CN1300197C - 可水解交联氯乙烯/硅烷共聚树脂的制备方法 - Google Patents
可水解交联氯乙烯/硅烷共聚树脂的制备方法 Download PDFInfo
- Publication number
- CN1300197C CN1300197C CNB200510049879XA CN200510049879A CN1300197C CN 1300197 C CN1300197 C CN 1300197C CN B200510049879X A CNB200510049879X A CN B200510049879XA CN 200510049879 A CN200510049879 A CN 200510049879A CN 1300197 C CN1300197 C CN 1300197C
- Authority
- CN
- China
- Prior art keywords
- silane
- vinylchlorid
- vinyl chloride
- silicane
- copolymer resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 96
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title claims abstract description 85
- 229920006026 co-polymeric resin Polymers 0.000 title claims abstract description 62
- 230000007062 hydrolysis Effects 0.000 title claims abstract description 19
- 238000006460 hydrolysis reaction Methods 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title description 3
- 229910000077 silane Inorganic materials 0.000 claims abstract description 68
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 54
- 239000000178 monomer Substances 0.000 claims abstract description 47
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 238000007599 discharging Methods 0.000 claims abstract description 27
- 238000001914 filtration Methods 0.000 claims abstract description 27
- 238000003756 stirring Methods 0.000 claims abstract description 27
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 9
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 9
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 39
- -1 acryloxy propyl group Chemical group 0.000 claims description 31
- 238000001035 drying Methods 0.000 claims description 26
- 238000010792 warming Methods 0.000 claims description 26
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 22
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 22
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 claims description 12
- 239000003999 initiator Substances 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 9
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 8
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 8
- 235000019800 disodium phosphate Nutrition 0.000 claims description 8
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000005502 peroxidation Methods 0.000 claims description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 239000001856 Ethyl cellulose Substances 0.000 claims description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- 229920001249 ethyl cellulose Polymers 0.000 claims description 4
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 4
- 239000001923 methylcellulose Substances 0.000 claims description 4
- 229940045641 monobasic sodium phosphate Drugs 0.000 claims description 4
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 4
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 3
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 3
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N isopropyl-benzene Natural products CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 2
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical group CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 40
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 35
- 239000008367 deionised water Substances 0.000 abstract description 27
- 229910021641 deionized water Inorganic materials 0.000 abstract description 27
- 238000000034 method Methods 0.000 abstract description 23
- 238000012545 processing Methods 0.000 abstract description 16
- 229920005989 resin Polymers 0.000 abstract description 15
- 239000011347 resin Substances 0.000 abstract description 15
- 230000003301 hydrolyzing effect Effects 0.000 abstract description 13
- 238000007334 copolymerization reaction Methods 0.000 abstract description 6
- 239000000725 suspension Substances 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 description 29
- 238000001816 cooling Methods 0.000 description 23
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 11
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 6
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 5
- 235000017557 sodium bicarbonate Nutrition 0.000 description 5
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229920003020 cross-linked polyethylene Polymers 0.000 description 2
- 239000004703 cross-linked polyethylene Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 description 2
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 2
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000021050 feed intake Nutrition 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- DWUCCPNOMFYDOL-UHFFFAOYSA-N propyl(sulfanyl)silicon Chemical compound CCC[Si]S DWUCCPNOMFYDOL-UHFFFAOYSA-N 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
样品 | 树脂凝胶含量,% | 加工后大气中放置后凝胶含量,% | 热水浴中放置后凝胶含量,% |
实施例1 | 2.1 | 15.9 | 20.1 |
实施例2 | 2.2 | 22.2 | 25.1 |
实施例3 | 2.77 | 26.0 | 30.5 |
实施例4 | 3.94 | 32.6 | 37.3 |
实施例5 | 0.78 | 2.6 | 3.1 |
实施例6 | 1.55 | 3.1 | 3.6 |
实施例7 | 1.79 | 26.0 | 30.4 |
实施例8 | 1.84 | 33.2 | 36.1 |
实施例9 | 1.95 | 56.0 | 60.8 |
实施例10 | 3.02 | 75.9 | 87.2 |
实施例11 | 1.85 | 25.5 | 34.7 |
实施例12 | 1.82 | 23.2 | 29.5 |
实施例13 | 1.91 | 25.1 | 30.6 |
实施例14 | 1.87 | 24.5 | 30.1 |
实施例15 | 2.12 | 24.8 | 29.5 |
实施例16 | 2.89 | 10.9 | 22.5 |
实施例17 | 1.21 | 54.5 | 61.2 |
实施例18 | 0.75 | 55.3 | 61.3 |
实施例19 | 0.25 | 55.1 | 63.9 |
实施例20 | 0.05 | 55.0 | 64.5 |
比较例1 | 0 | 0 | 0 |
比较例2 | 40.7 | 43.2 | 45.5 |
比较例3 | 79.8(难加工) | -- | -- |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB200510049879XA CN1300197C (zh) | 2005-05-30 | 2005-05-30 | 可水解交联氯乙烯/硅烷共聚树脂的制备方法 |
Applications Claiming Priority (1)
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CNB200510049879XA CN1300197C (zh) | 2005-05-30 | 2005-05-30 | 可水解交联氯乙烯/硅烷共聚树脂的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1699435A CN1699435A (zh) | 2005-11-23 |
CN1300197C true CN1300197C (zh) | 2007-02-14 |
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CNB200510049879XA Expired - Fee Related CN1300197C (zh) | 2005-05-30 | 2005-05-30 | 可水解交联氯乙烯/硅烷共聚树脂的制备方法 |
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CN (1) | CN1300197C (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108752515A (zh) * | 2018-06-21 | 2018-11-06 | 江苏新汇烽塑胶有限公司 | 一种高强度聚氯乙烯树脂及其制备方法 |
CN111378238A (zh) * | 2020-04-29 | 2020-07-07 | 青岛鸿志道防水工程技术有限责任公司 | 抗老化防水卷材及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1045268A (zh) * | 1989-02-08 | 1990-09-12 | 挪威海德罗公司 | 一种热稳定交联含卤聚合物的制备方法 |
JPH10298381A (ja) * | 1997-04-24 | 1998-11-10 | Yazaki Corp | 架橋性塩化ビニル樹脂組成物及びその製造法 |
-
2005
- 2005-05-30 CN CNB200510049879XA patent/CN1300197C/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1045268A (zh) * | 1989-02-08 | 1990-09-12 | 挪威海德罗公司 | 一种热稳定交联含卤聚合物的制备方法 |
JPH10298381A (ja) * | 1997-04-24 | 1998-11-10 | Yazaki Corp | 架橋性塩化ビニル樹脂組成物及びその製造法 |
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CN1699435A (zh) | 2005-11-23 |
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Assignee: Deqing County Sanxing Plastics Chemical Co., Ltd. Assignor: Zhejiang University Contract fulfillment period: 2009.7.15 to 2014.7.15 contract change Contract record no.: 2009330001706 Denomination of invention: Process for preparing hydrolysis crosslinkable vinyl chloride / silicane copolymer resin Granted publication date: 20070214 License type: Exclusive license Record date: 2009.7.27 |
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Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.7.15 TO 2014.7.15; CHANGE OF CONTRACT Name of requester: DEQING COUNTY SANXING PLASTICS CHEMICAL INDUSTRY C Effective date: 20090727 |
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