CN1180034C - 一种纳米二氧化钛浆组合物及其制备方法 - Google Patents
一种纳米二氧化钛浆组合物及其制备方法 Download PDFInfo
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- CN1180034C CN1180034C CNB011282061A CN01128206A CN1180034C CN 1180034 C CN1180034 C CN 1180034C CN B011282061 A CNB011282061 A CN B011282061A CN 01128206 A CN01128206 A CN 01128206A CN 1180034 C CN1180034 C CN 1180034C
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- nano titanium
- titanium dioxide
- dispersing agent
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- ether
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- 239000000203 mixture Substances 0.000 title claims abstract description 35
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 title claims description 96
- 238000002360 preparation method Methods 0.000 title claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 141
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- 239000002270 dispersing agent Substances 0.000 claims abstract description 122
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 14
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- 150000002576 ketones Chemical class 0.000 claims abstract description 6
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- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
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- 239000013078 crystal Substances 0.000 claims description 16
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 11
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- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
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- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 6
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- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
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- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 3
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 3
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 3
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 3
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 3
- 229960004063 propylene glycol Drugs 0.000 claims description 3
- 235000013772 propylene glycol Nutrition 0.000 claims description 3
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims description 2
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- 150000007513 acids Chemical class 0.000 claims 1
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- 239000004408 titanium dioxide Substances 0.000 abstract description 12
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- 238000000034 method Methods 0.000 description 26
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
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- XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(z)-18-[1,3-bis[[(z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 5
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 4
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 2
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- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
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- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
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- Inorganic Compounds Of Heavy Metals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
纳米二氧化钛的晶型 | 纳米二氧化钛的平均粒径(nm) | 纳米二氧化钛的重量比% | 高分子分散剂名称 | 高分子分散剂的重量比(%) | 溶剂种类 | 粘度(mPa.s)或状态 | 离心沉降时间(小时) | 贮存期(天) | 纳米二氧化钛浆平均粒径(nm) | |
比较例1 | 金红石型 | 100 | 60 | 0 | 醋酸正丁酯 | 结团 | 590 | |||
实施例1 | 金红石型 | 100 | 60 | solsperse24000+Solsperse32500 | 4.8 | 醋酸正丁酯 | 264 | 6 | 360 | 130 |
实施例2 | 金红石型 | 100 | 60 | solsperse24000+Solsperse32500 | 0.6 | 醋酸正丁酯 | 296 | 5.2 | 312 | 152 |
实施例3 | 金红石型 | 100 | 60 | Solsperse24000+Solsperse32500 | 9.2 | 醋酸正丁酯 | 284 | 4.1 | 246 | 160 |
比较例2 | 锐钛矿型 | 90 | 55 | 0 | 200号溶剂油 | 结团 | 480 | |||
实施例4 | 锐钛矿型 | 90 | 55 | Disperbyk107 | 2.7 | 200号溶剂油 | 210 | 7.2 | 432 | 110 |
实施例5 | 锐钛矿型 | 90 | 55 | Disperbyk107 | 0.5 | 200号溶剂油 | 290 | 6.5 | 390 | 150 |
实施例6 | 锐钛矿型 | 90 | 55 | Disperbyk107 | 8.5 | 200号溶剂油 | 254 | 5.8 | 348 | 134 |
比较例3 | 锐钛矿型 | 60 | 50 | 0 | 甲氧基乙酸丙酯 | 结团 | 508 | |||
实施例7 | 锐钛矿型 | 60 | 50 | Dispers700+Dispers610 | 7.5 | 甲氧基乙酸丙酯 | 100 | 9.6 | 576 | 85 |
实施例8 | 锐钛矿型 | 60 | 50 | Dispers700+Dispers610 | 1.2 | 甲氧基乙酸丙酯 | 276 | 8.1 | 486 | 110 |
实施例9 | 锐钛矿型 | 60 | 50 | Dispers700+Dispers610 | 8.7 | 甲氧基乙酸丙酯 | 204 | 7.0 | 420 | 140 |
比较例4 | 非晶型 | 30 | 45 | 0 | 异丙醇 | 结团 | 450 | |||
实施例10 | 非晶型 | 30 | 45 | 902+904 | 6.5 | 异丙醇 | 52 | 3.5 | 210 | 68 |
实施例11 | 非晶型 | 30 | 45 | 902+904 | 1.5 | 异丙醇 | 230 | 3.1 | 186 | 96 |
实施例12 | 非晶型 | 30 | 45 | 902+904 | 10 | 异丙醇 | 162 | 2.5 | 150 | 87 |
比较例5 | 金红石型 | 10 | 40 | 0 | 正己烷 | 结团 | 267 | |||
实施例13 | 金红石型 | 10 | 40 | Hypersol L4708+Hypersol P4963 | 2.8 | 正己烷 | 30 | 4.5 | 270 | 52 |
实施例14 | 金红石型 | 10 | 40 | Hypersol L4708+Hypersol P4963 | 0.6 | 正己烷 | 285 | 4.2 | 252 | 79 |
实施例15 | 金红石型 | 10 | 40 | Hypersol L4708+Hypersol P4963 | 9 | 正己烷 | 219 | 3.5 | 210 | 95 |
比较例6 | 锐钛矿型 | 8 | 35 | 0 | 二甲苯和醋酸乙酯 | 结团 | 180 | |||
实施例16 | 锐钛矿型 | 8 | 35 | AB1010+AB1020 | 5.3 | 二甲苯和醋酸乙酯 | 128 | 5 | 300 | 22 |
实施例17 | 锐钛矿型 | 8 | 35 | AB1010+AB1020 | 0.4 | 二甲苯和醋酸乙酯 | 240 | 2.8 | 168 | 45 |
实施例18 | 锐钛矿型 | 8 | 35 | AB1010+AB1020 | 9.5 | 二甲苯和醋酸乙酯 | 210 | 3.1 | 186 | 36 |
比较例7 | 混晶型 | 100 | 30 | 0 | 环己烷十三氯乙烷 | 786 | 0.3 | 18 | 425 | |
实施例19 | 混晶型 | 100 | 30 | Incrosperse M | 3.6 | 环己烷十三氯乙烷 | 200 | 2.1 | 126 | 115 |
实施例20 | 混晶型 | 100 | 30 | Incrosperse M | 1.5 | 环已烷十三氯乙烷 | 270 | 1.8 | 108 | 120 |
实施例21 | 混晶型 | 100 | 30 | Incrosperse M | 8.5 | 环己烷十三氯乙烷 | 246 | 1.5 | 90 | 158 |
比较例8 | 金红石型 | 80 | 25 | 0 | 甲苯和环己酮 | 结团 | 379 | |||
实施例22 | 金红石型 | 80 | 25 | TEXAPHOR3241+TEXAPHOR3112 | 6.2 | 甲苯和环己酮 | 36 | 2.5 | 150 | 95 |
实施例23 | 金红石型 | 80 | 25 | TEXAPHOR3241+TEXAPHOR3112 | 1.7 | 甲苯和环己酮 | 236 | 2.1 | 126 | 140 |
实施例24 | 金红石型 | 80 | 25 | TEXAPHOR3241+TEXAPHOR3112 | 8.4 | 甲苯和环己酮 | 289 | 1.9 | 114 | 120 |
比较例9 | 非晶型 | 50 | 20 | 0 | 正丁醇 | 3000 | 0.2 | 12 | 357 | |
实施例25 | 非晶型 | 50 | 20 | Solsperse41090 | 4.2 | 正丁醇 | 45 | 2 | 120 | 83 |
实施例26 | 非晶型 | 50 | 20 | Solsperse41090 | 1.2 | 正丁醇 | 235 | 1.5 | 90 | 88 |
实施例27 | 非晶型 | 50 | 20 | Solsperse41090 | 9.5 | 正丁醇 | 279 | 1.8 | 108 | 104 |
比较例10 | 混晶型 | 30 | 15 | 0 | 水+乙二醇 | 150 | 0.2 | 12 | 274 | |
实施例28 | 混晶型 | 30 | 15 | Disperbyk182 | 2.3 | 水+乙二醇 | 120 | 3.5 | 210 | 67 |
实施例29 | 混晶型 | 30 | 15 | Disperbyk182 | 1 | 水+乙二醇 | 248 | 3.2 | 192 | 86 |
实施例30 | 混晶型 | 30 | 15 | Disperbyk182 | 10.2 | 水+乙二醇 | 269 | 2.8 | 168 | 92 |
比较例11 | 金红石型 | 15 | 10 | 0 | 水 | 54 | 0.1 | 6 | 304 | |
实施例31 | 金红石型 | 15 | 10 | EFKA-71 | 5.6 | 水 | 8 | 1.8 | 108 | 36 |
实施例32 | 金红石型 | 15 | 10 | EFKA-71 | 1.8 | 水 | 12 | 1.6 | 96 | 45 |
实施例33 | 金红石型 | 15 | 10 | EFKA-71 | 9.3 | 水 | 23 | 1.7 | 102 | 54 |
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