CN1814663A - 一种热固性丙烯酸乳液及其制备方法以及含有该乳液的涂料 - Google Patents
一种热固性丙烯酸乳液及其制备方法以及含有该乳液的涂料 Download PDFInfo
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- CN1814663A CN1814663A CN 200510033137 CN200510033137A CN1814663A CN 1814663 A CN1814663 A CN 1814663A CN 200510033137 CN200510033137 CN 200510033137 CN 200510033137 A CN200510033137 A CN 200510033137A CN 1814663 A CN1814663 A CN 1814663A
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- monomer
- acrylic
- emulsion
- consumption
- water
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims description 8
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- 229940114077 acrylic acid Drugs 0.000 title 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 53
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- -1 carboxylate salt Chemical class 0.000 claims description 43
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
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- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 229960004418 trolamine Drugs 0.000 claims description 4
- YTLYLLTVENPWFT-UPHRSURJSA-N (Z)-3-aminoacrylic acid Chemical class N\C=C/C(O)=O YTLYLLTVENPWFT-UPHRSURJSA-N 0.000 claims description 3
- LZDXRPVSAKWYDH-UHFFFAOYSA-N 2-ethyl-2-(prop-2-enoxymethyl)propane-1,3-diol Chemical group CCC(CO)(CO)COCC=C LZDXRPVSAKWYDH-UHFFFAOYSA-N 0.000 claims description 3
- 229920003180 amino resin Polymers 0.000 claims description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 3
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- 229930185605 Bisphenol Natural products 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
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- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical group C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims description 2
- 229940043237 diethanolamine Drugs 0.000 claims description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 2
- 229940059574 pentaerithrityl Drugs 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
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- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
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- 239000004971 Cross linker Substances 0.000 abstract 1
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- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 12
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- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 description 9
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- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
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- HVUMOYIDDBPOLL-XGKPLOKHSA-N [2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XGKPLOKHSA-N 0.000 description 1
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- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
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- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
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- 239000000194 fatty acid Substances 0.000 description 1
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- 235000010755 mineral Nutrition 0.000 description 1
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- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical compound CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- OZCWUNHGNVXCCO-UHFFFAOYSA-N oxiran-2-ylmethyl hydrogen carbonate Chemical group OC(=O)OCC1CO1 OZCWUNHGNVXCCO-UHFFFAOYSA-N 0.000 description 1
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- 235000011009 potassium phosphates Nutrition 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
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- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
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- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940083575 sodium dodecyl sulfate Drugs 0.000 description 1
- OWHUYYOLMQBAHA-UHFFFAOYSA-M sodium octadecanoate prop-2-enamide Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Na+].C(C=C)(=O)N OWHUYYOLMQBAHA-UHFFFAOYSA-M 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 description 1
- VFSRCMUUHLBQPY-UHFFFAOYSA-N sodium;ethene Chemical compound [Na+].[CH-]=C VFSRCMUUHLBQPY-UHFFFAOYSA-N 0.000 description 1
- BWYYYTVSBPRQCN-UHFFFAOYSA-M sodium;ethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=C BWYYYTVSBPRQCN-UHFFFAOYSA-M 0.000 description 1
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- 239000000243 solution Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
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- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical group CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
编号 | 外观 | Tg(℃)计算值 | 冻融循环(次数) | 机械稳定性 | 储存稳定性 | 泡沫量 |
实施例1 | 微蓝乳液 | 15 | 3 | ○ | ○ | ◎ |
实施例2 | 微蓝乳液 | 40 | 2 | ○ | ○ | ◎ |
实施例3 | 微蓝乳液 | 30 | 3 | ○ | ○ | ◎ |
实施例4 | 微蓝乳液 | -15 | 3 | ◎ | ○ | ◎ |
实施例5 | 微蓝乳液 | 15 | 3 | ◎ | ○ | ◎ |
实施例6 | 蓝相乳液 | 0 | 3 | ○ | ◎ | ○ |
实施例7 | 蓝相乳液 | -10 | 3 | ○ | ◎ | ○ |
实施例8 | 蓝相乳液 | 20 | 2 | ◎ | ◎ | ○ |
实施例9 | 微蓝乳液 | 0 | 3 | ○ | ○ | ○ |
实施例10 | 微蓝乳液 | 0 | 3 | ○ | ◎ | ◎ |
实施例11 | 蓝相乳液 | -10 | 3 | ◎ | ◎ | ◎ |
对比例1 | 蓝相乳液 | 0 | 3 | ◎ | ◎ | × |
对比例2 | 蓝相乳液 | 5 | 3 | × | × | × |
对比例3 | 微蓝相乳液 | 50 | × | × | × | ○ |
对比例4 | 蓝相乳液 | -25 | 3 | ◎ | ◎ | × |
对比例5 | 蓝相乳液 | 15 | 3 | ◎ | ◎ | × |
实施例 | 低皂丙烯酸乳液 | 水性树脂 | 附着力促进剂 | 水***联剂 | 催化剂 | 中和剂 | 助溶剂 | 水 |
实施例12 | 30(R01) | 10(A) | 0.5(E) | 6(H) | 0.2(L) | 0.1(O) | 14 | 39.2 |
实施例13 | 45(R02) | 2(C) | 1.0(G) | 9(I) | 0.3(L) | 0.2(P) | 13 | 31.0 |
实施例14 | 25(R03) | 20(B) | - | 15(J) | 0.2(M) | 0.1(O) | 10 | 27.9 |
实施例15 | 60(R04) | 1(D) | 2.0(F) | 7.5(H) | 0.3(M) | 0.2(P) | 12 | 18.0 |
实施例16 | 40(R05) | 2(B) | 2.0(F) | 12(J) | 0.3(L) | 0.2(O) | 6 | 37.8 |
实施例17 | 35(R06) | 2(A) | 1.0(E) | 12(H) | 0.2(M) | 0.1(P) | 14 | 35.7 |
实施例18 | 20(R07) | 15(A) | 0.5(G) | 6(H) | 0.2(M) | 0.1(P) | 15 | 43.2 |
实施例19 | 35(R08) | 10(C) | - | 10(J) | 0.3(L) | 0.2(P) | 10 | 33.8 |
实施例20 | 35(R09) | 5(D) | 1(F) | 10(I) | 0.3(N) | 0.1(O) | 15 | 34.6 |
实施例21 | 35(R10) | 10(B) | 2(G) | 5(K) | 0.3(N) | 0.2(Q) | 12 | 35.5 |
实施例22 | 50(R11) | 1(D) | 2(E) | 8(K) | 0.3(N) | 0.2(Q) | 13 | 25.5 |
对比例6 | 25(COR1) | 15(A) | 1(D) | 10(H) | 0.3(L) | 0.2(O) | 10 | 38.5 |
对比例7 | 35(COR2) | 10(B) | 2(E) | 5(J) | 0.3(L) | 0.1(P) | 15 | 35.4 |
对比例8 | 45(COR3) | 5(C) | 3(F) | 8(I) | 0.3(L) | 0.2(O) | 12 | 26.5 |
对比例9 | 45(COR4) | 0.5(D) | 2(E) | 15(J) | 0.3(L) | 0.2(O) | 13 | 22.5 |
对比例10 | 40(COR5) | 2(A) | 2(E) | 10(K) | 0.3(N) | 0.2(Q) | 14 | 30.5 |
实施例 | 底涂附着力 | 耐碱性 | 耐盐雾性 | 耐湿热性 | 耐水煮 | 面涂附着力 | 耐黄变性 | 后加工性 | 储存稳定性 |
实施例12 | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ○ |
实施例13 | ◎ | ○ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ○ |
实施例14 | ◎ | ○ | △ | ○ | ◎ | ◎ | ◎ | ◎ | ○ |
实施例15 | ◎ | ◎ | ◎ | ◎ | ○ | ◎ | ◎ | ◎ | ○ |
实施例16 | ◎ | ○ | ○ | ○ | ○ | ◎ | ◎ | ◎ | ○ |
实施例17 | ◎ | ◎ | ○ | ○ | ○ | ○ | ○ | ◎ | ◎ |
实施例18 | ◎ | ○ | △ | △ | ○ | ○ | ○ | ◎ | ◎ |
实施例19 | ◎ | ○ | ○ | ◎ | ○ | ○ | ○ | ◎ | ◎ |
实施例20 | ◎ | ○ | ○ | ○ | ○ | ○ | ○ | ◎ | ○ |
实施例21 | ◎ | ○ | ◎ | ○ | ◎ | ◎ | ○ | ◎ | ◎ |
实施例22 | ◎ | ○ | ◎ | ○ | ◎ | ◎ | ○ | ◎ | ◎ |
对比例6 | ◎ | △ | × | × | △ | × | ○ | × | ◎ |
对比例7 | ○ | △ | △ | △ | △ | × | ○ | × | △ |
对比例8 | ○ | ○ | △ | △ | △ | × | ○ | × | × |
对比例9 | ◎ | ○ | × | △ | △ | △ | ○ | ○ | ◎ |
对比例10 | ○ | ◎ | ○ | △ | × | △ | ○ | ○ | ◎ |
Claims (19)
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Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2004300345A (ja) * | 2003-03-31 | 2004-10-28 | Toto Ltd | 水性塗料組成物、防汚性部材及び塗膜形成方法 |
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