CN1268705C - 防粘包装材料在化学品及食品包装上的应用 - Google Patents
防粘包装材料在化学品及食品包装上的应用 Download PDFInfo
- Publication number
- CN1268705C CN1268705C CNB038032597A CN03803259A CN1268705C CN 1268705 C CN1268705 C CN 1268705C CN B038032597 A CNB038032597 A CN B038032597A CN 03803259 A CN03803259 A CN 03803259A CN 1268705 C CN1268705 C CN 1268705C
- Authority
- CN
- China
- Prior art keywords
- ester
- acid
- weight
- purposes
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000126 substance Substances 0.000 title claims abstract description 59
- 235000013305 food Nutrition 0.000 title claims abstract description 25
- 239000005022 packaging material Substances 0.000 title abstract description 8
- 230000000181 anti-adherent effect Effects 0.000 title abstract 2
- 238000004806 packaging method and process Methods 0.000 title abstract 2
- -1 scents Substances 0.000 claims abstract description 145
- 239000000203 mixture Substances 0.000 claims abstract description 99
- 238000002360 preparation method Methods 0.000 claims abstract description 22
- 239000012847 fine chemical Substances 0.000 claims abstract description 21
- 229940088594 vitamin Drugs 0.000 claims abstract description 14
- 239000011782 vitamin Substances 0.000 claims abstract description 14
- 238000009472 formulation Methods 0.000 claims abstract description 13
- 229930003231 vitamin Natural products 0.000 claims abstract description 13
- 235000013343 vitamin Nutrition 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims description 103
- 239000000463 material Substances 0.000 claims description 67
- 239000000654 additive Substances 0.000 claims description 60
- 150000001875 compounds Chemical class 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 34
- 239000008199 coating composition Substances 0.000 claims description 34
- 238000000465 moulding Methods 0.000 claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims description 32
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 30
- 238000006116 polymerization reaction Methods 0.000 claims description 30
- 150000002148 esters Chemical class 0.000 claims description 26
- 239000004593 Epoxy Substances 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 23
- 229920005989 resin Polymers 0.000 claims description 23
- 239000011347 resin Substances 0.000 claims description 23
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 22
- 229910052799 carbon Inorganic materials 0.000 claims description 19
- 239000003921 oil Substances 0.000 claims description 19
- 230000000996 additive effect Effects 0.000 claims description 18
- XEKOWRVHYACXOJ-UHFFFAOYSA-N ethyl acetate Substances CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 17
- 235000019198 oils Nutrition 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 238000007342 radical addition reaction Methods 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 238000012856 packing Methods 0.000 claims description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 13
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 12
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 12
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 claims description 11
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 10
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 10
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 10
- 239000003814 drug Substances 0.000 claims description 9
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 8
- 125000002723 alicyclic group Chemical group 0.000 claims description 8
- OZJPLYNZGCXSJM-UHFFFAOYSA-N delta-Valerolactone Natural products O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 claims description 8
- 229920000728 polyester Polymers 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 229920002223 polystyrene Polymers 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 8
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 7
- 229940079593 drug Drugs 0.000 claims description 7
- 239000002304 perfume Substances 0.000 claims description 7
- 125000006850 spacer group Chemical group 0.000 claims description 7
- 235000013311 vegetables Nutrition 0.000 claims description 7
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 6
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 6
- 229920001971 elastomer Polymers 0.000 claims description 6
- 229920001568 phenolic resin Polymers 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 235000013599 spices Nutrition 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 125000005907 alkyl ester group Chemical group 0.000 claims description 5
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 235000013336 milk Nutrition 0.000 claims description 5
- 239000008267 milk Substances 0.000 claims description 5
- 210000004080 milk Anatomy 0.000 claims description 5
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 5
- 239000005056 polyisocyanate Substances 0.000 claims description 5
- 229920001228 polyisocyanate Polymers 0.000 claims description 5
- 229920006305 unsaturated polyester Polymers 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 claims description 4
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004278 EU approved seasoning Substances 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910018540 Si C Inorganic materials 0.000 claims description 4
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims description 4
- 229940081735 acetylcellulose Drugs 0.000 claims description 4
- 239000003905 agrochemical Substances 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 229920002301 cellulose acetate Polymers 0.000 claims description 4
- 229960000735 docosanol Drugs 0.000 claims description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosanyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 4
- 235000011194 food seasoning agent Nutrition 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000000543 intermediate Substances 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 4
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 4
- 229920001567 vinyl ester resin Polymers 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims description 3
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- FTQKXCIZKBFTCH-UHFFFAOYSA-N CN=C=O.CC(C(=O)O)=C Chemical compound CN=C=O.CC(C(=O)O)=C FTQKXCIZKBFTCH-UHFFFAOYSA-N 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- 239000002537 cosmetic Substances 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims description 3
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 2
- SKYXLDSRLNRAPS-UHFFFAOYSA-N 1,2,4-trifluoro-5-methoxybenzene Chemical compound COC1=CC(F)=C(F)C=C1F SKYXLDSRLNRAPS-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- GBPYQWNNRUXTOF-UHFFFAOYSA-N C(C1CO1)[O].CC(C(=O)O)=C Chemical compound C(C1CO1)[O].CC(C(=O)O)=C GBPYQWNNRUXTOF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004801 Chlorinated PVC Substances 0.000 claims description 2
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 2
- 239000004812 Fluorinated ethylene propylene Substances 0.000 claims description 2
- 235000021559 Fruit Juice Concentrate Nutrition 0.000 claims description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 2
- 239000000020 Nitrocellulose Substances 0.000 claims description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- IAXXETNIOYFMLW-COPLHBTASA-N [(1s,3s,4s)-4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate Chemical compound C1C[C@]2(C)[C@@H](OC(=O)C(=C)C)C[C@H]1C2(C)C IAXXETNIOYFMLW-COPLHBTASA-N 0.000 claims description 2
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 claims description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 2
- LCJHLOJKAAQLQW-UHFFFAOYSA-N acetic acid;ethane Chemical compound CC.CC(O)=O LCJHLOJKAAQLQW-UHFFFAOYSA-N 0.000 claims description 2
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims description 2
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 claims description 2
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 2
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 claims description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 2
- CCGKOQOJPYTBIH-UHFFFAOYSA-N ethenone Chemical compound C=C=O CCGKOQOJPYTBIH-UHFFFAOYSA-N 0.000 claims description 2
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- 235000015203 fruit juice Nutrition 0.000 claims description 2
- 235000012907 honey Nutrition 0.000 claims description 2
- 229940119545 isobornyl methacrylate Drugs 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 2
- 229920001220 nitrocellulos Polymers 0.000 claims description 2
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229920009441 perflouroethylene propylene Polymers 0.000 claims description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 2
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 235000014347 soups Nutrition 0.000 claims description 2
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 claims description 2
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 claims description 2
- 235000020357 syrup Nutrition 0.000 claims description 2
- 239000006188 syrup Substances 0.000 claims description 2
- 125000002769 thiazolinyl group Chemical group 0.000 claims description 2
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 2
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 1
- 235000021466 carotenoid Nutrition 0.000 abstract description 3
- 150000001747 carotenoids Chemical class 0.000 abstract description 3
- 239000003205 fragrance Substances 0.000 abstract 1
- 239000002585 base Substances 0.000 description 34
- 239000004922 lacquer Substances 0.000 description 31
- 238000000576 coating method Methods 0.000 description 29
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 26
- 239000011248 coating agent Substances 0.000 description 26
- 229920003987 resole Polymers 0.000 description 26
- 238000000034 method Methods 0.000 description 22
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 21
- 239000000243 solution Substances 0.000 description 18
- 239000000178 monomer Substances 0.000 description 17
- 239000000049 pigment Substances 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 16
- 239000002966 varnish Substances 0.000 description 15
- 239000002519 antifouling agent Substances 0.000 description 14
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000003973 paint Substances 0.000 description 13
- VYGQUTWHTHXGQB-FFHKNEKCSA-N Retinol Palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C VYGQUTWHTHXGQB-FFHKNEKCSA-N 0.000 description 12
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 12
- 239000000499 gel Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 239000006185 dispersion Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 150000002924 oxiranes Chemical group 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 10
- 230000004048 modification Effects 0.000 description 9
- 238000012986 modification Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 239000012752 auxiliary agent Substances 0.000 description 8
- 229940043232 butyl acetate Drugs 0.000 description 8
- 238000004821 distillation Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 8
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 239000003999 initiator Substances 0.000 description 8
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 7
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 7
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 7
- 150000003863 ammonium salts Chemical class 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 7
- ZAKOWWREFLAJOT-UHFFFAOYSA-N d-alpha-Tocopheryl acetate Natural products CC(=O)OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000037452 priming Effects 0.000 description 7
- 229940042585 tocopherol acetate Drugs 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- VYGQUTWHTHXGQB-UHFFFAOYSA-N Retinol hexadecanoate Natural products CCCCCCCCCCCCCCCC(=O)OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C VYGQUTWHTHXGQB-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 235000013824 polyphenols Nutrition 0.000 description 6
- 229940108325 retinyl palmitate Drugs 0.000 description 6
- 235000019172 retinyl palmitate Nutrition 0.000 description 6
- 239000011769 retinyl palmitate Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000011719 vitamin A Substances 0.000 description 6
- 229940045997 vitamin a Drugs 0.000 description 6
- QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 5
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 5
- 241001233988 Erysimum cheiri Species 0.000 description 5
- 238000005481 NMR spectroscopy Methods 0.000 description 5
- 240000007817 Olea europaea Species 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 5
- 150000008065 acid anhydrides Chemical class 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- 235000019439 ethyl acetate Nutrition 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 5
- 235000019155 vitamin A Nutrition 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 description 4
- 229920002125 Sokalan® Polymers 0.000 description 4
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 235000008504 concentrate Nutrition 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 4
- 239000001530 fumaric acid Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 4
- 238000005502 peroxidation Methods 0.000 description 4
- 239000005011 phenolic resin Substances 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 150000003254 radicals Chemical class 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 3
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 3
- 239000004640 Melamine resin Substances 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 229930003427 Vitamin E Natural products 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 238000012644 addition polymerization Methods 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000005233 alkylalcohol group Chemical group 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 3
- 238000001311 chemical methods and process Methods 0.000 description 3
- 238000004581 coalescence Methods 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- 125000004386 diacrylate group Chemical group 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 3
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 3
- 238000003847 radiation curing Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000012966 redox initiator Substances 0.000 description 3
- 238000007761 roller coating Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 229940046009 vitamin E Drugs 0.000 description 3
- 235000019165 vitamin E Nutrition 0.000 description 3
- 239000011709 vitamin E Substances 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- YGHRJJRRZDOVPD-UHFFFAOYSA-N 3-methylbutanal Chemical compound CC(C)CC=O YGHRJJRRZDOVPD-UHFFFAOYSA-N 0.000 description 2
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 2
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 2
- 239000005792 Geraniol Substances 0.000 description 2
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- REFJWTPEDVJJIY-UHFFFAOYSA-N Quercetin Chemical compound C=1C(O)=CC(O)=C(C(C=2O)=O)C=1OC=2C1=CC=C(O)C(O)=C1 REFJWTPEDVJJIY-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- MUMGGOZAMZWBJJ-DYKIIFRCSA-N Testostosterone Chemical compound O=C1CC[C@]2(C)[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 MUMGGOZAMZWBJJ-DYKIIFRCSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GYDJEQRTZSCIOI-UHFFFAOYSA-N Tranexamic acid Chemical compound NCC1CCC(C(O)=O)CC1 GYDJEQRTZSCIOI-UHFFFAOYSA-N 0.000 description 2
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000004973 alkali metal peroxides Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000012874 anionic emulsifier Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- ZPUCINDJVBIVPJ-LJISPDSOSA-N ***e Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000005007 epoxy-phenolic resin Substances 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000007701 flash-distillation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229940113087 geraniol Drugs 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N glutaric acid Chemical compound OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 2
- 239000012948 isocyanate Substances 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N itaconic acid Chemical compound OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- YNBADRVTZLEFNH-UHFFFAOYSA-N methyl nicotinate Chemical compound COC(=O)C1=CC=CN=C1 YNBADRVTZLEFNH-UHFFFAOYSA-N 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- NBFQYHKHPBMJJV-UHFFFAOYSA-N risocaine Chemical compound CCCOC(=O)C1=CC=C(N)C=C1 NBFQYHKHPBMJJV-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- ULSUXBXHSYSGDT-UHFFFAOYSA-N tangeretin Chemical compound C1=CC(OC)=CC=C1C1=CC(=O)C2=C(OC)C(OC)=C(OC)C(OC)=C2O1 ULSUXBXHSYSGDT-UHFFFAOYSA-N 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 229960001295 tocopherol Drugs 0.000 description 2
- 239000011732 tocopherol Substances 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 239000000273 veterinary drug Substances 0.000 description 2
- 239000004034 viscosity adjusting agent Substances 0.000 description 2
- 239000011647 vitamin D3 Substances 0.000 description 2
- 235000005282 vitamin D3 Nutrition 0.000 description 2
- QYSXJUFSXHHAJI-YRZJJWOYSA-N vitamin D3 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-YRZJJWOYSA-N 0.000 description 2
- 229940021056 vitamin d3 Drugs 0.000 description 2
- HSYFJDYGOJKZCL-UHFFFAOYSA-L zinc;sulfite Chemical compound [Zn+2].[O-]S([O-])=O HSYFJDYGOJKZCL-UHFFFAOYSA-L 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 description 2
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 description 1
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 description 1
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- CEMAWMOMDPGJMB-UHFFFAOYSA-N (+-)-Oxprenolol Chemical compound CC(C)NCC(O)COC1=CC=CC=C1OCC=C CEMAWMOMDPGJMB-UHFFFAOYSA-N 0.000 description 1
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- QDGIAPPCJRFVEK-UHFFFAOYSA-N (1-methylpiperidin-4-yl) 2,2-bis(4-chlorophenoxy)acetate Chemical compound C1CN(C)CCC1OC(=O)C(OC=1C=CC(Cl)=CC=1)OC1=CC=C(Cl)C=C1 QDGIAPPCJRFVEK-UHFFFAOYSA-N 0.000 description 1
- APUDBKTWDCXQJA-XQBPLPMBSA-N (1R)-4-[(2S,6R)-2,6-dimethylpiperidin-1-yl]-1-phenyl-1-pyridin-2-ylbutan-1-ol Chemical compound C[C@H]1CCC[C@@H](C)N1CCC[C@](O)(C=1N=CC=CC=1)C1=CC=CC=C1 APUDBKTWDCXQJA-XQBPLPMBSA-N 0.000 description 1
- BFCDFTHTSVTWOG-YLJYHZDGSA-N (1S,2R)-2-(octylamino)-1-[4-(propan-2-ylthio)phenyl]-1-propanol Chemical compound CCCCCCCCN[C@H](C)[C@@H](O)C1=CC=C(SC(C)C)C=C1 BFCDFTHTSVTWOG-YLJYHZDGSA-N 0.000 description 1
- HLCSDJLATUNSSI-JXMROGBWSA-N (2e)-3,7-dimethylocta-2,6-dienenitrile Chemical compound CC(C)=CCC\C(C)=C\C#N HLCSDJLATUNSSI-JXMROGBWSA-N 0.000 description 1
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- 239000001707 (E,7R,11R)-3,7,11,15-tetramethylhexadec-2-en-1-ol Substances 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- GJJVAFUKOBZPCB-ZGRPYONQSA-N (r)-3,4-dihydro-2-methyl-2-(4,8,12-trimethyl-3,7,11-tridecatrienyl)-2h-1-benzopyran-6-ol Chemical class OC1=CC=C2OC(CC/C=C(C)/CC/C=C(C)/CCC=C(C)C)(C)CCC2=C1 GJJVAFUKOBZPCB-ZGRPYONQSA-N 0.000 description 1
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- CHLICZRVGGXEOD-UHFFFAOYSA-N 1-Methoxy-4-methylbenzene Chemical compound COC1=CC=C(C)C=C1 CHLICZRVGGXEOD-UHFFFAOYSA-N 0.000 description 1
- HDCUSMZVZWLDRZ-UHFFFAOYSA-N 1-benzyl-2-methylhydrazine Chemical compound CNNCC1=CC=CC=C1 HDCUSMZVZWLDRZ-UHFFFAOYSA-N 0.000 description 1
- LMAUULKNZLEMGN-UHFFFAOYSA-N 1-ethyl-3,5-dimethylbenzene Chemical compound CCC1=CC(C)=CC(C)=C1 LMAUULKNZLEMGN-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N 2-butenoic acid Chemical compound CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- DZVPGIORVGSQMC-UHFFFAOYSA-N 3,5-dichloro-2,4-dimethoxy-6-(trichloromethyl)pyridine Chemical compound COC1=NC(C(Cl)(Cl)Cl)=C(Cl)C(OC)=C1Cl DZVPGIORVGSQMC-UHFFFAOYSA-N 0.000 description 1
- MTDAKBBUYMYKAR-UHFFFAOYSA-N 3,7-dimethyloct-6-enenitrile Chemical compound N#CCC(C)CCC=C(C)C MTDAKBBUYMYKAR-UHFFFAOYSA-N 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N 3,7-dimethylocta-1,6-dien-3-yl acetate Chemical compound CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- ZSPOJBDHHFFJAP-UHFFFAOYSA-M 3-chlorobenzoate;tetrabutylazanium Chemical compound [O-]C(=O)C1=CC=CC(Cl)=C1.CCCC[N+](CCCC)(CCCC)CCCC ZSPOJBDHHFFJAP-UHFFFAOYSA-M 0.000 description 1
- AJBZENLMTKDAEK-UHFFFAOYSA-N 3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysene-4,9-diol Chemical compound CC12CCC(O)C(C)(C)C1CCC(C1(C)CC3O)(C)C2CCC1C1C3(C)CCC1C(=C)C AJBZENLMTKDAEK-UHFFFAOYSA-N 0.000 description 1
- XQJMXPAEFMWDOZ-UHFFFAOYSA-N 3exo-benzoyloxy-tropane Natural products CN1C(C2)CCC1CC2OC(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- NYYSPVRERVXMLJ-UHFFFAOYSA-N 4,4-difluorocyclohexan-1-one Chemical compound FC1(F)CCC(=O)CC1 NYYSPVRERVXMLJ-UHFFFAOYSA-N 0.000 description 1
- TYMLOMAKGOJONV-UHFFFAOYSA-N 4-nitroaniline Chemical compound NC1=CC=C([N+]([O-])=O)C=C1 TYMLOMAKGOJONV-UHFFFAOYSA-N 0.000 description 1
- JYJFNDQBESEHJQ-UHFFFAOYSA-N 5,5-dimethyloxazolidine-2,4-dione Chemical compound CC1(C)OC(=O)NC1=O JYJFNDQBESEHJQ-UHFFFAOYSA-N 0.000 description 1
- MXUNKHLAEDCYJL-UHFFFAOYSA-N 5-(hydroxymethyl)-3-(3-methylphenyl)-1,3-oxazolidin-2-one Chemical compound CC1=CC=CC(N2C(OC(CO)C2)=O)=C1 MXUNKHLAEDCYJL-UHFFFAOYSA-N 0.000 description 1
- OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 1
- NPDSHTNEKLQQIJ-SIGMCMEVSA-N 9-hode Chemical compound CCCCC\C=C\C=C\C(O)CCCCCCCC(O)=O NPDSHTNEKLQQIJ-SIGMCMEVSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- RYWSYCQQUDFMAU-UHFFFAOYSA-N Acetomenaphthone Chemical compound C1=CC=C2C(OC(=O)C)=CC(C)=C(OC(C)=O)C2=C1 RYWSYCQQUDFMAU-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- JEBFVOLFMLUKLF-IFPLVEIFSA-N Astaxanthin Natural products CC(=C/C=C/C(=C/C=C/C1=C(C)C(=O)C(O)CC1(C)C)/C)C=CC=C(/C)C=CC=C(/C)C=CC2=C(C)C(=O)C(O)CC2(C)C JEBFVOLFMLUKLF-IFPLVEIFSA-N 0.000 description 1
- 201000001320 Atherosclerosis Diseases 0.000 description 1
- 241000195940 Bryophyta Species 0.000 description 1
- NWGSEVZGFKQKDJ-UHFFFAOYSA-N C(CCCCC)C(CCCC)(O)O.ClC1=CC=CC=C1 Chemical compound C(CCCCC)C(CCCC)(O)O.ClC1=CC=CC=C1 NWGSEVZGFKQKDJ-UHFFFAOYSA-N 0.000 description 1
- FMRAEMFVWVWAQR-UHFFFAOYSA-N CC(=O)C.S(=O)(O)S(=O)O Chemical compound CC(=O)C.S(=O)(O)S(=O)O FMRAEMFVWVWAQR-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 235000003880 Calendula Nutrition 0.000 description 1
- 240000001432 Calendula officinalis Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- JWBOIMRXGHLCPP-UHFFFAOYSA-N Chloditan Chemical compound C=1C=CC=C(Cl)C=1C(C(Cl)Cl)C1=CC=C(Cl)C=C1 JWBOIMRXGHLCPP-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XCDXSSFOJZZGQC-UHFFFAOYSA-N Chlornaphazine Chemical compound C1=CC=CC2=CC(N(CCCl)CCCl)=CC=C21 XCDXSSFOJZZGQC-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000555825 Clupeidae Species 0.000 description 1
- 241000825055 Coilia Species 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 235000014493 Crataegus Nutrition 0.000 description 1
- 241001092040 Crataegus Species 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- SPKNARKFCOPTSY-UHFFFAOYSA-N D-asperlin Natural products CC1OC1C1C(OC(C)=O)C=CC(=O)O1 SPKNARKFCOPTSY-UHFFFAOYSA-N 0.000 description 1
- 235000004866 D-panthenol Nutrition 0.000 description 1
- 239000011703 D-panthenol Substances 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical compound CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 241000899749 Dypsis lutescens Species 0.000 description 1
- JHJOOSLFWRRSGU-UHFFFAOYSA-N Fenchlorphos Chemical compound COP(=S)(OC)OC1=CC(Cl)=C(Cl)C=C1Cl JHJOOSLFWRRSGU-UHFFFAOYSA-N 0.000 description 1
- 241000598860 Garcinia hanburyi Species 0.000 description 1
- 241000134874 Geraniales Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- FPCCDPXRNNVUOM-UHFFFAOYSA-N Hydroxycitronellol Chemical compound OCCC(C)CCCC(C)(C)O FPCCDPXRNNVUOM-UHFFFAOYSA-N 0.000 description 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 1
- NNJVILVZKWQKPM-UHFFFAOYSA-N Lidocaine Chemical compound CCN(CC)CC(=O)NC1=C(C)C=CC=C1C NNJVILVZKWQKPM-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229920003264 Maprenal® Polymers 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- BYBLEWFAAKGYCD-UHFFFAOYSA-N Miconazole Chemical compound ClC1=CC(Cl)=CC=C1COC(C=1C(=CC(Cl)=CC=1)Cl)CN1C=NC=C1 BYBLEWFAAKGYCD-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 1
- QORUGOXNWQUALA-UHFFFAOYSA-N N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 Chemical compound N=C=O.N=C=O.N=C=O.C1=CC=C(C(C2=CC=CC=C2)C2=CC=CC=C2)C=C1 QORUGOXNWQUALA-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- FQTLCLSUCSAZDY-ATGUSINASA-N Nerolidol Chemical compound CC(C)=CCC\C(C)=C\CC[C@](C)(O)C=C FQTLCLSUCSAZDY-ATGUSINASA-N 0.000 description 1
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- BLUHKGOSFDHHGX-UHFFFAOYSA-N Phytol Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C=CO BLUHKGOSFDHHGX-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- IFFPICMESYHZPQ-UHFFFAOYSA-N Prenylamine Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)CCNC(C)CC1=CC=CC=C1 IFFPICMESYHZPQ-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- JLRNKCZRCMIVKA-UHFFFAOYSA-N Simfibrate Chemical compound C=1C=C(Cl)C=CC=1OC(C)(C)C(=O)OCCCOC(=O)C(C)(C)OC1=CC=C(Cl)C=C1 JLRNKCZRCMIVKA-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- IECRXMSGDFIOEY-UHFFFAOYSA-N Tangeretin Natural products COC=1C(OC)=C(OC)C(OC)=C(C(C=2)=O)C=1OC=2C1=CC=C(O)C=C1 IECRXMSGDFIOEY-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- HNZBNQYXWOLKBA-UHFFFAOYSA-N Tetrahydrofarnesol Natural products CC(C)CCCC(C)CCCC(C)=CCO HNZBNQYXWOLKBA-UHFFFAOYSA-N 0.000 description 1
- KLBQZWRITKRQQV-UHFFFAOYSA-N Thioridazine Chemical compound C12=CC(SC)=CC=C2SC2=CC=CC=C2N1CCC1CCCCN1C KLBQZWRITKRQQV-UHFFFAOYSA-N 0.000 description 1
- HXWJFEZDFPRLBG-UHFFFAOYSA-N Timnodonic acid Natural products CCCC=CC=CCC=CCC=CCC=CCCCC(O)=O HXWJFEZDFPRLBG-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 241000030614 Urania Species 0.000 description 1
- ZYPGADGCNXOUJP-CXVPHVKISA-N Variotin Chemical compound CCCC[C@@H](O)\C=C(/C)\C=C\C=C\C(=O)N1CCCC1=O ZYPGADGCNXOUJP-CXVPHVKISA-N 0.000 description 1
- MECHNRXZTMCUDQ-UHFFFAOYSA-N Vitamin D2 Natural products C1CCC2(C)C(C(C)C=CC(C)C(C)C)CCC2C1=CC=C1CC(O)CCC1=C MECHNRXZTMCUDQ-UHFFFAOYSA-N 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- SPKNARKFCOPTSY-XWPZMVOTSA-N [(2r,3s)-2-[(2s,3r)-3-methyloxiran-2-yl]-6-oxo-2,3-dihydropyran-3-yl] acetate Chemical compound C[C@H]1O[C@@H]1[C@H]1[C@@H](OC(C)=O)C=CC(=O)O1 SPKNARKFCOPTSY-XWPZMVOTSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- YASYVMFAVPKPKE-UHFFFAOYSA-N acephate Chemical compound COP(=O)(SC)NC(C)=O YASYVMFAVPKPKE-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 125000005376 alkyl siloxane group Chemical group 0.000 description 1
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 description 1
- BOTWFXYSPFMFNR-OALUTQOASA-N all-rac-phytol Natural products CC(C)CCC[C@H](C)CCC[C@H](C)CCCC(C)=CCO BOTWFXYSPFMFNR-OALUTQOASA-N 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- PAZJSJFMUHDSTF-UHFFFAOYSA-N alprenolol Chemical compound CC(C)NCC(O)COC1=CC=CC=C1CC=C PAZJSJFMUHDSTF-UHFFFAOYSA-N 0.000 description 1
- 229960002213 alprenolol Drugs 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- YZQNFFLGIYEXMM-UHFFFAOYSA-N aminopromazine Chemical compound C1=CC=C2N(CC(CN(C)C)N(C)C)C3=CC=CC=C3SC2=C1 YZQNFFLGIYEXMM-UHFFFAOYSA-N 0.000 description 1
- 229950005325 aminopromazine Drugs 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000001961 anticonvulsive agent Substances 0.000 description 1
- 239000000935 antidepressant agent Substances 0.000 description 1
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 description 1
- 239000003443 antiviral agent Substances 0.000 description 1
- DFMMVLFMMAQXHZ-CMGSAFQJSA-N apocarotenal Chemical compound O=CC(/C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(\C)C=CC1=C(C)CCCC1(C)C DFMMVLFMMAQXHZ-CMGSAFQJSA-N 0.000 description 1
- 229940019834 apocarotenal Drugs 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- DIXRMZGIJNJUGL-UHFFFAOYSA-N arildone Chemical compound CCC(=O)C(C(=O)CC)CCCCCCOC1=CC=C(OC)C=C1Cl DIXRMZGIJNJUGL-UHFFFAOYSA-N 0.000 description 1
- 229950003470 arildone Drugs 0.000 description 1
- 150000008430 aromatic amides Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- MQZIGYBFDRPAKN-ZWAPEEGVSA-N astaxanthin Chemical compound C([C@H](O)C(=O)C=1C)C(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)C(=O)[C@@H](O)CC1(C)C MQZIGYBFDRPAKN-ZWAPEEGVSA-N 0.000 description 1
- 235000013793 astaxanthin Nutrition 0.000 description 1
- 239000001168 astaxanthin Substances 0.000 description 1
- 229940022405 astaxanthin Drugs 0.000 description 1
- 239000000305 astragalus gummifer gum Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- XTKDAFGWCDAMPY-UHFFFAOYSA-N azaperone Chemical compound C1=CC(F)=CC=C1C(=O)CCCN1CCN(C=2N=CC=CC=2)CC1 XTKDAFGWCDAMPY-UHFFFAOYSA-N 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- VVUYEFBRTFASAH-UHFFFAOYSA-N bamifylline Chemical compound N=1C=2N(C)C(=O)N(C)C(=O)C=2N(CCN(CCO)CC)C=1CC1=CC=CC=C1 VVUYEFBRTFASAH-UHFFFAOYSA-N 0.000 description 1
- 229960005176 bamifylline Drugs 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 description 1
- SXYFFMXPDDGOEK-UHFFFAOYSA-N binedaline Chemical compound C12=CC=CC=C2N(N(C)CCN(C)C)C=C1C1=CC=CC=C1 SXYFFMXPDDGOEK-UHFFFAOYSA-N 0.000 description 1
- 229950004874 binedaline Drugs 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZPOLOEWJWXZUSP-WAYWQWQTSA-N bis(prop-2-enyl) (z)-but-2-enedioate Chemical compound C=CCOC(=O)\C=C/C(=O)OCC=C ZPOLOEWJWXZUSP-WAYWQWQTSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 229940124630 bronchodilator Drugs 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- YFLRYAVDPKONNX-UHFFFAOYSA-N buramate Chemical compound OCCOC(=O)NCC1=CC=CC=C1 YFLRYAVDPKONNX-UHFFFAOYSA-N 0.000 description 1
- 229950009824 buramate Drugs 0.000 description 1
- XZKRXPZXQLARHH-UHFFFAOYSA-N buta-1,3-dienylbenzene Chemical compound C=CC=CC1=CC=CC=C1 XZKRXPZXQLARHH-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- VWYQKFLLGRBICZ-UHFFFAOYSA-N butanilicaine Chemical compound CCCCNCC(=O)NC1=C(C)C=CC=C1Cl VWYQKFLLGRBICZ-UHFFFAOYSA-N 0.000 description 1
- UULSXYSSHHRCQK-UHFFFAOYSA-N butibufen Chemical compound CCC(C(O)=O)C1=CC=C(CC(C)C)C=C1 UULSXYSSHHRCQK-UHFFFAOYSA-N 0.000 description 1
- 229960002973 butibufen Drugs 0.000 description 1
- 229960005074 butoconazole Drugs 0.000 description 1
- SWLMUYACZKCSHZ-UHFFFAOYSA-N butoconazole Chemical compound C1=CC(Cl)=CC=C1CCC(SC=1C(=CC=CC=1Cl)Cl)CN1C=NC=C1 SWLMUYACZKCSHZ-UHFFFAOYSA-N 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 229960002504 capsaicin Drugs 0.000 description 1
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940125692 cardiovascular agent Drugs 0.000 description 1
- 239000002327 cardiovascular agent Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- JCKYGMPEJWAADB-UHFFFAOYSA-N chlorambucil Chemical compound OC(=O)CCCC1=CC=C(N(CCCl)CCCl)C=C1 JCKYGMPEJWAADB-UHFFFAOYSA-N 0.000 description 1
- 229960004630 chlorambucil Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229950008249 chlornaphazine Drugs 0.000 description 1
- MXOAEAUPQDYUQM-UHFFFAOYSA-N chlorphenesin Chemical compound OCC(O)COC1=CC=C(Cl)C=C1 MXOAEAUPQDYUQM-UHFFFAOYSA-N 0.000 description 1
- ZPEIMTDSQAKGNT-UHFFFAOYSA-N chlorpromazine Chemical compound C1=C(Cl)C=C2N(CCCN(C)C)C3=CC=CC=C3SC2=C1 ZPEIMTDSQAKGNT-UHFFFAOYSA-N 0.000 description 1
- 229960001076 chlorpromazine Drugs 0.000 description 1
- 239000000812 cholinergic antagonist Substances 0.000 description 1
- 229940043350 citral Drugs 0.000 description 1
- 229960003920 ***e Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- KQWGXHWJMSMDJJ-UHFFFAOYSA-N cyclohexyl isocyanate Chemical compound O=C=NC1CCCCC1 KQWGXHWJMSMDJJ-UHFFFAOYSA-N 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- 239000000824 cytostatic agent Substances 0.000 description 1
- DKRSEIPLAZTSFD-UHFFFAOYSA-N d-quinotoxine Natural products C12=CC(OC)=CC=C2N=CC=C1C(=O)CCC1CCNCC1C=C DKRSEIPLAZTSFD-UHFFFAOYSA-N 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229960003949 dexpanthenol Drugs 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- WJIZVQNUJVMJAZ-UHFFFAOYSA-N difemerine Chemical compound C=1C=CC=CC=1C(O)(C(=O)OC(C)(C)CN(C)C)C1=CC=CC=C1 WJIZVQNUJVMJAZ-UHFFFAOYSA-N 0.000 description 1
- 229960004944 difemerine Drugs 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229950004446 dimethadione Drugs 0.000 description 1
- NPDSHTNEKLQQIJ-UHFFFAOYSA-N dimorphecolic acid Natural products CCCCCC=CC=CC(O)CCCCCCCC(O)=O NPDSHTNEKLQQIJ-UHFFFAOYSA-N 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229940075933 dithionate Drugs 0.000 description 1
- DVSZKTAMJJTWFG-UHFFFAOYSA-N docosa-2,4,6,8,10,12-hexaenoic acid Chemical compound CCCCCCCCCC=CC=CC=CC=CC=CC=CC(O)=O DVSZKTAMJJTWFG-UHFFFAOYSA-N 0.000 description 1
- MBMBGCFOFBJSGT-KUBAVDMBSA-N docosahexaenoic acid Natural products CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCC(O)=O MBMBGCFOFBJSGT-KUBAVDMBSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 1
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 1
- 210000001163 endosome Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229960002061 ergocalciferol Drugs 0.000 description 1
- FRPJXPJMRWBBIH-RBRWEJTLSA-N estramustine Chemical compound ClCCN(CCCl)C(=O)OC1=CC=C2[C@H]3CC[C@](C)([C@H](CC4)O)[C@@H]4[C@@H]3CCC2=C1 FRPJXPJMRWBBIH-RBRWEJTLSA-N 0.000 description 1
- 229960001842 estramustine Drugs 0.000 description 1
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N ethyl butyrate Chemical compound CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- IDNUEBSJWINEMI-UHFFFAOYSA-N ethyl nitrate Chemical compound CCO[N+]([O-])=O IDNUEBSJWINEMI-UHFFFAOYSA-N 0.000 description 1
- NPUKDXXFDDZOKR-LLVKDONJSA-N etomidate Chemical compound CCOC(=O)C1=CN=CN1[C@H](C)C1=CC=CC=C1 NPUKDXXFDDZOKR-LLVKDONJSA-N 0.000 description 1
- 229960001690 etomidate Drugs 0.000 description 1
- CKSJXOVLXUMMFF-UHFFFAOYSA-N exalamide Chemical compound CCCCCCOC1=CC=CC=C1C(N)=O CKSJXOVLXUMMFF-UHFFFAOYSA-N 0.000 description 1
- 229950010333 exalamide Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 229950010338 fencarbamide Drugs 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- CVHGCWVMTZWGAY-UHFFFAOYSA-N fomocaine Chemical compound C=1C=C(COC=2C=CC=CC=2)C=CC=1CCCN1CCOCC1 CVHGCWVMTZWGAY-UHFFFAOYSA-N 0.000 description 1
- 229950003051 fomocaine Drugs 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229940117709 gamboge Drugs 0.000 description 1
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 235000020251 goat milk Nutrition 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
- 229910000271 hectorite Inorganic materials 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- KRQAMFQCSAJCRH-UHFFFAOYSA-N hexobendine Chemical compound COC1=C(OC)C(OC)=CC(C(=O)OCCCN(C)CCN(C)CCCOC(=O)C=2C=C(OC)C(OC)=C(OC)C=2)=C1 KRQAMFQCSAJCRH-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- JUMYIBMBTDDLNG-OJERSXHUSA-N hydron;methyl (2r)-2-phenyl-2-[(2r)-piperidin-2-yl]acetate;chloride Chemical compound Cl.C([C@@H]1[C@H](C(=O)OC)C=2C=CC=CC=2)CCCN1 JUMYIBMBTDDLNG-OJERSXHUSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- WPFVBOQKRVRMJB-UHFFFAOYSA-N hydroxycitronellal Chemical compound O=CCC(C)CCCC(C)(C)O WPFVBOQKRVRMJB-UHFFFAOYSA-N 0.000 description 1
- SBGKURINHGJRFN-UHFFFAOYSA-N hydroxymethanesulfinic acid Chemical compound OCS(O)=O SBGKURINHGJRFN-UHFFFAOYSA-N 0.000 description 1
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 description 1
- 229960001680 ibuprofen Drugs 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 229940117955 isoamyl acetate Drugs 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 150000002561 ketenes Chemical class 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 229960004194 lidocaine Drugs 0.000 description 1
- 229950009619 lifibrate Drugs 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 229960004232 linoleic acid Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- MJFJKKXQDNNUJF-UHFFFAOYSA-N metixene Chemical compound C1N(C)CCCC1CC1C2=CC=CC=C2SC2=CC=CC=C21 MJFJKKXQDNNUJF-UHFFFAOYSA-N 0.000 description 1
- 229960005103 metixene Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229960002509 miconazole Drugs 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229960000350 mitotane Drugs 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 239000000206 moulding compound Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- MYCMTMIGRXJNSO-UHFFFAOYSA-N moxaverine Chemical compound N=1C(CC)=CC2=CC(OC)=C(OC)C=C2C=1CC1=CC=CC=C1 MYCMTMIGRXJNSO-UHFFFAOYSA-N 0.000 description 1
- 229960002902 moxaverine Drugs 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- CPYSWRYVSINXMC-UHFFFAOYSA-N n-ethyl-1,2-benzothiazol-3-amine Chemical compound C1=CC=C2C(NCC)=NSC2=C1 CPYSWRYVSINXMC-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- XXQBGBUZLWZPKT-UHFFFAOYSA-N n-prop-2-enoylbuta-2,3-dienamide Chemical compound C=CC(=O)NC(=O)C=C=C XXQBGBUZLWZPKT-UHFFFAOYSA-N 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
- 239000003176 neuroleptic agent Substances 0.000 description 1
- 230000000701 neuroleptic effect Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- NCYVXEGFNDZQCU-UHFFFAOYSA-N nikethamide Chemical compound CCN(CC)C(=O)C1=CC=CN=C1 NCYVXEGFNDZQCU-UHFFFAOYSA-N 0.000 description 1
- 229960003226 nikethamide Drugs 0.000 description 1
- MRIAQLRQZPPODS-UHFFFAOYSA-N nobiletin Chemical compound C1=C(OC)C(OC)=CC=C1C1=CC(=O)C2=C(OC)C(OC)=C(OC)C(OC)=C2O1 MRIAQLRQZPPODS-UHFFFAOYSA-N 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 229960004570 oxprenolol Drugs 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229960000599 pecilocin Drugs 0.000 description 1
- KQXKVJAGOJTNJS-HNNXBMFYSA-N penbutolol Chemical compound CC(C)(C)NC[C@H](O)COC1=CC=CC=C1C1CCCC1 KQXKVJAGOJTNJS-HNNXBMFYSA-N 0.000 description 1
- 229960002035 penbutolol Drugs 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- WEYVCQFUGFRXOM-UHFFFAOYSA-N perazine Chemical compound C1CN(C)CCN1CCCN1C2=CC=CC=C2SC2=CC=CC=C21 WEYVCQFUGFRXOM-UHFFFAOYSA-N 0.000 description 1
- 229960002195 perazine Drugs 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- MBWXNTAXLNYFJB-NKFFZRIASA-N phylloquinone Chemical compound C1=CC=C2C(=O)C(C/C=C(C)/CCC[C@H](C)CCC[C@H](C)CCCC(C)C)=C(C)C(=O)C2=C1 MBWXNTAXLNYFJB-NKFFZRIASA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- BOTWFXYSPFMFNR-PYDDKJGSSA-N phytol Chemical compound CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC\C(C)=C\CO BOTWFXYSPFMFNR-PYDDKJGSSA-N 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 229950008066 pirmenol Drugs 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- MVFGUOIZUNYYSO-UHFFFAOYSA-N prilocaine Chemical compound CCCNC(C)C(=O)NC1=CC=CC=C1C MVFGUOIZUNYYSO-UHFFFAOYSA-N 0.000 description 1
- 229960001807 prilocaine Drugs 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- REQCZEXYDRLIBE-UHFFFAOYSA-N procainamide Chemical compound CCN(CC)CCNC(=O)C1=CC=C(N)C=C1 REQCZEXYDRLIBE-UHFFFAOYSA-N 0.000 description 1
- 229960000244 procainamide Drugs 0.000 description 1
- CDOZDBSBBXSXLB-UHFFFAOYSA-N profenamine Chemical compound C1=CC=C2N(CC(C)N(CC)CC)C3=CC=CC=C3SC2=C1 CDOZDBSBBXSXLB-UHFFFAOYSA-N 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- YZZCJYJBCUJISI-UHFFFAOYSA-N propatylnitrate Chemical compound [O-][N+](=O)OCC(CC)(CO[N+]([O-])=O)CO[N+]([O-])=O YZZCJYJBCUJISI-UHFFFAOYSA-N 0.000 description 1
- 229960003402 propatylnitrate Drugs 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- 239000003368 psychostimulant agent Substances 0.000 description 1
- 229960001285 quercetin Drugs 0.000 description 1
- 235000005875 quercetin Nutrition 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 229950003447 risocaine Drugs 0.000 description 1
- 229940099204 ritalin Drugs 0.000 description 1
- 239000003128 rodenticide Substances 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- BZGIPVGCJGXQTA-UHFFFAOYSA-N s-[2-(diethylamino)ethyl] n,n-diphenylcarbamothioate Chemical compound C=1C=CC=CC=1N(C(=O)SCCN(CC)CC)C1=CC=CC=C1 BZGIPVGCJGXQTA-UHFFFAOYSA-N 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229960004058 simfibrate Drugs 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical group [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- RCIJACVHOIKRAP-UHFFFAOYSA-N sodium;1,4-dioctoxy-1,4-dioxobutane-2-sulfonic acid Chemical compound [Na+].CCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCC RCIJACVHOIKRAP-UHFFFAOYSA-N 0.000 description 1
- 235000021262 sour milk Nutrition 0.000 description 1
- 235000013322 soy milk Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229960003967 suloctidil Drugs 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 229960003604 testosterone Drugs 0.000 description 1
- VOCBWIIFXDYGNZ-IXKNJLPQSA-N testosterone enanthate Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H](OC(=O)CCCCCC)[C@@]1(C)CC2 VOCBWIIFXDYGNZ-IXKNJLPQSA-N 0.000 description 1
- 229960003484 testosterone enanthate Drugs 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 229960002372 tetracaine Drugs 0.000 description 1
- GKCBAIGFKIBETG-UHFFFAOYSA-N tetracaine Chemical compound CCCCNC1=CC=C(C(=O)OCCN(C)C)C=C1 GKCBAIGFKIBETG-UHFFFAOYSA-N 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 229960002784 thioridazine Drugs 0.000 description 1
- WRCITXQNXAIKLR-UHFFFAOYSA-N tiadenol Chemical compound OCCSCCCCCCCCCCSCCO WRCITXQNXAIKLR-UHFFFAOYSA-N 0.000 description 1
- 229960000822 tiadenol Drugs 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229930003802 tocotrienol Natural products 0.000 description 1
- 239000011731 tocotrienol Substances 0.000 description 1
- 229940068778 tocotrienols Drugs 0.000 description 1
- 235000019148 tocotrienols Nutrition 0.000 description 1
- NXQMNKUGGYNLBY-UHFFFAOYSA-N toliprolol Chemical compound CC(C)NCC(O)COC1=CC=CC(C)=C1 NXQMNKUGGYNLBY-UHFFFAOYSA-N 0.000 description 1
- 229960002309 toloxatone Drugs 0.000 description 1
- 229940125725 tranquilizer Drugs 0.000 description 1
- 239000003204 tranquilizing agent Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- ZESXUEKAXSBANL-UHFFFAOYSA-N trifluoromethyl prop-2-enoate Chemical compound FC(F)(F)OC(=O)C=C ZESXUEKAXSBANL-UHFFFAOYSA-N 0.000 description 1
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- GOZBHBFUQHMKQB-UHFFFAOYSA-N trimecaine Chemical compound CCN(CC)CC(=O)NC1=C(C)C=C(C)C=C1C GOZBHBFUQHMKQB-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- ZSCDBOWYZJWBIY-UHFFFAOYSA-N trimipramine Chemical compound C1CC2=CC=CC=C2N(CC(CN(C)C)C)C2=CC=CC=C21 ZSCDBOWYZJWBIY-UHFFFAOYSA-N 0.000 description 1
- 229960002431 trimipramine Drugs 0.000 description 1
- XQJMXPAEFMWDOZ-BTTYYORXSA-N tropa***e Chemical compound O([C@@H]1C[C@H]2CC[C@@H](C1)N2C)C(=O)C1=CC=CC=C1 XQJMXPAEFMWDOZ-BTTYYORXSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 1
- DKRSEIPLAZTSFD-LSDHHAIUSA-N viquidil Chemical compound C12=CC(OC)=CC=C2N=CC=C1C(=O)CC[C@@H]1CCNC[C@@H]1C=C DKRSEIPLAZTSFD-LSDHHAIUSA-N 0.000 description 1
- 229960003353 viquidil Drugs 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 239000011653 vitamin D2 Substances 0.000 description 1
- 235000001892 vitamin D2 Nutrition 0.000 description 1
- MECHNRXZTMCUDQ-RKHKHRCZSA-N vitamin D2 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)/C=C/[C@H](C)C(C)C)=C\C=C1\C[C@@H](O)CCC1=C MECHNRXZTMCUDQ-RKHKHRCZSA-N 0.000 description 1
- 239000011712 vitamin K Substances 0.000 description 1
- 229940046010 vitamin k Drugs 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/068—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1324—Flexible food casing [e.g., sausage type, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Wrappers (AREA)
- Medicinal Preparation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesive Tapes (AREA)
Abstract
本发明涉及防粘包装材料在包装化学品及食品、特别是精细化学品(如维生素、类胡萝卜素、香料和芳香剂以及药用化学品,以及其配方物和制剂)中的用途。
Description
说明
本发明涉及防粘包装材料在包装化学品及食品、特别是精细化学品(例如维生素、类胡萝卜素、香料和芳香剂以及药用化学品及其配方物和制剂)中的用途。
为了运输、储存或销售,化学品及食品被分装在罐、瓶、桶及其它容器中。迄今为止,这些容器上都必须用常规涂层材料或其它涂层技术涂上涂层,从而例如保证食品的接触安全性。为此,使用了许多涂层体系,例如,酚醛树脂,苯酚-甲醛树脂,或环氧-苯酚树脂。另外,也使用聚合物模制复合物(如聚乙烯)涂层。
表面的防粘性质-也被部分称作莲效应-可从特定的防粘涂层体系(如DE-A-3535283、EP-A-0835897、JP-11189701、US 5,324,566)得到。但是,这些涂层体系有各种缺点,例如需要使用高浓度、在某些情况下不耐水解或难于处理。
具有优良防粘性质的新型添加剂参见德国专利申请2420676(申请日2000年9月29日)。其内容包括使用用于罐内涂层和桶内涂层的添加剂涂层组合物,以使相关的装有油的容器得以完全排空。该文作为例子提及了矿物油和植物油。
所有的防粘涂层添加剂的优选应用范围都是在工业方面,一般是在自净表面或防涂写表面等的生产方面。已有技术中没有将防粘涂层添加剂用于化学品、特别是精细化学品(例如维生素、类胡萝卜素、香料和芳香剂和药用化学品等)的包装材料的描述。
与化学品和食品、特别是具有亲油性的食品和化学品的处理联系在一起的一个问题是有效完全排空容纳它们的容器。因为对容器的壁的粘附,至今所使用的体系中没有一种能保证完全排空容器,因此必须接受有价值的化合物的损失。另外,没有完全排空的包装不能直接回收,必不可少的清洁使其重新使用不经济。
据此,本发明的一个目标是提供用于化学品和食品、特别是亲油化学品和精细化学品的、能确保尽可能彻底的改良的完全容器排空的包装材料。另一个目标是,所应用的涂层组合物应表现出良好的机械强度,这对于保障食品接触的整体性是基本的必不可少的条件。
令人惊讶的是,这个目标可以通过使用通过向常规涂层组合物或聚合物模制复合物中加入防粘添加剂(即以下的“防粘添加剂”)而制成的包装材料达到,上述防粘添加剂包含由聚合物基础分子和直接或通过间隔基团共价连接到基础分子上的聚二有机基硅氧烷侧链所构成的支化聚合物。
本发明所需用的防粘添加剂的极低浓度使得已经广为接受并被详细考察多年的涂层组合物及聚合物模制复合物的使用成为可能。原涂层组合物及聚合物模制化合物的物理性质(例如在防腐性、保光性、风化稳定性和食品接触的整体性等方面)不会受低浓度的防粘添加剂的影响。
本发明首先提供了用于包装化学品和食品(不包括矿物油和植物油)的包装材料使用,所述包装材料含有涂层组合物和/或聚合物模制复合物,其包含由聚合物基础分子和直接或通过间隔基团共价连接到基础分子上的聚二有机基硅氧烷侧链构成的支化聚合物(防粘添加剂)。优选用于精细化学品的包装。非常优选用于亲油精细化学品的包装。
“亲油化学品”及“亲油精细化学品”包括在20℃、大气压力下水溶解度低于10重量%、优选低于5重量%、更优选低于3重量%、最优选1重量%的化合物。
“精细化学品”是所有全球年产量低于200000t、优选低于100000t、非常优选低于50000t的特殊化学品。它们包括例如维生素、脂肪酸、香料、调味剂、芳香剂、着色剂、药用化学品、农用化学品、化妆品用化学品、其前体及中间体,以及以上物质的配方物和制剂。
例如,精细化学品包括但不仅限于
a)维生素,特别是亲油性维生素,例如
-生育酚和生育三烯酚(在本发明中统称为维生素E)及其衍生物以及它们的化合物,例如维生素E乙酸酯、维生素E琥珀酸酯、维生素E烟酸酯。包括合成维生素E和天然来源的维生素E以及他们的衍生物。
-维生素A及其衍生物,例如视黄醇(维生素A1)及其化合物(例如酯,如乙酸酯、棕榈酸枝和丙酸酯)。
-维生素D及其衍生物,例如D3(胆钙化醇)或D2(麦角钙化醇)及其化合物。
-维生素K及其衍生物,例如维生素K1(叶绿醌)、K2、K3(甲萘醌)、K4和K5及其化合物。
-维生素F及其衍生物(例如必需脂肪酸(见下文))及其化合物。
b)脂肪酸(例如饱和或不饱和脂肪酸)及其衍生物和化合物,特别是
-多不饱和脂肪酸,例如花生四烯酸、二十碳五烯酸或二十二碳六烯酸。
-共轭多不饱和脂肪酸,例如共轭亚麻酸(CLA、亚油酸)、α-十八碳四烯酸(18∶4十八碳四烯酸)、桐酸(18∶3十八碳三烯酸)、dimorphecolic acid以及calendula acid。CLA是特征为共轭双键体系开始于第8、9、10或11个碳的亚麻酸的位置和结构异构体的统称。这些位置异构体各自存在几何异构体:顺-顺、反-顺、顺-反、反-反。特别令人感兴趣的是C18:2顺-9,反11和C18:2反-10,顺12CLA,它们是最具有生物活性的异构体,这是因为动物实验已经表明它们具有防止癌症、抗动脉粥样硬化和降低人和动物体内体脂肪比例的作用。
c)天然和合成调味剂、芳香剂和香料,特别是亲油性调味剂、芳香剂和香料,例如lysmeral、茴香醛、对甲酚甲醚、柠檬醛、D-泛酰醇、乙偶姻、乙酸异戊酯、茴香基丙醛、香茅醛、香茅醇、香茅醇乙酸酯、香茅腈、丁二酮、二甲基庚醇、香叶腈、香叶基内酯、Hydroxyciol、羟基香茅醛、β-紫罗酮、乙酸芳樟酯、叶绿醇、橙花叔醇和异戊醛、芳樟醇、薄荷醇、borneon(樟脑)、蒎烯、1,8-萜二烯或香叶醇及其衍生物和化合物。
d)着色剂,特别是亲油性着色剂,例如
-类视黄醇,例如维生素A,
-类黄酮,例如五羟黄酮、芸香苷、桔皮晶、川皮苷,
-类胡萝卜素,例如β-胡萝卜素(维生素原A)、apo-carotenal、番茄红素、虾青素,
及以上物质的衍生物和化合物。
e)药用化学品,特别是亲油性药用化学品及其衍生物、化合物、前体或中间体。药用化学品通常是所有用于人或兽药中或用于制备人或兽药的化合物。它们例如包括但不仅限于以下物质:
-***和麻痹药,例如丁苯胺卡因、福吗卡因、氨苯乙丁酯、利多卡因、利索卡因、丙胺卡因、拟柯卡因、丁卡因、美索卡因、托把柯卡因和依托咪酯;
-抗胆碱能药,例如美噻吨和普罗吩胺;
-抗抑郁药、精神兴奋药和精神安定药,例如alimenazine、苯奈达林、培拉嗪、氯丙嗪、氯苯己基戊二醇、fenanisol、fiuanisol、甲苄肼、哌醋甲酯、甲硫哒嗪、托洛沙酮和三甲丙咪嗪;
-抗癫病药,例如二甲双酮和尼可刹米;
-杀真菌药,例如布康唑、氯苯甘油醚、依替沙唑、己氧苯酰胺、培西洛星和咪康唑;
-抗炎药,例如布替布芬和布洛芬;
-支气管扩张药,例如巴米茶碱;
-心血管药,例如心得舒、克冠异丁胺、cloridazole、克冠二胺、降酯吡醇、喷布洛尔、吡美诺、心可定、普鲁卡因胺、propatyl nitrate、舒洛地尔、甲苯心安、xibendol和维喹地尔;
-细胞抑制药,例如asperlin、苯丁酸氮芥、萘氮芥、米托坦、雌莫司汀、泰素、penclomedine和三苄环磷酰胺;
-Hyperemics,例如辣椒素和烟酸甲酯;
-脂调节剂,例如尼可氯酯、烯丙氧心安、皮利贝特、双贝特和thiadenol;
-解痉药,例如氨基丙嗪、caronerine、双苯美林、苯胺硫酯、替落酰胺和莫沙维林;
-睾酮衍生物,例如testosterone enantate和睾酮(4-甲基戊酸酯);
-镇静剂,例如氮哌酮和布拉氨酯;
-抗病毒药,例如Arildone;
f)农用化学品,特别是亲油性农用化学品,例如杀虫剂、杀线虫剂、灭鼠剂、杀软体动物剂、生长调节剂和除草剂及其衍生物、前体或中间体,例如乙酰甲胺磷、氟氯氰菊酯、azinphosphomethyl、氯氰菊酯、取代苯基硫代磷酸酯、皮蝇磷、氯菊酯、胡椒醛、胺菊酯和氟乐灵。
g)化妆品用化学品,特别是消泡剂、表面活性化合物(即表面活性剂)乳化剂、起泡剂和增溶剂、防腐剂、芳香油、遮光剂、活性物质、UV过滤剂、护理物质(例如泛酰醇、胶原质、蛋白质水解物、α-和β-羟基羧酸)、稳定剂、pH调节剂、粘度调节剂、凝胶形成剂、盐、湿润剂、refattingagent。还包括阴离子、阳离子、中性或两性聚合物,特别是硅氧烷化合物,例如聚烷基硅氧烷、聚芳基硅氧烷、聚芳烷基硅氧烷、聚醚硅氧烷、硅树脂或二甲基硅油(CTFA)-多元醇共聚物和氨基官能化聚硅氧烷化合物(例如氨基二甲基硅油(CTFA))以及由此衍生得到的共聚物和接枝聚合物。另外还包括上述物质的配方物以及成品化妆品,其例子是化妆品类发用配方物(发处理剂、摩丝、发胶或喷发胶、发露、发树脂、香波、发乳液、发端分叉修复流体、烫发用中和剂、热油处理制剂、护发素或定型药水)以及用于护肤和身体护理产品、沐浴液、淋浴凝胶、口腔和其它卫生配方物、日光保护产品以及仿晒用品。特别优选油状或含油化妆品(例如美容洗液或沐浴油)。
最优选的亲油性精细化学品是维生素E和维生素A及其化合物,例如维生素E乙酸酯,维生素A棕榈酸酯或维生素A丙酸酯。
化学品或精细化学品指例如纯物质,在纯物质中,各化合物的量是至少95重量%,优选至少98重量%,更优选至少99重量%。
化学品或精细化学品还指两种以上的化学品或精细化学品的混合物或与其他物质的混合物。特别优选至少两种亲油性维生素的混合物或与其他维生素(例如亲水性维生素)的混合物。最优选包括至少一种选自维生素A、β-胡萝卜素、维生素D3、K1或生育酚的维生素的混合物。
化学品或精细化学品另外还包括化学品或精细化学品的配方物和制品。配方物是例如与至少一种溶剂或分散剂、优选亲油性溶剂或分散剂的溶液、混合物或乳液或分散液。最优选亲油精细化学品的溶液、混合物、乳液或分散液,尤其是亲油性维生素(例如维生素E乙酸酯、维生素A棕榈酸酯或维生素A丙酸酯)在植物油或合成油中的溶液、混合物、乳液或分散液。在此包括的植物油例如包括但不仅限于葵花籽油、油菜籽油、花生油、玉米胚芽油以及大豆油。合成油特别包括中等链的甘油三酯。溶液、混合物、乳液或分散液的化学品或精细化学品含量优选0-1到99.9重量%,更优选1到98重量%,非常优选10到95重量%,最优选30到92重量%。
化学品或精细化学品或配方物或制剂优选具有液体聚集态。该聚集态优选甚至在室温(20℃)下也存在,但也可以用升温到至少化学品或精细化学品或其配方物或其制剂的熔点的方法得到。在这种情况下,温度优选升温到不高于200℃,更优选升温到不高于100℃,最优选升温到不高于50℃。
本发明所包括的还有食品的包装,特别是亲油性食品或若非如此具有很高表面粘附性的食品的包装。例如其包括但不仅局限于
a)奶制品或奶制品替代品,如奶、奶油、酸奶、酸奶酪、豆奶等,
b)预制食品或汤,
c)蜂蜜或糖浆,
d)果汁或果汁浓缩物,
e)油中的食品,如油中的蔬菜(例如橄榄或辣椒)、干酪(如羊奶酪)或鱼产品(如沙丁鱼或凤尾鱼)。
包装材料中所使用的涂层组合物和聚合物模制复合物包含作为防粘添加剂的的支化聚合物,其含量(基于涂层组合物的固体含量或基于聚合物模制复合物的总重量)为0.1到10重量%,重均分子量为2000到200000,并且由聚合基础分子和聚二有机基硅氧烷侧链构成,其中侧链以Si-C共价键直接或通过间隔基团共价连接到基础分子上,所述侧链具有1000到30000的重均分子量,并且占支化聚合物总重量的5到25重量%。
作为防粘添加剂而加入涂层组合物和聚合物模制复合物的支化聚合物的聚合基础分子优选自由基加成聚合物、缩聚物或聚加成物并且作为共聚物也可以由结构不同的单体单元构成。
如果聚合基础分子是自由基加成聚合物,那么基础分子中所用单体可以是任何可以进行自由基聚合的烯属不饱和化合物。优选含有如下基团的化合物:(甲基)丙烯酸基、苯乙烯基、烯丙基、乙烯苯基、乙烯醚、乙烯酯或烯酮基。
对于自由基加成聚合,基础分子的特别优选的单体单元选自具有2到30个碳原子的烯烃和芳基烯烃、具有1到22个碳原子的直链、支化或脂环族醇的丙烯酸烷基酯和甲基丙烯酸烷基酯、具有8到18个碳原子的直链、支化或脂环族醇的丙烯酸芳烷基酯和甲基丙烯酸芳烷基酯、具有1到22个碳原子的直链、支化或脂环族胺的丙烯酰胺和甲基丙烯酰胺、具有2到8个碳原子的直链、支化或脂环族氨基醇的丙烯酸氨基烷基酯和甲基丙烯酸氨基烷基酯、具有1到22个碳原子的直链、支化或脂环族醇的马来酸酯、衣康酸酯和富马酸酯、具有3到20个碳原子的乙烯酯、乙烯醚和乙烯酮、具有5到8个碳原子的乙烯基三烷氧基硅烷以及具有10到16个碳原子的甲基丙烯酰氧丙基三烷氧基硅烷。
如果聚合基础分子是缩聚物,则可用于基础分子的单体单元包括所有可缩合形成聚合物的化合物。对此可优选使用的醇组分包括乙二醇、丙二醇、二丙二醇、1,4-丁二醇、1,6-己二醇、2-乙基己-1,3-二醇、新戊二醇、丙三醇、三羟甲基丙烷、季戊四醇和二季戊四醇。对此可优选使用的酸组分包括邻苯二甲酸、邻苯二甲酸酐、间苯二甲酸、对苯二甲酸、四氢邻苯二甲酸、四氢邻苯二甲酸酐、己二酸、癸二酸、马来酸、马来酸酐、富马酸、偏苯三酸、偏苯三酸酐以及均苯四酸和均苯四酸酐。此外还优选己内酯、戊内酯及其衍生物,以及β-丙内酯和十二烷基内酯。
如果聚合基础分子是聚加成物,则可用于基础分子的单体包括所有可通过聚加成互相连接到一起的化合物。所使用的聚加成物优选具有2到80个碳原子的二醇和二异氰酸酯、三异氰酸酯或多异氰酸酯的聚加成产物。所有常规的芳香族、脂肪族、脂环族双官能、三官能和多官能异氰酸酯都可以使用。所使用的二异氰酸酯优选1,6-六亚甲基二异氰酸酯、异佛尔酮二异氰酸酯、4,4’-二亚苯基二异氰酸酯、亚甲苯基二异氰酸酯、4,4’-亚甲基二环己基二异氰酸酯、1,4-二异氰酸酯基丁烷、二苯基甲烷二异氰酸酯等。所使用的三异氰酸酯优选三苯基甲烷三异氰酸酯、2,4,5-甲苯三异氰酸酯以及二异氰酸酯(例如1,6-六亚甲基二异氰酸酯和异佛尔酮二异氰酸酯)的三聚物。也可使用多异氰酸酯(例如多亚甲基多苯基异氰酸酯(PAPI)和异氰脲酸酯(例如六亚甲基二异氰酸酯和异佛尔酮二异氰酸酯的三聚物和聚合物))。
作为基础分子的单体单元,也可使用含聚乙二醇单体单元,以便使支化聚合物有水溶性或水乳化性。对于基础分子的自由基加成聚合,作为含聚乙二醇单体,可使用例如有5到80个碳原子的聚乙二醇单丙烯酸酯或聚乙二醇单甲基丙烯酸酯。这种产品特别适合于含水涂层体系。
还可以使用含有官能团的单体单元,以便以后能够结合到相应的聚合物基质或粘合剂中去。对于基础分子的自由基加成聚合,作为含官能团的单体单元,可以使用例如丙烯腈、丙烯酸、甲基丙烯酸、具有2到36个碳原子的直链、支化或脂环族二醇的丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯,具有3到6个碳原子的直链、支化或脂环族羟基环氧化合物的丙烯酸环氧烷基酯或甲基丙烯酸环氧烷基酯,或具有5到8个碳的乙烯基三烷氧基硅烷。含异氰酸酯基团的烯属不饱和化合物(例如甲基丙烯酸异氰酸甲酯或甲基丙烯酸异丙烯基枯基异氰酸酯)也可用于基础分子的自由基加成聚合。
为大幅度降低含聚二有机基硅氧烷侧链的支化聚合物的表面张力,用共聚的方法引入少量含有全氟烷基的单体单元是有益的。对于基础分子的自由基加成聚合,作为含全氟烷基的单体单元,可以使用有6到20个碳原子的丙烯酸全氟烷基酯、甲基丙烯酸全氟烷基酯或全氟甲基丙烯酸酯。
为保证含聚二有机基硅氧烷侧链的支化聚合物与涂层组合物和/或与聚合物模制复合物之间的足够的相容性,可在支化聚合物中引入羟基和酸官能团。优选OH数为70到150mg KOH/g和酸值为0.5到30mg KOH/g的支化聚合物。将形式为己内酯或戊内酯改性单体单元的聚酯引入聚合基础分子中也是可以的。对于基础分子的自由基加成聚合,优选其平均分子量为220到1200的己内酯和/或戊内酯改性丙烯酸羟烷基酯和己内酯和/或戊内酯改性甲基丙烯酸羟烷基酯,丙烯酸羟烷基酯和甲基丙烯酸羟烷基酯优选由具有有2到8个碳原子的直链的、支化或脂环族二醇衍生得到。
对于自由基加成聚合,基础分子的特别优选的单体单元选自丙烯酸、甲基丙烯酸、丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸正丁酯、甲基丙烯酸正丁酯、丙烯酸异丁酯、甲基丙烯酸异丁酯、丙烯酸叔丁酯、甲基丙烯酸叔丁酯、丙烯酸月桂醇酯、甲基丙烯酸月桂醇酯、丙烯酸2-乙基己酯、甲基丙烯酸2-乙基己酯、丙烯酸硬脂醇酯、甲基丙烯酸硬脂醇酯、丙烯酸山嵛醇酯、甲基丙烯酸山嵛醇酯、丙烯酸环己酯、甲基丙烯酸环己酯、丙烯酸异冰片酯、甲基丙烯酸异冰片酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯、丙烯酸缩水甘油氧丙酯、甲基丙烯酸缩水甘油氧丙酯、乙烯基三乙氧基硅烷、甲基丙烯酰氧丙基三甲氧基硅烷、甲基丙烯酸异氰酸甲酯、异丙烯基枯基异氰酸酯、苯乙烯、α-甲基苯乙烯、丙烯腈、单丙烯酸三亚乙基二醇酯、单甲基丙烯酸三亚乙基二醇酯、乙基乙烯基醚、丁基乙烯基醚、环己基乙烯基醚、乙酸乙烯酯、丙烯酸N,N-二甲胺乙酯、甲基丙烯酸N,N-二甲胺乙酯、丙烯酸N,N-二甲胺丙酯、甲基丙烯酸N,N-二甲胺丙酯、单丙烯酸聚乙二醇酯、单甲基丙烯酸聚乙二醇酯,以及其分子量为220到1200的己内酯-和/或戊内酯-改性丙烯酸羟乙酯和己内酯-和/或戊内酯-改性甲基丙烯酸羟乙酯。
加入涂层组合物和聚合物模制复合物里的支化聚合物中的聚二有机基硅氧烷侧链的重均分子量是1000到30000,并且经由Si-C键直接或通过间隔基团连接到基础分子上。如果基础分子上是自由基加成聚合得到的聚合物,则聚二有机基硅氧烷侧链就可以以单烯属不饱和聚二有机基硅氧烷(即聚二有机基硅氧烷大分子单体)的形式被共聚。作为单烯属不饱和聚二有机基硅氧烷,可以使用例如聚二有机基硅氧烷单(甲基)丙烯酸酯、聚二有机基硅氧烷单烯烃等等。如果基础分子是缩聚物或聚加成物,那么聚二有机基硅氧烷基团可以被共聚,例如以聚二有机基硅氧烷单醇的形式被共聚。
术语“间隔基团”指聚二有机基硅氧烷侧链的硅原子不必须直接连接到聚合物基础分子的碳原子上(如形式A,见下文),也可以在聚二有机基硅氧烷侧链的硅原子与聚合物基础分子的碳原子之间存在有其他分子构成片段,如例如形式B和C中所示。聚二有机基硅氧烷侧链连接到间隔基团的优选方式是通过Si-C键(如B和C)。例如,聚二有机基硅氧烷侧链可以以单异氰酸酯加成物的形式连接在聚合物基础分子上。
例如,可用于以共聚方法将聚二甲基硅氧烷侧链结合到聚合物上的单烯属不饱和聚二有机基硅氧烷大分子单体的例子是例如α-丁基二甲基硅氧-ω-(3-甲基丙烯酰氧丙基)聚二甲基硅氧烷:
可以作为聚二甲基硅氧烷大分子单体而被共聚到聚合物基础分子中的其它例子见例如Koichi Ito(1998)“Polymeric Design by MacromonomerTechnique”,Prog Polym Sci 23:607ff.。该文中还叙述了仅在其一个链端改性的聚二甲基硅氧烷的制备。
但是,原则上可以通过将聚合物基础分子与单末端羟基官能化的聚二有机基硅氧烷反应而使聚二有机基硅氧烷侧链接到基础分子上。也可以使用其它单末端改性的聚二有机基硅氧烷,例如单末端环氧改性的聚二有机基硅氧烷,其先决条件为基础分子含有相应的官能团,如羟基或羧基。
可以用于将聚二甲基硅氧烷侧链通过与聚合物基础分子反应而引入聚合物中的单末端羟基官能化的聚二甲基硅氧烷的例子是例如α-丁基二甲基硅氧-ω-(3-(2-羟乙氧)丙基)聚二甲基硅氧烷
此外,例如可用单末羟基官能化的聚二有机基硅氧烷与含酯的聚合物进行酯交换得到支化聚合物。在这种情况下,也可以使用链长不同的单末端羟基官能化的聚二有机硅烷的混合物。环氧官能化或异氰酸酯官能化的聚合物与单末端羟基官能化和羰基官能化的聚二有机基硅氧烷反应是另一种可用的方法。
通过活性自由基加成聚合和通过基团转移聚合制备支化聚合物也是可行的。
聚二有机基硅氧烷侧链的重均分子量在1000和30000之间,优选3000到10000。聚二有机基硅氧烷侧链在支化聚合物中所占比例在5到25重量%之间,优选5到20重量%之间,进一步优选7.5到12.5重量%。为了制备支化聚合物,可以使用链长相同的聚二有机基硅氧烷侧链,也可以使用链长不同的聚二有机基硅氧烷侧链的混合物。
聚二有机基硅氧烷侧链优选通过选自以下A到C的结构连接:
或
其中
基团R对应于有l到8个碳原子的直链烷基或有3到10个碳原子的全氟烷基,在聚二有机基硅氧烷侧链中,R可以是相同的或者是不同的,
R1基团对应于有2到8个碳原子的直链的或支化的烯基,
R2基团对应于氢原子或-COOR’基团,其中R’是氢原子或有l到22个碳原子的饱和或不饱和的、直链、支化或脂环族烷基基团。
R3基团,如果c是1,则对应于-COOR’基团,如果c是0,则对应于-(CH2)-COOR’基团或甲基,R’基团的定义如上。
系数a可以从0到10,优选0到5,其中
m的选择使聚二有机基硅氧烷侧链的分子量为1000到30000之间。
支化聚合物的重均分子量是200到200000,优选5000到75000,进一步优选5000到7000,更优选10000到50000。
非常特别优选的支化聚合物是添加剂Silclean3700(Byk-ChemieGmbH,Wesel,德国)。
聚合物基础分子可以用本领域的技术人员已知的方法制备。例如对于基础分子的自由基加成聚合,采用过氧化物或偶氮化合物作为自由基生成体(自由基聚合引发剂;亦即以下的引发剂)在有机溶剂中聚合或本体聚合。适宜的溶剂包括酯(如乙酸乙酯、乙酸正丁酯或乙酸1-甲氧基-2-丙酯)和芳族溶剂(例如甲苯或二甲苯)以及酮(例如甲基异丁基酮或甲乙酮)。溶剂的选择是由支化聚合物此后的用途所决定的。优选使用低沸点溶剂,以便在使用纯支化聚合物时可以将溶剂蒸馏出来。
适宜的自由基聚合引发剂包括所有可以引发自由基加成聚合的引发剂。这些引发剂可以是过氧化物、过氧化氢(如碱金属过氧化二硫酸盐)或偶氮化合物。也使用由至少一种有机还原剂和至少一种过氧化物和/或过氧化氢的组合引发剂,例如叔丁基过氧化氢和羟基甲烷亚磺酸的钠盐,过氧化氢和抗坏血酸或过氧化二硫酸钠与亚硫酸钠。其它合适的引发剂有过氧化硫酸或过氧化二硫酸的铵盐或碱金属盐,特别是过氧化二硫酸钠或过氧化二硫酸钾。也可以使用偶氮化合物,如偶氮异丁腈(AIBN)。优选的引发剂是过氧化物,例如过氧化苯甲酸叔丁酯或二苄基过氧化物。
聚合在约40℃到180℃、优选100℃到150℃、更优选110℃到130℃的温度下进行。
加成聚合或聚加成可以在其它助剂的存在下进行(见下文)。
此后支化聚合物还可以用聚合物类反应进行改性。例如通过其基础分子中含羟基单体单元的支化聚合物与马来酸酐反应,可引入活泼双键和酸官能团。其它适宜引入酸官能团的酸酐是例如琥珀酸酐、邻苯二甲酸酐、偏苯三酸酐。另一种可能性是使用结构不同的酸酐对支化聚合物中的含羟基单体单元进行酯化。为了得到更好的水溶性,可以例如用烷基醇胺将酸基团转化成盐形式。另外,可以随后将羟基基团丙烯酸酯化或甲基丙烯酸酯化,从而得到这样的产物,即甚至在辐射固化(例如紫外和电子束固化)的情况下,该产物也可以可靠地引入漆体系中。
可以将防粘添加剂引入适合于生产包装材料的涂层组合物和/或模制复合物中。所述组合物/复合物优选用于生产包装材料的内涂层,例如罐内涂层或桶内涂层。
“包装材料”泛指所有适合于例如包装、储存和运输的容器。其例子是(但并不仅限于此)桶、筒、罐、瓶、管、集装箱、箱、包或袋。适合制作此类包装的材料包括所有适合于制作包装的材料,例如金属、玻璃、木材、纸、织物、皮革、塑料及陶瓷。优选金属和塑料。优选金属是钢合金或铝合金。包装材料可能具有不同容积。其中包括例如容积高达1升、优选高达10升、更优选高达100升、最优选高达1000升的包装材料。
另外,使用防粘添加剂的模制化合物添加剂适用于包装材料的内涂层(例如罐的内涂层和桶的内涂层)。
一般而言,涂层组合物包括适合对用于生产包装材料的材料进行涂层的所有组合物。
使用防粘添加剂的模制组合物添加剂适宜并优选用作包装材料的内涂层,例如罐的内涂层和桶的内涂层。由于支化聚合物的优异的相容性,它们也非常适合用于生产透明涂层。
漆体系特别适合作为涂层组合物。用于包装材料的涂层的多种漆是本领域的技术人员所熟知的。
除了防粘添加剂之外,涂层组合物优选包含至少一种粘合剂以及(如果适当的话)其它组分(例如颜料,填料及常用助剂(见下文))。涂层组合物一般以其所含粘合剂(成膜剂)来表征。“粘合剂”指负责形成膜的大分子物质或形成大分子的物质。适合的例子包括2-组分反应性漆、空气干燥漆、湿气固化漆、酸固化漆、辐射固化漆、分散漆或烘烤漆。
作为例子可以提及的是乙烯基酯树脂、聚乙烯、聚酰胺、聚丙烯腈、氯化橡胶、醇酸树脂、聚酯树脂、聚氨酯树脂、不饱和聚酯树脂、聚酯/聚异氰酸酯组合(2-组分)、聚酯丙烯酸酯(可辐射固化)、丙烯酸树脂、乙酸纤维素酯(纤维素的乙酸酯)、纤维素乙酰丁酸酯(纤维素的乙酸/丁酸酯)、纤维素乙酰丙酸酯(纤维素的乙酸/丙酸酯)、纤维素硝酸酯(纤维素的硝酸酯)、氯磺酸化聚乙烯、环氧树脂、环氧树脂酯、环氧树脂/焦油组合、乙烯-乙酸乙烯酯聚合物、三聚氰胺-甲醛树脂、氯化聚乙烯、苯酚-甲醛树脂、聚甲基丙烯酸甲酯、聚丙烯、聚四氟乙烯、聚氨酯、聚氨酯/焦油组合、聚乙酸乙烯酯、聚丁酸乙烯酯、聚氯乙烯、氯化聚氯乙烯、聚偏二氯乙烯、聚偏二氟乙烯、聚氟乙烯、氯化橡胶、环化橡胶、聚苯乙烯、具有基于丁二烯的弹性体的聚苯乙烯、硅氧烷聚合物、饱和聚酯、尿素-甲醛树脂、不饱和聚酯、氯乙烯-乙酸乙烯酯聚合物、聚丁二烯等及上述物质的混合物。
各种优选的漆体系包括例如基于以下物质的体系:环氧苯酚树脂、醇酸树脂、三聚氰胺树脂、醇酸/三聚氰胺树脂、酚醛树脂、苯氧基苯酚树脂或苯酚/甲醛树脂。其他适宜的体系是丙烯酸漆或2-组分环氧树脂漆。
存在于粘合剂中的聚合物可例如由以下单体组成:C3-C10烷基醇的乙烯醚、带有或不带有支链的C3-C10烯烃、丙烯酸C1-C10烷基酯、甲基丙烯酸C5-Cl0烷基酯、(甲基)丙烯酸C5-C10环烷基酯、马来酸C1-C10二烷基酯和/或富马酸C1-C10二烷基酯。特别优选丙烯酸乙酯、丙烯酸正丙酯、丙烯酸正丁酯、丙烯酸异丁酯、丙烯酸仲丁酯、丙烯酸正己酯、丙烯酸2-乙基己酯、甲基丙烯酸正己酯、甲基丙烯酸2-乙基己酯、马来酸二正丁酯和/或富马酸二正丁酯。其他适宜的单体是乙烯基芳族单体和/或α,β-不饱和腈或二腈。“乙烯基芳族单体”指特别是苯乙烯或α-甲基苯乙烯的衍生物,其中苯环如果适当的话被1、2或3个C1-C4烷基、氯和/或甲氧基取代。特别优选的单体是苯乙烯、α-甲基苯乙烯、邻-或对-乙烯基甲苯、丙烯腈、甲基丙烯腈、马来腈、富马腈或其混合物。
粘合剂也可以含有有交联作用并含有至少两个非共轭烯属不饱和双键的某些单体。其例子有含两个乙烯基的单体、含两个亚乙烯基的单体和含两个链烯基的单体。此处特别有利的是带α,β-单烯属不饱和一元羧酸(其中优选丙烯酸和甲基丙烯酸)的二元醇的二酯。这种含两个非共轭烯属不饱和双键的单体例子有二丙烯酸烷基二醇酯和二异丁烯酸烷基二醇酯,例如二丙烯酸乙二醇酯、二丙烯酸1,2-丙二醇酯、二丙烯酸1,3-丙二醇酯、二丙烯酸l,3-丁二醇酯、二丙烯酸1,4-丁二醇酯和二异丁烯酸乙二醇酯、二异丁烯酸1,2-丙二醇酯、二异丁烯酸1,3-丙二醇酯、二异丁烯酸1,3-丁二醇酯、二异丁烯酸1,4-丁二醇酯,以及二乙烯基苯、甲基丙烯酸乙烯酯、丙烯酸乙烯酯、甲基丙烯酸烯丙酯、丙烯酸烯丙酯、马来酸二烯丙酯、富马酸二丙烯酯、亚甲基二丙烯酰胺、丙烯酸环戊二烯酯、三烯丙基氰尿酸酯或三烯丙基异氰尿酸酯。
涂层组合物可以各种形式存在,例如粉末或高固体涂层材料、水基涂层材料、辐射固化体系。
优选本身即具有憎水性的体系。最优选符合德国(BGA)或美国(FDA)食品法律的体系。
特别优选例如异氰酸酯交联2-组分体系(见实施例11.1)或烘烤清漆(如丙烯酸酯/三聚氰胺烘烤清漆(见实施例11.2))或环氧/苯酚树脂烘烤清漆(见实施例11.3)。
例如可将以下涂层材料用于防粘添加剂的基础涂层材料,但可使用的涂层材料并仅限于此:
名称 | 生产商 | 颜色 | 编号 | 粘合剂 |
桶内漆(R78433) | DuPont | 棕色 | 3208909100 | 酚醛树脂/环氧化物组合 |
桶外烘烤清漆 | DuPont | 无色,有光泽 | 380620101 | 醇酸-三聚氰胺树脂组合 |
桶内漆 | DuPont | 金色 | 379370101 | 酚醛树脂 |
底漆 | DuPont | 黄棕色 | 379930101 | 环氧/酚醛树脂组合 |
桶内漆 | DuPont | 红棕色 | 379380101 | 酚醛树脂 |
Protefan烘烤清漆10-1VSconc.FP>21℃ | Goldschmidt | 灰色,烘烤后橄榄色 | ’0020310l | 酚醛树脂 |
Protefan烘烤清漆10-1VSconc.橄榄色 | Goldschmidt | 灰色,烘烤后橄榄色 | ’00203131 | 酚醛树脂 |
桶内保护漆 | Grace | 金色 | DC 1002-01 | 环氧化物-酚醛组合 |
底漆N 48235 | ICI | 无色 | 7011520 | 环氧化物,mod. |
内保护漆T1/N47929 | ICI | 金色 | 7010745 | 酚醛树脂组合 |
L-1透明酚醛高烘烤浓缩 | KNS | 深琥珀色 | #114-1X | 酚醛树脂 |
L-15深棕酚醛/环氧高烘烤可立即喷雾 | KNS | 深棕色 | #407-8B-N53 | 酚醛-环氧树脂 |
L-35深米黄环氧/酚醛高烘烤浓缩 | KNS | 深米黄色 | #409-3H-J14 | 环氧-酚醛树脂 |
L-5X草绿酚醛高抗冲击高烘烤浓缩 | KNS | 草绿色 | #404-5-D84 | 酚醛树脂 |
L-5X褐色酚醛高抗冲击高烘烤浓缩 | KNS | 褐色 | #404-5-S83 | 酚醛树脂 |
L-40X透明环氧化物改性LoVoc LoCure“Prime Flex”可立即喷雾 | KNS | 水白色 | #119-PF-D99 | 环氧化物,mod. |
WL-105755粘结层 | Rembrandtin | 米色 | 210088 | 环氧(MG>700) |
WL-107031内保护漆 | Rembrandtin | 米色 | 210094 | 环氧(MG>700)/酚醛树脂 |
WL-105731内保护漆 | Rembrandtin | 黄色 | 210092 | 环氧(MG>700)/酚醛树脂 |
WL-105701滚涂底漆 | Rembrandtin | 金色 | 210090 | 环氧(MG>700) |
名称 | 生产商 | 颜色 | 编号 | 粘合剂 |
WL-105700内保护漆 | Rembrandtin | 金色,有光泽 | 210097 | 环氧(MG>700)/酚醛树脂 |
WL-107910内保护漆 | Rembrandtin | 金色,有光泽 | 210096 | 环氧(MG>700)/酚醛树脂 |
WL-106193滚涂底漆 | Rembrandtin | 灰色,约RAL 7035 | 210089 | 醇酸树脂,含OH |
WL-105720内保护漆 | Rembrandtin | 红棕色 | 210091 | 酚醛树脂,mod. |
内保护漆RDL16(Z3) | Van Leer | 金色透明 | RDL16S00VRE | 酚醛树脂 |
内保护漆RDL50(Z42) | Van Leer | 灰色,烘烤后橄榄色 | RDL50S00VRE | 酚醛树脂 |
RDL44(HB19金黄棕) | Van Leer | 黄棕色 | - | 环氧化物-酚醛树脂 |
RDL59(Z4) | Van Leer | 橄榄绿色 | - | 酚醛树脂 |
RDL68 | Van Leer | 无色 | - | Phenoxy酚醛树脂 |
漆体系及助剂例如可从下述公司购得:DuPont Performance CoatingsAustria GmbH VB Leipzig,Mlkau/Leipzig,德国;Dupont PerformanceCoatings Austria GmbH,Guntramsdorf,奥地利;Chem.Werke KlutheGmbH,海德堡,德国;Goldschmidt TIB GmbH,曼海姆,德国;GraceCoatings,Geschftsbereich Lacke,Norderstedt,德国;ICI Lacke FarbenGmbH,希尔敦,德国;KNS Companies Inc,Carol Stream,伊利诺伊州,美国;Rembrandtin Lack Gesellschaft mbH,维也纳,奥地利;Van LeerVerpackungen,Attendorn,德国;Van Leer Nederland B.V.,Vreelande,荷兰,等等。
涂层组合物含有作为防粘添加剂的支化聚合物的量从0.1到10重量%,优选0.5到7.5重量%,优选0.5到5重量%,非常优选1到5重量%(基于涂层组合物所含固体的量)。支化聚合物优选以溶液或乳液的形式加入涂层组合物中。
可以用多次涂层的方法将涂层施于底漆、表面涂料或底涂层上。
可以以下述方法进行加工,例如空气混合、真空、热或压缩空气喷雾、滚涂、刮刀涂、刷涂、喷涂、散布、电涂层、旋转涂层或磙涂等。在采用喷雾或离心涂层时,可以采用适当的稀释剂对加工粘度任意进行调整。
涂层组合物的固化取决于所用交联类别,并且可以在很宽的温度范围(如-10℃到250℃)内进行。令人惊奇的是,即使在室温下固化,涂层组合物仍表现出良好的防粘性。
聚合物模制复合物优选成膜树脂、醇酸树脂、聚酯树脂、环氧树脂、聚氨酯树脂、不饱和聚酯树脂、环氧树脂、乙烯酯树脂、聚乙烯、聚丙烯、聚酰胺、聚对苯二甲酸乙二醇酯、PVC、聚苯乙烯、聚丙烯腈、聚丁二烯、聚氯乙烯或这些聚合物的混合物。
聚合物模制复合物含有作为防粘添加剂的支化聚合物的量是0.1到10重量%,优选0.5到7.5重量%,优选0.5到5重量%,非常优选1到5重量%(基于聚合物模制复合物总重量)。支化聚合物优选以100%的形式加入聚合物模制复合物。另外,它们可以在上述复合物的制备过程(如聚加成或加成聚合)中已经存在。
聚合物模制复合物可以以其本身的形式用于生产包装材料,例如桶、杯、罐、筒或瓶。防粘添加剂可以在聚合物模制复合物的制备过程(即在加成聚合过程中)中加入,也可以在包装材料的生产过程中(例如在挤出阶段)加入。
聚合物模制复合物还可以用于另一些材料的涂层,例如金属罐或桶可以用聚合物模制复合物添加剂以聚合物内部涂层的形式涂层。
聚合物模制复合物可以加入复合材料中。其例子是(但不仅限于)将其用于叠层材料中,例如公知的TETRAPAK包装形式。在这些情况下,聚合物模制复合物(例如聚乙烯)以及(如合适的话)其它层(例如铝)被施于纸或卡片上,以便得到具有高气味和味道安全性的包装形式。相应的材料和方法见例如EP-A 0 423 511或EP-A 0 621 202。防粘添加剂可以加入这种材料中所使用的聚合物模制复合物中。
涂层组合物和聚合物模制复合物还可包含颜料、填料和/或其它助剂。助剂指一般以小量加入、具有特定的化学或技术效果的物质。所加入的助剂的总量一般小于10重量%(基于涂层组合物或聚合物模制复合物的重量),优选小于5重量%,更优选小于1重量%,非常优选小于0.1重量%。
助剂的物理基础是非常多样的,因为其应用在涂层组合物中时所希望的效果是非常不同的。根据其作用,助剂可以分成下面的几组,例如润湿剂、分散剂、固化加速剂(催化剂)、乳化剂、表面活性化合物(如润湿剂和分散剂)、稳定剂、粘度改进剂、粘合剂、增稠剂、防腐剂、成膜助剂、疏水化剂、光稳定剂、老化抑制剂、匀化剂和成膜助剂(如高沸点化合物、聚结剂)、表面改性剂(如滑爽添加剂、消光剂)、腐蚀抑制剂、杀生物剂、阻燃剂、光引发剂、防结皮剂、消泡剂、粘合促进剂等。
涂层组合物及聚合物模制复合物可以以加有颜料的或不加颜料的形式使用。“颜料”指例如细小的、能带来颜色的和/或抑制腐蚀的、实际上不溶于所用介质的粉末。
典型的无机颜料的例子是二氧化钛(优选金红石形式)、硫酸钡、氧化锌、亚硫酸锌、磷酸锌、碱式碳酸铅、三氧化锑、锌钡白(亚硫酸锌和硫酸钡)。但是,制剂可含有色颜料,例如氧化铁、碳黑、石墨、荧光颜料、锌黄、锌绿、群青、锰黑、锑黑、锰紫、巴黎蓝、珠光颜料或巴黎绿。除了无机颜料外,制剂还包含有有机有色颜料,例如乌贼墨、藤黄、颜料棕、甲苯胺红、对位红、汉撒黄、靛蓝、偶氮染料、anthraquinonoide和inditgoide染料,以及二噁嗪、喹吖酮、酞菁、isoindolinone和金属络合物颜料。
还可以加入颜料分散剂作为辅助材料,优选酸值小于600(根据DIN 53402测定)的颜料分散剂。适宜的颜料分散剂包括聚丙烯酸或丙烯酸、甲基丙烯酸、马来酸酐、衣康酸、富马酸或巴豆酸与共聚单体(例如(甲基)丙烯酸酯、苯乙烯、α-烯烃、马来酸单酯和Versatic acid的长链乙烯酯)的共聚物。其它可使用的颜料分散剂包括聚磷酸盐(例如聚磷酸钠或聚磷酸钾)。优选使用聚丙烯酸或丙烯酸、苯乙烯和α-甲基苯乙烯共聚物、丙烯酸和丙烯酸烷基酯(例如丙烯酸正丁酯)的共聚物、马来酸酐和C10-C30α-烯烃的(经水解后的)的共聚物或马来酸酐和苯乙烯的(经水解后的)共聚物的颜料分散剂III。其它适宜的颜料分散剂包括通过富含酸基团的聚合物(例如聚丙烯酸)与长链醇、胺或环氧化物的或含有羧酸酐的共聚物(例如马来酸酐和苯乙烯)与醇或胺的聚合物类反应制备的两性共聚物。
涂层组合物和聚合物的模制化合物还可包含填料。填料是实际上不溶于所用的介质并且赋予或改进特定的技术性质以及赋予涂层组合物更大的体积(充满度)的粉末。适宜的无机填料原则上包括铝硅酸盐如长石、硅酸盐如高岭土、滑石、云母、菱镁矿、碱土金属碳酸盐如碳酸钙(其形式为例如方解石或白垩)、碳酸镁、白云石、碱土金属硫酸盐如硫酸钙、二氧化硅等。填料可作为单独的组分使用。也可以使用特氟隆、二氧化钛、氢氧化铝、纤维素纤维和增强纤维如玻璃纤维、碳纤维和芳香酰胺纤维。也可使用适宜的混合物,如碳酸钙/高岭土、碳酸钙/滑石。
为了调整成膜性质,可以加入所谓成膜助剂,其例子是乙二醇、丙二醇、丁二醇、己二醇、二醇和多醇的烷基醚和烷基醚酯,例如二乙二醇单甲醚,乙酸二乙二醇单***酯,二乙二醇单丁醚,二乙酸己二醇酯,丙二醇单乙、单苯、单丁和单丙醚,二丙二醇单甲醚,二丙二醇单正丁醚,三乙二醇单正丁醚,以及以上单烷基醚的乙酸酯,例如乙酸丁氧丁基酯,以及脂肪族单羧酸和二羧酸的烷基酯、例如Eastman的Texanol、或丁二酸、戊二酸和己二酸的二丁基酯的技术级混合物。
增稠剂的例子是纤维素衍生物,例如甲基纤维素、羟乙基纤维素和羧甲基纤维素,以及酪蛋白、***胶、黄蓍胶、淀粉、藻朊酸钠、聚乙烯醇、聚乙烯吡咯烷酮、聚丙烯酸钠、基于丙烯酸和甲基丙烯酸的水溶性共聚物(例如丙烯酸/丙烯酰胺共聚物和甲基丙烯酸/丙烯酸酯共聚物),以及所谓缔合增稠剂,其例子是苯乙烯/马来酸酐聚合物或(优选地)憎水改性聚醚氨酯,如例如Chen N等,(1997)J Coatings Techn 69(867):73ff、和Hester RD等,(1997)J Coatings Techn 69(864):109ff.中所描述的,其公开的内容全部结合于此作为参考。也可使用无机增稠剂,例如膨润土或锂蒙脱石。
涂层组合物还可含有溶剂。溶剂是可以溶解成膜剂的液体或液体混合物。例如(但不仅限于)乙酸丁酯、丁二醇、石油溶剂和水。当用来调整加工性质(粘度)时,称其为稀释剂。涂料的稀释剂一般是醇、酯、脂肪族和/或芳香族化合物的、专门定制以适应特定涂层材料及涂层方法的混合物。值得叙述的合适的稀释剂的例子是V0449(DuPont;编号:38044105)、HAKU 4064-1(Kluthe;编号:’0140641)、HAKU 4062(Kluthe;编号:’014062)、Protefan稀释剂10T-V/F(Goldschmidt;编号:’00301757)。
分散剂一般是不溶解成膜剂而是使其保持在细小的、微观不均一的分散态(分散液、乳浊液)的液体。可提及的例子包括水以及(对于非水分散液)烃。
另外,还可以应用非离子或阴离子乳化剂作为助剂。有用的非离子乳化剂是芳香脂肪族或脂肪族非离子乳化剂,例如乙氧基化单-、二-、或三-烷基苯酚(EO单元:3到50,烷基:C4-C9)、长链醇的乙氧基化物(EO单元:3到50,烷基:C8-C36)和聚氧乙烯/聚氧丙烯嵌段共聚物。优选使用长链烷基醇的乙氧基化物(烷基:C10-C22,平均乙氧基化度10到50)并且其中特别优选使用具有直链C12-C18烷基基团并且平均乙氧基化度10到50的那些作为唯一的非离子乳化剂。阴离子乳化剂包括例如烷基硫酸(烷基:C12-C18)的碱金属盐和铵盐、乙氧基化烷基醇(EO单元:2到50,烷基:C12-C18)硫酸单酯的碱金属盐和铵盐和乙氧基化烷基酚(EO单元:3到50,烷基:C4-C9)硫酸单酯的碱金属盐和铵盐、烷基磺酸(烷基:C12-C18)的碱金属盐和铵盐和烷基芳基磺酸(烷基:C9-C18)的碱金属盐和铵盐的碱金属盐和铵盐。其他适宜的乳化剂可参见Houben-Weyl,《有机化学方法》(“Methoden der organischen Chemie”),第XIV/1卷,大分子化合物(“Makromolekulare Stoffe”),Georg-Thieme Verlag,Stuttgart,1961,第192-208页。优选的阴离子表面活性物质是例如Dowfax2A1(Dow Chemical Company的商标名)的化合物和US 4,269,749中所描述的化合物。
还可以使用适当的保护胶体,例如聚乙烯醇、纤维素衍生物或乙烯吡咯烷酮共聚物等。其它适宜的保护胶体的详细描述可参见Houben-Weyl,《有机化学方法》(“Methoden der Organischen Chemie”),第14/1卷,大分子化合物(“Makromolekulare Stoffe”),Georg-Thieme-Verlag,Stuttgart,1961,第411-420页。
作为粘合剂的共聚物的分子量可以用加入少量一种或几种分子量调节剂(例如含硫有机化合物或烯丙醇)加以调整。
制备防粘添加剂和/或粘合剂的共聚反应之后,将有气味的物质(如残存的单体或其他可挥发性有机物)从聚合物中大部分分离出去是有益的。这可用本身已知的物理方法、通过蒸馏(特别是水蒸汽蒸馏)或惰性气体气提完成。也可以采用化学方法通过自由基后聚合、特别是在氧化还原引发剂体系作用下的自由聚后聚合来降低残留单体的含量。参见DE-A 44 35 423、DE-A 44 19 518和DE-A 44 35 422。适宜于氧化还原引发后聚合的氧化剂包括特别是过氧化氢、特丁基过氧化氢,枯烯过氧化氢或碱金属过氧化物硫酸盐,适宜的还原剂是焦亚硫酸钠、亚硫酸氢钠、连二亚硫酸钠、羟甲基亚磺酸钠、甲脒亚磺酸、丙酮二亚硫酸盐(亚硫酸氢钠与丙酮的加成物)、抗坏血酸和有还原作用的糖类化合物,或水溶性硫醇,如巯基乙醇。使用氧化还原体系的后聚合在10℃到100℃、优选20到90℃的温度下进行。氧化还原对可以互相独立地完全加入、分若干部分加入或连续地在10分钟到4小时的时间内加入。为了改进氧化还原引发体系的后聚合效果,可以加入变价金属的可溶性盐,如铁盐、铜盐和钒盐。还经常加入络合剂,以使金属盐在反应条件下保持在溶液中。
用于支化聚合物制备的合成实施例
用于支化聚合物制备的自由基加成聚合的合成实施例
实施例1
在一个带有搅拌器、温度计、滴液漏斗、顶置式蒸馏设备和氮入口管的四颈烧瓶中装入10g有甲基丙烯酸端基且重均分子量为5000g的聚二甲基硅氧烷大分子单体和100g乙酸甲氧基丙酯,并且将这些组分彻底混合。在整个反应过程中氮从混合物上方通过。将温度升到122℃,并在4小时的过程中计量加入2g甲基丙烯酸、42.7g甲基丙烯酸异丁酯、26.0g甲基丙烯酸羟基丙酯、29.3g苯乙烯和1.5g TrigonoxC(过苯甲酸叔丁酯,AkzoNobel,Amersfoort,荷兰)的混合物。在进料结束后马上加入0.25gTrigonox C。在另外的30分钟和60分钟后,加入一份0.25g Trigonox C。此后将这一批次保温在122℃1小时。该批次透明粘稠。聚合物溶液的OH数约为53mg KOH/g。核磁共振分析显示含聚二甲基硅氧烷的甲基丙烯酸酯的希望的信号。
实施例2
在一个带有搅拌器、温度计、滴液漏斗、顶置式蒸馏设备和氮入口管的四颈烧瓶中装入10g有甲基丙烯酸端基且重均分子量为20000g的聚二甲基硅氧烷大分子单体和100g乙酸甲氧基丙酯,并且将这些组分彻底混合。在整个反应过程中氮从混合物上方通过。将温度升到122℃,并在3小时的过程中计量加入2g甲基丙烯酸、14.5g己内酯改性的丙烯酸羟基乙酯(Tone M-100,Union Carbide,平均分子量344)、12g甲基丙烯酸正丁酯、19.5g甲基丙烯酸羟基丙酯、22.8g苯乙烯、19.2g甲基丙烯酸甲酯和1.5g Trigonox C(过苯甲酸叔丁酯,Akzo Nobel,Amersfoort,荷兰)的混合物。在进料结束后马上加入0.25g Trigonox C。在另外的30分钟和60分钟后,各加入一份0.25g Trigonox C。此后将这一批次保温在122℃1小时。该批次透明粘稠。聚合物的OH数约为53mg KOH/g。核磁共振分析显示含聚二甲基硅氧烷的(甲基)丙烯酸酯的希望的信号。
实施例3
在一个带有搅拌器、温度计、滴液漏斗和氮入口管的四颈烧瓶中将34.5g苯乙烯和马来酸酐的共聚物(SMA2000,Atofina,重均分子量为2500,苯乙烯/马来酸酐的比例为2∶1)溶解于50.6g乙酸甲氧基丙酯中,并将溶液加热到120℃。在5分钟内,计量加入3.75g重均分子量为1000g的单端基羟基官能化改性的聚二甲基硅氧烷。30分钟后,在5分钟内计量加入12.6g 2-乙基己醇。此后将反应混合物保温在120℃下两个小时和在50℃下1小时。得到固含量约为50%的透明产物。通过红外光谱分析,没有检测到酸酐。聚合物的平均分子量约为3800g。核磁共振分析显示聚二甲基硅氧烷改性的苯乙烯/马来单酯共聚物的希望的信号。
实施例4
在一个带有搅拌器、温度计、滴液漏斗、顶置式蒸馏设备和氮入口管的四颈烧瓶中装入10g带有甲基丙烯酸端基且重均分子量为5000g的聚二甲基硅氧烷大分子单体和252g二甲苯,并且将这些组分彻底混合。在整个反应过程中氮从混合物上方通过。将混合物加热到130℃,并在220分钟的过程中计量加入5g己内酯改性的丙烯酸羟基乙酯(Tone M-100,UnionCarbide,平均分子量344)、49g甲基丙烯酸正丁酯、12g甲基丙烯酸羟基乙酯、23.5gα-甲基苯乙烯和1.5g TrigonoxC(过苯甲酸叔丁酯,Akzo Nobel,Amersfoort,荷兰)。计量进料结束后将反应混合物在130℃下保温1小时。这时候该批次呈不透明的乳白色。为除去溶剂和过量的反应物,将混合物减压蒸馏。在真空度为约20mbar和130℃下蒸馏2个小时后,得到一个产率为54.5%的不透明聚合物,其重均分子量约为14700g。核磁共振分析显示含聚二甲基硅氧烷的(甲基)丙烯酸酯的希望的信号。
实施例5:通过基团转移聚合制备添加剂
准备工作:将所有的单体和溶剂通过中性氧化铝玻璃柱从而提纯。
在干燥的N2气氛下,将100g预先纯化的四氢呋喃装入一个充分干燥的、装有机械搅拌机、回流冷凝器、滴液漏斗和橡胶塞的四颈烧瓶中。使用注射器将作为引发剂的1.5g 1-甲氧基-3-甲基硅氧基-2-甲基丙烯和作为催化剂的0.15ml 1M3-氯苯甲酸四丁铵的乙腈溶液通过橡胶塞加入到瓶中。在15分钟的过程内,将70g甲基丙烯酸丁酯和20g甲基丙烯酸N,N-二甲基氨基乙酯的混合物逐滴加入到反应混合物中。通过水浴保持反应温度在40℃。在随后的10分钟反应时间后,另外加入0.15ml 1M 3-氯苯甲酸四丁铵的乙腈溶液并在5分钟的过程内逐滴加入40g浓度为50%的、预先纯化的、重均分子量为1000g的、带有甲基丙烯酸端基的聚二甲基硅氧烷大分子单体的THF溶液,在没有冷却的情况下将反应溶液搅拌1小时,然后加入3ml的乙醇以终止活性链端。得到了轻微浑浊的聚合物溶液。
实施例6
在一个带有搅拌器、温度计、滴液漏斗、顶置式蒸馏设备和氮入口管的四颈烧瓶中装入10g有甲基丙烯酸端基且重均分子量为5000g的聚二甲基硅氧烷大分子单体和100g DIBK,并且将这些组分彻底混合。在整个反应过程中氮从混合物上方通过。将混合物加热到122℃,并在3小时的过程中计量加入15g己内酯改性的丙烯酸羟基乙酯(Tone M-100,UnionCarbide,平均分子量344)、12.0g甲基丙烯酸正丁酯、20g甲基丙烯酸羟基乙酯、22.5g苯乙烯、20.5g甲基丙烯酸甲酯和1.5g TrigonoxC(过苯甲酸叔丁酯,Akzo Nobel,Amersfoort,荷兰)的混合物。当计量结束时温度被保持在122℃。在计量添加结束后、30分钟后和另一个30分钟后,各加入一份0.25g TrigonoxC。在最终的添加后,连续搅拌1小时。反应混合物稍混浊。为除去溶剂和过量的反应物,将混合物减压蒸馏。在真空度为约20mbar和140℃下蒸馏90分钟后,得到产率为94%的不透明聚合物。通过以聚苯乙烯为标准的凝胶渗透色谱来确定其重均分子量,约为65000g。
实施例7
在一个带有搅拌器、温度计、滴液漏斗、顶置式蒸馏设备和氮入口管的四颈烧瓶中装入5g有甲基丙烯酸端基且重均分子量为5000g的聚二甲基硅氧烷大分子单体、5g有甲基丙烯酸端基且重均分子量为1000g聚二甲基硅氧烷大分子单体、50g二甲苯和50g乙酸丁酯,并且将这些组分充分混合。在整个反应过程中氮从混合物上方通过。将混合物加热到122℃,并在180分钟的过程中计量加入15g己内酯改性的丙烯酸羟基乙酯(ToneM-100,Union Carbide,平均分子量344)、12g丙烯酸正丁酯、20g甲基丙烯酸羟基乙酯、22.5g苯乙烯、20.5g甲基丙烯酸甲酯和1.5g TrigonoxC(过苯甲酸叔丁酯,Akzo Nobel,Amersfoort,荷兰)的混合物。当计量结束时温度被保持在122℃。在计量添加结束后、30分钟后和另一个30分钟后,各加入一份0.25g TrigonoxC。在最终的添加后,连续搅拌1小时。为除去溶剂和过量的反应物,将混合物减压蒸馏。在真空度为约20mbar和140℃下蒸馏90分钟后,得到产率为约99.5%的无色聚合物。将50g该聚合物溶解于25g二甲苯和25g乙酸丁酯的混合物中,并将溶液与0.05g对甲苯磺酸和0.42g马来酸酐混合。在90℃下加热3个小时后用红外光谱分析,没有检测到酸酐。
实施例8
将50g从实施例1得来的、OH数约为53mgKOH/g的聚合物溶液与4.3g马来酸酐混合,并将混合物在90℃下加热并搅拌6个小时。经过这段时间后通过红外光谱分析,没有检测到酸酐。得到浓度为56.3%的浅黄色聚合物溶液。
实施例9:缩聚物的合成例子
在一个带有搅拌器、温度计和水分离器的三颈烧瓶中装入100g Setal183 XX-60(饱和聚酯树脂,供给形式为60%二甲苯溶液,酸值为8.3mgKOH/g,Akzo Nobel Resins,Bergen op Zoom,荷兰)、7.5g有端羟基官能团且重均分子量为10000g的聚二甲基硅氧烷大分子单体和0.3g对甲苯磺酸,并且将这些组分彻底混合。其后该批次回流沸腾约6个小时直到形成的水已经被除去。温度为约142℃到145℃。得到黄棕色的聚合物溶液。核磁共振分析显示所希望的酯连接的聚二有机基硅氧烷。在红外光谱中没有看到OH基团。
实施例10:聚加成物的合成实施例
在一个带有搅拌器、温度计、氮入口管和滴液漏斗的四颈烧瓶中装入50g乙酸正丁酯、5.38g DesmodurN3300(基于二异氰酸环己酯的异氰尿酸酯,NCO含量为21.5%,Bayer AG,Leverkusen,德国)和10g有端羟基官能团且重均分子量约为1000g(OH数为51.5mg KOH/g)的聚二甲基硅氧烷大分子单体。在整个反应过程中干燥的氮从该批次上方通过。该批次被加热到60℃。然后加入0.2g浓度为1%月桂酸二丁基二锡酯的二甲苯溶液。30分钟后另外加入0.7g浓度为1%月桂酸二丁基二锡酯的二甲苯溶液并马上随后开始计量加入50g乙酸丁酯、25.17g异佛尔酮二异氰酸酯、55.79g Speziol C36/2(二醇二聚物,OH数为205mg KOH/g,CognisDeutschland GmbH,Düsseldorf,德国)和3.2g 1-丁醇的混合物。混合物以不会使混合物的温度升高到65℃以上的速度逐滴加入。溶液的粘度增加,并且在计量添加结束3个小时后,通过滴定测量没有检测到游离的异氰酸酯。得到透明无色的溶液。通过凝胶渗透色谱确定其重均分子量约为5200g。
实施例11:向涂层***中引入防粘添加剂
在不同的涂层***中进行防粘添加剂的性能测试。
11.1:2-组分体系,异氰酸交联
储存清漆:
75.00%MacrynalSM 510n(含羟基的丙烯酸树脂,Vianova Resins,法兰克福,德国),在二甲苯/溶剂石脑油/乙酸丁酯2∶1∶1中,60%
5.00%DowanolPMA
5.00%Solvesso100
6.50%二甲苯
8.00%乙酸丁酯
0.50%Byk066(消泡剂,BYK-CHEMIE,Wesel,德国)
100.00%
将所有组分搅拌均匀。
固化溶液:
50.00%DesmodurN3390(聚异氰酸酯,Bayer AG,Leverkusen,德国),在乙酸丁酯/SN100 1∶1中,90%
35.00%乙酸丁酯
15.00%二甲苯
100.00%
将所有组分搅拌均匀。储存清漆和固化溶液各自单独制备。在实施例1、2、3、4、6和7中制备得到的支化聚合物被搅拌加入到储存清漆中,其浓度为2.67%(基于总涂层材料的固体部分)。作为比较,也加入羟基烷基聚二甲基硅氧烷(TegoProtect5000)、聚丙烯酸硅氧烷酯(TegoProtect5001)和羟基官能化的、直链的、聚酯改性的聚二甲基硅氧烷(BYK-370)。在使用前才将储存清漆和固化溶液按2∶1的比例混合。混合后,通过一个螺旋涂板器将添加剂涂层材料在预先涂有底漆的铝板上下拉成100μm湿膜。在室温下干燥30分钟后,将板放到80℃的涂料干燥器中固化30分钟。对于每一个添加剂涂层材料,生产出两块板。一块板在实验室洗碗机中用常规家庭洗涤剂在80℃下洗涤。洗涤后,已完成涂层的板在室温条件下保存至少24个小时。其后已处理和未处理的板按下面指定的方法进行测试。11.2、丙烯酸酯/三聚氰胺烘烤漆
54.00% SetaluxC1502(丙烯酸烘烤树脂,Akzo Nobel Resins,Bergen opZoom,荷兰)
28.00% MaprenalMF600(三聚氰胺烘烤树脂,Vianova Resins,法兰克福,德国)
4.00% Shellsol
4.00% Solvesso150
10.00% 二甲苯
100.00%
丙烯酸酯/三聚氰胺烘烤漆的制备:将所有组分混合并用圆周速度为5m/s的溶解器均化10分钟。其后用二甲苯将粘度调整到24秒(DIN 4mm杯)。试验防粘添加剂在10分钟的过程中用Scandex振动器以2重量%(即于涂层材料的固体部分)活性物质混入。作为比较,混入与烘烤漆的制备有关的化合物(TegoProtect5000,TegoProtect5001 and BYK-370)。混入后,通过一个螺旋涂板器将添加剂涂层材料在预先涂有底漆的铝板上下拉成100μm湿膜。经10分钟的闪蒸后,将板在140℃下烘烤20分钟。对于每一个添加剂涂层材料,生产出两块板。一块板在实验室洗碗机中用常规家庭洗涤剂在80℃下洗涤。洗涤后,已完成涂层的板在室温条件下保存至少24个小时。其后已处理和未处理的板按下面指定的方法进行测试。
11.3、环氧化物/酚醛树脂烘烤漆
将由实施例1制得的防粘添加剂加到Goldlack WL-105700(基于环氧化物(MG>700)/酚醛树脂的内保护漆,制造商:Rembrandtin LackGesellschaft mbH,维也纳,奥地利;编号:210097;供给形式的漆),将组分一起充分搅拌。在第一批次中,为获得1%的防粘添加剂最终浓度,使用4%重量的添加剂配方物。为获得2%的防粘添加剂最终浓度,使用8%重量的添加剂配方物。
通过常规压缩空气喷雾法(手工涂层)准备用于随后的测试(见实施例13到16)的桶(钢桶每个净容量为25kg;Gottlieb Duttenhfer GmbH& Co.KG,Hassloch,德国)。烘烤条件:8到10分钟,桶温度210到220℃。
实施例12:将防粘添加剂引入聚合物模制复合物(凝胶涂层混合物)
由实施例8得到的聚合物溶液按下表与凝胶涂层和Butanox M-50反应,形成聚合物模制复合物A和B(=凝胶涂层混合物A和凝胶涂层混合物B)。
测试凝胶涂层混合物的配方(重量百分比):
凝胶涂层混合物A | 凝胶涂层混合物B | |
Gel-Coat(自由基引发剂,Akzo Nobel,Amersfoort,荷兰) | 97 | 97 |
Butanox M-50(Oldopal 733-0001,Büfa GmbH,Oldenburg,德国 | 2 | 2 |
由实施例8得到的聚合物溶液 | 1 | - |
确定这些凝胶涂层混合物的防粘合特性。其方法是首先用乙酸乙酯洗涤金属容器将金属容器彻底脱脂。20分钟的闪蒸后,将凝胶涂层混合物A和B涂到容器的内壁上,涂层厚度均为750μm。将所有的凝胶涂层固化三天,然后按实施例13到16对排空的程度进行测试。
实施例13:桶的维生素E乙酸酯的排空程度测试
如上所述将每个净容量为25kg的钢桶(Gottlieb Duttenhfer GmbH &Co.KG,Hassloch,德国)涂上添加和未添加防粘添加剂的烘烤清漆Goldlack WL-105700(基于环氧化物(MG>700)/酚醛树脂的内保护漆,制造商:Rembrandtin Lack Gesellschzft mbH,维也纳,奥地利;编号:210097;供给形式的漆)。桶号为1和4上的漆含有1%的防粘添加剂,桶号为2和5上的漆含有2%的防粘添加剂,而桶号为3和6上的漆不含防粘添加剂。在桶中装入食品级的维生素E乙酸酯(BASF Aktiengesellschaft;PN 074099)。将桶1、2和3在60℃下在炉中加热约17小时。其后将桶从炉中移出,将内容物倒出,时间为1分钟。在再等候3分钟后,另外清空2分钟,确定残留量。
桶1 | 桶2 | 桶3 | |
净含量 | 25.02kg | 25.04kg | 25.04kg |
残留物含量 | 0.120kg | 0.130kg | 0.190kg |
将桶4、5和6首先从炉中移出并清空1分钟。随后将其在60℃下在炉中加热60分钟,又排空2分钟,然后确定残留量。
桶4 | 桶5 | 桶6 | |
净含量 | 25.03kg | 25.03kg | 25.07kg |
残留物含量 | 0.03kg | 0.03kg | 0.09kg |
实施例14:桶的维生素E乙酸酯的排空程度测试
如上所述将每个净容量为25kg的钢桶(Gottlieb Duttenhfer GmbH &Co.KG,Hassloch,德国)涂上添加和未添加防粘添加剂的烘烤清漆Goldlack WL-105700(基于环氧化物(MG>700)/酚醛树脂的内保护漆,制造商:Rembrandtin Lack Gesellschzft mbH,维也纳,奥地利;编号:210097;供给形式的漆)。桶号为1和4上的漆含有1%的防粘添加剂,桶号为2和5上的漆含有2%的防粘添加剂,而桶号为3和6上的漆不含防粘添加剂。在桶中装入食品级的维生素E乙酸酯(BASF Aktiengesellschaft;PN 074099)。
将桶1、2和3在80℃的炉中加热约16小时。其后将桶从炉中移出,将内容物倒出,时间为1分钟。在再等候3分钟后,另外清空2分钟,然后确定残留量。
桶1 | 桶2 | 桶3 | |
净含量 | 25.03kg | 25.08kg | 25.00kg |
残留物含量 | 0.08kg | 0.085kg | 0.121kg |
实施例15:桶的维生素A棕榈酸酯的排空程度测试
如上所述将每个净容量为25kg的钢桶(Gottlieb Duttenhfer GmbH &Co.KG,Hassloch,德国)涂上添加和未添加防粘添加剂的烘烤清漆Goldlack WL-105700(基于环氧化物(MG>700)/酚醛树脂的内保护漆,制造商:Rembrandtin Lack Gesellschzft mbH,维也纳,奥地利;编号:210097;供给形式的漆)。桶号为1和4上的漆含有1%的防粘添加剂,桶号为2和5上的漆含有2%的防粘添加剂,而桶号为3和6上的漆不含防粘添加剂。在桶中装入ph级的维生素A棕榈酸酯1.6百万(BASFAktiengesellschaft;PN 073930)。将桶1、2和3在60℃下在炉中加热约16小时。其后将桶从炉中移出,将内容物倒出,时间为1分钟。在再等候3分钟后,另外进一步清空2分钟,确定残留量。
桶1 | 桶2 | 桶3 | |
净含量 | 25.02kg | 25.025kg | 25.018kg |
残留物含量 | 0.024kg | 0.023kg | 0.100kg |
实施例16:桶的维生素A棕榈酸酯的排空程度测试
如上所述将每个净容量为25kg的钢桶(Gottlieb Duttenhfer GmbH &Co.KG,Hassloch,德国)涂上添加和未添加防粘添加剂的烘烤清漆Goldlack WL-105700(基于环氧化物(MG>700)/酚醛树脂的内保护漆,制造商:Rembrandtin Lack Gesellschzft mbH,维也纳,奥地利;编号:210097;供给形式的漆)。桶号为1和4上的漆含有1%的防粘添加剂,桶号为2和5上的漆含有2%的防粘添加剂,而桶号为3和6上的漆不含防粘添加剂。在桶中装入ph级的维生素A棕榈酸酯1.0百万(BASFAktiengesellschaft;PN 078915)。
将桶1、2和3在60℃下在炉中加热约16小时。其后将桶从炉中移出,将内容物倒出,时间为1分钟。在再等候3分钟后,另外进一步清空2分钟,确定残留量。
桶1 | 桶2 | 桶3 | |
净含量 | 25.01kg | 25.00kg | 25.00kg |
残留物含量 | 0.009kg | 0.010kg | 0.075kg |
Claims (17)
1、包含至少一种具有防粘性能的涂层组合物的包装材料的用途,用于包装除矿物和植物油的化学品和食品,所述组合物包含作为添加剂的基于涂层组合物的固体部分0.1到10重量%的、重均分子量为2000到200000的并且由以下物质构成的支化聚合物:
(a)聚合物基础分子,和
(b)通过Si-C键和、如果希望的话、间隔基团与基础分子连接的,重均分子量为1000到30000,并且占支化聚合物总重量的5到25重量%的聚二有机基硅氧烷侧链。
2、包含至少一种具有防粘性能的聚合物模制复合物的包装材料的用途,用于包装除矿物和植物油的化学品和食品,所述聚合物模制复合物包含基于聚合物模制复合物的总重量0.1到10重量%的、权利要求1中所述支化聚合物的添加剂。
3、权利要求1或2中包装材料的用途,用于包装亲油化学品或精细化学品。
4、权利要求3中包装材料的用途,用于包装选自以下的精细化学品:维生素、脂肪酸、香料、调味剂和芳香剂、着色剂、药用化学品、农用化学品和化妆品用化学品以及其前体、中间体、配方物和制剂。
5、权利要求1或2中的包装材料的用途,用于包装选自以下的食品:奶制品、预制食品或汤、蜂蜜、糖浆、果汁、果汁浓缩物和油中的食品。
6、权利要求1或2中的包装材料的用途,其中聚二有机基硅氧烷侧链通过选自以下结构的结构连接在基础分子上:
或
其中
基团R对应于具有1到8个碳原子的直链烷基或具有3到10个碳原子的全氟烷基,在聚二有机基硅氧烷侧链中,R是相同的或者是不同的,R1基团对应于具有2到8个碳原子的直链或支化的烯基,R2基团对应于氢原子或-COOR’基团,其中R’是氢原子或具有1到22个碳原子的饱和或不饱和的、直链、支化或脂环族烷基基团,R3基团,如果c是1,对应于-COOR’基团,并且,如果c是0,对应于-(CH2)-COOR’基团或甲基,R’基团的定义如上,系数a是从0到10,并且其中m的选择使聚二有机基硅氧烷侧链的分子量为1000到30000之间。
7、权利要求1或2中的包装材料的用途,其中聚二有机基硅氧烷侧链以单异氰酸酯加成物的形式连接在聚合物基础分子上。
8、权利要求1或2中的包装材料的用途,其中作为由自由基加成聚合得到的聚合物基础分子由选自以下的单体单元构成:具有2到30个碳原子的烯烃和芳基烯烃、具有1到22个碳原子的直链、支化或脂环族醇的丙烯酸烷基酯和甲基丙烯酸烷基酯、具有8到18个碳原子的芳烷基醇的丙烯酸芳烷基酯和甲基丙烯酸芳烷基酯、具有5到80个碳原子的聚乙二醇单丙烯酸酯或聚乙二醇单甲基丙烯酸酯、具有2到36个碳原子的丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯,具有3到6个碳原子的直链、支化或脂环族羟基环氧化合物的丙烯酸环氧烷基酯或甲基丙烯酸环氧烷基酯、具有1到22个碳原子的直链、支化或脂环族胺的丙烯酰胺和甲基丙烯酰胺、具有2到8个碳原子的直链、支化或脂环族氨基醇的丙烯酸氨基烷基酯和甲基丙烯酸氨基烷基酯、具有1到22个碳原子的直链、支化或脂环族醇的马来酸酯、衣康酸酯和富马酸酯、具有6到20个碳原子的丙烯酸全氟烷基酯或甲基丙烯酸全氟烷基酯、具有3到20个碳原子的乙烯酯、乙烯醚和乙烯酮、具有5到8个碳原子的乙烯基三烷氧基硅烷、和具有10到16个碳原子的甲基丙烯酰氧基丙基三烷氧基硅烷、以及平均分子量为220到1200的己内酯和/或戊内酯改性丙烯酸羟烷基酯和己内酯和/或戊内酯改性甲基丙烯酸羟烷基酯。
9、权利要求8中的包装材料的用途,其中丙烯酸羟烷基酯和甲基丙烯酸羟烷基酯由具有有2到8个碳原子的直链的、支化或脂环族二醇衍生得到。
10、权利要求1或2中的包装材料的用途,其中基础分子通过选自以下的单体单元的自由基加成聚合形成:丙烯酸、甲基丙烯酸、丙烯酸甲酯、甲基丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸乙酯、丙烯酸正丁酯、甲基丙烯酸正丁酯、丙烯酸异丁酯、甲基丙烯酸异丁酯、丙烯酸叔丁酯、甲基丙烯酸叔丁酯、丙烯酸月桂醇酯、甲基丙烯酸月桂醇酯、丙烯酸2-乙基己酯、甲基丙烯酸2-乙基己酯、丙烯酸硬脂醇酯、甲基丙烯酸硬脂醇酯、丙烯酸山嵛醇酯、甲基丙烯酸山嵛醇酯、丙烯酸环己酯、甲基丙烯酸环己酯、丙烯酸异冰片酯、甲基丙烯酸异冰片酯、丙烯酸羟乙酯、甲基丙烯酸羟乙酯、丙烯酸缩水甘油氧丙酯、甲基丙烯酸缩水甘油氧丙酯、乙烯基三乙氧基硅烷、甲基丙烯酰氧丙基三甲氧基硅烷、甲基丙烯酸异氰酸甲酯、异丙烯基枯基异氰酸酯、苯乙烯、α-甲基苯乙烯、丙烯腈、单丙烯酸三亚乙基二醇酯、单甲基丙烯酸三亚乙基二醇酯、乙基乙烯基醚、丁基乙烯基醚、环己基乙烯基醚、乙酸乙烯酯、丙烯酸N,N-二甲胺乙酯、甲基丙烯酸N,N-二甲胺乙酯、丙烯酸N,N-二甲胺丙酯、甲基丙烯酸N,N-二甲胺丙酯、单丙烯酸聚乙二醇酯、单甲基丙烯酸聚乙二醇酯,以及平均分子量为220到1200的己内酯-和/或戊内酯-改性丙烯酸羟乙酯和己内酯-和/或戊内酯-改性甲基丙烯酸羟乙酯。
11、权利要求1或2中的包装材料的用途,其中聚二有机基硅氧烷侧链部分占支化聚合物总重量的5到20重量%。
12、权利要求11中的包装材料的用途,其中聚二有机基硅氧烷侧链部分占支化聚合物总重量的7.5到12.5重量%。
13、权利要求1或2中的包装材料的用途,其中存在于聚合物基础分子中的羟基官能团被选自以下的化合物酯化:马来酸酐、琥珀酸酐、邻苯二甲酸酐、偏苯三酸酐、丙烯酸和甲基丙烯酸。
14、权利要求1或2中的包装材料的用途,其中支化聚合物的重均分子量为5000到75000。
15、权利要求1或2中的包装材料的用途,其中涂层组合物或聚合物模制复合物包含基于涂层组合物的或聚合物模制复合物的固体部分0.5到5重量%的作为添加剂的支化聚合物。
16、权利要求1或2中的包装材料的用途,其中聚合物模制复合物是成膜树脂、醇酸树脂、聚酯树脂、环氧树脂、聚氨酯树脂、不饱和聚酯树脂、乙烯酯树脂、聚乙烯、聚丙烯、聚酰胺、聚对苯二甲酸乙二醇酯、聚氯乙烯、聚苯乙烯、聚丙烯腈、聚丁二烯、聚氯乙烯或这些聚合物的混合物。
17、权利要求1或2中的包装材料的用途,其中涂层组合物包含选自以下物质的粘合剂:乙烯基酯树脂、聚乙烯、聚酰胺、聚丙烯腈、氯化橡胶、醇酸树脂、聚酯树脂、聚氨酯树脂、不饱和聚酯树脂、聚酯/聚异氰酸酯组合、聚酯丙烯酸酯、丙烯酸树脂、乙酸纤维素酯、纤维素乙酰丁酸酯、纤维素乙酰丙酸酯、纤维素硝酸酯、氯磺酸化聚乙烯、环氧树脂、环氧树脂酯、环氧树脂/焦油组合、乙烯-乙酸乙烯酯聚合物、三聚氰胺-甲醛树脂、氯化聚乙烯、苯酚-甲醛树脂、聚甲基丙烯酸甲酯、聚丙烯、聚苯乙烯、聚四氟乙烯、聚氨酯、聚氨酯/焦油组合、聚乙酸乙烯酯、聚丁酸乙烯酯、聚氯乙烯、氯化聚氯乙烯、聚偏二氯乙烯、聚偏二氟乙烯、聚氟乙烯、氯化橡胶、环化橡胶、聚苯乙烯、具有基于丁二烯的弹性体的聚苯乙烯、硅氧烷聚合物、饱和聚酯、尿素-甲醛树脂、不饱和聚酯、氯乙烯-乙酸乙烯酯聚合物、聚丁二烯及上述物质的混合物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10204562 | 2002-02-04 | ||
DE10204562.3 | 2002-02-04 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1628161A CN1628161A (zh) | 2005-06-15 |
CN1268705C true CN1268705C (zh) | 2006-08-09 |
Family
ID=27674556
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB038032597A Expired - Fee Related CN1268705C (zh) | 2002-02-04 | 2003-01-30 | 防粘包装材料在化学品及食品包装上的应用 |
Country Status (9)
Country | Link |
---|---|
US (2) | US20050079301A1 (zh) |
EP (1) | EP1474491B1 (zh) |
CN (1) | CN1268705C (zh) |
AT (1) | ATE319789T1 (zh) |
AU (1) | AU2003205710A1 (zh) |
DE (1) | DE50302603D1 (zh) |
DK (1) | DK1474491T3 (zh) |
ES (1) | ES2259758T3 (zh) |
WO (1) | WO2003066763A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109134801A (zh) * | 2017-06-15 | 2019-01-04 | 狄超 | 一种用生产二甲氨基乙基丙烯酸酯的精馏残渣制备聚氨酯催化剂的方法 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007083194A2 (en) * | 2005-10-20 | 2007-07-26 | Virtual Reach Inc. | Managing content to constrained devices |
DE102007013369A1 (de) * | 2007-03-16 | 2008-09-18 | Kalle Gmbh | Nahrungsmittelhülle mit einer übertragbaren Additivschicht |
CN102131494B (zh) * | 2008-04-23 | 2016-05-11 | 巴斯夫欧洲公司 | 疏水性有益剂从沐浴剂等到角蛋白基质上的递送 |
WO2012051749A1 (en) * | 2010-10-19 | 2012-04-26 | Ablestik (Shanghai) Ltd. | Hybrid silicone composition for light emitting device |
CN103122184B (zh) * | 2013-03-14 | 2015-01-07 | 孙恩福 | 树木防虫防火漆的生产方法 |
CN104194480A (zh) * | 2014-08-12 | 2014-12-10 | 安徽猛牛彩印包装有限公司 | 一种含山竹果皮的芳香型印刷油墨 |
CN105086684A (zh) * | 2015-07-30 | 2015-11-25 | 无锡卡秀堡辉涂料有限公司 | 一种不含bpa的耐碱性涂料及其制备方法 |
CN106117974A (zh) * | 2016-06-27 | 2016-11-16 | 苏州市鼎立包装有限公司 | 一种高阻隔性化妆品包装材料及其制备方法 |
CN106496429A (zh) * | 2016-10-14 | 2017-03-15 | 无锡三帝特种高分子材料有限公司 | 一种饼干包装用镀铝膜 |
CN109647194B (zh) * | 2019-01-31 | 2021-02-12 | 中国科学院城市环境研究所 | 一种城市街谷汽车尾气自适应吸附处置装备 |
CN112898617B (zh) * | 2021-01-22 | 2022-06-07 | 应城市恒天药业包装有限公司 | 一种卤化丁基橡胶塞及其制备方法 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2287063A (en) * | 1939-01-30 | 1942-06-23 | Raolin Corp | Container closure liner |
US3436251A (en) * | 1964-08-04 | 1969-04-01 | Midland Silicones Ltd | Process for rendering paper abrasion resistant,adhesive and water-repellent employing siloxane composition |
SE373239B (zh) * | 1973-05-21 | 1975-01-27 | Asea Ab | |
US3986629A (en) * | 1973-07-16 | 1976-10-19 | The Southland Corporation | Thermoplastic can end sealant composition |
DE2654893A1 (de) * | 1976-12-03 | 1978-06-15 | Wacker Chemie Gmbh | Verfahren zum herstellen von klebrige stoffe abweisenden ueberzuegen |
US4397916A (en) * | 1980-02-29 | 1983-08-09 | Mitsui Petrochemical Industries, Ltd. | Laminated multilayer structure |
FR2565233B1 (fr) * | 1984-05-30 | 1986-09-12 | Rhone Poulenc Rech | Copolymere greffe de silicone et de polylactone lie par une liaison urethanne |
US4651885A (en) * | 1984-08-13 | 1987-03-24 | Sunbeam Plastics Corp. | Tamper indicating dispensing closure (for edible oils) |
DE3535283A1 (de) * | 1985-10-03 | 1987-04-09 | Byk Chemie Gmbh | Polyestergruppenhaltige polysiloxane fuer lacke und formmassen und die verwendung hierfuer |
JPH0813891B2 (ja) * | 1990-06-01 | 1996-02-14 | 信越化学工業株式会社 | 新規なグラフト共重合体及びそれを用いた被覆組成物 |
US5665822A (en) * | 1991-10-07 | 1997-09-09 | Landec Corporation | Thermoplastic Elastomers |
CA2059733C (en) * | 1991-01-23 | 1999-10-05 | Kazufumi Ogawa | Water- and oil-repelling film and method of manufacturing the same |
US5364555A (en) * | 1991-04-30 | 1994-11-15 | Advanced Oxygen Technologies, Inc. | Polymer compositions containing salicylic acid chelates as oxygen scavengers |
DE4123423A1 (de) * | 1991-07-15 | 1993-01-21 | Wacker Chemie Gmbh | Alkenylgruppen aufweisende siloxancopolymere, deren herstellung und verwendung |
JP3032673B2 (ja) * | 1993-11-10 | 2000-04-17 | 信越化学工業株式会社 | 合成樹脂含有塗料用改質剤 |
JPH07326439A (ja) * | 1994-05-31 | 1995-12-12 | Sumitomo Wiring Syst Ltd | プリント基板へのフラットケーブルの取付構造及びプリント基板用コネクタ |
CN1120180C (zh) * | 1994-06-03 | 2003-09-03 | 巴斯福股份公司 | 聚合物水分散液的制备 |
DE4435422A1 (de) * | 1994-10-04 | 1996-04-18 | Basf Ag | Verfahren zur Herstellung einer wäßrigen Polymerisatdispersion |
DE4438527C2 (de) * | 1994-10-31 | 2002-05-23 | Lohmann Therapie Syst Lts | Verwendung eines mehrschichtigen Verpackungsmaterials zur Herstellung einer Verpackung für Wirkstoffpflaster mit kindersicherer Aufreißfestigkeit |
DE19519807A1 (de) * | 1995-05-31 | 1997-02-13 | Basf Lacke & Farben | Beschichtungsmittel auf der Basis eines hydroxylgruppenhaltigen Polyacrylatharzes und seine Verwendung in Verfahren zur Herstellung einer Mehrschichtlackierung |
EP0808881B1 (de) * | 1996-05-23 | 1999-09-22 | Ewald Dörken Ag | Beschichtung aus einem Pulverlack mit Antihaft-Effekt und Verfahren zu seiner Herstellung |
DK0835897T3 (da) * | 1996-10-11 | 2002-02-18 | Goldschmidt Ag Th | Siliconepoly(meth)acrylater, deres fremstilling og deres anvendelse i belægninger |
US5866261A (en) * | 1996-12-20 | 1999-02-02 | Rhodia Inc. | Release composition |
DE19707786A1 (de) * | 1997-02-27 | 1998-09-03 | Ppg Industries Inc | Kunststoffolie, ihre Verwendung in Verfahren zur Herstellung von Verpackungsbehältern, die so hergestellten Verpackungsbehälter sowie die Verwendung von Lacken zur Applikation über Druckfarbe |
US6011947A (en) * | 1997-09-29 | 2000-01-04 | Xerox Corporation | Apparatus and method for automatically adjusting water film thickness on conditioner metering rolls |
DE10048259A1 (de) * | 2000-09-29 | 2002-04-18 | Byk Chemie Gmbh | Beschichtungsmittel und polymere Formmassen mit anti-adhäsiven, schmutzabweisenden Eigenschaften |
-
2003
- 2003-01-30 ES ES03702566T patent/ES2259758T3/es not_active Expired - Lifetime
- 2003-01-30 WO PCT/EP2003/000922 patent/WO2003066763A1/de not_active Application Discontinuation
- 2003-01-30 US US10/503,475 patent/US20050079301A1/en not_active Abandoned
- 2003-01-30 EP EP03702566A patent/EP1474491B1/de not_active Expired - Lifetime
- 2003-01-30 DE DE50302603T patent/DE50302603D1/de not_active Expired - Fee Related
- 2003-01-30 AU AU2003205710A patent/AU2003205710A1/en not_active Abandoned
- 2003-01-30 DK DK03702566T patent/DK1474491T3/da active
- 2003-01-30 AT AT03702566T patent/ATE319789T1/de not_active IP Right Cessation
- 2003-01-30 CN CNB038032597A patent/CN1268705C/zh not_active Expired - Fee Related
-
2007
- 2007-10-31 US US11/930,733 patent/US20080107909A1/en not_active Abandoned
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109134801A (zh) * | 2017-06-15 | 2019-01-04 | 狄超 | 一种用生产二甲氨基乙基丙烯酸酯的精馏残渣制备聚氨酯催化剂的方法 |
CN109134801B (zh) * | 2017-06-15 | 2021-01-12 | 狄超 | 一种用生产二甲氨基乙基丙烯酸酯的精馏残渣制备聚氨酯催化剂的方法 |
Also Published As
Publication number | Publication date |
---|---|
ES2259758T3 (es) | 2006-10-16 |
CN1628161A (zh) | 2005-06-15 |
DE50302603D1 (de) | 2006-05-04 |
EP1474491B1 (de) | 2006-03-08 |
US20080107909A1 (en) | 2008-05-08 |
AU2003205710A1 (en) | 2003-09-02 |
WO2003066763A1 (de) | 2003-08-14 |
DK1474491T3 (da) | 2006-05-29 |
US20050079301A1 (en) | 2005-04-14 |
EP1474491A1 (de) | 2004-11-10 |
ATE319789T1 (de) | 2006-03-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1190466C (zh) | 用于表面涂料的流平剂 | |
CN1268705C (zh) | 防粘包装材料在化学品及食品包装上的应用 | |
CN1282714C (zh) | 亲水性硅氧烷胶乳乳液 | |
CN1252157C (zh) | 聚合物-颜料复合材料 | |
JP5989237B2 (ja) | 防汚塗料組成物、防汚塗膜、防汚基材および防汚基材の製造方法 | |
CN1175076C (zh) | 具有抗粘性和抗污性的涂料组合物和聚合模塑料 | |
CN1198888C (zh) | 可去除涂料组合物和制备方法 | |
CN1281632C (zh) | 含水多段乳液聚合物组合物 | |
CN1081454A (zh) | 含水的热固化性涂料,其制备及应用 | |
CN1957049A (zh) | 涂料组合物、涂膜及降低水中摩擦的方法 | |
CN1729222A (zh) | 特别用于涂料组合物的聚氨酯加成聚合物杂化物颗粒的含水分散体 | |
CN1112594A (zh) | 耐磨涂料 | |
CN101037558A (zh) | 含有聚合的消光剂颗粒的水性组合物 | |
CN1077718A (zh) | 共聚物 | |
CN1576334A (zh) | 含水聚合物组合物 | |
CN101098902A (zh) | 含有纳米粒子的有机共聚物 | |
CN1488693A (zh) | 具有选择的侧基的聚合物颗粒以及由其制备的组合物 | |
CN1271149C (zh) | 活性能量射线固化性水性涂料组合物、涂装金属材料及其制造方法 | |
FR2621592A1 (fr) | Procede de preparation d'une dispersion aqueuse contenant des particules de polymere | |
CN1155667C (zh) | 水性涂料用抗污染剂、抗污染型水性涂料组合物及其使用方法 | |
CN1200130A (zh) | 含至少三组分的涂料组合物及其制备方法和应用 | |
TW200948899A (en) | Binders containing nanoparticles | |
CN1666863A (zh) | 层合膜 | |
CN1749342A (zh) | 具有提高的防污性及提高的粘合性的聚硅氧烷面漆 | |
CN1155890A (zh) | 热固性组合物,涂覆方法和涂覆制品 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |