CN1219740C - 顺式双键的环氧化方法 - Google Patents
顺式双键的环氧化方法 Download PDFInfo
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- CN1219740C CN1219740C CNB011196181A CN01119618A CN1219740C CN 1219740 C CN1219740 C CN 1219740C CN B011196181 A CNB011196181 A CN B011196181A CN 01119618 A CN01119618 A CN 01119618A CN 1219740 C CN1219740 C CN 1219740C
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- 229910052787 antimony Inorganic materials 0.000 claims abstract description 6
- 229910052699 polonium Inorganic materials 0.000 claims abstract description 6
- 229910052714 tellurium Inorganic materials 0.000 claims abstract description 6
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract description 5
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- 239000011669 selenium Substances 0.000 claims abstract description 5
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
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- 125000000217 alkyl group Chemical group 0.000 description 2
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- 239000001257 hydrogen Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
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- ZUZLIXGTXQBUDC-UHFFFAOYSA-N methyltrioctylammonium Chemical compound CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC ZUZLIXGTXQBUDC-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
Description
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 24,3 | <0,1 | 24,3 | >99 | 243 |
2,5 | 42,0 | 4,2 | 46,2 | 90,9 | 185 |
4 | 51,9 | 7,2 | 60,1 | 86,4 | 150 |
6 | 56,1 | 15,4 | 71,5 | 78,5 | 119 |
30 | 38,3 | 58,9 | 97,2 | 39,4 | 41 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 12,1 | <0,1 | 12,1 | >99 | 121 |
4 | 38,9 | <0,1 | 38,9 | >99 | 97 |
6 | 52,9 | 6,9 | 59,8 | 88,5 | 99 |
24 | 55,4 | 36,1 | 91,5 | 60,5 | 38 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 12,4 | <0,1 | 12,4 | >99 | 124 |
4 | 51,3 | <0,1 | 51,3 | >99 | 128 |
6 | 66,2 | 1,5 | 67,7 | 97,8 | 113 |
24 | 48,7 | 45,4 | 94,1 | 51,8 | 39 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 9,0 | <0,1 | 9,0 | >99 | 90 |
4 | 57,4 | 0,8 | 58,2 | 98,2 | 146 |
6 | 57,9 | 11,1 | 69,0 | 83,9 | 115 |
24 | 53,8 | 38,8 | 92,6 | 58,1 | 39 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 16,0 | 0,3 | 16,3 | 98,2 | 163 |
2 | 36,8 | 7,3 | 44,1 | 83,4 | 221 |
4 | 53,4 | 10,7 | 64,1 | 83,3 | 160 |
6 | 59,9 | 18,3 | 78,2 | 76,6 | 130 |
24 | 45,1 | 52,1 | 97,2 | 46,4 | 41 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 4,4 | <0,1 | 4,4 | >99 | 44 |
2 | 10,2 | <0,1 | 10,2 | >99 | 51 |
4 | 19,0 | <0,1 | 19,0 | >99 | 48 |
6 | 24,2 | 0,1 | 24,3 | >99 | 41 |
24 | 28,4 | 0,2 | 28,6 | >99 | 12 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 12,1 | <0,1 | 12,1 | >99 | 121 |
2 | 18,5 | <0,1 | 18,5 | >99 | 93 |
4 | 38,9 | 0,1 | 39,0 | >99 | 97 |
6 | 52,9 | 6,9 | 59,8 | 88,5 | 99 |
24 | 55,4 | 36,0 | 91,4 | 60,6 | 38 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 12,6 | <0,1 | 12,6 | >99 | 126 |
2 | 28,0 | <0,1 | 28,0 | >99 | 140 |
4 | 43,2 | 0,2 | 43,4 | >99 | 109 |
6 | 51,1 | 7,6 | 58,7 | 87,1 | 98 |
24 | 54,9 | 34,7 | 91,4 | 60,0 | 38 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 10,7 | <0,1 | 10,7 | >99 | 107 |
2 | 20,1 | 0,1 | 20,2 | >99 | 101 |
4 | 41,2 | 4,2 | 45,4 | 90,7 | 109 |
6 | 52,9 | 8,6 | 61,5 | 86,0 | 103 |
24 | 57,8 | 28,1 | 85,9 | 67,2 | 36 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 13,4 | <0,1 | 13,4 | >99 | 134 |
2 | 24,9 | <0,1 | 24,9 | >99 | 125 |
4 | 41,3 | 0,2 | 41,5 | >99 | 104 |
6 | 50,3 | 6,7 | 57,0 | 88,2 | 95 |
24 | 55,2 | 22,9 | 78,1 | 70,7 | 33 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 17,0 | <0,1 | 17,0 | >99 | 170 |
2 | 22,0 | <0,1 | 22,0 | >99 | 110 |
4 | 43,5 | 0,4 | 43,9 | 99,0 | 110 |
6 | 55,1 | 9,7 | 64,8 | 85,0 | 108 |
24 | 63,9 | 24,9 | 88,8 | 71,9 | 37 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 7,0 | <0,1 | 7,0 | >99 | 70 |
2 | 10,1 | <0,1 | 10,1 | >99 | 50 |
4 | 18,1 | 0,1 | 18,2 | >99 | 46 |
6 | 26,3 | 0,2 | 26,5 | >99 | 44 |
24 | 54,0 | 7,9 | 63,9 | 84,5 | 27 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | <0,1 | 0,0 | <0,1 | - | 0 |
4 | 1,5 | <0,1 | 1,5 | >99 | 4 |
24 | 10,6 | 0,1 | 10,7 | 99,0 | 4 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
24 | <0,1 | 0,0 | <0,1 | - | 0 |
75 | 0,6 | <0,1 | 0,6 | >99 | <1 |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
24 | 0,0 | 0,0 | 0,0 | - | - |
75 | <0,1 | 0,0 | <0,1 | - | - |
时间[h] | 单环氧化物[%] | 二环氧化物[%] | 转化率CDT[%] | 选择性[%] | TOF[mmolCDT/(mmolKat·h)] |
1 | 13,1 | <0,1 | 13,1 | >99 | 131 |
2 | 22,4 | 0,3 | 22,7 | 98,6 | 114 |
6,5 | 60,4 | 14,4 | 74,8 | 80,7 | 115 |
24* | 22,1 | 76,7 | 98,8 | 22,3 | 41 |
Claims (18)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10055173.4 | 2000-11-08 | ||
DE10055173A DE10055173A1 (de) | 2000-11-08 | 2000-11-08 | Verfahren zur Epoxidation von cis-ständigen Doppelbindungen |
Publications (2)
Publication Number | Publication Date |
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CN1353102A CN1353102A (zh) | 2002-06-12 |
CN1219740C true CN1219740C (zh) | 2005-09-21 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CNB011196181A Expired - Fee Related CN1219740C (zh) | 2000-11-08 | 2001-05-18 | 顺式双键的环氧化方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US6610864B2 (zh) |
EP (1) | EP1205474B1 (zh) |
JP (1) | JP2002155066A (zh) |
CN (1) | CN1219740C (zh) |
AT (1) | ATE271552T1 (zh) |
DE (2) | DE10055173A1 (zh) |
ES (1) | ES2225341T3 (zh) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
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DE10161038A1 (de) * | 2001-12-12 | 2003-06-26 | Degussa | pH-Wert geregeltes Polyamidpulver für Kosmetikanwendungen |
DE10247495A1 (de) * | 2002-10-11 | 2004-04-22 | Degussa Ag | Verfahren zur Epoxidierung cyclischer Alkene |
DE10248406A1 (de) * | 2002-10-17 | 2004-04-29 | Degussa Ag | Laser-Sinter-Pulver mit Titandioxidpartikeln, Verfahren zu dessen Herstellung und Formkörper, hergestellt aus diesem Laser-Sinterpulver |
DE10251790A1 (de) * | 2002-11-07 | 2004-05-19 | Degussa Ag | Polyamidpulver mit dauerhafter, gleichbleibend guter Rieselfähigkeit |
DE10344469A1 (de) | 2003-09-25 | 2005-04-14 | Degussa Ag | Coammoximierung von Ketonen |
DE202004018390U1 (de) * | 2004-11-27 | 2005-02-17 | Degussa Ag | Thermoplastische Kunststoffpulverformulierung für Beschichtungen mit einem metallischen, insbesondere edelstahlähnlichen Farbeindruck |
DE102004062761A1 (de) * | 2004-12-21 | 2006-06-22 | Degussa Ag | Verwendung von Polyarylenetherketonpulver in einem dreidimensionalen pulverbasierenden werkzeuglosen Herstellverfahren, sowie daraus hergestellte Formteile |
JP4911919B2 (ja) * | 2005-05-16 | 2012-04-04 | 昭和電工株式会社 | ジオレフィン化合物の選択酸化による2官能性エポキシモノマーの製造方法 |
DE102005033379A1 (de) | 2005-07-16 | 2007-01-18 | Degussa Ag | Verwendung von cyclischen Oligomeren in einem formgebenden Verfahren und Formkörper, hergestellt nach diesem Verfahren |
US7514577B2 (en) * | 2006-05-31 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Pd- and Pt-substituted polyoxometalates and process for their preparation |
US7820868B2 (en) | 2007-01-19 | 2010-10-26 | Exxonmobil Chemical Patents Inc. | Transition metal substituted polyoxometalates and process for their preparation |
US7645907B2 (en) | 2007-03-23 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Transition metal substituted polyoxometalates and process for their preparation |
US9227947B2 (en) | 2008-08-01 | 2016-01-05 | Hexion Inc. | Process for the manufacture of epichlorohydrin |
CN102471297A (zh) | 2009-07-24 | 2012-05-23 | 荒川化学工业株式会社 | 环氧化合物的制造方法和碳-碳双键的环氧化方法 |
CN102329222B (zh) * | 2011-07-14 | 2014-04-09 | 烟台大学 | 一步法氧化环己烷制备己二酸的方法及其使用的催化剂 |
DE102014209421A1 (de) * | 2014-05-19 | 2015-11-19 | Evonik Degussa Gmbh | Membrangestützte Katalysatorabtrennung bei der Epoxidierung von cyclischen, ungesättigten C12-Verbindungen zum Beispiel Cyclododecen (CDEN) |
CN109824626B (zh) * | 2017-11-23 | 2023-10-27 | 西姆莱斯股份公司 | 用于制备17-氧杂双环[14.1.0]十七碳-8-烯的方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE747316A (fr) * | 1969-03-14 | 1970-08-17 | Sumitomo Chemical Co | Procede de production de composes epoxydes |
NL8004084A (nl) * | 1979-07-19 | 1981-01-21 | Donegani Guido Ist | Werkwijze voor de katalytische epoxydatie van alkenen met waterstofperoxyde. |
IT1205277B (it) * | 1982-11-10 | 1989-03-15 | Montedison Spa | Nuovo composizioni perossidiche a base di tungsteno e fosforo o arsenico |
US4864041A (en) | 1987-02-04 | 1989-09-05 | Emory University | Transition metal-substituted polyoxometalates as catalysts for homogenous liquid-phase organic oxidation processes |
GB9114127D0 (en) | 1991-06-29 | 1991-08-14 | Laporte Industries Ltd | Epoxidation |
IT1252669B (it) * | 1991-12-23 | 1995-06-21 | Donegani Guido Ist | Classe di composti perossidici a base di tungsteno e acidi difosfonici e procedimento per il loro ottenimento |
EP0661342B1 (en) | 1993-12-28 | 2003-04-02 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Additive for thermoplastic resins and flame retardant resin composition |
IL120942A0 (en) * | 1997-05-29 | 1997-09-30 | Yissum Res Dev Co | A process for the epoxidation of alkenes |
US6043383A (en) * | 1998-04-14 | 2000-03-28 | Ube Industries, Ltd. | Process for producing 1,2-epoxy-5,9-cyclododecadiene |
-
2000
- 2000-11-08 DE DE10055173A patent/DE10055173A1/de not_active Withdrawn
-
2001
- 2001-04-27 DE DE50102910T patent/DE50102910D1/de not_active Expired - Lifetime
- 2001-04-27 AT AT01110421T patent/ATE271552T1/de not_active IP Right Cessation
- 2001-04-27 ES ES01110421T patent/ES2225341T3/es not_active Expired - Lifetime
- 2001-04-27 EP EP01110421A patent/EP1205474B1/de not_active Expired - Lifetime
- 2001-05-01 JP JP2001134595A patent/JP2002155066A/ja not_active Withdrawn
- 2001-05-18 CN CNB011196181A patent/CN1219740C/zh not_active Expired - Fee Related
- 2001-11-05 US US09/985,478 patent/US6610864B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP1205474B1 (de) | 2004-07-21 |
DE10055173A1 (de) | 2002-05-29 |
DE50102910D1 (de) | 2004-08-26 |
EP1205474A2 (de) | 2002-05-15 |
ES2225341T3 (es) | 2005-03-16 |
EP1205474A3 (de) | 2002-05-22 |
US20020091275A1 (en) | 2002-07-11 |
CN1353102A (zh) | 2002-06-12 |
JP2002155066A (ja) | 2002-05-28 |
US6610864B2 (en) | 2003-08-26 |
ATE271552T1 (de) | 2004-08-15 |
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