CN1528207A - Alfalfa plant concentrated extract preparing process - Google Patents
Alfalfa plant concentrated extract preparing process Download PDFInfo
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- CN1528207A CN1528207A CNA200310107960XA CN200310107960A CN1528207A CN 1528207 A CN1528207 A CN 1528207A CN A200310107960X A CNA200310107960X A CN A200310107960XA CN 200310107960 A CN200310107960 A CN 200310107960A CN 1528207 A CN1528207 A CN 1528207A
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Abstract
The present invention relates to a production process of clover and perilla concentrated extract. Firstly, said invention selects the clover variety richly containing polysaccharide, saponin and flavone health-care nutrient components as material for germination and making leaf powder and selects large-leaf perilla as material for making perilla leaf powder, then said invention adopts the following steps: preparing selenium-enriched clover germ powder, preparing fresh clover leaf powder and preparing fresh perilla leaf powder, then making preparation of clover and perilla plant concentrated extract, in aqueous solution extracting clover germ powder, clover leaf powder and perilla leaf powder, filtering extracts to oblain concentrated germ liquor and concentrated leaf liquor, combining them according to a certain ratio so as to obtain the invented clover and perilla concentrated extract with rich effective nutrient components and the functions of reducing blood fat and raising immunity.
Description
Technical field
What the present invention relates to is a kind of manufacture craft of health-care nutrient liquor, specifically is the manufacture craft of a kind of lucerne Soviet Union plant concentrated extracting solution.Belong to food processing field.
Background technology
For a long time, clover is one of main leguminous forage plant of the northern area of China always, cultivated area occupies the 5th in the world. nearly recent decades, along with people's deepening continuously to clover special dietary composition and functional study, physics, chemical method have been adopted as the U.S., France etc. abroad, developing single is raw material with the clover, or with the clover be primary raw material be aided with other chemicals nearly 20 surplus kind of clover health products, as products such as calcium magnesium sheet, natural beta-carotin nourishing capsules.And China still belongs to starting to the research of clover health care, and the exploitation of clover health food is limited to condition restriction such as human and material resources, still belongs to blankly, but market prospects should be very tempting.
Find that according to literature search calcium magnesium sheet that U.S. Amway Company produces and natural beta-carotin nourishing capsule are being sold for many years.Except that clover is the basis, be equipped with calcium carbonate in the calcium magnesium sheet, magnesia, Dicalcium Phosphate, 11 kinds of raw materials such as manganese citrate.Except that clover concentrates element, be equipped with carrotene, lecithin, corn oil, gelatin, oleum sojae, 9 kinds of raw materials of vitamin E wet goods in the same natural beta-carotin nourishing capsule.The clover proportion is very little in these two kinds of products, and it is chemicals or other composition greatly partly.These products do not show lipopenicillinase and liver-protecting function, and because of the vast scale chemicals is arranged, also just has to a certain degree intestinal absorption difficulty.
Summary of the invention
The present invention is directed to disadvantages of background technology and defective, the manufacture craft that provides a kind of lucerne to revive the plant concentrated extracting solution, this technology is raw material with the natural health plant fully, do not add any chemicals, chemical pigment and chemical preservative in the leaching process and can guarantee that again the plant concentrated extracting solution is rich in effective nutritional labeling, the lucerne Soviet Union plant concentrated extracting solution of making is a kind of product that human health is had security, reliability.
The present invention is achieved by the following technical solutions, the inventive method is: at first select to be rich in polysaccharide, saponin, health nutrient compositions such as flavones, Da Ye and stem/leaf ratio are near 1~1.2, the bright careless output of year accumulative total equals or is higher than alfalfa variety (the non-autumn dormancy type EUREKA of 6000Kg/ mu, half autumn dormancy type DERBY etc.) be germination and the material of making the leaf powder, select the blade face, blade back all is that mauve Chinese native kind one Da Ye purple perilla is for making the material of perilla leaf powder, carrying out rich selenium clover bud powder then makes, clover fresh leaf powder is made and purple perilla fresh leaf powder is made, carrying out lucerne Soviet Union plant concentrated extracting solution again makes, extraction clover bud powder in the aqueous solution, alfalfa leaf meal, the perilla leaf powder, extract must concentrate bud liquid and concentrated leaf liquid after filtering, and it is combined into lucerne Soviet Union plant concentrated extracting solution in proportion.Gained lucerne Soviet Union plant concentrated extracting solution has the lowering fat and protecting liver function that extremely significantly reduces T-CHOL, LDL-C.
Below the present invention is further illustrated, particular content is as follows:
1. rich selenium clover bud powder is made: the alfalfa seed of (a) selecting cleaning, mass of 1000 kernel 〉=1.5g, germination percentage 〉=90%; (b) under 22 ℃ ± 2 ℃ condition,, carry out germination treatment after making seed weightening finish 60% with clear water seed soaking 3-4 hour; (c) duration of germination, every day, twice usefulness 25ppm sodium selenite solution sprayed, and the decision of sodium selenite solution concentration should guarantee that poly-selenium amount is higher in the bud seedling, does not suppress the growth of bud seedling again; (d) results when the bud seedling grows into cotyledon and fully launches; (e) under ℃ condition of 55 ℃≤t≤60 the bud seedling being carried out aeration-drying pulverizes, the bud powder is kept in t<10 ℃ low temperature, the dry environment, by above making flow process, when the poly-selenium amount of rich selenium clover bud powder can reach 23.20ppm for contrast (water sprinkling) 10.4 times of 2.24ppm.
2. clover fresh leaf powder is made: the fresh blade of clover of (other regional clover fresh leaf powder health nutrient composition and content is close also can use) results is clean and air-dry (a) with Shanghai and in the neighbourhood during March~October; (b) under ℃ condition of 55 ℃≤t≤60 with blade aeration-drying, be ground into fine powder, low temperature drying is preserved under the condition of t<10 ℃ then.
3. purple perilla fresh leaf powder is made: (a) the purple perilla kind is that blade face, blade back all are mauve large-leaved variety, and its carotenoid content is higher than blue or green Soviet Union; (b) the results blade time is initial bloom stage plant middle part blade, and the content of its main nutrient composition is higher than spire and Lao Ye, and initial bloom stage bata-carotene content is 5.3 times of spire, and carotenoid content is 4.5 times of spire; (c) will gather in the crops blade and in time clean air-dryly, and then aeration-drying is ground into fine powder under ℃ condition of 55 ℃≤t≤60, low temperature, kept dry under ℃ condition of t<10.
4. lucerne Soviet Union plant concentrated extracting solution is made: (a) each personal 20 times of water of rich selenium clover bud powder, clover fresh leaf powder and purple perilla fresh leaf powder were stirred the back static 1 hour, make its abundant swelling, boil 1/20 of gradation simmer down to original volume then, PH is 6-7; (b) by volume with rich selenium clover bud liquid, cloverleaf liquid, perilla leaf liquid according to being mixed into the homogeneous concentrate at 1.56: 1: 1.44.
The germination environment of the required vegetable material of this concentrated extracting solution and growing environment must no pesticide growns, not to fertilize with without herbicide, by agricultural cultivation measures such as biological pesticide, natural enemy, fertilizer, crop rotations, guarantee the security that raw material is produced.
The present invention is different from the clover product of abroad having developed, and its feature is by clover, two kinds of natural health plants of the purple perilla comprehensive and complementary concentrated extracting solution of forming at three different growth phase health nutrient compositions.Rich selenium clover bud is except that containing macronutrient, and abundant plant Se content tool high anti-oxidation activity has certain tumor-inhibiting action; The fresh blade of clover is the good source of vitamin A, E, K, and contain 4 times outside the vitamin C of orange juice, osajin derivatives such as the plain alcohol of particularly contained lucernol, lucerne are a kind of plant estrogens, can prevention of osteoporosis disease, cancer, heart disease and adjusting blood fat, diuresis, antibiotic function; And purple perilla is the research focus of domestic and international food, medicine, field of light industry always, the initial bloom stage perilla leaf powder that adopts in this concentrated extracting solution more is rich in terpene, flavones and glucoside, lipoidis, anthocyanidin and polysaccharide etc. than stem and spire, Lao Ye, have antibacterial, press down cancer, regulate blood fat, antioxidation, particularly volatile oil content is 0.5~0.7% in the perilla leaf, mainly class terpenoids such as perillaldehyde, perilla ketone, dihydroperilla alcohol in the volatile oil, can play the plant antiseptic agent function, its bacteriostasis surpasses benzoic acid and nipagin ethylester.Comprehensive and complementary with the health nutrient composition of 3 different growth phases of two kinds of plants makes this concentration extraction liquor ratio existing product have more extensive health care for this reason.
The present invention has substantive distinguishing features and marked improvement, product of the present invention is that natural plants is formed fully, and be again concentrated the forming of elite height that 3 different growth phases of two kinds of plants extract, the concentrate that extracts in wherein rich selenium clover bud and the alfalfa leaf meal, account for 64% of entire product, the composition of product has guaranteed to have easy absorption, the tangible characteristics of lipid-lowering effect, and price accounting has only about 1/3rd of U.S.'s Amway product calcium magnesium sheet, natural beta-carotin capsule.The origin of health care of the present invention is except containing nutrient and trace element, and polysaccharide abundant, peculiar structure, saponin, isoflavone content play a decisive role to the function of lipopenicillinase and enhancing immunological effect.The plant that the present invention relates to is bigger in China's cultivated area, has very big using value.
The specific embodiment
Particular content in conjunction with technology of the present invention provides following examples:
Embodiment 1
1. rich selenium clover bud powder is made: (a) selecting cleaning, 1 year storage period, mass of 1000 kernel is that 1.5g, germination percentage are 90% alfalfa seed; (b) under 24 ℃ condition,, carry out germination treatment after making seed weightening finish 60% with clear water seed soaking 3 hours; (c) duration of germination, every day, twice usefulness 25ppm sodium selenite solution sprayed; (d) cotyledon when clover fully launches, and gathers in the crops when presenting green; (e) be under 60 ℃ of conditions the bud seedling to be carried out aeration-drying to pulverize at t, it is in 5 ℃ of dry environments that the bud powder is kept at t, by above making flow process, and when the poly-selenium amount of rich selenium clover bud powder reaches 23.20ppm for contrast (water sprinkling) 10.4 times of 2.24ppm.
2. clover fresh leaf powder is made: (a) the fresh blade of clover with area, Shanghai results in March is clean and air-dry; (b) t be under 60 ℃ of conditions with blade aeration-drying, be ground into fine powder, be kept dry under 9 ℃ the condition at t then.It is green that alfalfa leaf meal is, and have peat-reek, and health nutrient composition and content should reach (ppm): Ca:11820, P:5086, Fe:1049, Mg:2757, Zn:38.57, K:28970, Cu:17.57, Se:0.46, thick polysaccharide: 7880, thick saponin: 1540.
3. purple perilla fresh leaf powder is made: (a) the purple perilla kind is that blade face, blade back all are mauve large-leaved variety, and its carotenoid content is higher than blue or green Soviet Union; (b) the results blade time is initial bloom stage plant middle part blade, and the content of its main nutrient composition is higher than spire and Lao Ye, and initial bloom stage bata-carotene content is 5.3 times of spire, and carotenoid content is 4.5 times of spire; (c) will gather in the crops blade and in time clean air-dryly, and then aeration-drying is ground into fine powder under t=60 ℃ of condition, is kept dry under 9 ℃ of conditions at t.Purple perilla fresh leaf powder health nutrient composition and content reach (ppm): Ca:23580, P:3857, and Fe:8454, Mg:3090, Zn:139.4, K:15500, Cu:20.2, anthocyanin: 19000, flavones: 123.4, beta carotene: 1050.
4. lucerne Soviet Union plant concentrated extracting solution is made: (a) each personal 20 times of warm water of rich selenium clover bud powder, clover fresh leaf powder and purple perilla fresh leaf powder were stirred the back static 1 hour, make its abundant swelling, boil 1/20 of gradation simmer down to original volume then, PH is 6; (b) after the filtration, remove plant residue, rich selenium clover bud liquid, cloverleaf liquid, perilla leaf liquid are complied be mixed into the homogeneous concentrate at 1.56: 1: 1.44 by volume.Health nutrient composition and content reach (ppm): Ca:676.6ppm, P:2159.0ppm, Fe:714.2ppm, Zn:14.31ppm, K:8336.0ppm, Cu:3.83ppm, Na:5270.0ppm, Se:14.34ppm, thick polysaccharide: 23800ppm, thick saponin: 8990ppm, crude flavonoid powder: 600ppm.
Embodiment 2
1. rich selenium clover bud powder is made: (a) selecting cleaning, 1 year storage period, mass of 1000 kernel is that 1.6g, germination percentage are 92% alfalfa seed; (b) under 24 ℃ condition,, carry out germination treatment after making seed weightening finish 60% with clear water seed soaking 4 hours; (c) duration of germination, every day, twice usefulness 25ppm sodium selenite solution sprayed; (d) results when the cotyledon of clover fully launches; (e) be under 55 ℃ of conditions the bud seedling to be carried out aeration-drying to pulverize at t, it is in 9 ℃ of dry environments that the bud powder is kept at t, by above making flow process, and when the poly-selenium amount of rich selenium clover bud powder reaches 23.20ppm for contrast (water sprinkling) 10.4 times of 2.24ppm.
2. clover fresh leaf powder is made: (a) the fresh blade of clover with area, Shanghai results in March is clean and air-dry; (b) t be under 55 ℃ of conditions with blade aeration-drying, be ground into fine powder, be kept dry under 6 ℃ the condition at t then.
3. purple perilla fresh leaf powder is made: (a) the purple perilla kind is that blade face, blade back all are mauve large-leaved variety; (b) the results blade time is initial bloom stage plant middle part blade, and the content of its main nutrient composition is higher than spire and Lao Ye, and initial bloom stage bata-carotene content is 5.3 times of spire, and carotenoid content is 4.5 times of spire; (c) will gather in the crops blade and in time clean air-dryly, and then aeration-drying is ground into fine powder under t=55 ℃ of condition, is kept dry under 5 ℃ of conditions at t.
4. lucerne Soviet Union plant concentrated extracting solution is made: (a) each personal 20 times of boiling water of rich selenium clover bud powder, clover fresh leaf powder and purple perilla fresh leaf powder are soaked into also plant powder and slowly stir, make after its abundant swelling static 1 hour, 1/20 of gradation simmer down to original volume, PH are 7; (b) after the filtration, rich selenium clover bud liquid, cloverleaf liquid, perilla leaf liquid are complied be mixed into the homogeneous concentrate at 1.56: 1: 1.44 by volume.Carry out spray-drying, obtain concentrating powder and make every and be the 500mg tablet.The lowering fat and protecting liver function that extremely significantly reduces T-CHOL, LDL-C is arranged.
Rich selenium clover bud powder or clover fresh leaf powder or purple perilla fresh leaf powder are ground powdered can directly be made the health food raw material or make clover young tea leaves, cloverleaf tea and purple perilla tea.
Embodiment 3
1. rich selenium clover bud powder is made: (a) selecting cleaning, 1 year storage period, mass of 1000 kernel is that 1.8g, germination percentage are 91% alfalfa seed; (b) under 24 ℃ condition,, carry out germination treatment after making seed weightening finish 60% with clear water seed soaking 4 hours; (c) duration of germination, every day, twice usefulness 25ppm sodium selenite solution sprayed; (d) results when the cotyledon of clover fully launches; (e) be under 58 ℃ of conditions the bud seedling to be carried out aeration-drying to pulverize at t, it is in 6 ℃ of dry environments that the bud powder is kept at t, by above making flow process, and when the poly-selenium amount of rich selenium clover bud powder reaches 23.20ppm for contrast (water sprinkling) 10.4 times of 2.24ppm.
2. clover fresh leaf powder is made: (a) the fresh blade of clover with area, Shanghai results in March is clean and air-dry; (b) t be under 58 ℃ of conditions with blade aeration-drying, be ground into fine powder, be kept dry under 2 ℃ the condition at t then.
3. purple perilla fresh leaf powder is made: (a) the purple perilla kind is that blade face, blade back all are mauve large-leaved variety; (b) the results blade time is initial bloom stage plant middle part blade, and the content of its main nutrient composition is higher than spire and Lao Ye, and initial bloom stage bata-carotene content is 5.3 times of spire, and carotenoid content is 4.5 times of spire; (c) will gather in the crops blade and in time clean air-dryly, and then aeration-drying is ground into fine powder under t=58 ℃ of condition, is kept dry under 3 ℃ of conditions at t.
4. lucerne Soviet Union plant concentrated extracting solution is made: (a) each personal 20 times of boiling water of rich selenium clover bud powder, clover fresh leaf powder and purple perilla fresh leaf powder are soaked into also plant powder and slowly stir, make after its abundant swelling static 1 hour, 1/20 of gradation simmer down to original volume, PH are 6.5; (b) after the filtration, rich selenium clover bud liquid, cloverleaf liquid, perilla leaf liquid are complied be mixed into the homogeneous concentrate at 1.56: 1: 1.44 by volume.
With the powder that obtains after the spray-drying, pulverization is suspended in 1: 30 the perilla herb oil, makes soft capsule by the known method of pharmaceuticals industry.
Lucerne Soviet Union plant concentrated extracting solution health care example: through Shanghai * * hospital clinical Nutriology Dept. result of study is as follows: (a) research method: adopt the completely randomized experiment design, if handle 4,1. normal feed group, 2. high lipoprotein emulsion group, 3. high lipoprotein emulsion+extract low dose group, 4. high lipoprotein emulsion+extract high dose group.Each is handled with 10 of the SD rats of body weight 220-300g, raises after 14 days and puts to death, and carries out the lipid content of blood parameters detection, liver and aorta wall and measures and the pathology light microscopy checking; (b) measurement result statistical analysis: adopt low dosage or high dose no matter table 1 shows extract, compare serum total cholesterol (TC) with high lipoprotein emulsion group and reduce by 29% and 35% respectively, LDL-C (LDL-C) reduces by 43% and 63% respectively, and difference all reaches the utmost point level of signifiance.
Table 1. lucerne Soviet Union extract is to the influence (mmol/L) of animal used as test serum TC, LDL-C level
TC LDL-C
Handle
Average α=0.05 α=0.01 average α=0.05 α=0.01
① 1.4289±0.0064 a A 0.2797±0.0502 a A
② 3.3731±0.2406 c C 2.1931±0.2067 d D
③
*?2.3789±0.1563 b B 1.2456±0.1496 c C
④
*?2.1829±0.0918 b B 0.8070±0.1193 b C
*The extract consumption of high dose is 1.7 times of low dosage
Table 2 shows that equally lucerne Soviet Union extract adopts low dosage or high dose, compares with high lipoprotein emulsion group, and T-CHOL in the liver organization (TC) reduces by 47% and 49% respectively, reduces by 28% and 37% in the aorta wall tissue respectively, and difference all reaches the utmost point level of signifiance.
Table 2. lucerne Soviet Union extract is to the influence (mmol/g) of liver of laboratory animal and aorta wall lipid content
TC (liver) TC (sustainer)
Handle
Average α=0.05 α=0.01 average α=0.05 α=0.01
① 0.00177±0.00014 a A 0.00268±0.00049 a A
② 0.00737±0.00062 c C 0.00429±0.00041 b B
③
*?0.00392±0.00031 b B 0.00307±0.00028 a AB
④
*?0.00378±0.00016 b B 0.00271±0.00023 a A
*The extract consumption of high dose is 1.7 times of low dosage
To the pathology light microscopy checking of liver and aorta wall, the hepatic tissue part of hepatocytes swelling of visible high lipoprotein emulsion group rat, in have fat to drip, the foreign body granuloma that the liver tunicle is formed by cholesterol crystal down as seen; And do not see that in high lipoprotein emulsion+extract low dose group and high lipoprotein emulsion+extract high dose group obvious lipid soaks into performance.For this this extract causes that to hyperlipidemia and hyperlipidemia liver and aorta wall damage have remarkable protective action to set up.
Each position of alfalfa plants all contains profuse saponin, but the highest with content in the clover root, for this reason in prescription available make raw material, to improve saponin content in the extract.
Claims (5)
1, the manufacture craft of a kind of lucerne Soviet Union plant concentrated extracting solution, it is characterized in that, at first select to be rich in polysaccharide, saponin, flavones health nutrient composition, Da Ye and stem/leaf ratio are near 1~1.2, year bright careless output of accumulative total equal or the alfalfa variety that is higher than 6000Kg/ mu for germinateing and making the material of leaf powder, select the blade face, blade back all is that mauve Da Ye purple perilla is for making the material of perilla leaf powder, carrying out rich selenium clover bud powder then makes, clover fresh leaf powder is made and purple perilla fresh leaf powder is made, carrying out lucerne Soviet Union plant concentrated extracting solution again makes, extraction clover bud powder in the aqueous solution, alfalfa leaf meal, the perilla leaf powder, extract must concentrate bud liquid and concentrated leaf liquid after filtering, and it is combined into lucerne Soviet Union plant concentrated extracting solution in proportion.
2, the manufacture craft of lucerne according to claim 1 Soviet Union plant concentrated extracting solution is characterized in that, described rich selenium clover bud powder is made, and is specific as follows:
(a) select cleaning, mass of 1000 kernel 〉=1.5g, the alfalfa seed of germination percentage 〉=90%, (b) under 22 ℃ ± 2 ℃ condition, with clear water seed soaking 3-4 hour, carry out germination treatment after making seed weightening finish 60%, (c) duration of germination, every day, twice usefulness 25ppm sodium selenite solution sprayed, (d) results when the bud seedling grows into cotyledon and fully launches, (e) under ℃ condition of t≤60 the bud seedling being carried out aeration-drying pulverizes, the bud powder is kept at t<10 ℃ low temperature, in the dry environment, by above making flow process, when the poly-selenium amount of rich selenium clover bud powder reaches 23.20ppm for contrast 10.4 times of 2.24ppm.
3, the manufacture craft of lucerne according to claim 1 Soviet Union plant concentrated extracting solution is characterized in that described clover fresh leaf powder is made, and is specific as follows:
(a) Shanghai and the fresh blade of clover gathered in the crops during March~October in the neighbourhood is clean and air-dry, (b) under ℃ condition of t≤60 with blade aeration-drying, be ground into fine powder, low temperature drying is preserved under the condition of t<10 ℃ then.
4, the manufacture craft of lucerne according to claim 1 Soviet Union plant concentrated extracting solution is characterized in that described purple perilla fresh leaf powder is made, and is specific as follows:
(a) the purple perilla kind is that blade face, blade back all are mauve large-leaved variety, its carotenoid content is higher than blue or green Soviet Union, (b) the results blade time is initial bloom stage plant middle part blade, the content of its main nutrient composition is higher than spire and Lao Ye, initial bloom stage bata-carotene content is 5.3 times of spire, and carotenoid content is 4.5 times of spire, (c) will gather in the crops blade and in time clean air-dry, and then aeration-drying is ground into fine powder under ℃ condition of t≤60, low temperature, kept dry under ℃ condition of t<10.
5, the manufacture craft of lucerne according to claim 1 Soviet Union plant concentrated extracting solution is characterized in that, described lucerne Soviet Union plant concentrated extracting solution is made, and is specific as follows:
(a) each personal 20 times of water of rich selenium clover bud powder, clover fresh leaf powder and purple perilla fresh leaf powder were stirred the back static 1 hour, make its abundant swelling, boil 1/20 of gradation simmer down to original volume then, PH is 6-7, (b) by 1.56: 1: 1.44 volume ratios rich selenium clover bud liquid, cloverleaf liquid, perilla leaf liquid is mixed into the homogeneous concentrate.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102172129A (en) * | 2010-12-31 | 2011-09-07 | 苏州硒谷科技有限公司 | High-selenium alfalfa and cultivation method and application thereof |
CN106721810A (en) * | 2016-12-19 | 2017-05-31 | 蚌埠鲲鹏食品饮料有限公司 | A kind of selenium-supply alfalfa bud juice |
CN107041897A (en) * | 2016-02-05 | 2017-08-15 | 大汉酵素生物科技股份有限公司 | It is a kind of to improve cachectic composition and preparation method thereof to prepare |
CN108354177A (en) * | 2018-01-26 | 2018-08-03 | 安徽天马生物科技有限公司 | Selenium-enriched scallop oral liquid with good selenium supplementing effect |
CN116602403A (en) * | 2023-05-06 | 2023-08-18 | 金木集团有限公司 | Lycopene vitamin E soft capsule and preparation method thereof |
-
2003
- 2003-10-16 CN CN 200310107960 patent/CN1241499C/en not_active Expired - Fee Related
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102172129A (en) * | 2010-12-31 | 2011-09-07 | 苏州硒谷科技有限公司 | High-selenium alfalfa and cultivation method and application thereof |
CN107041897A (en) * | 2016-02-05 | 2017-08-15 | 大汉酵素生物科技股份有限公司 | It is a kind of to improve cachectic composition and preparation method thereof to prepare |
CN106721810A (en) * | 2016-12-19 | 2017-05-31 | 蚌埠鲲鹏食品饮料有限公司 | A kind of selenium-supply alfalfa bud juice |
CN108354177A (en) * | 2018-01-26 | 2018-08-03 | 安徽天马生物科技有限公司 | Selenium-enriched scallop oral liquid with good selenium supplementing effect |
CN116602403A (en) * | 2023-05-06 | 2023-08-18 | 金木集团有限公司 | Lycopene vitamin E soft capsule and preparation method thereof |
CN116602403B (en) * | 2023-05-06 | 2024-05-24 | 金木集团有限公司 | Lycopene vitamin E soft capsule and preparation method thereof |
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CN1241499C (en) | 2006-02-15 |
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