CN1274391A - 特别适用于汽车应用的、新的可焊、耐腐蚀、高镁含量的铝-镁合金 - Google Patents
特别适用于汽车应用的、新的可焊、耐腐蚀、高镁含量的铝-镁合金 Download PDFInfo
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- CN1274391A CN1274391A CN99801195A CN99801195A CN1274391A CN 1274391 A CN1274391 A CN 1274391A CN 99801195 A CN99801195 A CN 99801195A CN 99801195 A CN99801195 A CN 99801195A CN 1274391 A CN1274391 A CN 1274391A
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- Prior art keywords
- aluminium
- weight
- magnesium
- scandium
- magnesium alloy
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Powder Metallurgy (AREA)
- Prevention Of Electric Corrosion (AREA)
- Arc Welding In General (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Extrusion Of Metal (AREA)
- Conductive Materials (AREA)
- Forging (AREA)
Abstract
可焊、高镁含量的铝—镁合金,由至少5—6重量%镁(Mg)、0.05—1.5重量%锆(Zr)、0.7—1重量%锰(Mn)、0.01—0.2重量%钛(Ti)、至少0.005重量%铈(Ce)、0.05—0.5重量%一种或多种钪族元素和/或铽(Tb),其中至少含有钪、以及铝和不可避免的杂质,杂质中至多有0.2重量%硅(Si)。
Description
本发明涉及一种可焊、耐腐蚀、高镁含量的铝-镁合金,它含有一种三元铝-钪-锆相作为基本成分。这种合金已于例如US 5,624,632中已知,且由于它的低密度、高强度和耐腐蚀而首先用于航空应用中。加入稀土或类似稀土元素能在该铝-镁合金中产生弥散体,按上述US专利,这种弥散体产生较高的强度和耐腐蚀性。上述US专利来叙及这种合金的可焊接性。
本发明的目的是提供一种可焊、耐腐蚀、高镁含量的铝-镁合金,其强度和耐腐蚀性至少与所说已知合金一样好,并显示了一种高的再结晶临界值,这导致好的可焊接性。该目的可按权利要求1的铝-镁合金达到。
由于该合金的可焊接性和强度,它特别适用于制造汽车车体,且相比于已知的合金还添加了钛和铈。当一种合金的锰对钪之比<2时,它具有特别好的耐腐蚀性。不同于已知合金含有的钛含量还起着组织颗粒细化剂和提高强度的作用,因为钛可替代在三元Al-Sc-Zr相中的锆,其中钛的可溶性低于锆的,添加铈同样起着提高强度和进一步提高伸展极限及导致热稳定性的效果。
现已证明,至少在某种限度内钪可被铽替代。但是必须加入比被替代的钪量更多的铽,以获得不变的性能。
一种特别牢固的和耐腐蚀的合金含有至少0.15重量%钪。优选加入0.05-0.35重量%的镧系元素(Lanthaniden),该含量范围是针对使用一种镧系混合物时的混合物总重量而言的。该合金承受至多0.2重量%的硅杂质;初步地说,高于这个含量水平则损伤合金的动力性能。
Claims (5)
1.可焊、高镁含量的铝-镁合金,由至少5-6重量%镁(Mg)、0.05-0.15重量%锆(Zr)、0.7-1重量%锰(Mn)、0.01-0.2重量%钛(Ti)、至少0.005重量%铈(Ce)、0.05-0.5重量%一种或多种钪族元素和/或铽(Tb),其中至少含有钪、以及铝和不可避免的杂质,杂质中至多有0.2重量%硅(Si)。
2.按权利要求1的铝-镁合金,其特征在于,锰与钪的含量比小于2。
3.按权利要求1的铝-镁合金,其特征在于,含有至少0.15重量%钪(Sc)。
4.按权利要求1或2的铝-镁合金,其特征在于,含有0.05-0.45重量%的一种或多种镧系元素、尤其是铈(Ce)、钕(Nd)、铕(Eu)、钆(Gd)、镝(Dy)、钬(Ho)或铒(Er)。
5.用于汽车制造的、轧制的、挤压的、焊接的或锻造的构件,由按权利要求1-3中之一的铝-镁合金组成。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19838015.1 | 1998-08-21 | ||
DE19838015A DE19838015C2 (de) | 1998-08-21 | 1998-08-21 | Gewalztes, stranggepreßtes, geschweißtes oder geschmiedetes Bauteil aus einer schweißbaren, korrosionsbeständigen hochmagnesiumhaltigen Aluminium-Magnesium-Legierung |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1274391A true CN1274391A (zh) | 2000-11-22 |
CN1107120C CN1107120C (zh) | 2003-04-30 |
Family
ID=7878284
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN99801195A Expired - Lifetime CN1107120C (zh) | 1998-08-21 | 1999-08-10 | 特别适用于汽车应用的、新的可焊、耐腐蚀、高镁含量的铝-镁合金 |
Country Status (10)
Country | Link |
---|---|
US (1) | US6315948B1 (zh) |
EP (1) | EP1025270B1 (zh) |
JP (1) | JP2002523621A (zh) |
CN (1) | CN1107120C (zh) |
AT (1) | ATE216735T1 (zh) |
CA (1) | CA2306726C (zh) |
DE (2) | DE19838015C2 (zh) |
ES (1) | ES2173759T3 (zh) |
RU (1) | RU2226567C2 (zh) |
WO (1) | WO2000011231A1 (zh) |
Cited By (1)
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CN102699564A (zh) * | 2012-04-27 | 2012-10-03 | 浙江宇光铝材有限公司 | 高性能铝合金自动焊丝 |
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DE10248594B4 (de) * | 2001-12-14 | 2006-04-27 | Eads Deutschland Gmbh | Verfahren zum Herstellen eines Scandium (Sc)- legierten Aluminiumblechmaterials mit hoher Risszähigkeit |
US20040156739A1 (en) | 2002-02-01 | 2004-08-12 | Song Shihong Gary | Castable high temperature aluminum alloy |
AT501867B1 (de) * | 2005-05-19 | 2009-07-15 | Aluminium Lend Gmbh & Co Kg | Aluminiumlegierung |
US7875132B2 (en) * | 2005-05-31 | 2011-01-25 | United Technologies Corporation | High temperature aluminum alloys |
US7584778B2 (en) * | 2005-09-21 | 2009-09-08 | United Technologies Corporation | Method of producing a castable high temperature aluminum alloy by controlled solidification |
CN100445019C (zh) * | 2006-09-14 | 2008-12-24 | 中国航空工业第一集团公司北京航空材料研究院 | Al-Mg-Sc系焊丝 |
WO2009062866A1 (en) | 2007-11-15 | 2009-05-22 | Aleris Aluminum Koblenz Gmbh | Al-mg-zn wrought alloy product and method of its manufacture |
US7875133B2 (en) | 2008-04-18 | 2011-01-25 | United Technologies Corporation | Heat treatable L12 aluminum alloys |
US8409373B2 (en) * | 2008-04-18 | 2013-04-02 | United Technologies Corporation | L12 aluminum alloys with bimodal and trimodal distribution |
US8002912B2 (en) * | 2008-04-18 | 2011-08-23 | United Technologies Corporation | High strength L12 aluminum alloys |
US7811395B2 (en) * | 2008-04-18 | 2010-10-12 | United Technologies Corporation | High strength L12 aluminum alloys |
US7875131B2 (en) * | 2008-04-18 | 2011-01-25 | United Technologies Corporation | L12 strengthened amorphous aluminum alloys |
US20090263273A1 (en) * | 2008-04-18 | 2009-10-22 | United Technologies Corporation | High strength L12 aluminum alloys |
US8017072B2 (en) * | 2008-04-18 | 2011-09-13 | United Technologies Corporation | Dispersion strengthened L12 aluminum alloys |
US20090260724A1 (en) * | 2008-04-18 | 2009-10-22 | United Technologies Corporation | Heat treatable L12 aluminum alloys |
US7879162B2 (en) * | 2008-04-18 | 2011-02-01 | United Technologies Corporation | High strength aluminum alloys with L12 precipitates |
US7871477B2 (en) * | 2008-04-18 | 2011-01-18 | United Technologies Corporation | High strength L12 aluminum alloys |
US8778098B2 (en) * | 2008-12-09 | 2014-07-15 | United Technologies Corporation | Method for producing high strength aluminum alloy powder containing L12 intermetallic dispersoids |
US8778099B2 (en) * | 2008-12-09 | 2014-07-15 | United Technologies Corporation | Conversion process for heat treatable L12 aluminum alloys |
US20100143177A1 (en) * | 2008-12-09 | 2010-06-10 | United Technologies Corporation | Method for forming high strength aluminum alloys containing L12 intermetallic dispersoids |
US20100226817A1 (en) * | 2009-03-05 | 2010-09-09 | United Technologies Corporation | High strength l12 aluminum alloys produced by cryomilling |
US20100252148A1 (en) * | 2009-04-07 | 2010-10-07 | United Technologies Corporation | Heat treatable l12 aluminum alloys |
US20100254850A1 (en) * | 2009-04-07 | 2010-10-07 | United Technologies Corporation | Ceracon forging of l12 aluminum alloys |
US9611522B2 (en) * | 2009-05-06 | 2017-04-04 | United Technologies Corporation | Spray deposition of L12 aluminum alloys |
US9127334B2 (en) * | 2009-05-07 | 2015-09-08 | United Technologies Corporation | Direct forging and rolling of L12 aluminum alloys for armor applications |
DE102010020268A1 (de) | 2009-05-12 | 2010-11-18 | Aleris Aluminum Duffel Bvba | Aluminium-Magnesium-Legierungsprodukt für geformte Autmobilteile |
US20110044844A1 (en) * | 2009-08-19 | 2011-02-24 | United Technologies Corporation | Hot compaction and extrusion of l12 aluminum alloys |
US8728389B2 (en) * | 2009-09-01 | 2014-05-20 | United Technologies Corporation | Fabrication of L12 aluminum alloy tanks and other vessels by roll forming, spin forming, and friction stir welding |
US8409496B2 (en) * | 2009-09-14 | 2013-04-02 | United Technologies Corporation | Superplastic forming high strength L12 aluminum alloys |
US20110064599A1 (en) * | 2009-09-15 | 2011-03-17 | United Technologies Corporation | Direct extrusion of shapes with l12 aluminum alloys |
US9194027B2 (en) * | 2009-10-14 | 2015-11-24 | United Technologies Corporation | Method of forming high strength aluminum alloy parts containing L12 intermetallic dispersoids by ring rolling |
US20110091345A1 (en) * | 2009-10-16 | 2011-04-21 | United Technologies Corporation | Method for fabrication of tubes using rolling and extrusion |
US20110091346A1 (en) * | 2009-10-16 | 2011-04-21 | United Technologies Corporation | Forging deformation of L12 aluminum alloys |
US8409497B2 (en) * | 2009-10-16 | 2013-04-02 | United Technologies Corporation | Hot and cold rolling high strength L12 aluminum alloys |
AU2016218269B2 (en) | 2015-02-11 | 2019-10-03 | Scandium International Mining Corporation | Scandium-containing master alloys and methods for making the same |
CN105499832A (zh) * | 2016-01-28 | 2016-04-20 | 东北大学 | 一种铝镁铈焊丝及其制备方法 |
CN106624428A (zh) * | 2016-12-16 | 2017-05-10 | 吴中区穹窿山天仲高分子材料技术研究所 | 一种环保型焊接合金材料及其制备方法 |
CN107363122B (zh) * | 2017-06-14 | 2018-12-14 | 飞龙精工科技(苏州)有限公司 | 铝镁合金丝的制备工艺 |
RU2663446C1 (ru) * | 2017-12-06 | 2018-08-06 | Общество с ограниченной ответственностью "Опытный завод "Авиаль" (ООО "ОЗА") | Сплав на основе алюминия для сварочной проволоки |
CN111378878B (zh) * | 2018-12-29 | 2021-10-26 | 嘉丰工业科技(惠州)有限公司 | 一种高延展性非热处理压铸铝合金及其制备方法 |
CN110029252B (zh) * | 2019-04-12 | 2021-08-24 | 范卫忠 | 一种5g手机中板用高强高韧抗氧化铝镁合金材料及其制备方法 |
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1998
- 1998-08-21 DE DE19838015A patent/DE19838015C2/de not_active Expired - Fee Related
-
1999
- 1999-08-10 WO PCT/DE1999/002491 patent/WO2000011231A1/de active IP Right Grant
- 1999-08-10 RU RU2000112645/02A patent/RU2226567C2/ru not_active IP Right Cessation
- 1999-08-10 JP JP2000566481A patent/JP2002523621A/ja active Pending
- 1999-08-10 CA CA002306726A patent/CA2306726C/en not_active Expired - Lifetime
- 1999-08-10 CN CN99801195A patent/CN1107120C/zh not_active Expired - Lifetime
- 1999-08-10 EP EP99952346A patent/EP1025270B1/de not_active Expired - Lifetime
- 1999-08-10 AT AT99952346T patent/ATE216735T1/de active
- 1999-08-10 DE DE59901293T patent/DE59901293D1/de not_active Expired - Lifetime
- 1999-08-10 ES ES99952346T patent/ES2173759T3/es not_active Expired - Lifetime
- 1999-08-10 US US09/530,067 patent/US6315948B1/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102699564A (zh) * | 2012-04-27 | 2012-10-03 | 浙江宇光铝材有限公司 | 高性能铝合金自动焊丝 |
CN102699564B (zh) * | 2012-04-27 | 2015-04-22 | 浙江宇光铝材有限公司 | 铝合金自动焊丝 |
Also Published As
Publication number | Publication date |
---|---|
CA2306726C (en) | 2008-07-29 |
US6315948B1 (en) | 2001-11-13 |
DE19838015C2 (de) | 2002-10-17 |
EP1025270B1 (de) | 2002-04-24 |
EP1025270A1 (de) | 2000-08-09 |
CA2306726A1 (en) | 2000-03-02 |
ES2173759T3 (es) | 2002-10-16 |
RU2226567C2 (ru) | 2004-04-10 |
WO2000011231A1 (de) | 2000-03-02 |
ATE216735T1 (de) | 2002-05-15 |
JP2002523621A (ja) | 2002-07-30 |
DE59901293D1 (de) | 2002-05-29 |
DE19838015A1 (de) | 2000-03-02 |
CN1107120C (zh) | 2003-04-30 |
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