CN104830151A - Photosensitive metal frosting ink and preparing method thereof - Google Patents
Photosensitive metal frosting ink and preparing method thereof Download PDFInfo
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- CN104830151A CN104830151A CN201510299242.XA CN201510299242A CN104830151A CN 104830151 A CN104830151 A CN 104830151A CN 201510299242 A CN201510299242 A CN 201510299242A CN 104830151 A CN104830151 A CN 104830151A
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- photosensitive metal
- frosted ink
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- metal frosted
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the technical field of inks, in particular to photosensitive metal frosting ink and a preparing method thereof. The photosensitive metal frosting ink comprises, by weight, 30 to 60 parts of ultraviolet curable resin, 5 to 10 parts of filler, 10 to 30 parts of dimethyldichlorosilance modified epoxy resin, 5 to 8 parts of activated diluent, 1 to 5 parts of photoinitiator, and 5 to 10 parts of solvent. The photosensitive metal frosting ink is of good frosting effect, allows the surface of a printed product to be white free and has good adhesion, good heat resistance, chemical resistance and high hardness; the preparing method has simple process and is convenient to operate and control, the quality is stable, production efficiency is high, and the preparing method is suitable for large-scale industrial production.
Description
Technical field
The present invention relates to technical field of ink, be specifically related to a kind of photosensitive metal frosted ink and preparation method thereof.
Background technology
Photosensitive metal frosted ink, also known as pseud metal-etching ink, be a kind of ultraviolet ray spot light-curable ink, the first-selected silk screen printing of its mode of printing, base material mostly is gold and silver paperboard or other paper-plastic stick etc. and has strong mirror effect material, and drying mode is UV ultraviolet photo-curing.Because its printing has strong sand sense, attractive in appearance, graceful, generous, thus promote be exceedingly fast, a few years, just occupies sizable ratio in high-grade packages printing fields such as tobacco bale, Jiu Bao, makeup.But because the investment threshold of this ink is lower, formulator's level is uneven, and it is too wide that available starting material relate to face; And this ink all goes back standard International or National at present.Thus problems such as in printing process, particularly in mass industrialized production, unavoidably there is such or such problem, such as sand sense is bad, printed matter surface has grey, not inking phenomenon, printed matter sticking power bad.
Therefore, a kind of high performance photosensitive metal frosted ink is needed badly.
Summary of the invention
In order to overcome the shortcoming and defect existed in prior art, the object of the present invention is to provide the photosensitive metal frosted ink that a kind of sand sense is good, printed matter surface non-whitening, sticking power are good.
Another object of the present invention is to the preparation method providing a kind of photosensitive metal frosted ink, this preparation method's technique is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Object of the present invention is achieved through the following technical solutions.
A kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 30-60 part
Weighting agent 5-10 part
Dimethyldichlorosilane(DMCS) modified epoxy 10-30 part
Reactive thinner 5-8 part
Light trigger 1-5 part
Solvent 5-15 part.
Preferably, a kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 40-50 part
Weighting agent 6-8 part
Dimethyldichlorosilane(DMCS) modified epoxy 15-25 part
Reactive thinner 5-8 part
Light trigger 1-3 part
Solvent 8-13 part.
Preferably, the raw material of following weight part is also comprised: hollow glass micropearl 1-5 part.Containing gas, there is good cold-and-heat resistent shrinkability in hollow glass micropearl, thus strengthen the elasticity of coating, make ink have good tinting strength and sticking power.Hollow glass micropearl is under the prerequisite of high filler loading capacity, and the viscosity of ink increases not obvious, and therefore the usage quantity of solvent can reduce, and just can reduce the quantity discharged of ink in use toxic gas, effectively reduce VOC index, improve environmental-protecting performance of the present invention.
Preferably, the raw material of following weight part is also comprised: dextrin 1-5 part.Dextrin has good mobility, stronger adhesive capacity and adsorptive power, can permeate, act synergistically with other raw material, improve the physicals of ink in raw material, improves the stability of ink.
Preferably, described UV-cured resin is one or more the mixture in epoxy acrylate, urethane acrylate, polyester acrylate.This several UV-cured resin has good solidification rate, chemical-resistant and hardness.
The small molecules organosilicon short chain of dimethyldichlorosilane(DMCS) modified epoxy has firmly been wedged in epoxy cross-linking network by the mode that chemical bond connects, the packing density of curing system is made to increase, molecular weight increases, the Si-O key bond energy simultaneously generated is large, C-Si is rotatable etc. again, so the thermotolerance of modified resin cured article, anti-impact, tension and ductility etc. have improvement in various degree.Thermotolerance of the present invention and endurance are well improved preferably.
Preferably, the mixture that is made up of with weight ratio 2-4:1 talcum powder and calcium carbonate of described weighting agent.
Weighting agent of the present invention is by adopting talcum powder and the composite use of calcium carbonate, and to control its weight ratio be 2-4:1, can improve the sticking power after ink film forming.
Preferably, the mixture that is made up of with weight ratio 0.8-1.2:1:1.4-2.2 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate of described reactive thinner.
Reactive thinner of the present invention is by adopting Viscoat 295, ethoxyquin Viscoat 295 and the composite use of Dipentaerythritol tetraacrylate, and to control its weight ratio be 0.8-1.2:1:1.4-2.2, effectively can improve the curing speed of ink, improve hardness and the chemical resistant properties of ink.
Preferably; described light trigger is by 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2; the mixture that 4,6-trimethylbenzoy-dipheny phosphine oxide forms with weight ratio 0.8-1.2:1.4-2.2:1.
Light trigger of the present invention is by adopting 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2; 4; the composite use of 6-trimethylbenzoy-dipheny phosphine oxide; and to control its weight ratio be 0.8-1.2:1.4-2.2:1, obtained ink solidification speed is fast.
Preferably, the mixture that is made up of with weight ratio 1:1.4-2.2:2-4 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether of described solvent.
Solvent of the present invention by adopting 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether composite use, and controls its weight ratio 1:1.4-2.2:2-4, and the consistency of it and other component of ink is good, can be stablized, homogeneous ink.
Another object of the present invention is achieved through the following technical solutions: a kind of preparation method of photosensitive metal frosted ink, take above-mentioned raw materials by weight, join high speed dispersor, 20-40min is stirred under 400-600rpm rotating speed, then fineness is ground to lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
Preparation method's technique of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Beneficial effect of the present invention is: photosensitive metal frosted ink sand of the present invention sense is good, printed matter surface non-whitening, sticking power are good, and have good resistance toheat simultaneously, chemical resistance is good, hardness is high.Preparation method's technique of the present invention is simple, and convenient operation and control, steady quality, production efficiency is high, can large-scale industrial production.
Embodiment
For the ease of the understanding of those skilled in the art, below in conjunction with embodiment, the present invention is further illustrated, and the content that embodiment is mentioned not is limitation of the invention.
Embodiment 1
A kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 30 parts
Weighting agent 10 parts
Dimethyldichlorosilane(DMCS) modified epoxy 10 parts
Reactive thinner 8 parts
Light trigger 1 part
Solvent 15 parts.
Described UV-cured resin is epoxy acrylate.
The mixture that described weighting agent is made up of with weight ratio 2:1 talcum powder and calcium carbonate.
The mixture that described reactive thinner is made up of with weight ratio 0.8:1:1.4 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate.
Described light trigger is the mixture be made up of with weight ratio 0.8:1.4:1 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2,4,6-trimethylbenzoy-dipheny phosphine oxide.
The mixture that described solvent is made up of with weight ratio 1:1.4:2 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether.
A preparation method for photosensitive metal frosted ink, takes above-mentioned raw materials by weight, joins high speed dispersor, under 400rpm rotating speed, stir 20min, is then ground to fineness lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
Embodiment 2
A kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 60 parts
Weighting agent 5 parts
Dimethyldichlorosilane(DMCS) modified epoxy 30 parts
Reactive thinner 5 parts
Light trigger 5 parts
Solvent 5 parts.
Described UV-cured resin is urethane acrylate.
The mixture that described weighting agent is made up of with weight ratio 2.5:1 talcum powder and calcium carbonate.
The mixture that described reactive thinner is made up of with weight ratio 0.9:1:1.6 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate.
Described light trigger is the mixture be made up of with weight ratio 0.9:1.6:1 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2,4,6-trimethylbenzoy-dipheny phosphine oxide.
The mixture that described solvent is made up of with weight ratio 1:1.6:2.5 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether.
A preparation method for photosensitive metal frosted ink, takes above-mentioned raw materials by weight, joins high speed dispersor, under 450rpm rotating speed, stir 25min, is then ground to fineness lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
Embodiment 3
A kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 40 parts
Weighting agent 8 parts
Dimethyldichlorosilane(DMCS) modified epoxy 15 parts
Reactive thinner 8 parts
Light trigger 1 part
Solvent 13 parts
1 part, dextrin.
Described UV-cured resin is polyester acrylate.
The mixture that described weighting agent is made up of with weight ratio 3:1 talcum powder and calcium carbonate.
The mixture that described reactive thinner is made up of with weight ratio 1:1:1.8 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate.
Described light trigger is the mixture be made up of with weight ratio 1:1.8:1 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2,4,6-trimethylbenzoy-dipheny phosphine oxide.
The mixture that described solvent is made up of with weight ratio 1:1.8:3 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether.
A preparation method for photosensitive metal frosted ink, takes above-mentioned raw materials by weight, joins high speed dispersor, under 500rpm rotating speed, stir 30min, is then ground to fineness lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
Embodiment 4
A kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 50 parts
Weighting agent 6 parts
Dimethyldichlorosilane(DMCS) modified epoxy 25 parts
Reactive thinner 5 parts
Light trigger 3 parts
Solvent 8 parts
Hollow glass micropearl 5 parts.
Described UV-cured resin is the mixture of epoxy acrylate 25 parts, urethane acrylate 25 parts.
The mixture that described weighting agent is made up of with weight ratio 3.5:1 talcum powder and calcium carbonate.
The mixture that described reactive thinner is made up of with weight ratio 1.1:1:2 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate.
Described light trigger is the mixture be made up of with weight ratio 1.1:2:1 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2,4,6-trimethylbenzoy-dipheny phosphine oxide.
The mixture that described solvent is made up of with weight ratio 1:2:3.5 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether.
A preparation method for photosensitive metal frosted ink, takes above-mentioned raw materials by weight, joins high speed dispersor, under 550rpm rotating speed, stir 35min, is then ground to fineness lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
Embodiment 5
A kind of photosensitive metal frosted ink, comprises the raw material of following weight part:
UV-cured resin 45 parts
Weighting agent 7 parts
Dimethyldichlorosilane(DMCS) modified epoxy 20 parts
Reactive thinner 7 parts
Light trigger 2 parts
Solvent 10 parts
Hollow glass micropearl 3 parts
3 parts, dextrin.
Described UV-cured resin is the mixture of urethane acrylate 25 parts, polyester acrylate 20 parts.
The mixture that described weighting agent is made up of with weight ratio 4:1 talcum powder and calcium carbonate.
The mixture that described reactive thinner is made up of with weight ratio 1.2:1:2.2 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate.
Described light trigger is the mixture be made up of with weight ratio 1.2:2.2:1 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2,4,6-trimethylbenzoy-dipheny phosphine oxide.
The mixture that described solvent is made up of with weight ratio 1:2.2:4 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether.
A preparation method for photosensitive metal frosted ink, takes above-mentioned raw materials by weight, joins high speed dispersor, under 600rpm rotating speed, stir 40min, is then ground to fineness lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
The assay of the photosensitive metal frosted ink that embodiment 1-5 obtains is as shown in table 1.
As can be seen from Table 1, the photosensitive metal frosted ink photosensitive metal frosted ink sand sense that the present invention obtains is good, printed matter surface non-whitening, sticking power are good, and have good resistance toheat simultaneously, chemical resistance is good, hardness is high.
Above-described embodiment is the present invention's preferably implementation, and in addition, the present invention can also realize by alternate manner, and any apparent replacement is all within protection scope of the present invention without departing from the inventive concept of the premise.
Claims (10)
1. a photosensitive metal frosted ink, is characterized in that: the raw material comprising following weight part:
UV-cured resin 30-60 part
Weighting agent 5-10 part
Dimethyldichlorosilane(DMCS) modified epoxy 10-30 part
Reactive thinner 5-8 part
Light trigger 1-5 part
Solvent 5-15 part.
2. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: the raw material comprising following weight part:
UV-cured resin 40-50 part
Weighting agent 6-8 part
Dimethyldichlorosilane(DMCS) modified epoxy 15-25 part
Reactive thinner 5-8 part
Light trigger 1-3 part
Solvent 8-13 part.
3. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: the raw material also comprising following weight part: hollow glass micropearl 1-5 part.
4. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: the raw material also comprising following weight part: dextrin 1-5 part.
5. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: described UV-cured resin is one or more the mixture in epoxy acrylate, urethane acrylate, polyester acrylate.
6. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: the mixture that described weighting agent is made up of with weight ratio 2-4:1 talcum powder and calcium carbonate.
7. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: the mixture that described reactive thinner is made up of with weight ratio 0.8-1.2:1:1.4-2.2 Viscoat 295, ethoxyquin Viscoat 295 and Dipentaerythritol tetraacrylate.
8. a kind of photosensitive metal frosted ink according to claim 1; it is characterized in that: described light trigger is by 2-hydroxy-2-methyl-1-phenyl-acetone, 2-methyl isophthalic acid-(4-methylthio group phenyl)-2-morpholinyl-1-acetone and 2; the mixture that 4,6-trimethylbenzoy-dipheny phosphine oxide forms with weight ratio 0.8-1.2:1.4-2.2:1.
9. a kind of photosensitive metal frosted ink according to claim 1, is characterized in that: the mixture that described solvent is made up of with weight ratio 1:1.4-2.2:2-4 1-Methoxy-2-propyl acetate, methyl iso-butyl ketone (MIBK) and ethylene glycol monobutyl ether.
10. the preparation method of a kind of photosensitive metal frosted ink as described in any one of claim 1-9, it is characterized in that: take above-mentioned raw materials by weight, join high speed dispersor, 20-40min is stirred under 400-600rpm rotating speed, then fineness is ground to lower than 15 μm with three-roll grinder, obtained photosensitive metal frosted ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510299242.XA CN104830151A (en) | 2015-06-03 | 2015-06-03 | Photosensitive metal frosting ink and preparing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510299242.XA CN104830151A (en) | 2015-06-03 | 2015-06-03 | Photosensitive metal frosting ink and preparing method thereof |
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| CN104830151A true CN104830151A (en) | 2015-08-12 |
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| CN201510299242.XA Pending CN104830151A (en) | 2015-06-03 | 2015-06-03 | Photosensitive metal frosting ink and preparing method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912834A (en) * | 2018-09-11 | 2018-11-30 | 江苏世泰实验器材有限公司 | A kind of glass slide imitative frosting ink and preparation method thereof |
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| CN1896156A (en) * | 2006-06-23 | 2007-01-17 | 中国乐凯胶片集团公司 | Ultraviolet light-curing sand vein ink |
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2015
- 2015-06-03 CN CN201510299242.XA patent/CN104830151A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1896156A (en) * | 2006-06-23 | 2007-01-17 | 中国乐凯胶片集团公司 | Ultraviolet light-curing sand vein ink |
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| Title |
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| 吴绍祖等: "《实用精细化工》", 31 January 1993, 兰州大学出版社 * |
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| 百度文库: "空心玻璃微珠", 《HTTP://WENKU.BAIDU.COM/LINK?URL=N0DRAPMUVMO11LCZP50YPGJPWGCDRTVWUMN6NYCPLCIQWGBXGMCGGGNQTI7O-GVLDJEQDPU2R__JXSFL2JECMBK35PKSFTNJOCJXU75VA7S》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108912834A (en) * | 2018-09-11 | 2018-11-30 | 江苏世泰实验器材有限公司 | A kind of glass slide imitative frosting ink and preparation method thereof |
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