CN1720293A - 具有磷-硅化合物的阻燃聚碳酸酯组合物 - Google Patents
具有磷-硅化合物的阻燃聚碳酸酯组合物 Download PDFInfo
- Publication number
- CN1720293A CN1720293A CNA2003801051848A CN200380105184A CN1720293A CN 1720293 A CN1720293 A CN 1720293A CN A2003801051848 A CNA2003801051848 A CN A2003801051848A CN 200380105184 A CN200380105184 A CN 200380105184A CN 1720293 A CN1720293 A CN 1720293A
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- composition
- phosphorus
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- alkyl
- silicon compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/5406—Silicon-containing compounds containing elements other than oxygen or nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- C08L69/005—Polyester-carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/16—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
- C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
组分(数值以重量份为单位) | 1 2 3 4(对比例) |
A1(PC)E3(磷-硅化合物) | 100 100 100 100- 1 3 5 |
UL94V试验中的等级在UL94V试验中的总燃烧时间[s]白炽金属丝试验-火焰高度[mm]白炽金属丝试验-燃烧时间[s]是否通过白炽金属丝试验LOI-筛选试验[%O2] | V-2 V-2 V-0 V-056 15 0 083 55 45 47>30 20 3 1未 通过 通过 通过26 28 29 29 |
TGA-质量损失[%] | 0.3 0.2 0.4 0.7 |
组分(数值以重量份计) | 5 6 7 8 9(对照例) (对照例)(对照例) |
A2(PC)C1(PTFE/ABS--接枝聚合物-混凝物)D1(脱模剂)D2(稳定剂)E1(磷酸酯)E2(硅酮)E3(磷-硅-化合物) | 94,5 94,5 94,5 94,5 94,55,0 5,0 5,0 5,0 5,00,4 0,4 0,4 0,4 0,40,1 0,1 0,1 0,1 0,1- - - 5 -- - - - 5- 3 5 - - |
B(ABS-C1的接枝聚合物)C1的PTFE | 4,5 4,5 4,5 4,5 4,50,5 0,5 0,5 0,5 0,5 |
UL94V-试验等级UL94V-试验中的总燃烧时间[s]白炽金属丝试验-最大火焰高度[mm]白炽金属丝试验-燃烧时间[s]白炽金属丝试验通过与否LOI-筛选试验[%O2] | NB V-2 V-2 NB NB>250 75 30 >250 >250110 97 92 80 100>30 9 9 10 >30否 是 是 是 否25 26 27 27 28 |
TGA-质量损失[%] | 0,4 0,6 0,9 1,8 0,3 |
Claims (19)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10257081.7 | 2002-12-06 | ||
DE10257081A DE10257081A1 (de) | 2002-12-06 | 2002-12-06 | Flammwidrige Polycarbonat-Zusammensetzungen mit Phosphor-Silizium-Verbindungen |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1720293A true CN1720293A (zh) | 2006-01-11 |
CN100354353C CN100354353C (zh) | 2007-12-12 |
Family
ID=32336055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003801051848A Expired - Fee Related CN100354353C (zh) | 2002-12-06 | 2003-11-22 | 具有磷-硅化合物的阻燃聚碳酸酯组合物 |
Country Status (13)
Country | Link |
---|---|
US (1) | US7144935B2 (zh) |
EP (1) | EP1570002B1 (zh) |
JP (1) | JP4677234B2 (zh) |
KR (1) | KR100985945B1 (zh) |
CN (1) | CN100354353C (zh) |
AT (1) | ATE388203T1 (zh) |
AU (1) | AU2003302908A1 (zh) |
BR (1) | BR0317042A (zh) |
CA (1) | CA2508628A1 (zh) |
DE (2) | DE10257081A1 (zh) |
ES (1) | ES2300657T3 (zh) |
MX (1) | MXPA05005905A (zh) |
WO (1) | WO2004052990A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102079758A (zh) * | 2009-11-30 | 2011-06-01 | 中国中化股份有限公司 | 一种磷硅化合物的制备方法 |
CN102344583A (zh) * | 2011-07-07 | 2012-02-08 | 西南科技大学 | 含硅含双螺环季戊四醇二膦酸酯阻燃剂及其制备方法 |
CN102893443A (zh) * | 2010-05-21 | 2013-01-23 | 三井化学株式会社 | 包含含有甲硅烷基酯基的膦酸衍生物的非水电解液及锂二次电池 |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080014446A1 (en) * | 2004-10-07 | 2008-01-17 | General Electric Company | Window shade and a multi-layered article, and methods of making the same |
US20070066737A1 (en) * | 2005-09-16 | 2007-03-22 | Gallucci Robert R | Flame retardant polymer blends |
US9006348B2 (en) | 2005-09-16 | 2015-04-14 | Sabic Global Technologies B.V. | Poly aryl ether ketone polymer blends |
EP1937774A2 (en) | 2005-09-16 | 2008-07-02 | General Electric Company | Blends of poly aryl ether ketones and polyetherimide sulfones |
US8445568B2 (en) * | 2008-09-25 | 2013-05-21 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic composition and articles formed therefrom |
US8912272B2 (en) | 2008-12-19 | 2014-12-16 | Sabic Innovative Plastics Ip B.V. | Moisture resistant polyimide compositions |
BR112013013627B1 (pt) * | 2010-12-02 | 2021-03-30 | Dow Global Technologies Llc | Polímero de silício-fósforo-nitrogênio livre de halogênio intumescente, sistema retardante de chama, composição de polímero de silício-fósforo-nitrogênio livre de halogênio intumescente e artigo |
US9953742B2 (en) | 2013-03-15 | 2018-04-24 | General Cable Technologies Corporation | Foamed polymer separator for cabling |
BR112016027765B1 (pt) | 2014-06-06 | 2022-06-28 | General Cable Technologies Corporation | Cabo de comunicação |
EP3078723B1 (de) * | 2015-04-09 | 2018-10-31 | Evonik Degussa GmbH | Addukte aus isocyanatoalkyltrimethoxysilanen und mit ihnen reaktiven flammschutzmitteln |
WO2019115541A1 (en) * | 2017-12-13 | 2019-06-20 | Basf Se | Electrolyte composition comprising oligomeric silyl ester phosphonates |
CN108129825B (zh) * | 2017-12-29 | 2020-05-05 | 青岛海尔新材料研发有限公司 | 一种高cti、高耐热无卤阻燃pc/abs组合物及其制备方法 |
CN115124707B (zh) * | 2022-07-25 | 2023-10-13 | 万华化学集团股份有限公司 | 一种含磷硅共聚聚碳酸酯及其制备方法与应用 |
CN115181407B (zh) * | 2022-08-15 | 2023-12-19 | 万华化学(宁波)有限公司 | 一种无卤阻燃低烟密度聚碳酸酯材料及其制备方法和应用 |
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DE2013547C3 (de) | 1969-05-19 | 1974-02-14 | Toyama Chemical Co., Ltd., Tokio | Verwendung von organischen Phosphorsiliciumverbindungen als flammhemmende Mittel |
JPS4941438A (zh) * | 1972-08-30 | 1974-04-18 | ||
US4093641A (en) | 1977-09-26 | 1978-06-06 | Dow Corning Corporation | Preparation of silylalkyl esters of phosphorus |
DE3819081A1 (de) | 1988-06-04 | 1989-12-07 | Bayer Ag | Flammwidrige, schlagzaehe polycarbonat-formmassen |
US5204394A (en) | 1988-09-22 | 1993-04-20 | General Electric Company | Polymer mixture having aromatic polycarbonate, styrene I containing copolymer and/or graft polymer and a flame-retardant, articles formed therefrom |
DE3911558A1 (de) * | 1989-04-08 | 1990-10-11 | Bayer Ag | Brandwidrige polycarbonate und polyester |
DE4328656A1 (de) | 1993-08-26 | 1995-03-02 | Bayer Ag | Flammwidrige, spannungsrißbeständige Polycarbonat-ABS-Formmassen |
DE4411067A1 (de) * | 1994-03-30 | 1995-10-05 | Bayer Ag | Polymerformmassen zur partiellen farblichen Veränderung durch Laserenergie, insbesondere zur Erzeugung bunter Zeichen |
EP0728811B1 (en) | 1995-02-27 | 2003-09-17 | Mitsubishi Chemical Corporation | Flame retardant thermoplastic resin composition |
WO1997038051A1 (fr) * | 1996-04-08 | 1997-10-16 | Kaneka Corporation | Composition de resine de plastique ignifuge |
US6001921A (en) | 1997-09-11 | 1999-12-14 | Nec Corporation | Flame retardant resin composition |
TW544462B (en) | 1997-11-28 | 2003-08-01 | Sumitomo Dow Ltd | Flame-retardant polycarbonate resin compositions |
DE19832094A1 (de) * | 1998-07-16 | 2000-01-27 | Consortium Elektrochem Ind | Flammhemmende Dispersionszusammensetzung |
JP4121056B2 (ja) | 1998-08-24 | 2008-07-16 | 日本化学工業株式会社 | 難燃剤組成物及び難燃性樹脂組成物 |
US6221939B1 (en) | 1998-08-31 | 2001-04-24 | General Electric Company | Flame retardant resin compositions containing phosphoramides, and method for making |
US5973041A (en) | 1998-08-31 | 1999-10-26 | General Electric Company | Resinous compositions containing aromatic bisphosphoramidates as flame retardants |
EP1162235B1 (en) | 1998-12-25 | 2003-12-03 | Idemitsu Petrochemical Co., Ltd. | Frame-retardant polycarbonate resin composition and formed article |
US6569929B2 (en) | 1999-01-22 | 2003-05-27 | General Electric Company | Method to prepare phosphoramides, and resin compositions containing them |
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JP4211121B2 (ja) * | 1999-03-08 | 2009-01-21 | 東ソー株式会社 | 含ケイ素有機リン酸化合物、その製造方法、これを含む難燃剤及び難燃性樹脂組成物 |
JP4408309B2 (ja) | 1999-04-23 | 2010-02-03 | 住友ダウ株式会社 | 難燃性ポリカーボネート樹脂組成物 |
US6414060B1 (en) | 1999-07-07 | 2002-07-02 | Albemarle Corporation | Flame retardant polycarbonate-ABS polymer compositions |
DE19941826A1 (de) | 1999-09-02 | 2001-03-08 | Bayer Ag | Flammwidrige Polycarbonat-Formmassen |
JP2001247582A (ja) * | 2000-03-08 | 2001-09-11 | Nippon Unicar Co Ltd | リン酸化ポリオルガノシロキサン、それを含有する組成物、及びその製造方法 |
JP2001294866A (ja) * | 2000-04-14 | 2001-10-23 | Kanegafuchi Chem Ind Co Ltd | 難燃剤 |
DE60134279D1 (de) | 2000-12-04 | 2008-07-10 | Gen Electric | Flammwidrige harzzusammensetzung und daraus hergestellte formkörper |
US6753365B2 (en) * | 2002-02-19 | 2004-06-22 | General Electric Company | Polyetherimide composition, method, and article |
-
2002
- 2002-12-06 DE DE10257081A patent/DE10257081A1/de not_active Withdrawn
-
2003
- 2003-11-22 AT AT03812588T patent/ATE388203T1/de not_active IP Right Cessation
- 2003-11-22 JP JP2004557926A patent/JP4677234B2/ja not_active Expired - Fee Related
- 2003-11-22 ES ES03812588T patent/ES2300657T3/es not_active Expired - Lifetime
- 2003-11-22 DE DE50309343T patent/DE50309343D1/de not_active Expired - Lifetime
- 2003-11-22 EP EP03812588A patent/EP1570002B1/de not_active Expired - Lifetime
- 2003-11-22 CN CNB2003801051848A patent/CN100354353C/zh not_active Expired - Fee Related
- 2003-11-22 WO PCT/EP2003/013151 patent/WO2004052990A1/de active IP Right Grant
- 2003-11-22 KR KR1020057010076A patent/KR100985945B1/ko not_active IP Right Cessation
- 2003-11-22 BR BR0317042-0A patent/BR0317042A/pt unknown
- 2003-11-22 AU AU2003302908A patent/AU2003302908A1/en not_active Abandoned
- 2003-11-22 CA CA002508628A patent/CA2508628A1/en not_active Abandoned
- 2003-11-22 MX MXPA05005905A patent/MXPA05005905A/es active IP Right Grant
- 2003-12-03 US US10/726,368 patent/US7144935B2/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102079758A (zh) * | 2009-11-30 | 2011-06-01 | 中国中化股份有限公司 | 一种磷硅化合物的制备方法 |
CN102079758B (zh) * | 2009-11-30 | 2013-09-11 | 中国中化股份有限公司 | 一种磷硅化合物的制备方法 |
CN102893443A (zh) * | 2010-05-21 | 2013-01-23 | 三井化学株式会社 | 包含含有甲硅烷基酯基的膦酸衍生物的非水电解液及锂二次电池 |
US8993158B2 (en) | 2010-05-21 | 2015-03-31 | Mitsui Chemicals, Inc. | Nonaqueous electrolyte solution containing silyl ester group-containing phosphonic acid derivative, and lithium secondary battery |
CN102344583A (zh) * | 2011-07-07 | 2012-02-08 | 西南科技大学 | 含硅含双螺环季戊四醇二膦酸酯阻燃剂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
US7144935B2 (en) | 2006-12-05 |
DE50309343D1 (de) | 2008-04-17 |
EP1570002A1 (de) | 2005-09-07 |
DE10257081A1 (de) | 2004-06-24 |
KR20050085338A (ko) | 2005-08-29 |
BR0317042A (pt) | 2005-10-25 |
ES2300657T3 (es) | 2008-06-16 |
ATE388203T1 (de) | 2008-03-15 |
AU2003302908A1 (en) | 2004-06-30 |
WO2004052990A1 (de) | 2004-06-24 |
MXPA05005905A (es) | 2005-08-29 |
US20040110879A1 (en) | 2004-06-10 |
JP2006509079A (ja) | 2006-03-16 |
KR100985945B1 (ko) | 2010-10-06 |
JP4677234B2 (ja) | 2011-04-27 |
CA2508628A1 (en) | 2004-06-24 |
EP1570002B1 (de) | 2008-03-05 |
CN100354353C (zh) | 2007-12-12 |
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