CN1207958A - 一种含高硫化氢浓度的合成气制甲硫醇的催化剂 - Google Patents
一种含高硫化氢浓度的合成气制甲硫醇的催化剂 Download PDFInfo
- Publication number
- CN1207958A CN1207958A CN 98118187 CN98118187A CN1207958A CN 1207958 A CN1207958 A CN 1207958A CN 98118187 CN98118187 CN 98118187 CN 98118187 A CN98118187 A CN 98118187A CN 1207958 A CN1207958 A CN 1207958A
- Authority
- CN
- China
- Prior art keywords
- mos
- catalyzer
- carrier
- methyl mercaptan
- load
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
实施例 | 催化剂组成(w/w)(活性组分Mo-S-K以MoS2计) | 生成CH3SH选择性(%) | CH3SH的时空得率(g/h·gcm) |
1 | MoS2/Fe2O3/SiO2=0.15/0.03/1 | 95.2 | 0.36 |
2 | MoS2/Fe2O3/γAl2O3=0.15/0.03/1 | 75.3 | 0.21 |
3 | MoS2/Fe2O3/TiO2=0.15/0.03/1 | 82.7 | 0.25 |
4 | MoS2/MnO2/SiO2=0.15/0.025/1 | 90.2 | 0.26 |
5 | MoS2/NiO/SiO2=0.15/0.03/1 | 95.2 | 0.33 |
6 | MoS2/CoO/SiO2=0.15/0.03/1 | 93.8 | 0.34 |
7 | MoS2/La2O3/SiO2=0.15/0.025/1 | 98.6 | 0.37 |
8 | MoS2/Ce2O3/SiO2=0.15/0.025/1 | 96.6 | 0.35 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN98118187A CN1072523C (zh) | 1998-09-10 | 1998-09-10 | 一种含高硫化氢浓度的合成气制甲硫醇的催化剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN98118187A CN1072523C (zh) | 1998-09-10 | 1998-09-10 | 一种含高硫化氢浓度的合成气制甲硫醇的催化剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1207958A true CN1207958A (zh) | 1999-02-17 |
CN1072523C CN1072523C (zh) | 2001-10-10 |
Family
ID=5225952
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN98118187A Expired - Fee Related CN1072523C (zh) | 1998-09-10 | 1998-09-10 | 一种含高硫化氢浓度的合成气制甲硫醇的催化剂 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1072523C (zh) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100334075C (zh) * | 2003-04-30 | 2007-08-29 | 巴斯福股份公司 | 用于由甲醇和硫化氢制备甲硫醇的催化剂 |
CN100345629C (zh) * | 2003-10-10 | 2007-10-31 | 德古萨股份公司 | 一种由含高浓度硫化氢的合成气合成甲硫醇的催化剂 |
CN100443165C (zh) * | 2004-03-12 | 2008-12-17 | 德古萨股份公司 | 一种用于一氧化碳与硫化氢反应合成甲硫醇的催化剂 |
US7569731B2 (en) | 2003-10-10 | 2009-08-04 | Degussa Ag | Process for the manufacture of methylmercaptan |
US7723261B2 (en) | 2007-04-17 | 2010-05-25 | Evonik Degussa Gmbh | Catalyst for the preparation of methyl mercaptan |
US8883670B2 (en) | 2006-09-11 | 2014-11-11 | Evonik Degussa Gmbh | Mo containing catalyst, a preparation method and a method for preparing methyl mercaptan |
JP2016515935A (ja) * | 2013-03-29 | 2016-06-02 | アルケマ フランス | メチルメルカプタンの合成用触媒ならびに合成ガスおよび硫化水素からメチルメルカプタンを製造する方法 |
US9409153B2 (en) | 2007-12-28 | 2016-08-09 | Evonik Degussa Gmbh | Supported Mo—O—K—MexOy catalyst for the synthesis of methanethiol from high H2S-containing syngas |
CN112316959A (zh) * | 2020-11-18 | 2021-02-05 | 昆明理工大学 | 一种K***型1T-MoS2催化剂及其制备方法和应用 |
CN115228454A (zh) * | 2022-02-07 | 2022-10-25 | 昆明理工大学 | 二氧化钛在合成甲硫醇中的应用 |
RU2805660C2 (ru) * | 2019-01-18 | 2023-10-23 | Адиссео Франс С.А.С. | Способ получения соединения формулы rsh путем гидросульфуризации |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0167354A1 (en) * | 1984-06-29 | 1986-01-08 | Exxon Research And Engineering Company | Catalysts comprising niobia and/or tantala supported on titania |
US5283369A (en) * | 1992-03-24 | 1994-02-01 | Elf Atochem North America, Inc. | Selective synthesis of mercaptans and catalyst therefor |
DE19639584A1 (de) * | 1996-09-26 | 1998-04-23 | Degussa | Katalysator, Verfahren zu seiner Herstellung und Verwendung zur Synthese von Methylmercaptan |
CN1178136A (zh) * | 1996-09-26 | 1998-04-08 | 底古萨股份公司 | 催化剂、其制备方法和在合成甲硫醇中的应用 |
-
1998
- 1998-09-10 CN CN98118187A patent/CN1072523C/zh not_active Expired - Fee Related
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100334075C (zh) * | 2003-04-30 | 2007-08-29 | 巴斯福股份公司 | 用于由甲醇和硫化氢制备甲硫醇的催化剂 |
US7833929B2 (en) | 2003-10-10 | 2010-11-16 | Evonik Degussa Gmbh | Process for the manufacture of methylmercaptan |
CN100345629C (zh) * | 2003-10-10 | 2007-10-31 | 德古萨股份公司 | 一种由含高浓度硫化氢的合成气合成甲硫醇的催化剂 |
US7569731B2 (en) | 2003-10-10 | 2009-08-04 | Degussa Ag | Process for the manufacture of methylmercaptan |
CN100443165C (zh) * | 2004-03-12 | 2008-12-17 | 德古萨股份公司 | 一种用于一氧化碳与硫化氢反应合成甲硫醇的催化剂 |
US8883670B2 (en) | 2006-09-11 | 2014-11-11 | Evonik Degussa Gmbh | Mo containing catalyst, a preparation method and a method for preparing methyl mercaptan |
US7723261B2 (en) | 2007-04-17 | 2010-05-25 | Evonik Degussa Gmbh | Catalyst for the preparation of methyl mercaptan |
US9409153B2 (en) | 2007-12-28 | 2016-08-09 | Evonik Degussa Gmbh | Supported Mo—O—K—MexOy catalyst for the synthesis of methanethiol from high H2S-containing syngas |
JP2016515935A (ja) * | 2013-03-29 | 2016-06-02 | アルケマ フランス | メチルメルカプタンの合成用触媒ならびに合成ガスおよび硫化水素からメチルメルカプタンを製造する方法 |
US9944594B2 (en) * | 2013-03-29 | 2018-04-17 | Arkema France | Catalyst for the synthesis of methyl mercaptan and process for producing methyl mercaptan from synthesis gas and hydrogen sulphide |
US10377704B2 (en) | 2013-03-29 | 2019-08-13 | Arkema France | Catalyst for the synthesis of methyl mercaptan and process for producing methyl mercaptan from synthesis gas and hydrogen sulphide |
RU2805660C2 (ru) * | 2019-01-18 | 2023-10-23 | Адиссео Франс С.А.С. | Способ получения соединения формулы rsh путем гидросульфуризации |
CN112316959A (zh) * | 2020-11-18 | 2021-02-05 | 昆明理工大学 | 一种K***型1T-MoS2催化剂及其制备方法和应用 |
CN115228454A (zh) * | 2022-02-07 | 2022-10-25 | 昆明理工大学 | 二氧化钛在合成甲硫醇中的应用 |
Also Published As
Publication number | Publication date |
---|---|
CN1072523C (zh) | 2001-10-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110801861B (zh) | 一种环境友好型丙烷直接脱氢制丙烯催化剂及其制备方法 | |
CN1072523C (zh) | 一种含高硫化氢浓度的合成气制甲硫醇的催化剂 | |
JPH11217343A (ja) | 化学工業原料及びハイオク燃料の合成法 | |
US5516741A (en) | Reduced chlorine containing platinum catalysts | |
CN109433247B (zh) | 一种用于富co2胺溶液解吸的mcm-41分子筛基负载型催化剂的制备方法 | |
CN110102338A (zh) | 一种高氮气选择性的氨氧化催化剂及其制备方法 | |
US5283055A (en) | Process using novel catalysts for the selective reduction of nitrogen oxides | |
JPH0336571B2 (zh) | ||
CN110479346A (zh) | 一种用于甲醛净化的氮掺杂非贵金属催化剂及其制备方法 | |
CN1072522C (zh) | 一种由含硫化氢的合成气合成甲硫醇的催化剂 | |
CN110026182A (zh) | 高抗硫中低温脱硝催化剂及其制备与应用 | |
CN109701547B (zh) | 一种高甲烷催化活性的锰铈催化剂制备方法及产品 | |
US4551444A (en) | Catalyst for alcohol synthesis | |
CN113262779A (zh) | 具有晶面效应的低温scr脱硝催化剂的制备方法及应用 | |
Basinska et al. | The influence of alkali metals on the activity of supported ruthenium catalysts for the water-gas shift reaction | |
JPS5929633B2 (ja) | 炭化水素の低温水蒸気改質法 | |
CN111672536A (zh) | 一种用于甲醛净化的贵金属催化剂及其制备方法 | |
CN114160144B (zh) | 一种无铬催化剂、其制备方法及应用 | |
CN1363544A (zh) | 浸渍法制备3-羟基丙醛加氢催化剂 | |
CN107952448A (zh) | 一种复合金属氧化物催化剂及其制备方法和应用 | |
CN106944083B (zh) | 一种乙烷氧化脱氢制乙烯催化剂的制备方法 | |
CN100389872C (zh) | 一种含高浓度硫化氢的合成气一步法制甲硫醇的催化剂 | |
CN112604709A (zh) | 一种含硫废气处理用加氢催化剂及其应用 | |
CN113058586A (zh) | 用于二氧化碳氧化低碳烷烃制烯烃的催化剂及其制备方法 | |
CN110496641A (zh) | 一种室温下甲醛完全氧化催化剂和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: XIAMEN UNIVERSITY ASSET MANAGEMENT LTD. Free format text: FORMER OWNER: XIAMEN UNIVERSITY Effective date: 20050415 Owner name: DEGAOSA CO., LTD. Free format text: FORMER OWNER: XIAMEN UNIVERSITY ASSET MANAGEMENT LTD. Effective date: 20050415 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20050415 Address after: Hanau Patentee after: JCDecaux Shakespeare Co. Address before: Xiamen City, Fujian Province, 361005 South Siming Road No. 422 Patentee before: Xiamen University Asset Management Co.,Ltd. Effective date of registration: 20050415 Address after: Xiamen City, Fujian Province, 361005 South Siming Road No. 422 Patentee after: Xiamen University Asset Management Co.,Ltd. Address before: Xiamen City, Fujian Province, 361005 South Siming Road No. 422 Patentee before: Xiamen University |
|
C56 | Change in the name or address of the patentee |
Owner name: EVONIK DEGUSSA CO., LTD. Free format text: FORMER NAME: DEGUSSA CO., LTD. |
|
CP03 | Change of name, title or address |
Address after: essen Patentee after: EVONIK DEGUSSA GmbH Address before: Hanau Patentee before: JCDecaux Shakespeare Co. |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20011010 Termination date: 20170910 |
|
CF01 | Termination of patent right due to non-payment of annual fee |