (en) | 2015-02-20 | 2019-11-19 | 3M Innovative Properties Company | Addition-fragmentation oligomers |
WO2016133759A1 (en) | 2015-02-20 | 2016-08-25 | Carbon3D, Inc. | Methods and apparatus for continuous liquid interface printing with electrochemically supported dead zone |
WO2016140891A1 (en) | 2015-03-05 | 2016-09-09 | Carbon3D, Inc. | Continuous liquid interface production with sequential patterned exposure |
WO2016140888A1 (en) | 2015-03-05 | 2016-09-09 | Carbon3D, Inc. | Fabrication of three dimensional objects with variable slice thickness |
US10391711B2 (en) | 2015-03-05 | 2019-08-27 | Carbon, Inc. | Fabrication of three dimensional objects with multiple operating modes |
US10369086B2 (en) | 2015-03-05 | 2019-08-06 | 3M Innovative Properties Company | Composite material having ceramic fibers |
WO2016145050A1 (en) | 2015-03-10 | 2016-09-15 | Carbon3D, Inc. | Microfluidic devices having flexible features and methods of making the same |
WO2016145182A1 (en) | 2015-03-12 | 2016-09-15 | Carbon3D, Inc. | Additive manufacturing using polymerization initiators or inhibitors having controlled migration |
WO2016149151A1 (en) | 2015-03-13 | 2016-09-22 | Carbon3D, Inc. | Three-dimensional printing with concurrent delivery of different polymerizable liquids |
WO2016149097A1 (en) | 2015-03-13 | 2016-09-22 | Carbon3D, Inc. | Three-dimensional printing with reduced pressure build plate unit |
US10792856B2 (en) | 2015-03-13 | 2020-10-06 | Carbon, Inc. | Three-dimensional printing with flexible build plates |
CN107636067A (zh) | 2015-05-11 | 2018-01-26 | 3M创新有限公司 | 高性能(甲基)丙烯酸酯粘合剂组合物 |
WO2017048710A1 (en) | 2015-09-14 | 2017-03-23 | Carbon, Inc. | Light-curable article of manufacture with portions of differing solubility |
JP6889155B2 (ja) | 2015-09-25 | 2021-06-18 | カーボン,インコーポレイテッド | ライティングパネルを有する継続的液体相間印刷用のビルドプレートアセンブリー、及び関連した方法、システム並びにデバイス |
WO2017059082A1 (en) | 2015-09-30 | 2017-04-06 | Carbon, Inc. | Method and apparatus for producing three-dimensional objects |
EP3156466B1 (en) | 2015-10-15 | 2020-11-25 | 3M Innovative Properties Company | Multilayer pressure sensitive adhesive foam tape for outdooor applications |
EP3156465A1 (en) | 2015-10-15 | 2017-04-19 | 3M Innovative Properties Company | Multilayer pressure sensitive adhesive foam tape for outdooor applications |
US10647873B2 (en) | 2015-10-30 | 2020-05-12 | Carbon, Inc. | Dual cure article of manufacture with portions of differing solubility |
CN108348403B (zh) | 2015-11-06 | 2021-06-18 | 3M创新有限公司 | 含有光不稳定过渡金属络合物的氧化还原可聚合组合物 |
EP3370681A1 (en) | 2015-11-06 | 2018-09-12 | 3M Innovative Properties Company | Redox polymerizable dental composition with photolabile transition metal complexes |
WO2017083039A1 (en) | 2015-11-11 | 2017-05-18 | 3M Innovative Properties Company | Kit of parts for producing a glass ionomer cement, process of production and use thereof |
JP6872548B2 (ja) | 2015-12-03 | 2021-05-19 | スリーエム イノベイティブ プロパティズ カンパニー | 光解離性還元剤を有するレドックス重合性組成物 |
US10538031B2 (en) | 2015-12-22 | 2020-01-21 | Carbon, Inc. | Dual cure additive manufacturing of rigid intermediates that generate semi-rigid, flexible, or elastic final products |
US10647054B2 (en) | 2015-12-22 | 2020-05-12 | Carbon, Inc. | Accelerants for additive manufacturing with dual cure resins |
EP3341792A1 (en) | 2015-12-22 | 2018-07-04 | Carbon, Inc. | Dual precursor resin systems for additive manufacturing with dual cure resins |
WO2017112682A1 (en) | 2015-12-22 | 2017-06-29 | Carbon, Inc. | Fabrication of compound products from multiple intermediates by additive manufacturing with dual cure resins |
WO2017112521A1 (en) | 2015-12-22 | 2017-06-29 | Carbon, Inc. | Production of flexible products by additive manufacturing with dual cure resins |
US11123920B2 (en) | 2016-01-13 | 2021-09-21 | Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Science | 3D printing apparatus and method |
RU2018128362A (ru) | 2016-02-05 | 2020-03-05 | 3М Инновейтив Пропертиз Компани | Стоматологические композиции, содержащие наночастицы, обеспечивающие разницу между показателями преломления полимеризуемой смолы и наполнителя |
US10105289B2 (en) | 2016-05-26 | 2018-10-23 | Essential Dental Systems, Inc. | Biomimetic mineral based endodontic cement composition and uses thereof |
CA3024147A1 (en) | 2016-05-31 | 2017-12-07 | Northwestern University | Method for the fabrication of three-dimensional objects and apparatus for same |
CN109415326A (zh) | 2016-06-29 | 2019-03-01 | 3M创新有限公司 | 可聚合的离子液体组合物 |
JP7026058B2 (ja) | 2016-07-01 | 2022-02-25 | カーボン,インコーポレイテッド | ビルドプレート経由での脱ガスによって気泡を低減する三次元印刷法および装置 |
CN109843861B (zh) | 2016-10-20 | 2022-05-13 | 3M创新有限公司 | 具有受保护羰基基团的光引发剂 |
CN110023056B (zh) | 2016-11-21 | 2021-08-24 | 卡本有限公司 | 通过递送反应性组分用于后续固化来制造三维物体的方法 |
EP3547988A1 (en) | 2016-12-01 | 2019-10-09 | 3M Innovative Properties Company | Basic core material encapsulated in an inorganic shell suitable for use in biological carrier materials |
CN106539694A (zh) * | 2016-12-09 | 2017-03-29 | 苏州纳贝通环境科技有限公司 | 一种牙齿硬组织用粘合剂及其制备方法 |
US10785288B2 (en) | 2017-02-22 | 2020-09-22 | International Business Machines Corporation | Deferential support of request driven cloud services |
US10239255B2 (en) | 2017-04-11 | 2019-03-26 | Molecule Corp | Fabrication of solid materials or films from a polymerizable liquid |
US11160733B2 (en) | 2017-05-15 | 2021-11-02 | 3M Innovative Properties Company | Dental adhesive composition, preparation and use thereof |
JP2020520919A (ja) * | 2017-05-18 | 2020-07-16 | スリーエム イノベイティブ プロパティズ カンパニー | 水混和性のシラン処理したナノサイズシリカ粒子を含む、グラスアイオノマー組成物及び方法。 |
EP3630903B1 (en) | 2017-05-24 | 2020-10-07 | 3M Innovative Properties Company | Adhesive article and methods of making and using the same |
US11135766B2 (en) | 2017-06-29 | 2021-10-05 | Carbon, Inc. | Products containing nylon 6 produced by stereolithography and methods of making the same |
JP6949606B2 (ja) * | 2017-07-31 | 2021-10-13 | クラレノリタケデンタル株式会社 | ジルコニア成形体の製造方法 |
US11612548B2 (en) | 2017-11-08 | 2023-03-28 | 3M Innovative Properties Company | Radiopaque dental composition |
US11975082B2 (en) * | 2017-12-29 | 2024-05-07 | Avrupa Implant Sanayi Ve Dis Ticaret Limited Sirketi | Production of antibacterial and regenerative dental composite using supportive phases (fillers) antibacterial and bioactive properties of which are improved |
US11616302B2 (en) | 2018-01-15 | 2023-03-28 | Rogers Corporation | Dielectric resonator antenna having first and second dielectric portions |
KR20200111235A (ko) | 2018-01-31 | 2020-09-28 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 제조된 웨브의 검사를 위한 가상 카메라 어레이 |
US11327010B2 (en) | 2018-01-31 | 2022-05-10 | 3M Innovative Properties Company | Infrared light transmission inspection for continuous moving web |
WO2019152267A1 (en) | 2018-01-31 | 2019-08-08 | 3M Innovative Properties Company | Photolabile beta-dicarbonyl compounds |
JP7373490B2 (ja) | 2018-01-31 | 2023-11-02 | スリーエム イノベイティブ プロパティズ カンパニー | 光解離性バルビツール酸系化合物 |
CN108186371B (zh) * | 2018-02-05 | 2020-09-22 | 上海御齿台医疗科技有限公司 | 安全种植牙用粘合剂及其制备方法 |
US11174326B2 (en) | 2018-02-20 | 2021-11-16 | The Regents Of The University Of Michigan | Polymerization photoinhibitor |
WO2019211724A2 (en) | 2018-05-02 | 2019-11-07 | 3M Innovative Properties Company | One-part dental adhesive composition for fixing dental composite materials |
EP3569669A1 (en) | 2018-05-14 | 2019-11-20 | 3M Innovative Properties Company | Method of manufacturing an electronic control device |
PL3569622T3 (pl) | 2018-05-14 | 2021-05-31 | 3M Innovative Properties Company | Wielowarstwowy zestaw kleju przylepcowego |
CN112566585B (zh) | 2018-06-06 | 2022-07-12 | 3M创新有限公司 | 包含包封于无机壳体中的碱性芯材料的可硬化牙科组合物及其分配装置 |
US11552390B2 (en) | 2018-09-11 | 2023-01-10 | Rogers Corporation | Dielectric resonator antenna system |
WO2020075007A1 (en) | 2018-10-09 | 2020-04-16 | 3M Innovative Properties Company | Addition-fragmentation agent with pendent amine groups |
TWI820237B (zh) | 2018-10-18 | 2023-11-01 | 美商羅傑斯公司 | 聚合物結構、其立體光刻製造方法以及包含該聚合物結構之電子裝置 |
CN112996472A (zh) | 2018-11-14 | 2021-06-18 | 3M创新有限公司 | 储存稳定的双组分双固化牙科组合物 |
KR20210095632A (ko) | 2018-12-04 | 2021-08-02 | 로저스코포레이션 | 유전체 전자기 구조 및 이의 제조방법 |
NL2022372B1 (en) | 2018-12-17 | 2020-07-03 | What The Future Venture Capital Wtfvc B V | Process for producing a cured 3d product |
WO2020210520A1 (en) | 2019-04-09 | 2020-10-15 | Cdj Technologies, Inc | Methodologies to rapidly cure and coat parts produced by additive manufacturing |
KR20220016812A (ko) | 2019-05-30 | 2022-02-10 | 로저스코포레이션 | 스테레오리소그래피용 광경화성 조성물, 조성물을 사용한 스테레오리소그래피 방법, 스테레오리소그래피 방법에 의해 형성된 폴리머 성분, 및 폴리머 성분을 포함하는 장치 |
CN114144487A (zh) | 2019-07-26 | 2022-03-04 | 3M创新有限公司 | 将粘合剂设置到基底上的方法和制品 |
US11951191B2 (en) | 2019-12-20 | 2024-04-09 | University Of Tabuk | Dental material containing nanosized fillers and preparation methods thereof |
CN115380053A (zh) | 2020-04-08 | 2022-11-22 | 3M创新有限公司 | 可固化组合物以及使用可固化组合物的方法 |
EP4132452B1 (en) | 2020-04-08 | 2024-05-29 | 3M Innovative Properties Company | Curable compositions and methods of using the same |
US11482790B2 (en) | 2020-04-08 | 2022-10-25 | Rogers Corporation | Dielectric lens and electromagnetic device with same |
JP2024503594A (ja) | 2020-12-30 | 2024-01-26 | スリーエム イノベイティブ プロパティズ カンパニー | 接着可能な歯科矯正アセンブリ及び接着方法 |
WO2022195364A1 (en) | 2021-03-17 | 2022-09-22 | 3M Innovative Properties Company | Polymerizable 4,4'-spirobi[chromane]-2,2'-diones and curable compositions including the same |
CN117836333A (zh) | 2021-09-01 | 2024-04-05 | 3M创新有限公司 | 可自由基聚合的组合物、其聚合的方法以及聚合的组合物 |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001030307A1 (en) * | 1999-10-28 | 2001-05-03 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
WO2003086328A1 (en) * | 2002-04-12 | 2003-10-23 | 3M Innovative Properties Company | Medical compositions containing an ionic salt |
Family Cites Families (124)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1316129A (en) | 1969-12-15 | 1973-05-09 | Nat Res Dev | Surgical cement |
US4209434A (en) | 1972-04-18 | 1980-06-24 | National Research Development Corporation | Dental cement containing poly(carboxylic acid), chelating agent and glass cement powder |
GB1569021A (en) | 1976-03-17 | 1980-06-11 | Kuraray Co | Adhesive cementing agents containing partial phosphonic orphosphonic acid esters |
US4070321A (en) | 1976-12-02 | 1978-01-24 | Nalco Chemical Company | Process for the preparation of water-in-oil emulsions of water soluble vinyl carboxylic acid polymers and copolymers |
DE2830927A1 (de) | 1978-07-14 | 1980-01-31 | Basf Ag | Acylphosphinoxidverbindungen und ihre verwendung |
DE2909994A1 (de) | 1979-03-14 | 1980-10-02 | Basf Ag | Acylphosphinoxidverbindungen, ihre herstellung und verwendung |
DE2909992A1 (de) | 1979-03-14 | 1980-10-02 | Basf Ag | Photopolymerisierbare aufzeichnungsmassen, insbesondere zur herstellung von druckplatten und reliefformen |
US4695251A (en) | 1980-04-07 | 1987-09-22 | Minnesota Mining And Manufacturing Company | Orthodontic bracket adhesive and abrasive for removal thereof |
US4356296A (en) | 1981-02-25 | 1982-10-26 | The United States Of America As Represented By The Secretary Of The Navy | Fluorinated diacrylic esters and polymers therefrom |
US4539382A (en) | 1981-07-29 | 1985-09-03 | Kuraray Co., Ltd. | Adhesive composition |
ES8301593A1 (es) | 1981-11-16 | 1983-01-01 | Union Ind Y Agro Ganader S A U | Procedimiento de obtencion de una leche humanizada adiciona-da de nucleotidos con destino a la alimentacion infantil. |
JPS59135272A (ja) | 1983-01-21 | 1984-08-03 | Kuraray Co Ltd | 接着剤 |
US4503169A (en) | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
GR852068B (zh) | 1984-08-30 | 1985-12-24 | Johnson & Johnson Dental Prod | |
DE3443221A1 (de) | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
US4642126A (en) | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
DE3516257A1 (de) | 1985-05-07 | 1986-11-13 | Bayer Ag, 5090 Leverkusen | (meth)-acrylsaeureester und ihre verwendung |
DE3516256A1 (de) | 1985-05-07 | 1986-11-13 | Bayer Ag, 5090 Leverkusen | (meth)-acrylsaeureester und ihre verwendung |
US4652274A (en) | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
DE3536076A1 (de) | 1985-10-09 | 1987-04-09 | Muehlbauer Ernst Kg | Polymerisierbare zementmischungen |
US4772530A (en) | 1986-05-06 | 1988-09-20 | The Mead Corporation | Photosensitive materials containing ionic dye compounds as initiators |
US4798814A (en) | 1986-09-26 | 1989-01-17 | Minnesota Mining And Manufacturing Company | Oxidation resistant alumina-silica articles containing silicon carbide and carbon |
US4874450A (en) | 1987-01-29 | 1989-10-17 | The Mead Corporation | Laminating transparent or translucent materials using ionic dye-counter ion complexes |
JPH0755882B2 (ja) | 1987-02-13 | 1995-06-14 | 而至歯科工業株式会社 | 歯科用グラスアイオノマーセメント用ガラス粉末 |
CA1323949C (en) | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
US5078129A (en) | 1987-05-01 | 1992-01-07 | Research Foundation Of State University Of New York | Device for stimulating salivation |
US4954462A (en) | 1987-06-05 | 1990-09-04 | Minnesota Mining And Manufacturing Company | Microcrystalline alumina-based ceramic articles |
AU618772B2 (en) | 1987-12-30 | 1992-01-09 | Minnesota Mining And Manufacturing Company | Photocurable ionomer cement systems |
US4871786A (en) | 1988-10-03 | 1989-10-03 | Minnesota Mining And Manufacturing Company | Organic fluoride sources |
US4954414A (en) | 1988-11-08 | 1990-09-04 | The Mead Corporation | Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same |
DE3844619A1 (de) | 1988-12-10 | 1990-07-12 | Goldschmidt Ag Th | Verwendung von perfluoroalkylgruppen aufweisenden (meth-)acrylsaeureestern in der dentaltechnik |
US5076844A (en) | 1988-12-10 | 1991-12-31 | Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH | Perfluoroalkyl group-containing (meth-)acrylate esters, their synthesis and use in dental technology |
US5026902A (en) | 1988-12-10 | 1991-06-25 | Th. Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH | Dental compsition of perfluoroalkyl group-containing (meth-)acrylate esters |
JPH0627047B2 (ja) | 1988-12-16 | 1994-04-13 | 而至歯科工業株式会社 | 歯科用グラスアイオノマーセメント組成物 |
US5057393A (en) | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
GB8924129D0 (en) | 1989-10-26 | 1989-12-13 | Ellis John | Polyvinylphosphonic acid glass ionomer cement |
US5037579A (en) | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
US5055372A (en) | 1990-04-23 | 1991-10-08 | The Mead Corporation | Photohardenable composition containing borate salts and ketone initiators |
DE4024322A1 (de) * | 1990-07-31 | 1992-02-06 | Thera Ges Fuer Patente | Verformbare masse und deren verwendung als fuellmaterial fuer zahnwurzelkanaele |
DE4105550A1 (de) | 1991-02-22 | 1992-08-27 | Bayer Ag | Adhaesivkomponente zur behandlung der zahnhartsubstanz |
US5154762A (en) | 1991-05-31 | 1992-10-13 | Minnesota Mining And Manufacturing Company | Universal water-based medical and dental cement |
US5332429A (en) | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
US5252122B1 (en) | 1991-08-22 | 1999-12-07 | Mion Int Corp | Ionic bond between amalgam and glas ionomer |
JP2732968B2 (ja) | 1991-09-06 | 1998-03-30 | 鐘紡株式会社 | 歯科用充填組成物 |
US5367002A (en) | 1992-02-06 | 1994-11-22 | Dentsply Research & Development Corp. | Dental composition and method |
US5227413A (en) | 1992-02-27 | 1993-07-13 | Minnesota Mining And Manufacturing Company | Cements from β-dicarbonyl polymers |
DE4306997A1 (de) | 1993-03-05 | 1994-09-08 | Thera Ges Fuer Patente | Hydrophilierte Polyether |
US5372796A (en) | 1993-04-13 | 1994-12-13 | Southwest Research Institute | Metal oxide-polymer composites |
US6417244B1 (en) | 1993-04-13 | 2002-07-09 | Southwest Research Institute | Metal oxide compositions and methods |
US6696585B1 (en) | 1993-04-13 | 2004-02-24 | Southwest Research Institute | Functionalized nanoparticles |
US6258974B1 (en) | 1993-04-13 | 2001-07-10 | Southwest Research Institute | Metal oxide compositions composites thereof and method |
US5720805A (en) | 1993-04-13 | 1998-02-24 | Southwest Research Institute | Titanium-tin-oxide nanoparticles, compositions utilizing the same, and the method of forming the same |
US5883153A (en) | 1993-04-15 | 1999-03-16 | Shofu Inc. | Fluoride ion sustained release preformed glass ionomer filler and dental compositions containing the same |
JP3452379B2 (ja) * | 1993-05-18 | 2003-09-29 | 大日本塗料株式会社 | 顆粒状歯科用セメントの調製方法 |
US5530038A (en) | 1993-08-02 | 1996-06-25 | Sun Medical Co., Ltd. | Primer composition and curable composition |
US5501727A (en) | 1994-02-28 | 1996-03-26 | Minnesota Mining And Manufacturing Company | Color stability of dental compositions containing metal complexed ascorbic acid |
JP3214982B2 (ja) | 1994-07-04 | 2001-10-02 | 株式会社トクヤマ | 無機組成物 |
JP3471431B2 (ja) | 1994-07-18 | 2003-12-02 | 株式会社ジーシー | 歯科用グラスアイオノマーセメント組成物 |
DE69511822T2 (de) | 1994-11-21 | 2000-05-25 | Tokuyama Corp | Dentalmasse und Kit |
US5694701A (en) | 1996-09-04 | 1997-12-09 | Minnesota Mining And Manufacturing Company | Coated substrate drying system |
CN1090038C (zh) | 1995-09-18 | 2002-09-04 | 美国3M公司 | 包括冷凝机构的组分分离*** |
US6391286B1 (en) | 1995-11-17 | 2002-05-21 | 3M Innovative Properties Company | Use of metallofluorocomplexes for dental compositions |
US6050815A (en) | 1996-03-15 | 2000-04-18 | 3M Innovative Properties Company | Precoated dental cement |
IL118460A (en) | 1996-05-28 | 1999-09-22 | Dead Sea Works Ltd | Edible salt mixture |
US6136885A (en) | 1996-06-14 | 2000-10-24 | 3M Innovative Proprerties Company | Glass ionomer cement |
US20030180414A1 (en) | 1996-11-27 | 2003-09-25 | Gudas Victor V. | Method of controlling release of bitterness inhibitors in chewing gum and gum produced thereby |
US5871360A (en) | 1996-12-31 | 1999-02-16 | Gc Corporation | Method for restoration of a cavity of a tooth using a resin reinforced type glass ionomer cement |
DE19711514B4 (de) | 1997-03-19 | 2006-09-14 | 3M Espe Ag | Triglyceride enthaltende Abformmassen |
JP4083257B2 (ja) | 1997-03-19 | 2008-04-30 | 株式会社ジーシー | 歯科充填用レジン組成物 |
US6353040B1 (en) | 1997-04-02 | 2002-03-05 | Dentsply Research & Development Corp. | Dental composite restorative material and method of restoring a tooth |
US6262142B1 (en) | 1997-04-02 | 2001-07-17 | Dentsply Research & Development | Translucent wear resistant dental enamel material and method |
US5965632A (en) | 1997-06-20 | 1999-10-12 | Scientific Pharmaceuticals Inc. | Dental cement compositions |
US5859089A (en) | 1997-07-01 | 1999-01-12 | The Kerr Corporation | Dental restorative compositions |
DE19740234B4 (de) | 1997-09-12 | 2008-07-10 | 3M Espe Ag | Verwendung von Dentalmassen auf Polyetherbasis zur Abformung im zahnmedizinischen oder zahntechnischen Bereich |
BR9806297A (pt) * | 1997-10-03 | 2000-03-14 | Dentsply Int Inc | Material dental, carga , agente de ligação dental, e, verniz dental. |
US6693143B2 (en) * | 1997-10-03 | 2004-02-17 | Dentsply Detrey Gmbh | Dental materials having a nanoscale filler |
DE19753456B4 (de) | 1997-12-02 | 2007-01-11 | 3M Espe Ag | Zweikomponente, kationisch aushärtende Zubereitungen auf der Basis von Aziridinopolyethern und deren Verwendung |
JPH11228327A (ja) | 1998-02-18 | 1999-08-24 | Gc Corp | 歯科用ペースト系グラスアイオノマーセメント組成物 |
IT1299563B1 (it) | 1998-07-17 | 2000-03-16 | Giovanni Dolci | Uso odontostomatologico di materiali a base apatitica nanostrutturati |
AU752388B2 (en) | 1998-07-20 | 2002-09-19 | Dentsply International Inc. | Translucent wear resistant dental enamel material and method |
DE19832965A1 (de) | 1998-07-22 | 2000-02-03 | Fraunhofer Ges Forschung | Sphärische Ionomerpartikel und deren Herstellung |
US6669927B2 (en) | 1998-11-12 | 2003-12-30 | 3M Innovative Properties Company | Dental compositions |
US6312666B1 (en) | 1998-11-12 | 2001-11-06 | 3M Innovative Properties Company | Methods of whitening teeth |
US6312667B1 (en) | 1998-11-12 | 2001-11-06 | 3M Innovative Properties Company | Methods of etching hard tissue in the oral environment |
SE9904080D0 (sv) | 1998-12-03 | 1999-11-11 | Ciba Sc Holding Ag | Fotoinitiatorberedning |
WO2000038536A2 (en) | 1998-12-23 | 2000-07-06 | Mount Sinai School Of Medicine Of New York University | Inhibitors of the bitter taste response |
DE19860364C2 (de) | 1998-12-24 | 2001-12-13 | 3M Espe Ag | Polymerisierbare Dentalmassen auf der Basis von zur Aushärtung befähigten Siloxanverbindungen, deren Verwendung und Herstellung |
DE19860361A1 (de) | 1998-12-24 | 2000-06-29 | Espe Dental Ag | Vernetzbare Monomere auf Cyclosiloxanbasis, deren Herstellung und deren Verwendung in polymerisierbaren Massen |
JP2000217547A (ja) | 1999-01-27 | 2000-08-08 | Ajinomoto Co Inc | 苦味が低減されたアミノ酸類含有組成物 |
WO2000058316A1 (en) | 1999-03-31 | 2000-10-05 | Kuraray Co., Ltd. | Organophosphorus compounds for dental polymerizable compositions |
TWI284540B (en) | 1999-05-13 | 2007-08-01 | Kuraray Co | Bonding composition suitable to tooth tissue |
US6194481B1 (en) | 1999-05-19 | 2001-02-27 | Board Of Regents Of The University Of Texas System | Mechanically strong and transparent or translucent composites made using zirconium oxide nanoparticles |
JP4636656B2 (ja) | 1999-07-08 | 2011-02-23 | 株式会社松風 | 歯科用接着剤組成物 |
DE19934407A1 (de) | 1999-07-22 | 2001-01-25 | Espe Dental Ag | Hydrolysierbare und polymerisierbare Silane mit geringer Viskosität und deren Verwendung |
US6472454B1 (en) | 1999-10-22 | 2002-10-29 | Kerr Corporation | Endodontic dental compositions |
US6730156B1 (en) | 1999-10-28 | 2004-05-04 | 3M Innovative Properties Company | Clustered particle dental fillers |
US6387981B1 (en) | 1999-10-28 | 2002-05-14 | 3M Innovative Properties Company | Radiopaque dental materials with nano-sized particles |
US6376590B2 (en) | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
US6572693B1 (en) | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
EP1101484B1 (en) | 1999-11-17 | 2007-01-10 | Kabushiki Kaisha Shofu | Dental fillers |
DE10026432A1 (de) | 2000-05-29 | 2002-02-14 | 3M Espe Ag | Präpolymere (Meth)acrylate mit polycyclischen oder aromatischen Segmenten |
US6565873B1 (en) | 2000-10-25 | 2003-05-20 | Salvona Llc | Biodegradable bioadhesive controlled release system of nano-particles for oral care products |
US6613812B2 (en) * | 2001-01-03 | 2003-09-02 | 3M Innovative Properties Company | Dental material including fatty acid, dimer thereof, or trimer thereof |
US6593395B2 (en) | 2001-05-16 | 2003-07-15 | Kerr Corporation | Dental composition containing discrete nanoparticles |
DE10124028B4 (de) | 2001-05-16 | 2010-02-18 | 3M Espe Ag | Selbstadhäsive Dentalmaterialien |
US6942874B2 (en) | 2001-05-25 | 2005-09-13 | Linguagen Corp. | Nucleotide compounds that block the bitter taste of oral compositions |
JP4822617B2 (ja) | 2001-06-28 | 2011-11-24 | クラレメディカル株式会社 | 歯科用セメント組成物 |
US6765038B2 (en) | 2001-07-27 | 2004-07-20 | 3M Innovative Properties Company | Glass ionomer cement |
US6620405B2 (en) | 2001-11-01 | 2003-09-16 | 3M Innovative Properties Company | Delivery of hydrogel compositions as a fine mist |
US7173074B2 (en) | 2001-12-29 | 2007-02-06 | 3M Innovative Properties Company | Composition containing a polymerizable reducing agent, kit, and method |
US6765036B2 (en) | 2002-01-15 | 2004-07-20 | 3M Innovative Properties Company | Ternary photoinitiator system for cationically polymerizable resins |
JP4748938B2 (ja) | 2002-01-31 | 2011-08-17 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科ペースト、歯科物品、および方法 |
US7129281B2 (en) | 2002-03-19 | 2006-10-31 | Dentsply-Sankin K.K. | One-bottle dental bonding composition |
US20040197401A1 (en) | 2002-06-14 | 2004-10-07 | Calton Gary J | Modifying undesirable tastes |
JP2004067597A (ja) | 2002-08-07 | 2004-03-04 | Gc Corp | 歯科用組成物 |
US20040120901A1 (en) | 2002-12-20 | 2004-06-24 | Dong Wu | Dental compositions including enzymes and methods |
US20040206932A1 (en) | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
US20040185013A1 (en) | 2003-01-30 | 2004-09-23 | Burgio Paul A. | Dental whitening compositions and methods |
US20040151691A1 (en) | 2003-01-30 | 2004-08-05 | Oxman Joel D. | Hardenable thermally responsive compositions |
US7223826B2 (en) | 2003-01-30 | 2007-05-29 | 3M Innovative Properties Company | Amide-functional polymers, compositions, and methods |
US20050203207A1 (en) | 2004-01-21 | 2005-09-15 | Thomas Klettke | Dental compositions and kits containing bitterness inhibitors, and related methods |
US7090721B2 (en) * | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Use of nanoparticles to adjust refractive index of dental compositions |
US7156911B2 (en) * | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
US7090722B2 (en) | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Acid-reactive dental fillers, compositions, and methods |
-
2004
- 2004-05-17 US US10/847,782 patent/US7649029B2/en active Active
-
2005
- 2005-03-29 AU AU2005249354A patent/AU2005249354B2/en not_active Ceased
- 2005-03-29 CA CA002567036A patent/CA2567036A1/en not_active Abandoned
- 2005-03-29 WO PCT/US2005/010410 patent/WO2005117807A1/en active Application Filing
- 2005-03-29 EP EP05744014A patent/EP1771143B1/en not_active Not-in-force
- 2005-03-29 CN CN2005800239473A patent/CN1984633B/zh not_active Expired - Fee Related
- 2005-03-29 AT AT05744014T patent/ATE554741T1/de active
- 2005-03-29 JP JP2007527215A patent/JP4851454B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001030307A1 (en) * | 1999-10-28 | 2001-05-03 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
WO2003086328A1 (en) * | 2002-04-12 | 2003-10-23 | 3M Innovative Properties Company | Medical compositions containing an ionic salt |
Also Published As
Publication number | Publication date |
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US7649029B2 (en) | 2010-01-19 |
JP4851454B2 (ja) | 2012-01-11 |
ATE554741T1 (de) | 2012-05-15 |
US20050256223A1 (en) | 2005-11-17 |
CN1984633A (zh) | 2007-06-20 |
CA2567036A1 (en) | 2005-12-15 |
JP2007538073A (ja) | 2007-12-27 |
AU2005249354A1 (en) | 2005-12-15 |
WO2005117807A1 (en) | 2005-12-15 |
AU2005249354B2 (en) | 2011-11-10 |
EP1771143B1 (en) | 2012-04-25 |
EP1771143A1 (en) | 2007-04-11 |
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