CN1210893A - 常温下硫酸浸取锰矿石的方法 - Google Patents
常温下硫酸浸取锰矿石的方法 Download PDFInfo
- Publication number
- CN1210893A CN1210893A CN 97108214 CN97108214A CN1210893A CN 1210893 A CN1210893 A CN 1210893A CN 97108214 CN97108214 CN 97108214 CN 97108214 A CN97108214 A CN 97108214A CN 1210893 A CN1210893 A CN 1210893A
- Authority
- CN
- China
- Prior art keywords
- manganese
- manganese ore
- add
- sulfuric acid
- hour
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011572 manganese Substances 0.000 title claims abstract description 74
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 72
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 72
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 31
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 21
- 239000000654 additive Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 11
- 229940099596 manganese sulfate Drugs 0.000 claims abstract description 9
- 239000011702 manganese sulphate Substances 0.000 claims abstract description 9
- 235000007079 manganese sulphate Nutrition 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 claims description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- AOSFMYBATFLTAQ-UHFFFAOYSA-N 1-amino-3-(benzimidazol-1-yl)propan-2-ol Chemical compound C1=CC=C2N(CC(O)CN)C=NC2=C1 AOSFMYBATFLTAQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000007789 gas Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 claims description 2
- 235000019252 potassium sulphite Nutrition 0.000 claims description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 239000002699 waste material Substances 0.000 abstract description 5
- 239000003792 electrolyte Substances 0.000 abstract description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000004537 pulping Methods 0.000 abstract description 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000002386 leaching Methods 0.000 description 9
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000003756 stirring Methods 0.000 description 4
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN97108214A CN1075120C (zh) | 1997-09-09 | 1997-09-09 | 常温下硫酸浸取锰矿石的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN97108214A CN1075120C (zh) | 1997-09-09 | 1997-09-09 | 常温下硫酸浸取锰矿石的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1210893A true CN1210893A (zh) | 1999-03-17 |
CN1075120C CN1075120C (zh) | 2001-11-21 |
Family
ID=5170233
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN97108214A Expired - Fee Related CN1075120C (zh) | 1997-09-09 | 1997-09-09 | 常温下硫酸浸取锰矿石的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1075120C (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101260471B (zh) * | 2008-04-28 | 2010-06-02 | 中国环境科学研究院 | 一种采用阳极液提取锰渣中可溶性锰的成套清洁生产工艺 |
CN101880767A (zh) * | 2010-06-07 | 2010-11-10 | 姚茂君 | 一种铁粉还原浸出软锰矿的工艺 |
CN103757249A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 碳酸锰矿的浸出方法 |
CN103757247A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 碳酸锰矿的浸出方法 |
CN103757444A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 软锰矿的浸出方法 |
CN103937973A (zh) * | 2014-04-16 | 2014-07-23 | 广西民族大学 | 一种有机-无机复合还原软锰矿的方法 |
CN113088999A (zh) * | 2021-03-31 | 2021-07-09 | 广西桂柳化工有限责任公司 | 一种无汞碱性锌锰电池用的电解二氧化锰的制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1295355C (zh) * | 2004-07-19 | 2007-01-17 | 中南大学 | 利用钛白废酸和二氧化锰矿制取电解金属锰的方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1034517C (zh) * | 1992-11-02 | 1997-04-09 | 冶金工业部长沙冶研究院 | 高收率制取高纯硫酸锰溶液 |
-
1997
- 1997-09-09 CN CN97108214A patent/CN1075120C/zh not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101260471B (zh) * | 2008-04-28 | 2010-06-02 | 中国环境科学研究院 | 一种采用阳极液提取锰渣中可溶性锰的成套清洁生产工艺 |
CN101880767A (zh) * | 2010-06-07 | 2010-11-10 | 姚茂君 | 一种铁粉还原浸出软锰矿的工艺 |
CN103757249A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 碳酸锰矿的浸出方法 |
CN103757247A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 碳酸锰矿的浸出方法 |
CN103757444A (zh) * | 2013-12-29 | 2014-04-30 | 四川师范大学 | 软锰矿的浸出方法 |
CN103937973A (zh) * | 2014-04-16 | 2014-07-23 | 广西民族大学 | 一种有机-无机复合还原软锰矿的方法 |
CN113088999A (zh) * | 2021-03-31 | 2021-07-09 | 广西桂柳化工有限责任公司 | 一种无汞碱性锌锰电池用的电解二氧化锰的制备方法 |
CN113088999B (zh) * | 2021-03-31 | 2021-12-31 | 广西桂柳新材料股份有限公司 | 一种无汞碱性锌锰电池用的电解二氧化锰的制备方法 |
WO2022205534A1 (zh) * | 2021-03-31 | 2022-10-06 | 广西桂柳化工有限责任公司 | 一种无汞碱性锌锰电池用的电解二氧化锰的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1075120C (zh) | 2001-11-21 |
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Owner name: XIANGTAN UNIV. Free format text: FORMER OWNER: DENG JIANCHENG Effective date: 20040203 |
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Effective date of registration: 20040203 Address after: 411105 Hunan city of Xiangtan province donkey pond scientific research department of Xiangtan University Patentee after: Xiangtan University Address before: 411105 Hunan city of Xiangtan province donkey pond village 11 Beidou No. 106 Xiangtan University Patentee before: Deng Jiancheng |
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