CN1356214A - Water-transferring patterned paper for ceramics, its making method and its application - Google Patents
Water-transferring patterned paper for ceramics, its making method and its application Download PDFInfo
- Publication number
- CN1356214A CN1356214A CN 01130101 CN01130101A CN1356214A CN 1356214 A CN1356214 A CN 1356214A CN 01130101 CN01130101 CN 01130101 CN 01130101 A CN01130101 A CN 01130101A CN 1356214 A CN1356214 A CN 1356214A
- Authority
- CN
- China
- Prior art keywords
- counterdie
- marble paper
- paper
- pattern
- ceramic water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Landscapes
- Decoration By Transfer Pictures (AREA)
Abstract
A water-transferring patterned paper for ceramic is make up through preparing ink from inorganic pigment and ink oil containing ethylene-vinyl acetate, dibutyl phthalate and solvent, printing pattern, and coating surface film, which incldues coating prime film and printing screwn film. The liquid for prime film is prepared from ethylene-vinyl acetate, dibutyl phthalate and xylene. The liquie for screen film is prepared from methyl polymethylacrylate, dibutyl phthalate, xylene and butyl acetate. Its advantages include once calcining high productivity and high stability of product.
Description
Technical field: the present invention relates to a kind of ceramic printing technique and equipment thereof.
Background technology:
Existing stringcourse, the water transfering printing process on the flower sheet that is widely used in ceramic decoration mainly is made of following processing step:------------decal paper---dries---decoration firing---product to the raw glaze base to the table burning to moulded pottery not yet put in a kiln to bake in glaze firing.Marble paper used in the production process mainly is made of paper substrate, patterned layer, face glued membrane, the production technology of marble paper is with silk screen porcelain to be formed pattern with ink printing on the paper substrate face earlier, dry back is coated with one deck glue with the silk screen seal on pattern, treat promptly to form the face glued membrane after the glue drying, pattern just is attached to becomes the marble paper finished product on the face glued membrane.The using method of paper substrate is to be soaked in water earlier marble paper 2-3 minute, treat with the face glued membrane of pattern with after paper substrate separates, with the paving of face glued membrane on ceramic plane, the bubble that venting comprises dries moisture, carries out decoration firing in the kiln below 900 ℃, in the decoration firing process, the face glued membrane volatilizees through pyrolytic, the pottery on the pattern with pigment then fusion stick in ceramic surface, form decorative pattern.There is following shortcoming in above-mentioned technology:
1, process links is many in the production process, and complex process causes breakage easily.
2, will carry out earlier after the glaze firing vitreous could decal paper for porcelain, and energy consumption is big, the production cost height.
3, because the independence of each operation is strong, discontinuous, be difficult to form streamline production, therefore, give birth to
Product efficient is low.
4, because the restriction of material that marble paper adopts wants drying more than half a day after marble paper moves and is attached on the porcelain
Draining moisture could decoration firing, otherwise can be because moisture is not drained fully during the high temperature decoration firing produce
The steam of giving birth to breaks through the face glued membrane.Cause snuff and destroy pattern.
5, the stringcourse of traditional decal paper production and flower sheet.All to burn till warp through secondary or three glazes
Cross the glaze that repeatedly burns till and the glaze of once-firing and compare, its color developing effect is inconsistent,
Particularly contain the darker glaze of colorant, can produce tangible aberration, this is tradition two, three times
The insurmountable at all a great problem of Low fire ceramic marble paper also is the shortcoming of traditional marble paper maximum
And weak point.In order to solve the above problems, general stringcourse factory adopts the saw brick more
Method is sawn into strip with stringcourse and end brick separates, and is to reduce the aberration of stringcourse, still right
The aberration that exists in the flower sheet is insurmountable at all, and general glazed tile manufacturer,
As stringcourse and the flower sheet of will forming a complete production network, then want other configuration device, increased production cost,
So stringcourse factory and ceramics factory are difficult to organically combine.
Summary of the invention:
Goal of the invention of the present invention be to provide a kind of when producing the stamp pottery with marble paper technology simple, production cost is low, less energy consumption, small investment, can not produce aberration, the production efficiency height, the ceramic water of constant product quality shifts the using method of marble paper and manufacture method and this marble paper.
It is to realize like this that ceramic water of the present invention shifts marble paper, comprise and be coated with the paper substrate that is covered with the hydrosol, be printed on stamp on the hydrosol face, be printed on the face glued membrane on the stamp, the printing ink that constitutes decalcomania mainly is made of inorganic pigment, binding agent, it is that a kind of fusing point is higher but be lower than 100 ℃ organic compound than room temperature that its special feature is to link agent, and counterdie is that a kind of fusing point is higher but be lower than 100 ℃ organic compound binder than room temperature.
Here, the binding agent of being adopted is ethene-acetate ethylene copolymer, also can be ethlyene dichloride-acetate ethylene copolymer.Also contain dibutyl phthalate in the printing ink, and solvent.The effect of dibutyl phthalate is a plasticization, can increase the pliability and the stability of marble paper pattern.
Counterdie mainly is made of ethene-acetate ethylene copolymer, dibutyl phthalate, solvent.
Also be coated with shop one deck nethike embrane on the counterdie surface.The effect of nethike embrane is the effect of playing skeleton, makes counterdie not yielding, guarantees that the pattern on the counterdie is stable.Because base film material is ethene-acetate ethylene copolymer, this kind physical property is softer, to responsive to temperature, the size temperature influence changes greatly, so when using separately, cause the easy surrounding environment influence of pattern above it easily and be out of shape, destroyed the integrality of pattern.Therefore, need be coated with shop one deck nethike embrane on counterdie, the effect of skeleton had both been played in the effect of nethike embrane, simultaneously can overslaugh glaze firing process yet in gas purging, the gas that is produced in the glaze firing process can be drained along the mesh on the nethike embrane.
The chemical composition of nethike embrane mainly is polymethyl methacrylate, dibutyl phthalate, dimethylbenzene, butyl acetate.Polymethyl methacrylate is a kind of thermoplastic resin, its hardness height, and good toughness, not yielding, be coated with the effect that can play skeleton and carrier on the counterdie that is layered on.
The manufacture process of marble paper is to realize like this, comprise the preparation of printing ink, stamp, be coated with the face glued membrane, wherein printing ink is by inorganic pigment, ink oil is formulated, ethene in the ink oil-acetate ethylene copolymer content accounts for 5-20%, dibutyl phthalate content is 1-5%, solvent xylene is 65-94%, vinyl acetate is more than 10% in ethene-acetate ethylene copolymer, ethene-acetate ethylene copolymer MI (melt index (MI)) is more than the 120g/10min, be coated with face glued membrane operation successively by the seal counterdie, seal nethike embrane operation constitutes, the counterdie glue is mainly accounted for ethene-acetate ethylene copolymer of 15-30% by content, content accounts for the dibutyl phthalate of 1-5%, the dimethylbenzene that content accounts for 65-75% constitutes, and the nethike embrane glue is mainly accounted for the polymethyl methacrylate of 20-30% by content, content accounts for the dibutyl phthalate of 2-8%, the solvent that content accounts for 60-75 constitutes.Printing technology is pattern to be printed on the hydrosol face of paper substrate with shining the silk screen that makes pattern with printing-ink, and carry out drying, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, treat with the silk screen that is shaped on net-like pattern the nethike embrane glue to be printed on the counterdie face again after the counterdie glue is dried to counterdie, become marble paper after the drying.
The using method of marble paper be realize like this comprise moulded pottery not yet put in a kiln to bake operation, biscuiting operation, raw glaze blank process, revenue stamp process, its special feature is that revenue stamp process mainly is made of decal paper operation, glaze firing, before the applique, earlier marble paper is soaked in water a period of time, treat with the film of pattern with after paper substrate separates, to the raw glaze base, can carry out klining to the film transfer of having pattern to ceramics.Because stamp and face glued membrane on the marble paper have adopted low-melting binding agent and low-melting film glue respectively, make the incipient stage of glaze firing link agent thawing already before the gas generation in the glaze firing process, make water and organic matter in the glaze firing process can drain the pattern that does not destroy ceramic tile surface swimmingly, thereby realize the purpose of once-firing because of high-temperature evaporation or gas that decomposition produced.
Marble paper of the present invention also can use on the glaze after the glaze firing, if the intensity of moulded pottery not yet put in a kiln to bake is enough, also can directly use after the moulded pottery not yet put in a kiln to bake glazing, and using method is consistent with above-mentioned using method.
Compared with the prior art the present invention can realize the once-firing finished product when producing the stamp pottery with the present invention, and it is simple to have technology when therefore producing the stamp pottery with the present invention, production cost is low, less energy consumption, small investment, manufactured goods can not produce aberration, production efficiency height, the advantage of constant product quality.
Description of drawings:
Fig. 1 is the structural representation of marble paper of the present invention.
The specific embodiment:
Now in conjunction with the embodiments the present invention is done and describes in further detail:
As shown in the figure, marble paper of the present invention comprises and is coated with the paper substrate 2 that is covered with the hydrosol 1, is printed on stamp 3 on 1 of the hydrosol, is printed on the counterdie 4 on the stamp 3, the printing ink that constitutes stamp 3 patterns mainly is made of inorganic pigment, binding agent, it is that a kind of fusing point is higher but be lower than 100 ℃ organic compound than room temperature that its special feature is to link agent, and counterdie 4 is that a kind of fusing point is higher but be lower than 100 ℃ organic compound binder than room temperature.
Here, the binding agent of being adopted is ethene-acetate ethylene copolymer.Also contain dibutyl phthalate in the printing ink, and xylene solvent.
Also be coated with shop one deck nethike embrane 5 on counterdie 4 surfaces.
The manufacture method of marble paper of the present invention is to realize like this, comprise the preparation of printing ink, stamp, be coated with the face glued membrane, wherein printing ink is by inorganic pigment, ink oil is formulated, ethene in the ink oil-acetate ethylene copolymer content accounts for 5-20%, dibutyl phthalate content is 1-5%, solvent xylene is 65-89%, vinyl acetate is more than 50% in ethene-acetate ethylene copolymer, ethene-acetate ethylene copolymer MI (melt index (MI)) is more than the 200g/10min, be coated with face glued membrane operation successively by the seal counterdie, seal nethike embrane operation constitutes, the counterdie glue is mainly accounted for ethene-acetate ethylene copolymer of 24-30% by content, content accounts for the dibutyl phthalate of 1-5%, the dimethylbenzene that content accounts for 65-75% constitutes, and the nethike embrane glue is mainly accounted for the polymethyl methacrylate of 20-30% by content, content accounts for the dibutyl phthalate of 2-8%, content accounts for the dimethylbenzene of 15-25%, the butyl acetate that content accounts for 35-60% constitutes.Printing technology is pattern to be printed on the hydrosol face of paper substrate with shining the silk screen that makes pattern with printing-ink, and carry out drying, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, treat with the silk screen that is shaped on net-like pattern the nethike embrane glue to be printed on the counterdie face again after the counterdie glue is dried to counterdie, become marble paper after the drying.
The using method of marble paper of the present invention be realize like this comprise moulded pottery not yet put in a kiln to bake operation, biscuiting operation, raw glaze blank process, revenue stamp process, its special feature is that revenue stamp process mainly is made of decal paper operation, glaze firing, before the applique, earlier marble paper is soaked in water a period of time, treat with the film of pattern with after paper substrate separates, to the raw glaze base, can carry out klining to the film transfer of having pattern to ceramics.
Here, for applique can be finished smoothly, spraying one deck hydrosol on the glaze of applique is Cai treat applique behind its drying and forming-film.
Claims (11)
1, a kind of ceramic water shifts marble paper, comprise and be coated with the paper substrate that is covered with the hydrosol, be printed on stamp on the hydrosol face, be printed on the face glued membrane on the stamp, the printing ink that constitutes decalcomania mainly is made of inorganic pigment, binding agent, it is higher but be lower than 100 ℃ hot melt organic compound than room temperature to it is characterized in that linking agent and be a kind of fusing point, and counterdie is that a kind of fusing point is higher but be lower than 100 ℃ hot melt organic compound binder than room temperature.
2, ceramic water according to claim 1 shifts marble paper, it is characterized in that the binding agent of being adopted is ethene-acetate ethylene copolymer, also can be ethlyene dichloride-acetate ethylene copolymer.
3, ceramic water according to claim 1 shifts marble paper, and the chemical composition that it is characterized in that counterdie mainly is that fusing point is higher but be lower than 100 ℃ hot melt, film forming organic compound than room temperature.
4, ceramic water according to claim 3 shifts marble paper, it is characterized in that the counterdie chemical composition mainly is ethene-acetate ethylene copolymer.
5, ceramic water according to claim 1 shifts marble paper, it is characterized in that also being coated with on the counterdie surface shop one deck nethike embrane.
6, ceramic water according to claim 1 shifts marble paper, and the chemical composition that it is characterized in that nethike embrane mainly is a polymethyl methacrylate.
7, the manufacture process of ceramic water transfer marble paper is to realize like this, comprise printing ink preparation, stamp, be coated with the face glued membrane, it is characterized in that printing ink is formulated by inorganic pigment, ink oil, ethene in the ink oil-acetate ethylene copolymer content accounts for 5-20%, dibutyl phthalate content is 1-5%, solvent is 65-94%, and vinyl acetate is more than 10% in ethene-acetate ethylene copolymer, and ethene-acetate ethylene copolymer MI (melt index (MI)) is more than the 120g/10min.
8, ceramic water according to claim 7 shifts the manufacture process of marble paper, it is characterized in that being coated with face glued membrane operation successively is made of seal counterdie, seal nethike embrane operation, the counterdie glue mainly by content account for ethene-acetate ethylene copolymer of 15-30%, dibutyl phthalate that content accounts for 1-5%, solvent that content accounts for 65-84% constitutes, the nethike embrane glue mainly accounts for the polymethyl methacrylate of 20-30%, the dibutyl phthalate that content accounts for 2-8%, the solvent that content accounts for 60-75% by content and constitutes.
9, ceramic water according to claim 7 shifts the manufacture process of marble paper, it is characterized in that printing technology is pattern to be printed on the hydrosol face of paper substrate with shining the silk screen that makes pattern with printing-ink, and carry out drying, drawing glued membrane operation is after treating the abundant drying of pattern printing ink, with silk screen the counterdie glue is printed on the pattern, carry out drying then, treat with the silk screen that is shaped on net-like pattern the nethike embrane glue to be printed on the counterdie face again after the counterdie glue is dried to counterdie, become marble paper after the drying.
10, ceramic water shift marble paper using method, comprise moulded pottery not yet put in a kiln to bake operation, biscuiting operation, raw glaze blank process, revenue stamp process, it is characterized in that revenue stamp process mainly is made of decal paper operation, glaze firing, before the applique, earlier marble paper is soaked in water a period of time, treat with the film of pattern to the raw glaze base, can to carry out klining to the film transfer of having pattern to ceramics with after paper substrate separates.
11, ceramic water according to claim 10 shift marble paper using method, it is characterized in that applique before, the water-soluble glue of spraying one deck on the glaze of raw glaze base earlier.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011301015A CN1142067C (en) | 2001-12-14 | 2001-12-14 | Water-transferring patterned paper for ceramics, its making method and its application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011301015A CN1142067C (en) | 2001-12-14 | 2001-12-14 | Water-transferring patterned paper for ceramics, its making method and its application |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1356214A true CN1356214A (en) | 2002-07-03 |
CN1142067C CN1142067C (en) | 2004-03-17 |
Family
ID=4669730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011301015A Expired - Fee Related CN1142067C (en) | 2001-12-14 | 2001-12-14 | Water-transferring patterned paper for ceramics, its making method and its application |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1142067C (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1318695C (en) * | 2005-10-13 | 2007-05-30 | 中国制浆造纸研究院<Del/> | Production method of coated water transferal base paper for water transfer ceramic applique bottom paper |
CN102153904A (en) * | 2011-01-12 | 2011-08-17 | 郑州鸿盛数码科技股份有限公司 | Ceramic transfer digital printing ink-jet ink and using method thereof |
CN102174788A (en) * | 2011-01-01 | 2011-09-07 | 蔡锋盛 | Decal suitable for resin coating and production method and use method thereof |
CN102555564A (en) * | 2012-01-12 | 2012-07-11 | 宗海燕 | Ceramic decal paper printing method by directly unrolling roll paper on multicolor synchronous overprinting line |
CN103465662A (en) * | 2013-08-09 | 2013-12-25 | 上海高诚艺术包装有限公司 | Preparation method of burn-free stained paper |
CN109094278A (en) * | 2018-10-29 | 2018-12-28 | 广东非凡实业有限公司 | The preparation method of ancient painted pottery porcelain utensil is printed under a kind of glaze |
CN110154611A (en) * | 2019-05-28 | 2019-08-23 | 江苏拜富科技有限公司 | A kind of low-temperature nano ceramic water transfer paste marble paper |
CN110382250A (en) * | 2017-03-06 | 2019-10-25 | 雷恩哈德库兹基金两合公司 | For manufacturing the method for stamp, stamp, the equipment for manufacturing stamp and for the method on decorative object surface |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102774160B (en) * | 2012-08-13 | 2015-04-22 | 宁波长青家居用品有限公司 | Method for printing water-absorption cup mat |
-
2001
- 2001-12-14 CN CNB011301015A patent/CN1142067C/en not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1318695C (en) * | 2005-10-13 | 2007-05-30 | 中国制浆造纸研究院<Del/> | Production method of coated water transferal base paper for water transfer ceramic applique bottom paper |
CN102174788A (en) * | 2011-01-01 | 2011-09-07 | 蔡锋盛 | Decal suitable for resin coating and production method and use method thereof |
CN102153904A (en) * | 2011-01-12 | 2011-08-17 | 郑州鸿盛数码科技股份有限公司 | Ceramic transfer digital printing ink-jet ink and using method thereof |
CN102153904B (en) * | 2011-01-12 | 2013-06-19 | 郑州鸿盛数码科技股份有限公司 | Ceramic transfer digital printing ink-jet ink and using method thereof |
CN102555564A (en) * | 2012-01-12 | 2012-07-11 | 宗海燕 | Ceramic decal paper printing method by directly unrolling roll paper on multicolor synchronous overprinting line |
CN103465662A (en) * | 2013-08-09 | 2013-12-25 | 上海高诚艺术包装有限公司 | Preparation method of burn-free stained paper |
CN110382250A (en) * | 2017-03-06 | 2019-10-25 | 雷恩哈德库兹基金两合公司 | For manufacturing the method for stamp, stamp, the equipment for manufacturing stamp and for the method on decorative object surface |
US11124015B2 (en) | 2017-03-06 | 2021-09-21 | Leonhard Kurz Stiftung & Co. Kg | Method for producing a decal, and a decal and a device for producing a decal, and method for decorating surfaces of objects |
CN109094278A (en) * | 2018-10-29 | 2018-12-28 | 广东非凡实业有限公司 | The preparation method of ancient painted pottery porcelain utensil is printed under a kind of glaze |
CN110154611A (en) * | 2019-05-28 | 2019-08-23 | 江苏拜富科技有限公司 | A kind of low-temperature nano ceramic water transfer paste marble paper |
Also Published As
Publication number | Publication date |
---|---|
CN1142067C (en) | 2004-03-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11001534B2 (en) | Semi-transparent ceramic sheet decorated with ink light-absorbance and preparation method thereof | |
CN110746203A (en) | Ceramic product with mold effect texture manufactured by digital process and manufacturing method thereof | |
CN101054043B (en) | Manufacturing technique for stereo porcelain plate painting | |
CN1142067C (en) | Water-transferring patterned paper for ceramics, its making method and its application | |
CN110436936B (en) | Photochromic ceramic tile with decorative patterns and preparation method thereof | |
CN102092229B (en) | Manufacturing process of clay ornaments | |
CN109574632A (en) | A kind of the polychrome Imitation Rock Porcelain Tiles and manufacturing method of substitution mould flower production concave-convex surface effect | |
CN202106699U (en) | Water transfer stained paper of lower temperature sintering ceramic | |
CN104591786A (en) | Manufacturing method of ceramic sheet with infiltration layer | |
CN100581844C (en) | Carved porcelain ware production technique | |
CN100337972C (en) | Process for making a chinaware | |
KR101076168B1 (en) | Ceramic tile using inorganic heat-transfer method and process for preparing the same | |
CN1039843C (en) | Decorative paint paper and its prodn process | |
US2566735A (en) | Decoration of ceramic ware | |
CN1686721A (en) | Manufacturing method of pottary imitation paper bandicraft article | |
CN86105795A (en) | Artistic glazed brick | |
CN1508023A (en) | Micro Crystal galss wall floor brick decorating process and product thereof | |
CN1775709A (en) | Low-temperature underglaze blue colour decorative artistic earthenware and its preparing method | |
CN100423955C (en) | Manufacturing method of decorative artistic pottery ware | |
JP3169581B2 (en) | A method of decorating thick glazing by transferring thick glaze of ceramics, and a thick glazing transfer paper for decorating thick glazing by firing at a temperature of 1000 ° C. to 1200 ° C. or higher. | |
CN110590347B (en) | High-plasticity pug, manufacturing method of ceramic paper-cut/derivative paper and obtained product | |
CN201321700Y (en) | Glazed composite board with rich pattern colors | |
KR20100085585A (en) | Method for transcribing picture on pottery and pottery thereby | |
JP2547132B2 (en) | Method for manufacturing pottery with flow pattern | |
CN113896544B (en) | Granite-like ceramic tile and manufacturing method and application thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |