CN1177891C - 耐磨热塑性弹性体材料组合物 - Google Patents
耐磨热塑性弹性体材料组合物 Download PDFInfo
- Publication number
- CN1177891C CN1177891C CNB011269022A CN01126902A CN1177891C CN 1177891 C CN1177891 C CN 1177891C CN B011269022 A CNB011269022 A CN B011269022A CN 01126902 A CN01126902 A CN 01126902A CN 1177891 C CN1177891 C CN 1177891C
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- CN
- China
- Prior art keywords
- antioxygen
- wear
- agent
- thermoplastic elastomer
- material composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000463 material Substances 0.000 title claims abstract description 22
- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 17
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 229920001971 elastomer Polymers 0.000 claims abstract description 11
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 10
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 9
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 5
- 239000004611 light stabiliser Substances 0.000 claims abstract description 3
- -1 polypropylene Polymers 0.000 claims description 24
- 239000004698 Polyethylene Substances 0.000 claims description 14
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 claims description 10
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims description 6
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- KWUZCAVKPCRJPO-UHFFFAOYSA-N n-ethyl-4-(6-methyl-1,3-benzothiazol-2-yl)aniline Chemical compound C1=CC(NCC)=CC=C1C1=NC2=CC=C(C)C=C2S1 KWUZCAVKPCRJPO-UHFFFAOYSA-N 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 3
- 229920003192 poly(bis maleimide) Polymers 0.000 claims description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 claims description 2
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims description 2
- PGCBRGRKKOCPAN-UHFFFAOYSA-N 4-triethoxysilylbutanamide Chemical compound CCO[Si](OCC)(OCC)CCCC(N)=O PGCBRGRKKOCPAN-UHFFFAOYSA-N 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229950002083 octabenzone Drugs 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract description 11
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract description 11
- 239000000806 elastomer Substances 0.000 abstract description 4
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 description 5
- 238000001746 injection moulding Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
1# | |
EPDM | 700 |
PE | 300 |
PTFE | 30 |
硅酮 | 10 |
抗氧1010 | 2 |
UV-3346 | 2 |
UV-3853S | 2 |
双马来酰亚胺 | 5 |
测试项目 | 单位 | 1# |
熔融指数 | G/10min | 1.32 |
拉伸强度 | MPa | 20.6 |
断裂伸长率 | % | 450 |
邵氏(A)硬度 | Ha | 80 |
阿克隆磨耗 | Cm3/1.61km | 0.09 |
2# | 3# | 4# | |
POE | 900 | 800 | 600 |
PP | 100 | 200 | 400 |
PTFE | 50 | 50 | 30 |
硅酮 | 30 | 30 | 30 |
抗氧2777 | 1 | 1 | 1 |
UV-531 | 1 | 1 | 1 |
A-1106 | 5 | 5 | 5 |
PE蜡 | 5 | 5 | 5 |
测试项目 | 单位 | 2# | 3# | 4# |
熔融指数 | G/10min | 1.23 | 2.06 | 2.58 |
拉伸强度 | MPa | 8.83 | 11.92 | 13.08 |
断裂伸长率 | % | 1100 | 918 | 13.08 |
邵氏(A)硬度 | Ha | 71 | 78 | 90 |
阿克隆磨耗 | Cm3/1.61km | 0 | 0 | 0 |
5# | 6# | |
EVA | 800 | 700 |
PE | 100 | 300 |
PTFE | 80 | 60 |
硅酮 | 50 | 50 |
抗氧1010 | 1 | 1 |
抗氧168 | 3 | 3 |
UV-531 | 2 | 2 |
分子量调节剂 | 4 | 4 |
测试项目 | 单位 | 5# | 6# |
熔融指数 | G/10min | 1.34 | 2.21 |
拉伸强度 | MPa | 10.17 | 14.17 |
断裂伸长率 | % | 1600 | 1100 |
邵氏(A)硬度 | Ha | 53 | 65 |
阿克隆磨耗 | Cm3/1.61km | 0 | 0 |
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011269022A CN1177891C (zh) | 2001-09-28 | 2001-09-28 | 耐磨热塑性弹性体材料组合物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB011269022A CN1177891C (zh) | 2001-09-28 | 2001-09-28 | 耐磨热塑性弹性体材料组合物 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1408757A CN1408757A (zh) | 2003-04-09 |
CN1177891C true CN1177891C (zh) | 2004-12-01 |
Family
ID=4666905
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB011269022A Expired - Lifetime CN1177891C (zh) | 2001-09-28 | 2001-09-28 | 耐磨热塑性弹性体材料组合物 |
Country Status (1)
Country | Link |
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CN (1) | CN1177891C (zh) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101704970B (zh) * | 2009-10-28 | 2012-07-11 | 无锡润鹏复合新材料有限公司 | 一种高耐磨热塑性弹性体组合物及其制备方法 |
CN102336954A (zh) * | 2010-07-19 | 2012-02-01 | 哈尔滨鑫达高分子材料工程中心有限责任公司 | 一种用于汽车内饰的哑光、耐刮擦改性聚丙烯复合材料 |
CN102268159A (zh) * | 2011-06-03 | 2011-12-07 | 江西人民线缆科技集团有限公司 | 生产三元乙丙/聚乙烯热塑性弹性体的工艺 |
CN102492196A (zh) * | 2011-12-04 | 2012-06-13 | 上海金发科技发展有限公司 | 一种高温耐磨擦聚烯烃复合物及其制备方法 |
CN103613947B (zh) * | 2013-11-20 | 2015-11-25 | 威县盛达密封件有限公司 | 汽车密封条用橡胶料 |
CN103724968A (zh) * | 2013-12-27 | 2014-04-16 | 上海普塑达复合材料有限公司 | 一种高耐热高刚无卤阻燃耐刮擦pc-abs合金材料及其制备方法 |
CN104945744A (zh) * | 2014-03-27 | 2015-09-30 | 苏州欣港神工贸有限公司 | 一种高分子热塑弹性体材质滚轮及其制作工艺 |
CN104497453A (zh) * | 2014-11-26 | 2015-04-08 | 上海品科橡塑材料有限公司 | 一种新型橡胶耐磨剂及其组合物 |
CN104479533B (zh) * | 2014-12-31 | 2016-10-26 | 艾艾精密工业输送***(上海)股份有限公司 | 一种耐溶剂tpu复合材料及其用于制备轻型输送带的方法 |
CN104559071A (zh) * | 2015-01-14 | 2015-04-29 | 长沙五犇新材料科技有限公司 | 一种抗疲劳热塑性弹性体及其梅花联轴器元件的制备方法 |
CN105038235A (zh) * | 2015-06-24 | 2015-11-11 | 厦门迈图新材料有限公司 | 一种应用于eva发泡鞋材的高性能耐磨剂及其制造方法 |
CN105131536B (zh) * | 2015-08-31 | 2018-01-16 | 宁波海雨新材料科技有限公司 | 高耐磨tpee热塑性聚酯弹性体 |
CN108504005A (zh) * | 2018-03-28 | 2018-09-07 | 陈太师 | 一种增韧耐磨油封材料的制备方法 |
CN109627590B (zh) * | 2018-12-24 | 2021-12-07 | 宁波汉吉高分子材料有限公司 | 一种汽车密封条用耐磨tpv材料及其制备方法 |
CN114159628B (zh) * | 2021-12-20 | 2022-07-22 | 厦门银丰科技有限公司 | 一种微创手术导丝 |
-
2001
- 2001-09-28 CN CNB011269022A patent/CN1177891C/zh not_active Expired - Lifetime
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Publication number | Publication date |
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CN1408757A (zh) | 2003-04-09 |
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Owner name: LIAONING JIESHIJIE NEW MATERIALS CO., LTD. Free format text: FORMER OWNER: JIESHIJIE NOVEL MATERIALS CO., LTD, SHANGHAI Effective date: 20090403 |
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Effective date of registration: 20090403 Address after: Panshan Economic Development Zone, Panjin, Liaoning Patentee after: LIAONING GENIUS NEW MATERIAL Co.,Ltd. Address before: No. 800, North Song Road, North Qiao Town, Shanghai, Minhang District Patentee before: Shanghai Genius Advanced Material Co.,Ltd. |
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Address after: 124101 new material industrial park, Taiping Town, Panshan County, Liaoning, Panjin Patentee after: LIAONING GENIUS NEW MATERIAL Co.,Ltd. Address before: 124000 Panshan Economic Development Zone, Panjin, Liaoning Patentee before: LIAONING GENIUS NEW MATERIAL Co.,Ltd. |
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Date of cancellation: 20110119 Granted publication date: 20041201 Pledgee: Management Committee of Panshan Economic Development Zone Pledgor: LIAONING GENIUS NEW MATERIAL Co.,Ltd. Registration number: 2009210000665 |
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Owner name: SHANGHAI GENIUS ADVANCED MATERIALS (GROUP) CO., LT Free format text: FORMER OWNER: LIAONING GENIUS ADVANCED MATERIALS CO., LTD. Effective date: 20110316 Owner name: HEFEI GENIUS ADVANCED MATERIALS CO., LTD. Free format text: FORMER OWNER: SHANGHAI GENIUS ADVANCED MATERIALS (GROUP) CO., LTD. Effective date: 20110316 |
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Free format text: CORRECT: ADDRESS; FROM: 124101 NEW MATERIALS INDUSTRIAL PARK, TAIPING TOWN, PANSHAN COUNTY, PANJIN CITY, LIAONING PROVINCE TO: 201109 NO. 800, BEISONG ROAD, MINHANG ROAD, SHANGHAI Free format text: CORRECT: ADDRESS; FROM: 201109 NO. 800, BEISONG ROAD, MINHANG ROAD, SHANGHAI TO: 230601 NO. 2388, LIANHUA ROAD, ECONOMIC DEVELOPMENT ZONE, HEFEI CITY, ANHUI PROVINCE |
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