CN1221850C - 卤化银乳剂、其制备方法和使用该乳剂的卤化银彩色照相感光材料以及成像方法 - Google Patents
卤化银乳剂、其制备方法和使用该乳剂的卤化银彩色照相感光材料以及成像方法 Download PDFInfo
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- CN1221850C CN1221850C CNB011313447A CN01131344A CN1221850C CN 1221850 C CN1221850 C CN 1221850C CN B011313447 A CNB011313447 A CN B011313447A CN 01131344 A CN01131344 A CN 01131344A CN 1221850 C CN1221850 C CN 1221850C
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- silver
- emulsion
- silver halide
- compound
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/09—Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39208—Organic compounds
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- G—PHYSICS
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- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/392—Additives
- G03C7/39208—Organic compounds
- G03C7/3924—Heterocyclic
- G03C7/39276—Heterocyclic the nucleus containing nitrogen and sulfur
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- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Abstract
Description
单元 | JP-A-7-104448 | JP-A-7-77775 | JP-A-7-301895 |
反射载体 | 第7栏第12行-第12栏第19行 | 第35栏第43行-第44栏第1行 | 第5栏第40行-第9栏第26行 |
卤化银乳剂 | 第72栏第29行-第74栏第18行 | 第44栏第36行-第46栏第29行 | 第77栏第48行-第80栏第28行 |
各种不同金属离子 | 第74栏第19-44行 | 第46栏第30行-第47栏第5行 | 第80栏第29行-第81栏第6行 |
贮藏稳定剂和防灰雾剂 | 第75栏第9-18行 | 第47栏第20-29行 | 第18栏第11行-第31栏第37行(特别是巯基杂环化合物) |
化学增感法(化学增感剂) | 第74栏第45行-第75栏第6行 | 第47栏第7-17行 | 第81栏第9-17行 |
光谱增感法(光谱增感剂) | 第75栏第19行-第76栏第45行 | 第47栏第30行-第49栏第6行 | 第81栏第21行-第82栏第48行 |
成青色剂 | 第12栏第20行-第39栏第49行 | 第62栏第50行-第63栏第16行 | 第88栏第49行-第89栏第16行 |
成黄色剂 | 第87栏第40行-第88栏第3行 | 第63栏第17-30行 | 第89栏第17-30行 |
成品红色剂 | 第88栏第4-18行 | 第63栏第3行-第64栏第11行 | 第31栏第34行-第77栏第44行和第88栏第32-46行 |
成色剂的乳化和分散法 | 第71栏第3行-第72栏第11行 | 第61栏第36-49行 | 第87栏第35-48行 |
彩色图像稳定性增强剂(着色抑制剂) | 第39栏第50行-第70栏第9行 | 第61栏第50行-第62栏第49行 | 第87栏第49行-第88栏第48行 |
褐色抑制剂 | 第70栏第10行-第71栏第2行 | ||
染料(着色剂) | 第77栏第42行-第78栏第41行 | 第7栏第14行-第19栏第42行和第50栏第3行-第51栏第14行 | 第9栏第27行-第18栏第10行 |
明胶种类 | 第78栏第42-48行 | 第51栏第15-20行 | 第83栏第13-19行 |
感光材料的层结构 | 第39栏第11-26行 | 第44栏第2-35行 | 第31栏第38行-第32栏第33行 |
感光材料的涂层pH | 第72栏第12-28行 | ||
扫描曝光 | 第76栏第6行-第77栏第41行 | 第49栏第7行-第50栏第2行 | 第82栏第49行-第83栏第12行 |
显影液中的防腐剂 | 第88栏第19行-第89栏第22行 |
样品号 | 乳剂 | 氯化银含量(摩尔%) | 金增感剂(17μmol/mol.Ag) | 介离子化合物(μmol/mol.Ag) | 感光度(10秒钟) | 感光度(10-4秒钟) | dS(因RH的感光度差) | 备注 |
101 | B | 99.5 | 氯金酸 | 无 | 100 | 100 | 12 | 对比实施例 |
102 | D | 99.5 | 对比化合物A | 无 | 108 | 112 | 10 | 对比实施例 |
103 | E | 99.5 | 对比化合物A | 无 | 104 | 105 | 11 | 对比实施例 |
104 | F | 99.5 | 对比化合物A | I-1 | 108 | 112 | 10 | 对比实施例 |
105 | G | 99.5 | 对比化合物B | 无 | 107 | 110 | 10 | 对比实施例 |
106 | H | 99.5 | 氯金酸 | I-1(34) | 114 | 118 | 6 | 本发明 |
107 | I | 99.5 | 氯金酸 | I-3(34) | 115 | 119 | 6 | 本发明 |
108 | J | 99.5 | 氯金酸 | I-3(34) | 115 | 119 | 6 | 本发明 |
109 | K | 99.5 | 氯金酸 | I-5(34) | 115 | 119 | 5 | 本发明 |
110 | L | 99.5 | 氯金酸 | I-5(34) | 115 | 119 | 5 | 本发明 |
111 | M | 99.5 | 氯金酸 | I-6(34) | 115 | 119 | 5 | 本发明 |
112 | N | 99.5 | 氯金酸 | I-7(34) | 116 | 120 | 5 | 本发明 |
113 | O | 99.5 | 氯金酸 | I-21(34) | 114 | 118 | 6 | 本发明 |
114 | P | 99.5 | 氯金酸 | I-1(68) | 115 | 119 | 5 | 本发明 |
115 | Q | 99.5 | 氯金酸 | I-1(68) | 115 | 119 | 3 | 本发明 |
116 | R | 99.5 | 氯金酸 | I-1(34) | 115 | 119 | 4 | 本发明 |
乳剂 | 氯化银含量(摩尔%) | 碘化银含量(摩尔%) | 化学增感 | I | Ir | Ru(CN)6 | 金增感剂* | 感光度 | 阶度** | 备注 |
2A | 100 | - | X | 无 | 无 | 无 | HAuCl4 | 100 | 1.5 | 对比实施例 |
2A | 100 | - | Y | 无 | 无 | 无 | (S-2) | 107 | 1.6 | 对比实施例 |
2B | 99.7 | 0.3 | X | 有 | 无 | 无 | HAuCl4 | 186 | 1.2 | 对比实施例 |
2B | 99.7 | 0.3 | Y | 有 | 无 | 无 | (S-2) | 195 | 1.2 | 对比实施例 |
2C | 100 | - | X | 无 | K2IrCl6 | 无 | HAuCl4 | 132 | 1.8 | 对比实施例 |
2C | 100 | - | Y | 无 | K2IrCl6 | 无 | (S-2) | 138 | 1.9 | 对比实施例 |
2D | 100 | - | X | 无 | K2Ir(H2O)Cl5 | 无 | HAuCl4 | 135 | 1.6 | 对比实施例 |
2D | 100 | - | Y | 无 | K2Ir(H2O)Cl5 | 无 | (S-2) | 141 | 1.7 | 对比实施例 |
2E | 99.7 | 0.3 | X | 有 | K2IrCl6 | 无 | HAuCl4 | 219 | 1.7 | 对比实施例 |
2E | 99.7 | 0.3 | Y | 有 | K2IrCl6 | 无 | (S-2) | 240 | 2.1 | 实施例 |
2F | 99.7 | 0.3 | X | 有 | K2Ir(H2O)Cl5 | 无 | HAuCl4 | 209 | 1.6 | 对比实施例 |
乳剂 | 氯化银含量(摩尔%) | 碘化银含量(摩尔%) | 化学增感 | I | Ir | Ru(CN)6 | 金增感剂* | 感光度 | 阶度** | 备注 |
2F | 99.7 | 0.3 | Y | 有 | K2Ir(H2O)Cl5 | 无 | (S-2) | 229 | 2.2 | 实施例 |
2G | 99.7 | 0.3 | X | 有 | K2IrCl6+K2Ir(H2O)Cl5 | 无 | HAuCl4 | 195 | 1.8 | 对比实施例 |
2G | 99.7 | 0.3 | Y | 有 | K2IrCl6+K2Ir(H2O)Cl5 | 无 | (S-2) | 219 | 2.5 | 实施例 |
2H | 99.7 | 0.3 | Y | 有 | K2Ir(H2O)Cl5 | 有 | (S-2) | 245 | 2.3 | 实施例 |
2I | 99.7 | 0.3 | Y | 有 | K2IrCl6+K2Ir(H2O)Cl5 | 有 | (S-2) | 234 | 2.6 | 实施例 |
2I | 99.7 | 0.3 | Z | 有 | K2IrCl6+K2Ir(H2O)Cl5 | 有 | (S-3) | 229 | 2.6 | 实施例 |
Claims (13)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000298477A JP2002107865A (ja) | 2000-09-29 | 2000-09-29 | ハロゲン化銀乳剤及びそれを用いたハロゲン化銀カラー写真感光材料 |
JP298477/2000 | 2000-09-29 | ||
JP2000298473 | 2000-09-29 | ||
JP298473/2000 | 2000-09-29 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB2004101048339A Division CN1308771C (zh) | 2000-09-29 | 2001-09-26 | 卤化银乳剂、使用该乳剂的卤化银彩色照相感光材料以及成像方法 |
Publications (2)
Publication Number | Publication Date |
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CN1347005A CN1347005A (zh) | 2002-05-01 |
CN1221850C true CN1221850C (zh) | 2005-10-05 |
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CNB2004101048339A Expired - Lifetime CN1308771C (zh) | 2000-09-29 | 2001-09-26 | 卤化银乳剂、使用该乳剂的卤化银彩色照相感光材料以及成像方法 |
CNB011313447A Expired - Fee Related CN1221850C (zh) | 2000-09-29 | 2001-09-26 | 卤化银乳剂、其制备方法和使用该乳剂的卤化银彩色照相感光材料以及成像方法 |
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CNB2004101048339A Expired - Lifetime CN1308771C (zh) | 2000-09-29 | 2001-09-26 | 卤化银乳剂、使用该乳剂的卤化银彩色照相感光材料以及成像方法 |
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CN (2) | CN1308771C (zh) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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US20030232288A1 (en) * | 2001-11-05 | 2003-12-18 | Yutaka Oka | Photothermographic material and method of thermal development of the same |
JP4292051B2 (ja) * | 2003-03-13 | 2009-07-08 | 富士フイルム株式会社 | ハロゲン化銀乳剤およびハロゲン化銀カラー写真感光材料 |
US20050069827A1 (en) * | 2003-08-28 | 2005-03-31 | Fumito Nariyuki | Photosensitive silver halide emulsion, silver halide photographic photosensitive material, photothermographic material and image-forming method |
JP2005084612A (ja) * | 2003-09-11 | 2005-03-31 | Fuji Photo Film Co Ltd | ハロゲン化銀乳剤、ハロゲン化銀感光材料、および熱現像感光材料 |
US7135276B2 (en) | 2003-10-09 | 2006-11-14 | Fuji Photo Film Co., Ltd. | Photothermographic material and method for preparing photosensitive silver halide emulsion |
US7479463B2 (en) * | 2007-03-09 | 2009-01-20 | Tokyo Electron Limited | Method for heating a chemically amplified resist layer carried on a rotating substrate |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57643A (en) * | 1980-06-02 | 1982-01-05 | Oriental Shashin Kogyo Kk | Heat developing photosensitive material |
JPS6087322A (ja) * | 1983-10-20 | 1985-05-17 | Fuji Photo Film Co Ltd | ハロゲン化銀写真感光材料 |
JPS61170732A (ja) * | 1985-01-25 | 1986-08-01 | Fuji Photo Film Co Ltd | ハロゲン化銀写真感光材料 |
JPH0734103B2 (ja) | 1987-10-19 | 1995-04-12 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料 |
JP2534118B2 (ja) * | 1989-01-09 | 1996-09-11 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料及びその製造方法 |
US5049485A (en) * | 1990-11-16 | 1991-09-17 | Eastman Kodak Company | Photographic silver halide material comprising gold compound |
JP3332105B2 (ja) | 1993-07-19 | 2002-10-07 | 新日本製鐵株式会社 | チタン粉末製造における水素化熱処理方法およびその装置 |
JP3133874B2 (ja) * | 1993-09-16 | 2001-02-13 | 富士写真フイルム株式会社 | ハロゲン化銀写真感光材料 |
DE69534783T2 (de) | 1994-12-22 | 2006-10-12 | Eastman Kodak Co. | Kubische Silberiodochloridemulsionen, Verfahren zu ihrer Herstellung sowie fotografische Kopierelemente |
US5691119A (en) | 1995-06-23 | 1997-11-25 | Eastman Kodak Company | Process for preparation of digitally imaging high chloride emulsions |
US5719019A (en) * | 1996-07-31 | 1998-02-17 | Eastman Kodak Company | Room-light handleable direct reversal silver halide emulsions containing nitro-substituted imidazole rereversal suppressants |
US5830631A (en) * | 1996-10-11 | 1998-11-03 | Eastman Kodak Company | Photographic paper with iodochloride emulsion and disulfide compound |
US5783373A (en) | 1996-10-30 | 1998-07-21 | Eastman Kodak Company | Digital imaging with high chloride emulsions |
US5783378A (en) | 1996-10-30 | 1998-07-21 | Eastman Kodak Company | High chloride emulsion that contains a dopant and peptizer combination that increases high density contrast |
CN1224855A (zh) * | 1997-11-06 | 1999-08-04 | 伊斯曼柯达公司 | 含有水溶性双Au(I)络合物的照相材料 |
US5945270A (en) | 1997-11-06 | 1999-08-31 | Eastman Kodak Company | Photographic element containing water soluble bis Au(I) complexes |
US6140035A (en) * | 1998-09-10 | 2000-10-31 | Eastman Kodak Company | Photographic element comprising a mixture of sensitizing dyes |
US6368781B1 (en) * | 1999-10-20 | 2002-04-09 | Eastman Kodak Company | Heat sensitivity improvement with combinations of gold sensitization and spectral sensitizing dye and filter device |
-
2001
- 2001-09-26 CN CNB2004101048339A patent/CN1308771C/zh not_active Expired - Lifetime
- 2001-09-26 CN CNB011313447A patent/CN1221850C/zh not_active Expired - Fee Related
- 2001-10-01 US US09/966,984 patent/US6750004B2/en not_active Expired - Fee Related
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2003
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US7083907B2 (en) | 2006-08-01 |
US20060177780A1 (en) | 2006-08-10 |
CN1624582A (zh) | 2005-06-08 |
US20040202971A1 (en) | 2004-10-14 |
US20020155394A1 (en) | 2002-10-24 |
CN1347005A (zh) | 2002-05-01 |
US7258969B2 (en) | 2007-08-21 |
CN1308771C (zh) | 2007-04-04 |
US6750004B2 (en) | 2004-06-15 |
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