CN1313554C - 真空成型法层压水性粘合剂组合物及相关的基材和方法 - Google Patents
真空成型法层压水性粘合剂组合物及相关的基材和方法 Download PDFInfo
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- CN1313554C CN1313554C CNB038226391A CN03822639A CN1313554C CN 1313554 C CN1313554 C CN 1313554C CN B038226391 A CNB038226391 A CN B038226391A CN 03822639 A CN03822639 A CN 03822639A CN 1313554 C CN1313554 C CN 1313554C
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- 229920001568 phenolic resin Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229950000244 sulfanilic acid Drugs 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J111/00—Adhesives based on homopolymers or copolymers of chloroprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
- Y10T428/31587—Hydrocarbon polymer [polyethylene, polybutadiene, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
Description
成分 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 |
DISPERCOLLC-741 | 99.83 | 97.03 | 82.19 | 78.06 | 74.43 | 59.63 | 52.28 | - |
DISPERCOLLLS23242 | - | - | - | - | - | - | - | 56.36 |
CP 310W3 | - | - | 17.66 | 16.77 | - | 20.34 | 25.27 | 26.77 |
CYMEL 3034 | - | 2.81 | - | 5.03 | 4.32 | - | 3.79 | 6.02 |
LUPHEND207E5 | - | - | - | - | 19.19 | 18.08 | 16.85 | 8.92 |
XAMA 2206 | - | - | - | - | 0.22 | 0.20 | 0.19 | 0.20 |
UCARLINKXL29SE7 | - | - | - | - | 1.73 | 1.63 | 1.52 | 1.61 |
AKROSPER SEE988 | 0.17 | 0.16 | 0.15 | 0.14 | 0.12 | 0.12 | 0.11 | 0.11 |
剥离试验条件(板) | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 | 实施例7 | 实施例8 | 实施例9* |
初始 | 1.91(4.2) | 3.27(7.2) | 3.78(8.3) | 4.49(9.9)FT | 4.72(10.4)PFT | 5.03(11.1) | 4.17(9.2) | 4.22(9.3)FT | 0.91(2.0) |
24小时 | 0.45(1.0) | 5.35(11.8)PFT | 4.44(9.8) | 5.17(11.4)FT | 3.18(7) | 4.72(10.4) | 7.94(17.5)FT | 4.85(10.7)FT | 0.45(1.0) |
湿度 | 1天,delam. | 1天,delam. | 5小时,delam | 1天,delam. | 1天,delam. | 3.45/1.91(7.6/4.2) | 5.90(13.0)FT,4.72(10.4)FT/5.81(12.8)FT,4.0(8.8) | 5.03(11.1)FT5.40(11.9)FT/4.58(10.1)FT,4.94(10.9)FT | 0.41/0.73(0.9/1.6) |
剥离试验条件(门部件) | |||||||||
湿度 | - | - | - | - | - | - | - | 全部区域FT | - |
热 | - | - | - | - | - | - | - | 全部区域FT | - |
Claims (28)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/226,895 US6939432B2 (en) | 2002-08-23 | 2002-08-23 | Aqueous vacuum forming laminating adhesive composition, substrates and methods related thereto |
US10/226,895 | 2002-08-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1685027A CN1685027A (zh) | 2005-10-19 |
CN1313554C true CN1313554C (zh) | 2007-05-02 |
Family
ID=31887339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038226391A Expired - Lifetime CN1313554C (zh) | 2002-08-23 | 2003-08-20 | 真空成型法层压水性粘合剂组合物及相关的基材和方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US6939432B2 (zh) |
EP (1) | EP1546278B1 (zh) |
KR (1) | KR100623809B1 (zh) |
CN (1) | CN1313554C (zh) |
AT (1) | ATE352598T1 (zh) |
AU (1) | AU2003258294B2 (zh) |
CA (1) | CA2496819C (zh) |
DE (1) | DE60311488T2 (zh) |
ES (1) | ES2279218T3 (zh) |
MX (1) | MXPA05002021A (zh) |
WO (1) | WO2004018585A1 (zh) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004018014A1 (de) * | 2004-04-14 | 2005-11-10 | Basf Coatings Ag | Mindestens drei Komponenten enthaltendes Mehrkomponentensystem, Verfahren zu seiner Herstellung und seine Verwendung |
EP1598382A1 (de) * | 2004-05-17 | 2005-11-23 | Sika Technology AG | Einkomponentiger wässriger Dispersionsklebstoff |
EP1683845B1 (en) * | 2005-01-21 | 2007-02-21 | Advanced Elastomer Systems, L.P. | Aqueous adhesive composition and method of adhering a thermoplastic elastomer to polar substrates |
DE102005055793A1 (de) * | 2005-11-21 | 2007-05-24 | Röhm Gmbh | Transparente TPU (thermoplastische Polyurethane)/ PMMA (Polymethyl(meth)acrylat) Abmischungen mit verbesserter Kältesschlagzähigkeit |
US7858698B2 (en) * | 2006-02-16 | 2010-12-28 | A-Line Products Corporation | Compositions containing functionalized oils and polyolefins |
WO2007112294A1 (en) * | 2006-03-24 | 2007-10-04 | Henkel Corporation | Sprayable water-based adhesive |
US7964662B2 (en) * | 2006-04-27 | 2011-06-21 | Bostik, Inc. | Adhesive formulation for vacuum forming applications |
CN101857697B (zh) * | 2010-06-29 | 2012-06-06 | 上海氯碱化工股份有限公司 | 共混改性氯化聚丙烯及其制备方法 |
CN101974300A (zh) * | 2010-10-28 | 2011-02-16 | 苏州凯康化工科技有限公司 | 一种水性复膜封口胶及其制备方法 |
WO2013093037A1 (de) * | 2011-12-23 | 2013-06-27 | Sika Technology Ag | Einkomponenten-kontaktklebstoff mit verbesserter stabilität |
CN106010310A (zh) * | 2016-07-07 | 2016-10-12 | 阜南县铭钰柳木工艺品有限公司 | 竹编所用竹条防水胶黏剂及其制备方法 |
JP7318347B2 (ja) * | 2018-12-26 | 2023-08-01 | 東ソー株式会社 | ラテックス接着剤組成物 |
IT201800009263A1 (it) * | 2018-10-09 | 2020-04-09 | Lucio Palagano | Sistema di incollaggio della pelle su pc-tablet con colla bicomponente |
CN113004849B (zh) * | 2021-03-02 | 2023-06-27 | 广东普赛达密封粘胶有限公司 | 一种卷材粘结用硅烷改性密封胶及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5385979A (en) * | 1994-01-11 | 1995-01-31 | Lord Corporation | Primer and adhesive compositions based on chlorinated polyolefins having high chlorine contents |
US6310125B1 (en) * | 2000-04-05 | 2001-10-30 | 3M Innovative Properties Company | Water-dispersed adhesive compositions |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4463110A (en) * | 1981-02-24 | 1984-07-31 | National Starch And Chemical Corporation | Neoprene latex contact adhesives |
JPS6296576A (ja) * | 1985-10-24 | 1987-05-06 | Mitsui Toatsu Chem Inc | 接着剤組成物 |
JPH02127491A (ja) * | 1988-11-04 | 1990-05-16 | Dai Ichi Kogyo Seiyaku Co Ltd | 水系接着剤組成物 |
US5430094A (en) * | 1991-07-11 | 1995-07-04 | Ppg Industries, Inc. | Water-based vacuum forming laminating adhesive |
AU8091394A (en) * | 1994-01-13 | 1995-08-01 | Akron Paint And Varnish Co. | Water-based adhesive |
-
2002
- 2002-08-23 US US10/226,895 patent/US6939432B2/en not_active Expired - Lifetime
-
2003
- 2003-08-20 CA CA 2496819 patent/CA2496819C/en not_active Expired - Lifetime
- 2003-08-20 EP EP20030793161 patent/EP1546278B1/en not_active Expired - Lifetime
- 2003-08-20 AT AT03793161T patent/ATE352598T1/de not_active IP Right Cessation
- 2003-08-20 KR KR1020057003066A patent/KR100623809B1/ko not_active IP Right Cessation
- 2003-08-20 ES ES03793161T patent/ES2279218T3/es not_active Expired - Lifetime
- 2003-08-20 CN CNB038226391A patent/CN1313554C/zh not_active Expired - Lifetime
- 2003-08-20 DE DE2003611488 patent/DE60311488T2/de not_active Expired - Lifetime
- 2003-08-20 MX MXPA05002021A patent/MXPA05002021A/es active IP Right Grant
- 2003-08-20 AU AU2003258294A patent/AU2003258294B2/en not_active Ceased
- 2003-08-20 WO PCT/US2003/026044 patent/WO2004018585A1/en active IP Right Grant
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5385979A (en) * | 1994-01-11 | 1995-01-31 | Lord Corporation | Primer and adhesive compositions based on chlorinated polyolefins having high chlorine contents |
US6310125B1 (en) * | 2000-04-05 | 2001-10-30 | 3M Innovative Properties Company | Water-dispersed adhesive compositions |
Also Published As
Publication number | Publication date |
---|---|
EP1546278B1 (en) | 2007-01-24 |
AU2003258294B2 (en) | 2006-09-07 |
ES2279218T3 (es) | 2007-08-16 |
CA2496819A1 (en) | 2004-03-04 |
MXPA05002021A (es) | 2005-06-03 |
CN1685027A (zh) | 2005-10-19 |
AU2003258294A1 (en) | 2004-03-11 |
ATE352598T1 (de) | 2007-02-15 |
DE60311488D1 (de) | 2007-03-15 |
US6939432B2 (en) | 2005-09-06 |
US20040038041A1 (en) | 2004-02-26 |
CA2496819C (en) | 2010-01-12 |
DE60311488T2 (de) | 2007-10-31 |
KR100623809B1 (ko) | 2006-09-13 |
EP1546278A1 (en) | 2005-06-29 |
KR20050058469A (ko) | 2005-06-16 |
WO2004018585A1 (en) | 2004-03-04 |
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