CN1827864A - High temperature-microbe combined hemp degumming method - Google Patents
High temperature-microbe combined hemp degumming method Download PDFInfo
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- CN1827864A CN1827864A CN 200610050225 CN200610050225A CN1827864A CN 1827864 A CN1827864 A CN 1827864A CN 200610050225 CN200610050225 CN 200610050225 CN 200610050225 A CN200610050225 A CN 200610050225A CN 1827864 A CN1827864 A CN 1827864A
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- hemp
- high temperature
- degumming
- temperature
- softening
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- 244000025254 Cannabis sativa Species 0.000 title claims abstract description 64
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 title claims abstract description 64
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 title claims abstract description 64
- 235000009120 camo Nutrition 0.000 title claims abstract description 64
- 235000005607 chanvre indien Nutrition 0.000 title claims abstract description 64
- 239000011487 hemp Substances 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 13
- 108010029541 Laccase Proteins 0.000 claims abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000001301 oxygen Substances 0.000 claims abstract description 11
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000009835 boiling Methods 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 206010044565 Tremor Diseases 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 8
- 240000008564 Boehmeria nivea Species 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 5
- 150000004056 anthraquinones Chemical class 0.000 claims description 5
- 230000002255 enzymatic effect Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000009897 hydrogen peroxide bleaching Methods 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 5
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- 239000013638 trimer Substances 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000004902 Softening Agent Substances 0.000 claims description 2
- 239000007844 bleaching agent Substances 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 239000003513 alkali Substances 0.000 abstract description 5
- 238000004061 bleaching Methods 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 229920005610 lignin Polymers 0.000 abstract description 4
- 229920002488 Hemicellulose Polymers 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 4
- CYQFCXCEBYINGO-UHFFFAOYSA-N THC Natural products C1=C(C)CCC2C(C)(C)OC3=CC(CCCCC)=CC(O)=C3C21 CYQFCXCEBYINGO-UHFFFAOYSA-N 0.000 description 3
- CYQFCXCEBYINGO-IAGOWNOFSA-N delta1-THC Chemical compound C1=C(C)CC[C@H]2C(C)(C)OC3=CC(CCCCC)=CC(O)=C3[C@@H]21 CYQFCXCEBYINGO-IAGOWNOFSA-N 0.000 description 3
- 229960004242 dronabinol Drugs 0.000 description 3
- 238000011010 flushing procedure Methods 0.000 description 3
- 230000000813 microbial effect Effects 0.000 description 3
- 239000000084 colloidal system Substances 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 208000035992 Postmortem Changes Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses the high temperature-microorganism with hemp degumming method. The method comprises the following steps: cleaning hemp, then carrying out high temperature degumming boiling treatment; putting the hemp into enzymolysis jar, adding 10-15wt% laccase solution, at the meantime, pouring oxygen; carrying out hydroperoxide bleaching to hemp, water scrubbing, dewatering, softening, de-oiling, drying and getting fine hemp. The hemp made with the method is white, soft and good quality. The method adopts the high temperature low-alkali technology, reducing the pollution. Treating the hemp at high temperature low-alkali, it not only destroys the hemicellulose and lignin connected with between hemp fibers, but also lightens the press of enzymolysis, and reaches the purpose of hemp degumming.
Description
Technical field
The present invention relates to a kind of high temperature-microbe combined hemp degumming method, particularly high temperature and deviate from most colloids, the enzyme subsequent treatment can further be deviate from remaining colloid and the softening bleaching hemp in the hemp.
Background technology
Hemp is one of human natural textile fiber that utilizes the earliest.But because the tetrahydrocannabinol (THC) that contains in the hemp can be made excitant and drugs, therefore worldwide just begin the hemp of forbidding cultivating, cause research and development to stay cool substantially hemp as far back as nineteen thirty-seven.Cultivated low toxicity hemp (THC＜0.3%) in 1992 from Britain, western countries remove the ban of hemp plantation one after another.Hemp is also thought the functional environmental protection fiber of 21 century by many scientists, but " bottle strength " that hemp is used is hemp degumming, because the content of lignin height of hemp (about 5～7%, the height to 10% that has), simultaneously big harl is short (greatly about 12～25mm), can cause short flannel if come unstuck entirely and lose spinnability, now commonly used coming unstuck has natural retted fibre, chemical Degumming and microbial degumming etc., and natural retted fibre life period is long, be subjected to that natural environment influence is big, degumming quality is unstable, contaminated environment etc.; That chemical Degumming exist to pollute is big, raw material and energy consumption consumption are many; And the microbial degumming life period is long, the shortcomings such as efficient is low of coming unstuck.
Summary of the invention
In order to overcome in the prior art, the microbial method usually time that single chemical degumming contaminated environment is serious and single is long, the shortcoming that degumming rate is low.The object of the present invention is to provide a kind of high temperature-microbe combined hemp degumming method.
The technical solution used in the present invention is:
The present invention adopts high temperature to hang down the alkali treatment technology first, make adipocere matter, pectin, the hydrotrope in the hemp be able to remove substantially fully, and hemicellulose in the hemp and lignin is able to a large amount of removals; Further come unstuck softening with enzymolysis to the high-temperature process hemp then; With hydrogen peroxide the hemp after handling is bleached at last.
The step of high temperature-microbe combined hemp degumming method of the present invention is::
(1), carries out the high temperature degumming boiling-off then and handle with hemp weighing after washing;
(2) hemp after the high temperature degumming is put in the enzymatic vessel, adding and containing percentage by weight is 10～15% the laccase aqueous solution, wherein the percentage by weight of the hemp and the laccase aqueous solution is 1: 8～1: 10, temperature is controlled at 60～80 ℃, pH is 4.5～6.5, processing time is 8～10 hours, while aerating oxygen in solution, and the feeding amount of oxygen is 30～50 ml/min;
(3) hemp behind the enzymolysis is carried out hydrogen peroxide bleaching, the concentration of hydrogen peroxide is 7～10g/L, and bath raio is 1: 10～1: 15, and pH is 10～11, and temperature is to bleach 30～45 minutes under 70～85 ℃ the condition;
(4) hemp of handling well washes, dewaters, trembles that fiber crops, oil supply are softening, de-oiling, tremble fiber crops, oven dry, obtains degummed ramie at last.
When the high temperature degumming boiling-off, the NaOH 3～4% of boiling house solution, vulcanized sodium 8%, anthraquinone 0.02%, sodium metasilicate 1～2%, sodium phosphate trimer 1～2%; Bath raio was at 1: 3～1: 4, and heating rate is 1～3 ℃/minute, was warmed up to 135 ℃, and pressure is 0.4 MPa, was incubated 0～30 minute, took out with hot water and cleaned, oven dry.
In the oil supply softening process, the concentration of softening agent is 2.5～3.5%, and the softening processing time is 1.5～2 hours, and temperature is 75～85 ℃.
The hempen original ramie that the present invention chatted and the chemical composition analysis of degummed ramie are with reference to standard GB 5889-86.
The beneficial effect that the present invention has is: pure white loose by the hemp that above method is handled, and not only soft quality but also good.Owing to adopt the low alkali technology of high temperature, therefore environment is not almost polluted, reduce the enterprise pollution blowdown presssure.Simultaneously under the low alkali of high temperature, handle hemp, not only can destroy being attached at hemicellulose and lignin between the hemp element, thereby make degraded and be able to most of the removal, and alleviate the pressure that enzymolysis is deviate from, reach the hemp degumming purpose.
The specific embodiment
Embodiment 1:
1) with 50 gram hemps, put into high-temperature tank three times with the running water flushing, high temperature boiling-off then, the boiling-off prescription is: NaOH 3%, vulcanized sodium 8%, anthraquinone 0.02%, sodium metasilicate 2%, sodium phosphate trimer 1% (above percentage all is dried relatively hemp weight); Bath raio (ratio of hemp weight and aqueous solution volume) is 1: 4, and heating rate is 3 ℃/minute, is warmed up to 135 ℃, and pressure 0.4 MPa is incubated 30 minutes.Taking-up is cleaned with hot water, oven dry.
3) hemp of cleaning is put into enzymatic vessel, adding and containing percentage by weight is 10% laccase (available from the commercial laccase of Co., Ltd in the Novi's letter) aqueous solution, wherein the percentage by weight of the hemp and the laccase aqueous solution is 1: 8, temperature is controlled at 80 ℃, pH is 4.5, while aerating oxygen in solution, and the feeding amount of oxygen is 30 ml/min, handled 8 hours, and cleaned.
4) hemp behind the enzymolysis is carried out hydrogen peroxide bleaching, the concentration of hydrogen peroxide is 7g/L, and bath raio is 1: 10, and pH is 10, and temperature is bleaching 45 minutes under 70 ℃ the condition, washing then.
5) trembling fiber crops adopts and to tremble numb machine and make into the numb loose of piece.
6) with the softening processing hemp of softener (the SJ-501 fiber crops available from Zhejiang Province's silk research institute are used softener) of 2.5% concentration, the processing time is 1.5 hours, and treatment temperature is 75 ℃.
7) carry out after the soft treatment de-oiling, tremble fiber crops, and on dryer, dry, obtain degummed ramie.
Embodiment 2:
1) with 50 gram hemps, put into high-temperature tank three times with the running water flushing, high temperature boiling-off then, the boiling-off prescription is: NaOH 3.5%, vulcanized sodium 8%, anthraquinone 0.02%, sodium metasilicate 1.5%, sodium phosphate trimer 1.5%.Bath raio is 1: 3, and heating rate is 1 ℃/minute, is warmed up to 135 ℃, and pressure 0.4 MPa is incubated 0 minute.Taking-up is cleaned with hot water, oven dry.
3) hemp of cleaning is put into enzymatic vessel, adding and containing percentage by weight is 13% the laccase aqueous solution, wherein the percentage by weight of the hemp and the laccase aqueous solution is 1: 9, temperature is controlled at 70 ℃, pH is 6.5, while aerating oxygen in solution, and the feeding amount of oxygen is 40 ml/min, handled 9 hours, and cleaned.
4) hemp behind the enzymolysis is carried out hydrogen peroxide bleaching, the concentration of hydrogen peroxide is 10g/L, and bath raio is 1: 15, and pH is 10.5, and temperature is bleaching 30 minutes under 85 ℃ the condition, washing then.
5) trembling fiber crops adopts and to tremble numb machine and make into the numb loose of piece.
6) with the softening processing of the softener hemp of 3% concentration, the processing time is 1.75 hours, and treatment temperature is 80 ℃.
7) carry out after the soft treatment de-oiling, tremble fiber crops, and on dryer, dry, obtain degummed ramie.
Embodiment 3:
1) with 50 gram hemps, put into high-temperature tank three times with the running water flushing, high temperature boiling-off then, the boiling-off prescription is: NaOH 4%, vulcanized sodium 8%, anthraquinone 0.02%, sodium metasilicate 1%, sodium phosphate trimer 2%.Bath raio is 1: 3.5, and heating rate is 2 ℃/minute, is warmed up to 135 ℃, and pressure 0.4 MPa is incubated 15 minutes.Taking-up is cleaned with hot water, oven dry.
3) hemp of cleaning is put into enzymatic vessel, adding and containing percentage by weight is 15% the laccase aqueous solution, wherein the percentage by weight of the hemp and the laccase aqueous solution is 1: 10, temperature is controlled at 60 ℃, pH is 5.5, while aerating oxygen in solution, and the feeding amount of oxygen is 50 ml/min, handled 10 hours, and cleaned.
4) hemp behind the enzymolysis is carried out hydrogen peroxide bleaching, the concentration of hydrogen peroxide is 8g/L, and bath raio is 1: 13, and pH is 11, and temperature is bleaching 40 minutes under 80 ℃ the condition, washing then.
5) trembling fiber crops adopts and to tremble numb machine and make into the numb loose of piece.
6) with the softening processing of the softener hemp of 3.5% concentration, the processing time is 2 hours, and treatment temperature is 85 ℃.
7) carry out after the soft treatment de-oiling, tremble fiber crops, and on dryer, dry, obtain degummed ramie.
Claims (3)
1. high temperature-microbe combined hemp degumming method is characterized in that steps of the method are:
(1), carries out the high temperature degumming boiling-off then and handle with hemp weighing after washing;
(2) hemp after the high temperature degumming is put in the enzymatic vessel, adding and containing percentage by weight is 10～15% the laccase aqueous solution, wherein the percentage by weight of the hemp and the laccase aqueous solution is 1: 8～1: 10, temperature is controlled at 60～80 ℃, pH is 4.5～6.5, processing time is 8～10 hours, while aerating oxygen in solution, and the feeding amount of oxygen is 30～50 ml/min;
(3) hemp behind the enzymolysis is carried out hydrogen peroxide bleaching, the concentration of hydrogen peroxide is 7～10g/L, and bath raio is 1: 10～1: 15, and pH is 10～11, and temperature is to bleach 30～45 minutes under 70～85 ℃ the condition;
(4) hemp of handling well washes, dewaters, trembles that fiber crops, oil supply are softening, de-oiling, tremble fiber crops, oven dry, obtains degummed ramie at last.
2. according to the described a kind of high temperature-microbe combined hemp degumming method of claim 1, it is characterized in that: when the high temperature degumming boiling-off, the NaOH 3～4% of boiling house solution, vulcanized sodium 8%, anthraquinone 0.02%, sodium metasilicate 1～2%, sodium phosphate trimer 1～2%; Bath raio was at 1: 3～1: 4, and heating rate is 1～3 ℃/minute, was warmed up to 135 ℃, and pressure is 0.4 MPa, was incubated 0～30 minute, took out with hot water and cleaned, oven dry.
3. according to the described a kind of high temperature-microbe combined hemp degumming method of claim 1, it is characterized in that: in the oil supply softening process, the concentration of softening agent is 2.5～3.5%, and the softening processing time is 1.5～2 hours, and temperature is 75～85 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2006100502253A CN100355951C (en) | 2006-04-06 | 2006-04-06 | High temperature-microbe combined hemp degumming method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100502253A CN100355951C (en) | 2006-04-06 | 2006-04-06 | High temperature-microbe combined hemp degumming method |
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| CN1827864A true CN1827864A (en) | 2006-09-06 |
| CN100355951C CN100355951C (en) | 2007-12-19 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009049484A1 (en) * | 2007-09-27 | 2009-04-23 | Jiangsu Redbud Textile Technology Co., Ltd. | Method of using composite enzyme for degumming jute (2) |
| CN101187066B (en) * | 2007-09-27 | 2010-06-09 | 江苏紫荆花纺织科技股份有限公司 | Method for degelatinizing jute applying composite enzyme |
| CN101349004B (en) * | 2008-09-04 | 2011-03-30 | 黑龙江圆宝纺织股份有限公司 | Rescutched tow non-chlorine bleaching method |
| CN104630909A (en) * | 2015-02-15 | 2015-05-20 | 东华大学 | Method for preparing flax fiber by ultrasonic combination of mucor circinelloides DK1 strain and hydrogen peroxide |
| CN104630908A (en) * | 2015-02-15 | 2015-05-20 | 东华大学 | Method for preparing flax fiber by combined process of mucor circinelloides DK1 strain and hydrogen peroxide |
| CN104630910A (en) * | 2015-02-15 | 2015-05-20 | 东华大学 | Method for preparing flax fiber by combined process of candida tropicalis DK2 strain and hydrogen peroxide |
| CN106012298A (en) * | 2016-08-01 | 2016-10-12 | 薛常刚 | Preparation method of automotive noise lowering interior trim material |
| CN106795658A (en) * | 2014-08-13 | 2017-05-31 | 塞勒直布罗陀有限公司 | A kind of method for processing bast-fiber materials |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1089669A (en) * | 1993-10-08 | 1994-07-20 | 泰安市***科学纺织科研所 | Enzymolysis method for degumming of hemp |
| ES2189683B1 (en) * | 2001-12-17 | 2005-02-01 | Consejo Superior De Investigaciones Cientificas | NEW PROCEDURE FOR CHLORINE-FREE ENZYMATIC WHITENING OF HIGH-QUALITY PASTES OBTAINED FROM HERBAL OR ARBUSTIVE PLANTS. |
-
2006
- 2006-04-06 CN CNB2006100502253A patent/CN100355951C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009049484A1 (en) * | 2007-09-27 | 2009-04-23 | Jiangsu Redbud Textile Technology Co., Ltd. | Method of using composite enzyme for degumming jute (2) |
| CN101187066B (en) * | 2007-09-27 | 2010-06-09 | 江苏紫荆花纺织科技股份有限公司 | Method for degelatinizing jute applying composite enzyme |
| CN101349004B (en) * | 2008-09-04 | 2011-03-30 | 黑龙江圆宝纺织股份有限公司 | Rescutched tow non-chlorine bleaching method |
| CN106795658A (en) * | 2014-08-13 | 2017-05-31 | 塞勒直布罗陀有限公司 | A kind of method for processing bast-fiber materials |
| CN106795658B (en) * | 2014-08-13 | 2019-12-24 | 塞勒直布罗陀有限公司 | Method for processing bast fiber material |
| CN104630909A (en) * | 2015-02-15 | 2015-05-20 | 东华大学 | Method for preparing flax fiber by ultrasonic combination of mucor circinelloides DK1 strain and hydrogen peroxide |
| CN104630908A (en) * | 2015-02-15 | 2015-05-20 | 东华大学 | Method for preparing flax fiber by combined process of mucor circinelloides DK1 strain and hydrogen peroxide |
| CN104630910A (en) * | 2015-02-15 | 2015-05-20 | 东华大学 | Method for preparing flax fiber by combined process of candida tropicalis DK2 strain and hydrogen peroxide |
| CN104630909B (en) * | 2015-02-15 | 2016-08-17 | 东华大学 | A kind of volume branch Mucor DK1 bacterial strain and the ultrasonic combined method preparing flaxen fiber of hydrogen peroxide |
| CN106012298A (en) * | 2016-08-01 | 2016-10-12 | 薛常刚 | Preparation method of automotive noise lowering interior trim material |
| CN106012298B (en) * | 2016-08-01 | 2018-06-19 | 威海聚力轿车内饰股份有限公司 | A kind of preparation method of automobile noise reduction interior material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100355951C (en) | 2007-12-19 |
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