CN1176984C - 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 - Google Patents
聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜Info
- Publication number
- CN1176984C CN1176984C CNB001048376A CN00104837A CN1176984C CN 1176984 C CN1176984 C CN 1176984C CN B001048376 A CNB001048376 A CN B001048376A CN 00104837 A CN00104837 A CN 00104837A CN 1176984 C CN1176984 C CN 1176984C
- Authority
- CN
- China
- Prior art keywords
- component
- polyolefin resin
- temperature
- propylene
- tref
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 239000003607 modifier Substances 0.000 title description 4
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- 238000005259 measurement Methods 0.000 claims description 20
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- 239000000155 melt Substances 0.000 claims description 3
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- 238000006116 polymerization reaction Methods 0.000 description 52
- 230000000052 comparative effect Effects 0.000 description 47
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- 229910052726 zirconium Inorganic materials 0.000 description 42
- 239000003054 catalyst Substances 0.000 description 40
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- 229910052796 boron Inorganic materials 0.000 description 16
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- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 7
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 7
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 7
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
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- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
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- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 5
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- 238000005194 fractionation Methods 0.000 description 5
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- 239000000463 material Substances 0.000 description 5
- 150000002899 organoaluminium compounds Chemical class 0.000 description 5
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
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- 150000003609 titanium compounds Chemical class 0.000 description 5
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
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- 238000000746 purification Methods 0.000 description 4
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- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 3
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- 230000032683 aging Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- ZPECUSGQPIKHLT-UHFFFAOYSA-N bis(ethenyl)-dimethoxysilane Chemical compound CO[Si](OC)(C=C)C=C ZPECUSGQPIKHLT-UHFFFAOYSA-N 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical class FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- CYKLGTUKGYURDP-UHFFFAOYSA-L copper;hydrogen sulfate;hydroxide Chemical compound O.[Cu+2].[O-]S([O-])(=O)=O CYKLGTUKGYURDP-UHFFFAOYSA-L 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- QPJORFLSOJAUNL-UHFFFAOYSA-N dibenzo[a,d][7]annulene Chemical compound C1=CC2=CC=CC=C2CC2=CC=CC=C21 QPJORFLSOJAUNL-UHFFFAOYSA-N 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-O dicyclohexylazanium Chemical compound C1CCCCC1[NH2+]C1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-O 0.000 description 1
- VSYLGGHSEIWGJV-UHFFFAOYSA-N diethyl(dimethoxy)silane Chemical compound CC[Si](CC)(OC)OC VSYLGGHSEIWGJV-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- JVUVKQDVTIIMOD-UHFFFAOYSA-N dimethoxy(dipropyl)silane Chemical compound CCC[Si](OC)(OC)CCC JVUVKQDVTIIMOD-UHFFFAOYSA-N 0.000 description 1
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 1
- WERMRYHPOOABQT-UHFFFAOYSA-N dimethoxy-bis(prop-2-enyl)silane Chemical compound C=CC[Si](OC)(CC=C)OC WERMRYHPOOABQT-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- YGUFXEJWPRRAEK-UHFFFAOYSA-N dodecyl(triethoxy)silane Chemical compound CCCCCCCCCCCC[Si](OCC)(OCC)OCC YGUFXEJWPRRAEK-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- HTSRFYSEWIPFNI-UHFFFAOYSA-N ethyl-dimethoxy-methylsilane Chemical group CC[Si](C)(OC)OC HTSRFYSEWIPFNI-UHFFFAOYSA-N 0.000 description 1
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229960002337 magnesium chloride Drugs 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000005574 norbornylene group Chemical group 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 238000012673 precipitation polymerization Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229960004029 silicic acid Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- CDZULFMEYKOAEF-UHFFFAOYSA-N triethoxy(ethynyl)silane Chemical compound CCO[Si](OCC)(OCC)C#C CDZULFMEYKOAEF-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- FHVAUDREWWXPRW-UHFFFAOYSA-N triethoxy(pentyl)silane Chemical compound CCCCC[Si](OCC)(OCC)OCC FHVAUDREWWXPRW-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- MJINPUKGRATQAC-UHFFFAOYSA-N triethoxy(prop-1-enyl)silane Chemical compound CCO[Si](OCC)(OCC)C=CC MJINPUKGRATQAC-UHFFFAOYSA-N 0.000 description 1
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- MXSVLWZRHLXFKH-UHFFFAOYSA-N triphenylborane Chemical compound C1=CC=CC=C1B(C=1C=CC=CC=1)C1=CC=CC=C1 MXSVLWZRHLXFKH-UHFFFAOYSA-N 0.000 description 1
- RIOQSEWOXXDEQQ-UHFFFAOYSA-O triphenylphosphanium Chemical compound C1=CC=CC=C1[PH+](C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-O 0.000 description 1
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
MFRg/10min | TREF36-104105-106wt% | TREF>116104-105wt% | TREF<0℃wt% | TREF40-88105-106wt% | TREF44-68105-106wt% | 熔点℃ | 立构规整度mmmm | 共聚单体(mol%) | 分子量分布 | |
a | 3.1 | 4.3 | 2.5 | 2.7 | 4.0 | 2.8 | 159 | 0.932 | 乙烯0.5 | 7.0 |
b | 2.1 | 4.1 | 6.3 | 3.3 | 3.7 | 2.3 | 160 | 0.937 | - | 8.5 |
c | 2.3 | 2.3 | 7.8 | 2.0 | 1.1 | 0.9 | 161 | 0.962 | - | 6.2 |
d | 3.0 | 3.0 | 6.2 | 2.3 | 2.4 | 1.3 | 158 | 0.960 | 乙烯0.7 | 6.5 |
e | 1.9 | 44.1 | 0 | 5.2 | 35.2 | 23.5 | 145 | - | 乙烯5.3 | 4.3 |
f | 3.5 | 1.8 | 11.8 | 1.2 | 0.8 | 0.1 | 162 | 0.975 | - | 6.1 |
g | 7.5 | 55.0 | 0 | 6.1 | 39.2 | 28.8 | 137 | - | 乙烯8.1 | 4.5 |
h | 60 | 40.3 | 0 | 4.3 | 35.1 | 24.1 | 147 | - | 乙烯5.1 | 3.1 |
i | 8.7 | 45.2 | 0 | 0 | 12.3 | 10.2 | 125 | - | 乙烯5.1 | 2.3 |
j | 10.1 | 65.1 | 0 | 1.3 | 64.2 | 63.7 | 110·146 | - | 乙烯7.0 | 2.2 |
k | 13.2 | 95.7 | 0 | 0.5 | 92.2 | 90.3 | 85·146 | - | 乙烯12.3 | 2.3 |
l | 8 | 55.3 | 0 | 9.2 | 41.1 | 28.8 | 110 | - | 丁烯25 | 4.6 |
m | 8 | 4.8 | 0 | 95.2 | 0 | 0 | - | - | 乙烯18.2 | 2.0 |
n | 40 | 1.9 | 22.2 | 2.1 | 1.0 | 0.1 | 161 | 0.981 | - | 6.0 |
o | 40 | 0.8 | 39.8 | 0.5 | 0.5 | 0 | 163 | 0.993 | - | 5.8 |
原料1(量)wt% | 原料2(量)wt% | 原料3(量)wt% | TREF36-104105-106wt%A1 | TREF>116104-105wt%A2 | TREF<0℃wt% | ||||
实施例1 | a | 100 | - | - | - | - | 4.3 | 2.5 | 2.7 |
实施例2 | b | 100 | - | - | - | - | 4.1 | 6.3 | 3.3 |
对比实施例1 | c | 100 | - | - | - | - | 2.3 | 7.8 | 2.0 |
对比实施例2 | d | 100 | - | - | - | - | 3.0 | 6.2 | 2.3 |
对比实施例3 | e | 100 | - | - | - | - | 44.1 | 0 | 5.2 |
对比实施例4 | f | 100 | - | - | - | - | 1.8 | 11.8 | 1.2 |
实施例3 | c | 96 | g | 4 | - | - | 4.4 | 7.5 | 2.2 |
实施例4 | c | 92 | g | 8 | - | - | 6.5 | 7.2 | 2.3 |
实施例5 | c | 85 | g | 15 | - | - | 10.2 | 6.5 | 2.6 |
实施例6 | d | 92 | h | 8 | - | - | 6.0 | 5.7 | 2.5 |
实施例7 | d | 92 | i | 8 | - | - | 6.4 | 5.7 | 2.1 |
实施例8 | d | 92 | j | 8 | - | - | 8.0 | 5.7 | 2.2 |
实施例9 | d | 92 | k | 8 | - | - | 10.4 | 5.7 | 2.2 |
实施例10 | d | 92 | l | 8 | - | - | 7.2 | 5.7 | 2.9 |
实施例11 | d | 96 | l | 4 | - | - | 5.5 | 6.0 | 2.3 |
实施例12 | d | 98 | l | 2 | - | - | 4.2 | 6.0 | 2.3 |
对比实施例5 | c | 98 | l | 2 | - | - | 2.9 | 6.0 | 2.3 |
在0℃下TREF的峰顶分子量(×10-4) | TREF40-88105-106wt% | TREF44-68105-106wt% | A2/A1 | MFRg/10min | |
实施例1 | 22.3 | 4.0 | 2.8 | 0.58 | 3.1 |
实施例2 | 32.4 | 3.7 | 2.3 | 1.54 | 2.1 |
对比实施例1 | 22.9 | 1.1 | 0.9 | 3.39 | 2.3 |
对比实施例2 | 21.5 | 2.4 | 1.3 | 2.07 | 3.0 |
对比实施例3 | 11.5 | 35.2 | 23.5 | 0 | 1.9 |
对比实施例4 | 19.5 | 0.8 | 0.1 | 6.56 | 3.5 |
实施例3 | 22.9 | 2.6 | 2.0 | 1.70 | 2.4 |
实施例4 | 22.9 | 4.1 | 3.1 | 1.10 | 2.5 |
实施例5 | 16.9 | 6.8 | 5.1 | 0.65 | 2.8 |
实施例6 | 21.5 | 5.0 | 3.1 | 0.95 | 3.8 |
实施例7 | 21.5 | 3.2 | 2.0 | 0.89 | 3.3 |
实施例8 | 21.5 | 7.3 | 6.3 | 0.72 | 3.3 |
实施例9 | 21.5 | 9.6 | 8.4 | 0.55 | 3.4 |
实施例10 | 21.5 | 5.5 | 3.5 | 0.79 | 3.2 |
实施例11 | 21.5 | 4.9 | 3.8 | 1.09 | 3.1 |
实施例12 | 21.5 | 3.6 | 2.5 | 1.43 | 3.1 |
对比实施例5 | 22.9 | 2.4 | 1.3 | 2.07 | 2.4 |
原料1(量)wt% | 原料2(量)wt% | 原料3(量)wt% | TREF36-104105-106wt%A1 | TREF>116104-105wt%A2 | TREF<0℃wt% | ||||
实施例13 | c | 96 | l | 4 | - | - | 4.4 | 6.0 | 2.3 |
实施例14 | c | 85 | l | 15 | - | - | 10.3 | 6.0 | 3.1 |
对比实施例6 | c | 60 | l | 40 | - | - | 23.5 | 4.7 | 4.9 |
实施例15 | c | 95 | j | 5 | - | - | 5.4 | 7.4 | 2.0 |
实施例16 | c | 90 | j | 10 | - | - | 8.6 | 7.0 | 1.9 |
实施例17 | c | 75 | j | 25 | - | - | 18.0 | 5.9 | 1.8 |
实施例18 | c | 95 | k | 5 | - | - | 7.0 | 7.4 | 1.9 |
实施例19 | f | 95 | k | 5 | - | - | 6.5 | 5.4 | 4.6 |
实施例20 | f | 90 | k | 10 | - | - | 11.8 | 10.5 | 1.1 |
对比实施例7 | f | 90 | m | 10 | - | - | 2.1 | 10.6 | 10.6 |
实施例21 | d | 92 | l | 4 | n | 4 | 5.0 | 6.6 | 2.6 |
实施例22 | d | 84 | l | 8 | n | 8 | 7.1 | 7.0 | 2.8 |
实施例23 | c | 68 | k | 12 | n | 20 | 9.8 | 9.7 | 1.9 |
实施例24 | d | 94 | k | 4 | o | 2 | 6.7 | 6.6 | 2.2 |
实施例25 | d | 97 | k | 2 | o | 1 | 4.8 | 6.4 | 2.2 |
实施例26 | d | 70 | k | 10 | o | 20 | 11.8 | 12.3 | 1.8 |
在0℃下TREF的峰顶分子量(×10-4) | TREF40-88105-106wt% | TREF44-68105-106wt% | A2/A1 | MFRg/10min | |
实施例13 | 22.9 | 2.7 | 2.0 | 1.69 | 2.4 |
实施例14 | 22.9 | 7.1 | 5.1 | 0.65 | 2.8 |
对比实施例6 | 22.9 | 17.1 | 12.1 | 0.20 | 3.8 |
实施例15 | 22.9 | 4.3 | 4 | 1.36 | 2.5 |
实施例16 | 22.9 | 7.4 | 7.2 | 0.82 | 2.7 |
实施例17 | 22.9 | 16.9 | 16.6 | 0.33 | 3.3 |
实施例18 | 22.9 | 5.7 | 5.4 | 1.06 | 2.5 |
实施例19 | 24.1 | 1.2 | 11.2 | 1.73 | 3.7 |
实施例20 | 24.1 | 10.5 | 9.7 | 0.89 | 4.0 |
对比实施例7 | 9.1 | 0.7 | 0.1 | 5.01 | 3.8 |
实施例21 | 21.5 | 3.9 | 2.4 | 1.31 | 3.5 |
实施例22 | 20.8 | 5.4 | 3.4 | 0.98 | 4.0 |
实施例23 | 18.4 | 8.7 | 8.3 | 1.00 | 5.0 |
实施例24 | 21.5 | 6.0 | 4.8 | 0.99 | 3.4 |
实施例25 | 21.5 | 4.2 | 3.1 | 1.33 | 3.2 |
实施例26 | 16.8 | 11.0 | 9.9 | 1.04 | 5.8 |
成膜温度 | 温度宽度℃ | 机械负荷 | 膜断裂(次数) | 厚度精度 | 热收缩率 | ||||
下限℃ | 上限℃ | MDA | TDA | MD% | TD% | ||||
实施例1 | 146 | 157 | 11 | 4.4 | 28.0 | 0 | ○ | 3.8 | 3.7 |
实施例2 | 147 | 158 | 11 | 4.2 | 28.0 | 0 | ○ | 4.0 | 3.8 |
对比实施例1 | 157 | 160 | 3 | 5.3 | 31.0 | 13 | × | 2.9 | 2.1 |
对比实施例2 | 154 | 158 | 4 | 5.1 | 29.5 | 8 | △ | 3.4 | 3.2 |
对比实施例3 | 129 | 145 | 16 | 3.0 | 22.0 | 0 | ○ | 8.1 | 17.6 |
对比实施例4 | 158 | 160 | 2 | 5.7 | 32.5 | 17 | × | 2.0 | 1.7 |
实施例3 | 147 | 159 | 12 | 4.2 | 27.5 | 0 | ○ | 3.2 | 2.5 |
实施例4 | 142 | 158 | 16 | 3.6 | 24.5 | 0 | ◎ | 3.8 | 4.7 |
实施例5 | 137 | 156 | 19 | 3.2 | 23.0 | 0 | ◎ | 5.6 | 6.1 |
实施例6 | 144 | 157 | 14 | 4.0 | 26.0 | 0 | ◎ | 4.2 | 5.1 |
实施例7 | 143 | 158 | 15 | 4.0 | 25.5 | 0 | ◎ | 4.3 | 5.1 |
实施例8 | 141 | 158 | 17 | 3.6 | 23.5 | 0 | ◎ | 4.2 | 4.6 |
实施例9 | 139 | 158 | 19 | 3.3 | 24.0 | 0 | ◎ | 4.8 | 5.9 |
实施例10 | 141 | 157 | 16 | 3.5 | 24.5 | 0 | ◎ | 4.8 | 5.9 |
实施例11 | 145 | 158 | 13 | 4.1 | 26.0 | 0 | ○ | 4.2 | 5.3 |
实施例12 | 147 | 158 | 11 | 4.2 | 27.0 | 0 | ○ | 3.8 | 3.5 |
对比实施例5 | 156 | 160 | 4 | 5.2 | 32.5 | 10 | × | 3.4 | 3.0 |
成膜温度 | 温度宽度℃ | 机械负荷 | 膜断裂(次数) | 厚度精度 | 热收缩率 | ||||
上限℃ | 下限℃ | MDA | TDA | MD% | TD% | ||||
实施例13 | 147 | 159 | 12 | 4.3 | 27.5 | 0 | ○ | 3.4 | 2.9 |
实施例14 | 139 | 158 | 19 | 3.7 | 23.5 | 0 | ◎ | 4.8 | 5.7 |
对比实施例6 | 133 | 157 | 24 | 3.1 | 22.5 | 0 | ◎ | 7.8 | 14.6 |
实施例15 | 147 | 160 | 13 | 4.3 | 27.0 | 0 | ○ | 4.0 | 4.9 |
实施例16 | 142 | 159 | 18 | 3.8 | 24.0 | 0 | ◎ | 3.9 | 4.1 |
实施例17 | 141 | 157 | 26 | 3.8 | 23.5 | 0 | ○ | 5.9 | 12.4 |
实施例18 | 144 | 160 | 17 | 4.0 | 26.0 | 0 | ◎ | 4.6 | 4.3 |
实施例19 | 145 | 160 | 15 | 4.1 | 26.0 | 0 | ◎ | 5.8 | 6.8 |
实施例20 | 137 | 158 | 21 | 3.2 | 23.0 | 0 | ◎ | 4.5 | 4.7 |
对比实施例7 | 156 | 160 | 4 | 5.3 | 31.0 | 15 | × | 3.2 | 2.0 |
实施例21 | 146 | 158 | 12 | 4.0 | 26.5 | 0 | ○ | 4.0 | 4.9 |
实施例22 | 141 | 157 | 16 | 3.7 | 24.0 | 0 | ◎ | 4.5 | 4.1 |
实施例23 | 141 | 160 | 19 | 3.7 | 24.0 | 0 | ◎ | 4.2 | 4.4 |
实施例24 | 142 | 158 | 16 | 3.7 | 24.5 | 0 | ◎ | 4.2 | 4.1 |
实施例25 | 146 | 158 | 12 | 4.1 | 26.5 | 0 | ○ | 3.9 | 4.8 |
实施例26 | 136 | 157 | 21 | 3.2 | 22.5 | 0 | ◎ | 4.2 | 4.5 |
Claims (8)
Applications Claiming Priority (2)
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JP88365/1999 | 1999-03-30 | ||
JP8836599 | 1999-03-30 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNA031523315A Division CN1536011A (zh) | 1999-03-30 | 2000-03-30 | 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 |
Publications (2)
Publication Number | Publication Date |
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CN1269379A CN1269379A (zh) | 2000-10-11 |
CN1176984C true CN1176984C (zh) | 2004-11-24 |
Family
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Application Number | Title | Priority Date | Filing Date |
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CNB001048376A Expired - Fee Related CN1176984C (zh) | 1999-03-30 | 2000-03-30 | 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 |
CNB2005100999473A Expired - Fee Related CN100392010C (zh) | 1999-03-30 | 2000-03-30 | 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 |
CNA031523315A Pending CN1536011A (zh) | 1999-03-30 | 2000-03-30 | 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 |
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CNB2005100999473A Expired - Fee Related CN100392010C (zh) | 1999-03-30 | 2000-03-30 | 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 |
CNA031523315A Pending CN1536011A (zh) | 1999-03-30 | 2000-03-30 | 聚烯烃树脂改性剂,聚烯烃树脂组合物和取向聚烯烃膜 |
Country Status (4)
Country | Link |
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US (2) | US6339128B1 (zh) |
EP (1) | EP1041114B1 (zh) |
CN (3) | CN1176984C (zh) |
DE (1) | DE60029374T2 (zh) |
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Publication number | Priority date | Publication date | Assignee | Title |
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EP1572761A1 (en) * | 2002-12-16 | 2005-09-14 | Basell Polyolefine GmbH | Preparation of supported catalyst systems containing reduced amounts of aluminoxanes |
US20120184061A1 (en) * | 2009-09-29 | 2012-07-19 | Toppan Printing Co., Ltd | Sealing material sheet for solar cell module and a method of manufacturing solar cell module |
CA2786295A1 (en) * | 2010-01-04 | 2011-07-07 | Lawrence R. Sita | Scalable production of precision hydrocarbons from trialkylaluminum via ternary living coordinative chain transfer polymerization |
KR102024496B1 (ko) * | 2015-12-11 | 2019-09-23 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌계 중합체 조성물 |
WO2021011576A1 (en) * | 2019-07-17 | 2021-01-21 | Jindal Films Americas Llc | Heat-stable biaxially oriented polypropylene films |
JP2022083825A (ja) * | 2020-11-25 | 2022-06-06 | 住友化学株式会社 | プロピレン重合体組成物、および、フィルム |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5883006A (ja) | 1981-11-13 | 1983-05-18 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
US4798081A (en) * | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
DE69201180T2 (de) * | 1991-10-21 | 1995-06-14 | Mitsubishi Petrochemical Co | Propylencopolymerzusammensetzung. |
WO1994006859A1 (en) * | 1992-09-15 | 1994-03-31 | The Dow Chemical Company | Impact modification of thermoplastics |
JPH07292029A (ja) | 1994-04-28 | 1995-11-07 | Toho Titanium Co Ltd | オレフィン類重合用触媒および重合方法 |
JP3916681B2 (ja) | 1994-04-15 | 2007-05-16 | 三菱化学株式会社 | プロピレン系フィルム |
ES2221667T3 (es) * | 1994-05-24 | 2005-01-01 | Exxonmobil Chemical Patents Inc. | Peliculas preparadas a partir de copolimeros de propileno y alfa olefina superior. |
JP3580639B2 (ja) | 1996-06-04 | 2004-10-27 | 出光石油化学株式会社 | ポリプロピレン樹脂 |
JP3672395B2 (ja) * | 1996-11-06 | 2005-07-20 | 出光興産株式会社 | エチレン系共重合体及びそれからなるフィルム |
DE69909689T2 (de) * | 1998-08-25 | 2004-04-15 | Idemitsu Petrochemical Co., Ltd. | Propylenharzzusammensetzungen, Verfahren zur Herstellung und Verwendung |
JP2000230089A (ja) | 1998-10-16 | 2000-08-22 | Mitsubishi Chemicals Corp | オレフィン系熱可塑性エラストマー組成物及びその製造方法 |
-
2000
- 2000-03-29 US US09/536,980 patent/US6339128B1/en not_active Expired - Fee Related
- 2000-03-29 DE DE60029374T patent/DE60029374T2/de not_active Expired - Fee Related
- 2000-03-29 EP EP00302596A patent/EP1041114B1/en not_active Expired - Lifetime
- 2000-03-30 CN CNB001048376A patent/CN1176984C/zh not_active Expired - Fee Related
- 2000-03-30 CN CNB2005100999473A patent/CN100392010C/zh not_active Expired - Fee Related
- 2000-03-30 CN CNA031523315A patent/CN1536011A/zh active Pending
-
2001
- 2001-12-06 US US10/003,105 patent/US20020072569A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CN1269379A (zh) | 2000-10-11 |
EP1041114B1 (en) | 2006-07-19 |
CN1775840A (zh) | 2006-05-24 |
CN1536011A (zh) | 2004-10-13 |
CN100392010C (zh) | 2008-06-04 |
DE60029374D1 (de) | 2006-08-31 |
US6339128B1 (en) | 2002-01-15 |
US20020072569A1 (en) | 2002-06-13 |
EP1041114A1 (en) | 2000-10-04 |
DE60029374T2 (de) | 2007-07-12 |
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