CN1896156A - Ultraviolet light-curing sand vein ink - Google Patents
Ultraviolet light-curing sand vein ink Download PDFInfo
- Publication number
- CN1896156A CN1896156A CN 200610012860 CN200610012860A CN1896156A CN 1896156 A CN1896156 A CN 1896156A CN 200610012860 CN200610012860 CN 200610012860 CN 200610012860 A CN200610012860 A CN 200610012860A CN 1896156 A CN1896156 A CN 1896156A
- Authority
- CN
- China
- Prior art keywords
- parts
- ink
- ultraviolet light
- wax powder
- sand vein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
An ultraviolet photocurable sand-texture ink consists of acrylate resin 20-60 proportion, acrylate monomer 10-50 proportion, light initiating agent 3-10 proportion, initiating improver 3-15 proportion, wax powder 3-10 proportion and auxiliary 0.3-5 proportion. It has excellent grinding effect, adhesion and folding endurance. It can be used high-level package printin.
Description
Technical field
The present invention relates to a kind of printing ink, particularly a kind of ultraviolet light-curing sand vein ink.
Background technology
The radiation curing product have save the energy, be beneficial to environmental protection, economy and characteristics such as efficient, so be widely used in every field.At present, UV-curing technology is used widely in fields such as coating, printing ink, electronic chemical product, tackiness agent and medical devices.
At present, the UV curable ink that is used for silk screen printing is various in style, but its performance is single, and decorative effect is single, generally can only print off the pattern of Shamian Island or wrinkle effect.For example, the Chinese patent of application number 20051001269.2 discloses a kind of ultraviolet light solidified crepe printing ink, and its composition unit is by weight counted, 20～60 parts of acrylic resins, 10～50 parts of acrylic ester monomers, 3～10 parts of light triggers, 2～10 parts of pigment, 0.3～5 part of auxiliary agent.Printing ink of the present invention can once be imprinted on it on gold and silver paperboard or the PVC card by the screen painting mode, has overcome the shortcoming of conventional art register trouble, but there is the single shortcoming of decorative effect in this printing ink, and it can only print off the pattern of wrinkle effect.
Summary of the invention
The objective of the invention is to solve the single problem of decorative effect that common curing inks exists and a kind of ultraviolet light-curing sand vein ink is provided.
The technical scheme that addresses the above problem is such:
A kind of ultraviolet light-curing sand vein ink, its component and parts by weight thereof are: 20～60 parts of acrylate resins, 10～50 parts of acrylic ester monomers, 3～10 parts of light triggers cause 3～15 parts of promotor, 3～10 parts in wax powder, 0.3～5 part of auxiliary agent.
Above-mentioned ultraviolet light-curing sand vein ink, described acrylate resin are the mixture of epoxy acrylate and urethane acrylate.
Above-mentioned ultraviolet light-curing sand vein ink, described acrylic ester monomer is 1,6 hexanediol diacrylate, tripropylene glycol diacrylate, neopentylglycol diacrylate, PDDA or Viscoat 295 or their mixture.
Above-mentioned ultraviolet light-curing sand vein ink, described light trigger are 1-hydroxyl-cyclohexyl benzophenone, benzophenone, 2-hydroxy-2-methyl-1-phenyl-acetone-1 or 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholine-1-acetone or their mixtures.
Above-mentioned ultraviolet light-curing sand vein ink, described wax powder are that particle diameter is 8～35 microns PP (polyethylene) wax powder, PE (polypropylene) wax powder or PVC (polyvinyl chloride) wax powder or its mixture.
The quick initiated polymerization of UV-light that ultraviolet light polymerization product utilization mercury lamp sends has the energy of saving, is beneficial to characteristics such as environmental protection, economy and high-performance.UV curable ink provided by the invention, be to be the main body component with acrylate resin and acrylic ester monomer, light trigger is under UV-irradiation, produce living radical through cracking or hydrogen transference, living radical is attacked the unsaturated double-bond in acrylate monomer and the acrylate resin, makes acrylate resin and the crosslinked generation solid superpolymer of acrylate monomer thereby make two keys become singly-bound.Superpolymer and filler wherein, auxiliary agent etc. are membranaceous attached on the base material, form ink film.
Being fit to acrylate resin of the present invention is the mixture of the attached fat of epoxy acrylate, polyurethane acrylate resin, wherein, adopts the product of epoxy acrylic resin to have characteristics such as hardness, high abrasion after solidifying; Adopt the product of Polyurethane acrylate resin to have low smell, low volatilization, low irritant and good film-forming properties, its solidifying product has the wear resistance and the excellent high-temperature stability of high-tensile, brilliance.As, the epoxy acrylate 6104 of Jiangsu three wooden companies and urethane acrylate 6318; The epoxy acrylate 6219-100 of Changxing, Taiwan chemical company and urethane acrylate 6112-100; The epoxy acrylate DH306 of the good photochemical Science and Technology Ltd. of Shenzhen ancient cooking vessel and urethane acrylate DH318.
Being fit to acrylate monomer of the present invention can be HDDA (1, the 6-hexanediyl ester), PDDA (O-phthalic acid diethylene glycol diacrylate fat), TPGDA (tri (propylene glycol) diacrylate), TMPTA (Viscoat 295), TMPTA (Viscoat 295), PO-NPGDA (ethoxyquin neopentylglycol diacrylate), PO-TMPTA (the third oxidation Viscoat 295), EO-TMPTA (oxyethyl group Viscoat 295), NPGDA (neopentylglycol diacrylate), pentaerythritol triacrylate, double pentaerythritol C5 methacrylate etc., the preferred PDDA (O-phthalic acid diethylene glycol diacrylate fat) that uses, TPGDA (tripropylene glycol diacrylate), TMPTA (Viscoat 295), HDDA (1,6 hexanediol diacrylate) or NPGDA (neopentylglycol diacrylate).Wherein, the tripropylene glycol diacrylate is the low viscosity thinner, have remarkable solvability and viscosity reduction, O-phthalic acid diethylene glycol diacrylate fat has remarkable curing speed and snappiness, Viscoat 295 has good curing speed and toughness, and comprehensive collocation makes the ink film after the curing have the good flexible curing speed.
Being fit to light trigger of the present invention can be Irgacure 184 (1-hydroxyl-cyclohexyl benzophenone), OMBB (o-benzoyl yl benzoic acid methyl esters), BP (benzophenone), 907 (2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholine-1-acetone), Darocur1173 (2-hydroxy-2-methyl-1-phenyl-acetone-1) or their mixture; preferred Irgacure 184, OMBB or their mixture of using most preferably uses the combination of Irgacure 184 and OMBB.Wherein, Irgacure 184, Darocur 1173 and Irgacure 907 are crack type photoinitiator, and it solidifies fast, help the deep layer of product to solidify, and product is xanthochromia not; BP is a hydrogen transference type light trigger, and it helps the surface cure of product; OMBB is a kind of initiator of low smell, can make ink film smell after the curing help printing ink for a short time and use on the packaged product that smell is had requirement.
In order to improve the efficiency of initiation of light trigger, added initiation promotor in the ink product provided by the invention, being fit to initiation promotor of the present invention can be the P115 of UCB. S.A. (BE) Bruxelles Belgium, its main component is the Viscoat 295 tertiary amine.
The wax powder generally is used in the filler of doing surface effect in coating, the printing ink.Among the present invention, in order to produce frosted finish effect, added the wax powder in the printing ink, being fit to wax powder of the present invention is that particle diameter is 8～35 microns PP (polyethylene) wax powder, PE (polypropylene) wax powder, PVC (polyvinyl chloride) wax powder or its mixture.Polyethylene wax powder, Poly Propylene Wax powder, polyvinyl chloride wax powder are the meal with certain particle diameter that polyethylene, polypropylene or the polyvinyl chloride of certain polymerization degree obtains through pulverizing, for example, the B-12 of Honeywell company, B-18 wax powder, its composition is a polyethylene, particle diameter is respectively 12,18 microns; The HARWAX SD1225 wax powder of HASA chemical company, its composition is a polyethylene, particle diameter is 25 microns; The C65V of Shanghai moral note chemical industry, its composition is a polyvinyl chloride, particle diameter is 35 microns.
Being fit to auxiliary agent of the present invention can be polydimethylsiloxane, polyether-modified polydimethylsiloxane, polyester modification polydimethylsiloxane or its mixture, Foamex N as German Di Gao company, 6200 of the modest chemistry of Taiwan moral, its main component are polydimethylsiloxane; The Glide432 of Di Gao company, its main component of the BYK333 of Bi Ke chemistry is polyether-modified polydimethylsiloxane, both adding proportions are 5: 1～1: 5.
Printing ink of the present invention can prepare by following method:
Light trigger, initiation promotor are added in acrylate monomer and the acrylate resin, stirring and dissolving, and then at the uniform velocity add wax powder and defoamer, high-speed stirring is even, can obtain ultraviolet light-curing sand vein ink provided by the invention.
Printing ink of the present invention, on printed substrate, curing makes printed material present the frosted finish effect of uniform and smooth through medium pressure mercury lamp then by screen painting; After also can using the screen painting of low mesh, through solidifying to form the wrinkle effect through the medium pressure mercury lamp irradiation again after the low pressure mercury lamp irradiation; Can also use behind the screen painting of high mesh through the low pressure mercury lamp irradiation and solidify to form the hold concurrently effect of trickle texture of trickle frosted through the medium pressure mercury lamp irradiation again.
Beneficial effect
The ultraviolet light-curing sand vein ink that the present invention obtains is applied to silk screen printing, through the ultra-violet lamp irradiation, but once shaped, technology is easy.Can form superfine wrinkle effect and can form superfine frosted finish effect again, also can form the wrinkle effect of frosted finish effect of holding concurrently, its sticking power and folding resistance are all good.Using method flexibly and effect is changeable and curing speed is fast.This printing ink does not contain solvent, to the infringement of human body and little, for solvent type ink and drying-type printing ink, can enhance productivity to the pollution of environment, but and save energy.This printing ink can be widely used in the printing of high-grade packing, highlights the graceful quality of product.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment 1
6,104 10 parts
6,318 10 parts
25 parts of PDDA
10 parts of TMPTA
10 parts of TPGDA
184 10 parts of Irgacure
10 parts of P115
5 parts of B12
5 parts of Foamex N
10 parts Irgacure 184 are joined among the P115 of 10 parts 6104,10 parts 6318 and 25 parts PDDA, 10 parts TMPTA, 10 parts TPGDA and 10 parts, the heated and stirred dissolving, and then add 5 parts B12 wax powder and 5 parts Foamex N, high-speed stirring is even, can obtain ultraviolet light-curing sand vein ink.
This printing ink, solidifies through one 80 watts/centimetre medium pressure mercury lamp then and makes printed material present the frosted finish effect of uniform and smooth on printed substrate by 400 order screen painting; After also can using 80 purpose screen paintings, through after the irradiation of three 2 watts of/centimetre low pressure mercury lamps again the medium pressure mercury lamp irradiation through 80 watts/centimetre solidify to form the wrinkle effect; Can also use behind the 400 purpose screen paintings through three 2 watts/centimetre low pressure mercury lamp irradiation and solidify to form the hold concurrently effect of trickle texture of trickle frosted through one 80 watts/centimetre medium pressure mercury lamp irradiation again.
Embodiment 2
20 parts of 6219-100
20 parts of 6112-100
20 parts of HDDA
13 parts of NPGDA
184 7 parts of Irgacure
1,173 3 parts
10 parts of P115
4 parts of B18
3 parts of BYK333
1173 of 7 parts Irgacure 184 and 3 parts are joined among the NPGDA of the HDDA of 20 parts of 6219-10020 part 6112-100 and 20 parts and 13 parts, stirring and dissolving, and then adding 4 parts B18 wax powder and 3 parts BYK333, high-speed stirring is even, can obtain ultraviolet light-curing sand vein ink.
This printing ink on printed substrate, makes printed material present the frosted finish effect of uniform and smooth through 80 watts of/centimetre medium pressure mercury lamps curing by 350 order screen paintings then; After also can using 100 purpose screen paintings, through after the low pressure mercury lamp irradiation again the medium pressure mercury lamp irradiation through 80 watts/centimetre solidify to form the wrinkle effect; Can also use behind the 350 purpose screen paintings through three 2 watts of/centimetre low pressure mercury lamps irradiations and solidify to form the frosted effect of wrinkle of holding concurrently through the medium pressure mercury lamp irradiation again.
Embodiment 3
30 parts of DH306
30 parts of DH318
10 parts of TMPTA
3 parts of BP
907 2 parts
9 parts of P115
8 parts of C65V
2 parts of B18
6,200 5 parts
907 of 3 parts BP and 2 parts are joined among the TMPTA and 9 parts of P115 of 30 parts of DH306,30 parts of DH318 and 10 parts, stirring and dissolving, and then add 8 parts C65V wax powder, 2 parts of B18 and 5 parts 6200 in, high-speed stirring is even, can obtain ultraviolet light-curing sand vein ink.
This printing ink, solidifies through one 80 watts/centimetre medium pressure mercury lamp then and makes printed material present the frosted finish effect of uniform and smooth on printed substrate by 300 order screen painting; After also can using 80 purpose screen paintings, through after the irradiation of 2 watts of/centimetre low pressure mercury lamp again the irradiation through 80 watts of/centimetre medium pressure mercury lamps solidify to form the wrinkle effect; Can also use behind the 300 purpose screen paintings through the low pressure mercury lamp irradiation and solidify to form the trickle frosted effect of wrinkle of holding concurrently through one 80 watts/centimetre medium pressure mercury lamp irradiation again, this prescription speed can reach 40 meters/minute the speed of a motor vehicle, and printing efficiency can be compared with the common frosted ink printing speed of a motor vehicle.
Embodiment 4
6,104 25 parts
6,318 25 parts
25 parts of PDDA
1,173 3 parts
15 parts of P115
4.7 parts of SD1225
2 parts of B12
0.3 part of Glide432
With 3 parts 1173 join among 25 parts 6104,25 parts 6318 and 25 parts the PDDA and 15 parts of P115 parts, stirring and dissolving, and then adding the Glide432 of 4.7 parts SD1225 wax powder, 2 parts of B12 and 0.3 part, high-speed stirring is even, can obtain ultraviolet light-curing sand vein ink.
This printing ink, solidifies through one 80 watts/centimetre medium pressure mercury lamp then and makes printed material present the frosted finish effect of uniform and smooth on printed substrate by 380 order screen painting; After also can using 150 purpose screen paintings, through solidifying to form the wrinkle effect through the medium pressure mercury lamp irradiation again after three 2 watts of/centimetre low pressure mercury lamps irradiations; Can also use behind the 380 purpose screen paintings through three 2 watts of/centimetre low pressure mercury lamps irradiations and solidify to form the frosted effect of wrinkle of holding concurrently through one 80 watts/centimetre medium pressure mercury lamp irradiation again.
Embodiment 5
6,104 25 parts
6,318 15 parts
50 parts of NPGDA
3 parts of BP
3 parts of P115
3 parts of B12
1 part of BYK333
3 parts BP are joined among 25 parts 6104,15 parts 6318 and 20 parts the NPGDA and 3 parts of P115, stirring and dissolving, and then add 3 parts B12 wax powder and 1 part BYK333, high-speed stirring is even, can obtain ultraviolet light-curing sand vein ink.
This printing ink, solidifies through one 80 watts/centimetre medium pressure mercury lamp then and makes printed material present the frosted finish effect of uniform and smooth on printed substrate by 400 order screen painting; After also can using 150 purpose screen paintings, through solidifying to form the wrinkle effect through the medium pressure mercury lamp irradiation again after three 2 watts of/centimetre low pressure mercury lamps irradiations; Can also use behind the 400 purpose screen paintings through three 2 watts of/centimetre low pressure mercury lamps irradiations and solidify to form the frosted effect of wrinkle of holding concurrently through one 80 watts/centimetre medium pressure mercury lamp irradiation again.
Claims (5)
1. a ultraviolet light-curing sand vein ink is characterized in that, its component is counted by weight: 20～60 parts of acrylate resins, 10～50 parts of acrylic ester monomers, 3～10 parts of light triggers cause 3～15 parts of promotor, 3～10 parts in wax powder, 0.3～5 part of auxiliary agent.
2. according to the described ultraviolet light-curing sand vein ink of claim 1, it is characterized in that described acrylate resin is the mixture of epoxy acrylate and urethane acrylate.
3. according to the described ultraviolet light-curing sand vein ink of claim 1, it is characterized in that, described acrylic ester monomer is 1,6 hexanediol diacrylate, tripropylene glycol diacrylate, neopentylglycol diacrylate, PDDA or Viscoat 295 or their mixture.
4. according to the described ultraviolet light-curing sand vein ink of claim 1, it is characterized in that described light trigger is 1-hydroxyl-cyclohexyl benzophenone, benzophenone, 2-hydroxy-2-methyl-1-phenyl-acetone-1 or 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholine-1-acetone or their mixture.
5. according to the described ultraviolet light-curing sand vein ink of claim 1, it is characterized in that described wax powder is that particle diameter is 8～35 microns polyethylene wax powder, Poly Propylene Wax powder or polyvinyl chloride wax powder or its mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610012860 CN1896156A (en) | 2006-06-23 | 2006-06-23 | Ultraviolet light-curing sand vein ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610012860 CN1896156A (en) | 2006-06-23 | 2006-06-23 | Ultraviolet light-curing sand vein ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1896156A true CN1896156A (en) | 2007-01-17 |
Family
ID=37608808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610012860 Pending CN1896156A (en) | 2006-06-23 | 2006-06-23 | Ultraviolet light-curing sand vein ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1896156A (en) |
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948643A (en) * | 2010-09-29 | 2011-01-19 | 安徽光谷新材料科技有限公司 | UV photocuring ink material for printing window lens of digital product |
| CN101967336A (en) * | 2010-11-03 | 2011-02-09 | 苏州凯康化工科技有限公司 | UV overprinting varnish of polyvinyl chloride PVC fastening plate and preparation method thereof |
| CN102660171A (en) * | 2012-04-28 | 2012-09-12 | 武汉虹之彩包装印刷有限公司 | High-gloss abrasion-resisting ultraviolet (UV) gold-stamping gloss oil for the field of cigarette packet printing and preparation method thereof |
| CN102796417A (en) * | 2011-09-15 | 2012-11-28 | 武汉虹之彩包装印刷有限公司 | Gravure line ultraviolet (UV) frosted ink and method for preparing same |
| CN103666096A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Quick-solidification and environment-friendly UV solidification printing ink and preparation method thereof |
| CN104179065A (en) * | 2014-07-31 | 2014-12-03 | 东莞宏石功能材料科技有限公司 | Anti-permeable UV silk printing paper gloss oil and preparation method thereof |
| CN104830151A (en) * | 2015-06-03 | 2015-08-12 | 林振坤 | Photosensitive metal frosting ink and preparing method thereof |
| CN105419461A (en) * | 2015-12-08 | 2016-03-23 | 上海杰易森股份有限公司 | UV (ultraviolet) offset metal ink and preparation method thereof |
| CN108059874A (en) * | 2016-11-08 | 2018-05-22 | 上海烟草集团有限责任公司 | A kind of sense of touch effect ink and its surface finish technique for paper package box |
| CN108084781A (en) * | 2018-01-15 | 2018-05-29 | 广州市精合致新材料科技有限公司 | A kind of UV crackles ink and preparation method thereof |
| CN108084778A (en) * | 2017-12-29 | 2018-05-29 | 上海维凯光电新材料有限公司 | High solvent-proof optical fiber coloring ink composite and preparation method thereof |
| CN108312729A (en) * | 2018-02-02 | 2018-07-24 | 浙江迈高工艺礼品有限公司 | A kind of frosted printing process |
| CN108373647A (en) * | 2018-05-21 | 2018-08-07 | 成都市德工智动科技有限公司 | A kind of UV ink and preparation method thereof |
| CN109135413A (en) * | 2018-07-06 | 2019-01-04 | 深圳市海中辉新材料科技有限公司 | A kind of mute sand oil ink of LED-UV offset printing and preparation method thereof |
| CN109608934A (en) * | 2019-01-29 | 2019-04-12 | 浙江银鹿新材料有限公司 | A kind of ultraviolet light solidification silk-screen fission ink |
| CN111607284A (en) * | 2020-06-23 | 2020-09-01 | 深圳市柏星龙创意包装股份有限公司 | Manufacturing method of optically variable curvature metal ink and three-dimensional printing method thereof |
| WO2021055862A1 (en) * | 2019-09-19 | 2021-03-25 | Henkel IP & Holding GmbH | Photocurable (meth)acrylate compositions |
| CN112778835A (en) * | 2020-12-31 | 2021-05-11 | 重庆宏图新材料科技有限公司 | Treatment-free surface printing frosted matte oil special for in-mold sticking and preparation method thereof |
| CN113527938A (en) * | 2021-08-16 | 2021-10-22 | 东莞市彩工坊新材料有限公司 | Heat-conducting UV (ultraviolet) ink and preparation method and curing method thereof |
| CN115003046A (en) * | 2022-06-01 | 2022-09-02 | 江西一诺新材料有限公司 | Preparation method of flexible circuit board |
| CN115216179A (en) * | 2022-07-08 | 2022-10-21 | 郑州瑞珂环保材料有限公司 | Environment-friendly highlight wrinkle ink and preparation method thereof |
| CN115284762A (en) * | 2022-09-14 | 2022-11-04 | 四川蓝剑金印股份有限公司 | Holographic positioning screen printing wrinkle ink method |
-
2006
- 2006-06-23 CN CN 200610012860 patent/CN1896156A/en active Pending
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948643A (en) * | 2010-09-29 | 2011-01-19 | 安徽光谷新材料科技有限公司 | UV photocuring ink material for printing window lens of digital product |
| CN101967336A (en) * | 2010-11-03 | 2011-02-09 | 苏州凯康化工科技有限公司 | UV overprinting varnish of polyvinyl chloride PVC fastening plate and preparation method thereof |
| CN101967336B (en) * | 2010-11-03 | 2012-08-29 | 苏州凯康化工科技有限公司 | UV overprinting varnish of polyvinyl chloride PVC fastening plate and preparation method thereof |
| CN102796417A (en) * | 2011-09-15 | 2012-11-28 | 武汉虹之彩包装印刷有限公司 | Gravure line ultraviolet (UV) frosted ink and method for preparing same |
| CN102660171A (en) * | 2012-04-28 | 2012-09-12 | 武汉虹之彩包装印刷有限公司 | High-gloss abrasion-resisting ultraviolet (UV) gold-stamping gloss oil for the field of cigarette packet printing and preparation method thereof |
| CN103666096B (en) * | 2013-11-25 | 2016-03-23 | 铜陵方正塑业科技有限公司 | A kind of quick solidifying and UV curing inks of environmental protection and preparation method thereof |
| CN103666096A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Quick-solidification and environment-friendly UV solidification printing ink and preparation method thereof |
| CN104179065A (en) * | 2014-07-31 | 2014-12-03 | 东莞宏石功能材料科技有限公司 | Anti-permeable UV silk printing paper gloss oil and preparation method thereof |
| CN104179065B (en) * | 2014-07-31 | 2016-04-13 | 东莞宏石功能材料科技有限公司 | A kind of impermeable UV silk-screen paper gloss oil and preparation method thereof |
| CN104830151A (en) * | 2015-06-03 | 2015-08-12 | 林振坤 | Photosensitive metal frosting ink and preparing method thereof |
| CN105419461A (en) * | 2015-12-08 | 2016-03-23 | 上海杰易森股份有限公司 | UV (ultraviolet) offset metal ink and preparation method thereof |
| CN108059874A (en) * | 2016-11-08 | 2018-05-22 | 上海烟草集团有限责任公司 | A kind of sense of touch effect ink and its surface finish technique for paper package box |
| CN108084778A (en) * | 2017-12-29 | 2018-05-29 | 上海维凯光电新材料有限公司 | High solvent-proof optical fiber coloring ink composite and preparation method thereof |
| CN108084781A (en) * | 2018-01-15 | 2018-05-29 | 广州市精合致新材料科技有限公司 | A kind of UV crackles ink and preparation method thereof |
| CN108312729A (en) * | 2018-02-02 | 2018-07-24 | 浙江迈高工艺礼品有限公司 | A kind of frosted printing process |
| CN108373647A (en) * | 2018-05-21 | 2018-08-07 | 成都市德工智动科技有限公司 | A kind of UV ink and preparation method thereof |
| CN109135413A (en) * | 2018-07-06 | 2019-01-04 | 深圳市海中辉新材料科技有限公司 | A kind of mute sand oil ink of LED-UV offset printing and preparation method thereof |
| CN109608934A (en) * | 2019-01-29 | 2019-04-12 | 浙江银鹿新材料有限公司 | A kind of ultraviolet light solidification silk-screen fission ink |
| CN114391026A (en) * | 2019-09-19 | 2022-04-22 | 汉高股份有限及两合公司 | Photocurable (meth) acrylate composition |
| WO2021055862A1 (en) * | 2019-09-19 | 2021-03-25 | Henkel IP & Holding GmbH | Photocurable (meth)acrylate compositions |
| CN111607284A (en) * | 2020-06-23 | 2020-09-01 | 深圳市柏星龙创意包装股份有限公司 | Manufacturing method of optically variable curvature metal ink and three-dimensional printing method thereof |
| CN112778835A (en) * | 2020-12-31 | 2021-05-11 | 重庆宏图新材料科技有限公司 | Treatment-free surface printing frosted matte oil special for in-mold sticking and preparation method thereof |
| CN113527938A (en) * | 2021-08-16 | 2021-10-22 | 东莞市彩工坊新材料有限公司 | Heat-conducting UV (ultraviolet) ink and preparation method and curing method thereof |
| CN115003046A (en) * | 2022-06-01 | 2022-09-02 | 江西一诺新材料有限公司 | Preparation method of flexible circuit board |
| CN115003046B (en) * | 2022-06-01 | 2024-04-09 | 江西一诺新材料有限公司 | Preparation method of flexible circuit board |
| CN115216179A (en) * | 2022-07-08 | 2022-10-21 | 郑州瑞珂环保材料有限公司 | Environment-friendly highlight wrinkle ink and preparation method thereof |
| CN115284762A (en) * | 2022-09-14 | 2022-11-04 | 四川蓝剑金印股份有限公司 | Holographic positioning screen printing wrinkle ink method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1896156A (en) | Ultraviolet light-curing sand vein ink | |
| CN1959530B (en) | Ultraviolet light solidified coating in use for post processing of imaging material | |
| CN101979449B (en) | Ultraviolet curing coating for white board | |
| CN1247712C (en) | Visible light cured metal paint | |
| CN1185309C (en) | UV curable compositions for producing mar resistant coatings and method for depositing same | |
| CN1727417A (en) | Ultraviolet light solidified crepe printing ink | |
| CN1746235A (en) | Ultraviolet aluminium-silver size coating with light curing | |
| CN1657575A (en) | UV light solidified luminous printing ink | |
| CN1206288C (en) | UV curable paint compositions and method of making and applying same | |
| CN1526740A (en) | Photoinitiator composition capable of initiating via visible light and its use | |
| CN103396689A (en) | LED-UV light source curable coating and preparation method | |
| CN107216715A (en) | A kind of UV LED inkjet printing character inks and preparation method thereof | |
| CN1487035A (en) | Ultraviolet ray cured insulating paint | |
| WO2017185508A1 (en) | 3d ink-jet printing ink composition and ink set, and method for fabrication thereof | |
| EP3224323A1 (en) | Inks comprising liquid rubber for 3d printing | |
| CN1487033A (en) | Ultraviolet ray cured paint for surface treatment or alumium ou aluminium sections | |
| CN1247711C (en) | Visible light cured plastic paint | |
| JP2019104180A (en) | Printed matter | |
| CN1580149A (en) | Ultraviolet light curable ink | |
| CN1297972A (en) | Ultravoilet cured paint without irritation | |
| CN103509405A (en) | UV decorative ink for PET sheet and preparation method thereof | |
| CN1436824A (en) | Ultraviolet light cured burnished paint for wooden articles | |
| CN103013222B (en) | Ultraviolet light cured ink and application and preparation method thereof | |
| CN1486960A (en) | Ultraviolet light cured ceramic paint | |
| CN1294163A (en) | Ultraviolet ray solidified anticorrosion decorative paint for metal |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |