CN1210324C - 聚氨酯弹性体 - Google Patents
聚氨酯弹性体 Download PDFInfo
- Publication number
- CN1210324C CN1210324C CNB961998962A CN96199896A CN1210324C CN 1210324 C CN1210324 C CN 1210324C CN B961998962 A CNB961998962 A CN B961998962A CN 96199896 A CN96199896 A CN 96199896A CN 1210324 C CN1210324 C CN 1210324C
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- CN
- China
- Prior art keywords
- weight
- elastomerics
- storage modulus
- loss tangent
- polyisocyanates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/302—Water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6552—Compounds of group C08G18/63
- C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/914—Polyurethane cellular product formed from a polyol which has been derived from at least two 1,2 epoxides as reactants
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Developing Agents For Electrophotography (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
1 | 2 | 3 | 4 | 比较1 | 比较2 | |
多异氰酸酯I | 36.4 | 42.7 | - | - | - | - |
多异氰酸酯II | - | - | 46.8 | - | - | 42.9 |
多异氰酸酯III | - | - | - | - | 109 | - |
多异氰酸酯IV | - | - | - | 100 | - | - |
多元醇A | 100.0 | 50.0 | - | - | - | - |
多元醇B | - | 50.0 | 100.0 | - | - | - |
多元醇C | - | - | - | - | 100.0 | - |
多元醇D | - | - | - | - | 28.3 | - |
多元醇E | - | - | - | - | - | 100.0 |
乙二醇 | 5.0 | 7.0 | 7.0 | 4.55 | 8.9 | 6.0 |
水 | 0.3 | 0.3 | 0.3 | 0.21 | 0.6 | 0.3 |
催化剂1 | 1.0 | 0.5 | 1.0 | 0.7 | 2.6 | 1.0 |
催化剂2 | - | - | - | - | 0.4 | - |
模制物密度(千克/立方米) | 450 | 440 | 440 | 580 | 490 | 585 |
硬度 | 46(Asker C) | 51(Asker C) | 41(Asker C) | 62(Asker C) | 47(肖耳A) | N.M.* |
E′(20℃)/E′(120℃)比例 | 0.95 | 1.01 | 0.98 | 0.86 | 1.69 | 2.19 |
tanδ(100℃) | 0.002 | 0.013 | 0.024 | 0.005 | 0.070 | 0.078 |
tanδMAX(于℃之温度) | -23 | -26 | -11 | -11 | -43 | -45 |
tanδMAX(值) | 1.08 | 0.86 | 1.01 | 1.22 | 0.42 | 0.37 |
Claims (15)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95203405.6 | 1995-12-08 | ||
EP95203405 | 1995-12-08 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1208423A CN1208423A (zh) | 1999-02-17 |
CN1210324C true CN1210324C (zh) | 2005-07-13 |
Family
ID=8220920
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB961998962A Expired - Lifetime CN1210324C (zh) | 1995-12-08 | 1996-11-14 | 聚氨酯弹性体 |
Country Status (20)
Country | Link |
---|---|
US (1) | US7307136B2 (zh) |
EP (1) | EP0865458B2 (zh) |
JP (2) | JP3892042B2 (zh) |
KR (1) | KR100441926B1 (zh) |
CN (1) | CN1210324C (zh) |
AR (1) | AR005001A1 (zh) |
AT (1) | ATE198756T1 (zh) |
AU (1) | AU718820B2 (zh) |
BR (1) | BR9611977A (zh) |
CA (1) | CA2239482C (zh) |
DE (1) | DE69611623T3 (zh) |
DK (1) | DK0865458T4 (zh) |
ES (1) | ES2153601T5 (zh) |
ID (1) | ID19591A (zh) |
MY (1) | MY129258A (zh) |
PL (1) | PL187124B1 (zh) |
PT (1) | PT865458E (zh) |
TR (1) | TR199801042T2 (zh) |
TW (1) | TW419489B (zh) |
WO (1) | WO1997021750A1 (zh) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SI1161475T1 (en) * | 1999-03-17 | 2004-08-31 | Huntsman International Llc | Process for preparing moulded polyurethane material |
EP1172387A1 (en) * | 2000-07-14 | 2002-01-16 | Huntsman International Llc | Process for preparing an elastomer |
US6734273B2 (en) * | 2001-02-12 | 2004-05-11 | Noveon Ip Holdings Corp. | High molecular weight thermoplastic polyurethanes made from polyols having high secondary hydroxyl content |
US7687548B2 (en) | 2002-07-01 | 2010-03-30 | Huntsman International Llc | Process for preparing a moulded polyurethane material |
DE10303172A1 (de) * | 2003-01-27 | 2004-07-29 | Basf Ag | Verfahren zur Herstellung von Polyurethanintegralschaumstoffen |
US7168880B2 (en) * | 2004-11-17 | 2007-01-30 | Battelle Memorial Institute | Impact attenuator system |
DE102004062539A1 (de) * | 2004-12-24 | 2006-07-20 | Bayer Materialscience Ag | Verstärkte Polyurethanharnstoffelastomere und deren Verwendung |
US7579068B2 (en) * | 2005-04-05 | 2009-08-25 | Dow Global Technologies, Inc. | Rigid polyurethane-isocyanurate reinforcing foams |
US20060258831A1 (en) * | 2005-05-10 | 2006-11-16 | Nigel Barksby | High molecular weight thermoplastic polyurethanes made from polyols having high secondary hydroxyl content |
US20090035350A1 (en) * | 2007-08-03 | 2009-02-05 | John Stankus | Polymers for implantable devices exhibiting shape-memory effects |
CN101148494B (zh) * | 2007-10-26 | 2010-07-21 | 张勇 | 一种聚氨酯弹性体的生产方法及应用 |
US8894318B2 (en) * | 2008-03-17 | 2014-11-25 | Battelle Memorial Institute | Rebound control material |
US9259515B2 (en) | 2008-04-10 | 2016-02-16 | Abbott Cardiovascular Systems Inc. | Implantable medical devices fabricated from polyurethanes with grafted radiopaque groups |
US8871891B2 (en) * | 2011-05-16 | 2014-10-28 | Ashland Licensing And Intellectual Property Llc | Two part polyurea-urethane adhesive with elevated high temperature storage modulus |
CN102250313B (zh) | 2011-06-03 | 2012-09-26 | 山东东大一诺威聚氨酯有限公司 | 一种用于聚氨酯发泡轮胎的自结皮微孔弹性体组合物 |
US9339948B2 (en) | 2012-09-26 | 2016-05-17 | Dow Global Technologies Llc | Polyurethane bend stiffener |
US8720921B1 (en) * | 2012-10-30 | 2014-05-13 | SuperSprings International, Inc. | Vehicular suspension enhancement |
MX2014004304A (es) * | 2013-04-09 | 2015-05-07 | Dow Quimica Mexicana S A De C V | Composicion adhesiva de curado rapido. |
JP6253942B2 (ja) * | 2013-10-10 | 2017-12-27 | ヤマハ株式会社 | 発泡ウレタンゴム及び発泡ウレタンゴム形成用組成物 |
JP6681212B2 (ja) * | 2015-11-30 | 2020-04-15 | 株式会社潤工社 | ポリウレタンチューブ |
WO2017094699A1 (ja) * | 2015-11-30 | 2017-06-08 | 株式会社 潤工社 | ポリウレタンチューブ |
JP2021181538A (ja) * | 2020-05-19 | 2021-11-25 | 株式会社イノアック技術研究所 | 低膨潤親水性ウレタンフォーム |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
USRE31671E (en) * | 1974-09-09 | 1984-09-11 | The Upjohn Company | Thermoplastic polyurethane elastomers from polyoxypropylene polyoxyethylene block copolymers |
US3983094A (en) * | 1975-09-11 | 1976-09-28 | Uniroyal, Inc. | Thermally stable polyurethane elastomers produced from poly(oxypropylene)-poly(oxyethylene)glycols of high oxyethylene group content |
US4010146A (en) * | 1975-09-29 | 1977-03-01 | Samuel Moore And Company | Polyol blends and polyurethane prepared therefrom |
US4124572A (en) * | 1977-07-05 | 1978-11-07 | Uniroyal, Inc. | Thermoplastic polyurethane elastomer |
US4312973A (en) * | 1978-08-10 | 1982-01-26 | Union Carbide Corporation | Polyurethane elastomers prepared from polyol or polymer/polyol-chain extender mixtures |
DE2966876D1 (en) * | 1978-12-11 | 1984-05-10 | Ici Plc | Modified diisocyanate compositions and polyurethanes thereof |
US4379904A (en) * | 1980-11-24 | 1983-04-12 | The Upjohn Company | Novel polyurethane product |
DE3113690A1 (de) * | 1981-04-04 | 1982-10-28 | Elastogran GmbH, 2844 Lemförde | "verfahren zur herstellung von geschlossenzelligen polyurethan-formteilen mit einer verdichteten randzone" |
DE3219759A1 (de) * | 1982-05-26 | 1983-12-01 | Bayer Ag, 5090 Leverkusen | Einphasig lagerstabile polyolkompositionen mit hohem ethylenglykol-anteil und ihre verwendung zur herstellung von polyurethanen |
US4524102A (en) * | 1984-02-15 | 1985-06-18 | Fritz Hostettler | Microcellular polyurethane foams having integral skin |
JPH0680105B2 (ja) * | 1985-04-16 | 1994-10-12 | 旭硝子株式会社 | ポリウレタン系エラストマ−の製造方法 |
US4767825A (en) * | 1986-12-22 | 1988-08-30 | Kimberly-Clark Corporation | Superabsorbent thermoplastic compositions and nonwoven webs prepared therefrom |
JPH0794523B2 (ja) * | 1987-09-02 | 1995-10-11 | 東洋ゴム工業株式会社 | 高透湿性、低膨潤性、高モジュラス等のすぐれた特性を有するポリウレタン重合体の製造方法 |
US5001167A (en) * | 1989-03-21 | 1991-03-19 | The Dow Chemical Company | Solvent resistant polyetherpolyurethane products |
JP2566472B2 (ja) | 1989-12-04 | 1996-12-25 | 株式会社エポゾール | 耐熱性かつ熱可塑性の、ポリウレタンエラストマー及びその製造法 |
DE69220338T2 (de) * | 1991-12-17 | 1997-11-06 | Ici Plc | Polyurethanschäume |
US5418261A (en) * | 1993-01-25 | 1995-05-23 | Imperial Chemical Industries Plc | Polyurethane foams |
JP2733180B2 (ja) * | 1993-02-09 | 1998-03-30 | 東洋製罐株式会社 | フレキシブル包装用ラミネート、その製造方法及びそれに用いる接着剤 |
US5459170A (en) * | 1993-04-13 | 1995-10-17 | Imperial Chemical Industries Plc | Polyurethane foams |
US5591779A (en) * | 1994-11-22 | 1997-01-07 | Imperial Chemical Industries Plc | Process for making flexible foams |
EP1172387A1 (en) * | 2000-07-14 | 2002-01-16 | Huntsman International Llc | Process for preparing an elastomer |
-
1996
- 1996-11-14 EP EP96939064A patent/EP0865458B2/en not_active Expired - Lifetime
- 1996-11-14 ES ES96939064T patent/ES2153601T5/es not_active Expired - Lifetime
- 1996-11-14 AU AU76258/96A patent/AU718820B2/en not_active Expired
- 1996-11-14 KR KR10-1998-0704261A patent/KR100441926B1/ko active IP Right Grant
- 1996-11-14 BR BR9611977A patent/BR9611977A/pt not_active IP Right Cessation
- 1996-11-14 CA CA002239482A patent/CA2239482C/en not_active Expired - Lifetime
- 1996-11-14 JP JP52164897A patent/JP3892042B2/ja not_active Expired - Lifetime
- 1996-11-14 TR TR1998/01042T patent/TR199801042T2/xx unknown
- 1996-11-14 DE DE69611623T patent/DE69611623T3/de not_active Expired - Lifetime
- 1996-11-14 AT AT96939064T patent/ATE198756T1/de not_active IP Right Cessation
- 1996-11-14 DK DK96939064T patent/DK0865458T4/da active
- 1996-11-14 PT PT96939064T patent/PT865458E/pt unknown
- 1996-11-14 PL PL96327198A patent/PL187124B1/pl not_active IP Right Cessation
- 1996-11-14 WO PCT/EP1996/005035 patent/WO1997021750A1/en active IP Right Grant
- 1996-11-14 CN CNB961998962A patent/CN1210324C/zh not_active Expired - Lifetime
- 1996-11-19 TW TW085114199A patent/TW419489B/zh not_active IP Right Cessation
- 1996-12-06 MY MYPI96005128A patent/MY129258A/en unknown
- 1996-12-06 AR ARP960105558A patent/AR005001A1/es unknown
- 1996-12-09 ID IDP963663A patent/ID19591A/id unknown
-
2002
- 2002-02-04 US US10/061,186 patent/US7307136B2/en not_active Expired - Fee Related
-
2006
- 2006-07-07 JP JP2006188033A patent/JP3889435B2/ja not_active Expired - Lifetime
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