CN1206287C - 一种纳米氧化锆浆组合物及其制备方法 - Google Patents
一种纳米氧化锆浆组合物及其制备方法 Download PDFInfo
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- CN1206287C CN1206287C CN 02109457 CN02109457A CN1206287C CN 1206287 C CN1206287 C CN 1206287C CN 02109457 CN02109457 CN 02109457 CN 02109457 A CN02109457 A CN 02109457A CN 1206287 C CN1206287 C CN 1206287C
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- oxide slurry
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- zircon oxide
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- 239000002002 slurry Substances 0.000 title claims abstract description 103
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- 229910052845 zircon Inorganic materials 0.000 title claims description 91
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 title claims description 91
- 239000002270 dispersing agent Substances 0.000 claims abstract description 123
- 239000011164 primary particle Substances 0.000 claims abstract description 4
- 229920002521 macromolecule Polymers 0.000 claims description 123
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 36
- 239000002904 solvent Substances 0.000 claims description 31
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 27
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 22
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 18
- -1 polysiloxane Polymers 0.000 claims description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 16
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- 239000013078 crystal Substances 0.000 claims description 15
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- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical group [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 10
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 9
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- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 claims description 6
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 claims description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 6
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- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 6
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- 235000019439 ethyl acetate Nutrition 0.000 claims description 6
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
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- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
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- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
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- 229920000570 polyether Polymers 0.000 claims description 4
- 229920000098 polyolefin Polymers 0.000 claims description 4
- ODLMAHJVESYWTB-UHFFFAOYSA-N propylbenzene Chemical compound CCCC1=CC=CC=C1 ODLMAHJVESYWTB-UHFFFAOYSA-N 0.000 claims description 4
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- FUWDFGKRNIDKAE-UHFFFAOYSA-N 1-butoxypropan-2-yl acetate Chemical compound CCCCOCC(C)OC(C)=O FUWDFGKRNIDKAE-UHFFFAOYSA-N 0.000 claims description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 3
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 3
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- NQBXSWAWVZHKBZ-UHFFFAOYSA-N 2-butoxyethyl acetate Chemical compound CCCCOCCOC(C)=O NQBXSWAWVZHKBZ-UHFFFAOYSA-N 0.000 claims description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 3
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- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 3
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 3
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 3
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- 229960004063 propylene glycol Drugs 0.000 claims description 3
- 235000013772 propylene glycol Nutrition 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 150000003505 terpenes Chemical class 0.000 claims description 3
- 235000007586 terpenes Nutrition 0.000 claims description 3
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 claims description 2
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 229920002732 Polyanhydride Polymers 0.000 claims description 2
- NUPSHWCALHZGOV-UHFFFAOYSA-N acetic acid n-decyl ester Natural products CCCCCCCCCCOC(C)=O NUPSHWCALHZGOV-UHFFFAOYSA-N 0.000 claims description 2
- OCKPROYBCPQWJO-UHFFFAOYSA-N acetyl isocyanate Chemical compound CC(=O)N=C=O OCKPROYBCPQWJO-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
- 229940017144 n-butyl lactate Drugs 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
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- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 claims description 2
- 239000011297 pine tar Substances 0.000 claims description 2
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- XCRZAIPPBHIKOR-UHFFFAOYSA-N prop-2-enyl 4-amino-3-fluorobenzoate Chemical compound NC1=CC=C(C(=O)OCC=C)C=C1F XCRZAIPPBHIKOR-UHFFFAOYSA-N 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 abstract description 11
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- 239000004576 sand Substances 0.000 description 5
- XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(z)-18-[1,3-bis[[(z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 5
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- 235000021355 Stearic acid Nutrition 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
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- 229910010272 inorganic material Inorganic materials 0.000 description 3
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
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- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
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- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 2
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- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
纳米氧化锆的晶型 | 纳米氧化锆的平均粒径(nm) | 纳米氧化锆的重量比(%) | 高分子分散剂名 称 | 高分子分散剂的重量比(%) | 溶剂种类 | 粘度(mPa·s)或状态 | 纳米氧化锆浆平均粒径(nm) | |
比较例1 | 立方 | 100 | 75 | 0 | 醋酸正丁酯 | 结团 | 650 | |
实施例1 | 立方 | 100 | 75 | Solsperse24000+#2150 | 5 | 醋酸正丁酯 | 320 | 146 |
实施例2 | 立方 | 100 | 75 | Solsperse24000+#2150 | 0.6 | 醋酸正丁酯 | 388 | 152 |
实施例3 | 立方 | 100 | 75 | Solsperse24000+#2150 | 12 | 醋酸正丁酯 | 372 | 165 |
比较例2 | 四方 | 60 | 65 | 0 | 甲氧基乙酸丙酯 | 结团 | 743 | |
实施例4 | 四方 | 60 | 65 | Homogenol L-1820+Dispers610 | 7.5 | 甲氧基乙酸丙酯 | 286 | 106 |
实施例5 | 四方 | 60 | 65 | Homogenol L-1820+Dispers610 | 1.2 | 甲氧基乙酸丙酯 | 357 | 124 |
实施例6 | 四方 | 60 | 65 | Homogenol L-1820+Dispers610 | 13.5 | 甲氧基乙酸丙酯 | 297 | 144 |
比较例3 | 四方 | 90 | 55 | 0 | 200号溶剂油 | 结团 | 642 | |
实施例7 | 四方 | 90 | 55 | Disperbyk115 | 2.7 | 200号溶剂油 | 100 | 120 |
实施例8 | 四方 | 90 | 55 | Disperbyk115 | 0.5 | 200号溶剂油 | 170 | 130 |
实施例9 | 四方 | 90 | 55 | Disperbyk115 | 15 | 200号溶剂油 | 132 | 154 |
比较例4 | 非晶 | 30 | 45 | 0 | 异丙醇 | 结团 | 620 | |
实施例10 | 非晶 | 30 | 45 | EFKA-47+#1860 | 6.5 | 异丙醇 | 87 | 77 |
实施例11 | 非晶 | 30 | 45 | EFKA-47+#1860 | 1.5 | 异丙醇 | 159 | 87 |
实施例12 | 非晶 | 30 | 45 | EFKA-47+#1860 | 11 | 异丙醇 | 146 | 89 |
比较例5 | 立方 | 10 | 40 | 0 | 正己烷 | 结团 | 544 | |
实施例13 | 立方 | 10 | 40 | Solsperse3000+Hypersol P4963 | 9 | 正己烷 | 72 | 65 |
实施例14 | 立方 | 10 | 40 | Solsperse3000+Hypersol P4963 | 0.6 | 正己烷 | 133 | 85 |
实施例15 | 立方 | 10 | 40 | Solsperse3000+Hypersol P4963 | 125 | 正己烷 | 103 | 94 |
比较例6 | 四方 | 8 | 35 | 0 | 二甲苯和醋酸乙酯 | 结团 | 436 |
实施例16 | 四方 | 8 | 35 | #7004+DISPERS630S | 5.3 | 二甲苯和醋酸乙酯 | 33 | 45 |
实施例17 | 四方 | 8 | 35 | #7004+DISPERS630S | 0.4 | 二甲苯和醋酸乙酯 | 118 | 67 |
实施例18 | 四方 | 8 | 35 | #7004+DISPERS630S | 11.5 | 二甲苯和醋酸乙酯 | 92 | 83 |
比较例7 | 单斜 | 100 | 30 | 0 | 环己烷+三氯乙烷 | 923 | 369 | |
实施例19 | 单斜 | 100 | 30 | EFKA-POLYMER 453 | 3.6 | 环己烷+三氯乙烷 | 21 | 134 |
实施例20 | 单斜 | 100 | 30 | EFKA-POLYMER 453 | 1.5 | 环己烷+三氯乙烷 | 57 | 146 |
实施例21 | 单斜 | 100 | 30 | EFKA-POLYMER 453 | 10.5 | 环己烷+三氯乙烷 | 45 | 157 |
比较例8 | 四方 | 80 | 25 | 0 | 甲苯和环己酮 | 结团 | 353 | |
实施例22 | 四方 | 80 | 25 | TEXAPHOR3061+TEXAPHOR3112 | 6.2 | 甲苯和环己酮 | 13 | 126 |
实施例23 | 四方 | 80 | 25 | TEXAPHOR3061+TEXAPHOR3112 | 1.7 | 甲苯和环己酮 | 36 | 135 |
实施例24 | 四方 | 80 | 25 | TEXAPHOR3061+TEXAPHOR3112 | 12.5 | 甲苯和环己酮 | 24 | 154 |
比较例9 | 非晶 | 50 | 20 | 0 | 正丁醇 | 832 | 366 | |
实施例25 | 非晶 | 50 | 20 | Solsperse34750 | 4.2 | 正丁醇 | 5 | 75 |
实施例26 | 非晶 | 50 | 20 | Solsperse34750 | 1.2 | 正丁醇 | 14 | 87 |
实施例27 | 非晶 | 50 | 20 | Solsperse34750 | 13.5 | 正丁醇 | 8 | 110 |
比较例10 | 单斜 | 30 | 15 | 0 | 水+乙二醇 | 7 | 286 | |
实施例28 | 单斜 | 30 | 15 | Disperbyk190 | 2.3 | 水+乙二醇 | 4 | 76 |
实施例29 | 单斜 | 30 | 15 | Disperbyk190 | 1 | 水+乙二醇 | 6 | 88 |
实施例30 | 单斜 | 30 | 15 | Disperbyk190 | 11 | 水+乙二醇 | 4.7 | 102 |
比较例11 | 立方 | 15 | 10 | 0 | 水 | 2 | 277 | |
实施例31 | 立方 | 15 | 10 | SOLSPERSE20000 | 5.6 | 水 | 1.2 | 45 |
实施例32 | 立方 | 15 | 10 | SOLSPERSE20000 | 1.8 | 水 | 1.7 | 58 |
实施例33 | 立方 | 15 | 10 | SOLSPERSE20000 | 14 | 水 | 1.3 | 74 |
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