CN116041044A - Manufacturing process of ink-jet brick - Google Patents
Manufacturing process of ink-jet brick Download PDFInfo
- Publication number
- CN116041044A CN116041044A CN202211469908.8A CN202211469908A CN116041044A CN 116041044 A CN116041044 A CN 116041044A CN 202211469908 A CN202211469908 A CN 202211469908A CN 116041044 A CN116041044 A CN 116041044A
- Authority
- CN
- China
- Prior art keywords
- parts
- overglaze
- ink
- inkjet
- jet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/24—Manufacture of porcelain or white ware
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention aims to provide a manufacturing process of an inkjet brick with no ripple on the glaze, complete pattern, good color development and high color saturation. The method comprises the steps of sequentially carrying out a raw material crushing process, a batching grinding process, a slurry homogenizing process, a spray drying process, a stock bin aging process, a compression molding process, a glazing process, an ink-jet process and a sintering process, wherein the glazing process comprises the following steps of: spraying overglaze on the surface of the green body prepared in the compression molding process, wherein the overglaze is uniformly sprayed in three intervals according to the total amount of overglaze; wherein the overglaze comprises the following components in parts by mass: 46-56 parts of Gao Wenjia feldspar, 19-24 parts of quartz, 15-20 parts of barium carbonate, 1.5-3 parts of calcined zinc oxide and 8-13 parts of black mud. The invention is applied to the technical field of building ceramic production.
Description
Technical Field
The invention is applied to the technical field of building ceramic production, and particularly relates to a method for manufacturing an inkjet brick.
Background
Along with the upsizing and rapiding of the ink-jet technology, the domestic cultural market is continuously developing, the demand for artistic ornaments is increasingly larger, so that the oil painting ink-jet brick is taken as a novel ink-jet brick to enter households, the oil painting ink-jet brick has higher requirements on the color development of glaze, and meanwhile, the smoothness of the glaze of the brick body can be ensured only by spraying the pattern on the glaze of the brick body through ink. The traditional ink-jet process has no specific pattern design, does not need fine spraying, has lower requirements on the precision of the glaze in the production process, and does not need to treat the glaze corrugation. In addition, since the ink jet of the oil painting needs to use more ink in order to improve the saturation, the pattern of the product can be blurred and distorted after the ink jet printing and firing are carried out on the surface glaze of the traditional formula. Therefore, the traditional manufacturing process is adopted to produce the oil painting ink-jet bricks, so that the patterns are corrugated on the glaze, the display of the patterns is affected, meanwhile, the patterns are incomplete to display, the stable and continuous production cannot be realized, and the resource is wasted.
Disclosure of Invention
The invention aims to solve the technical problem of overcoming the defects of the prior art and providing the manufacturing process of the inkjet brick with no ripple on the glaze, complete pattern, good color development and high color saturation.
The technical scheme adopted by the invention is as follows: the method comprises the steps of sequentially carrying out a raw material crushing process, a batching grinding process, a slurry homogenizing process, a spray drying process, a stock bin aging process, a compression molding process, a glazing process, an ink-jet process and a sintering process, wherein the glazing process comprises the following steps of: spraying overglaze on the surface of the green body prepared in the compression molding process, wherein the overglaze is uniformly sprayed in three intervals according to the total amount of overglaze; wherein the overglaze comprises the following components in parts by mass: 46-56 parts of Gao Wenjia feldspar, 19-24 parts of quartz, 15-20 parts of barium carbonate, 1.5-3 parts of calcined zinc oxide and 8-13 parts of black mud.
According to the scheme, the overglaze is sprayed for three or more times at intervals, so that the glaze is smoother and more textured. Wherein, 15-20 parts by weight of barium carbonate is added into the overglaze, so that the content of the whole barium element in the overglaze is about 0.3mol, barium feldspar crystals are separated out from the overglaze in the firing process, and the barium feldspar crystals are matt, so that the color development of the oil painting pattern on the overglaze is purer and more stable than the previous matt glaze mainly containing calcium and magnesium, and the ink is not dispersed and blurred in the subsequent firing process. By adjusting K2O, al2O3 and SiO2 in the glaze ingredients, the generation of glaze melt is facilitated to be further promoted, and the coloring agent in the glaze is not easy to agglomerate and settle. Meanwhile, the amounts of quartz and potassium feldspar are increased, so that the expansion coefficient of the base glaze is slightly smaller than that of a green brick, and the defects of air holes, glaze flowing and the like can be avoided. And further, the method effectively solves the problems of high saturation required glaze pattern integrity, smooth surface and no blurring of the pattern in the firing process.
In a preferred embodiment, the specific gravity of the overglaze slip is 1.50g/ml to 1.70g/ml, the overglaze flow rate is 17s to 19s, and the glazing amount is 9g/cm 2 To 10g/cm 2 。
The scheme shows that the concentration, the viscosity and the spraying amount ensure the fluidity and the coverage rate of the overglaze after being sprayed on the green body, and simultaneously avoid the aggregation of the glaze, so that the glaze surface is smooth and ripple-free.
Further preferable scheme is that the specific gravity of the overglaze slip is 1.60g/ml, the overglaze flow rate is 18s, and the glazing quantity is 9.57g/cm 2 。
In a preferred embodiment, the overglaze comprises the following components in parts by weight: gao Wenjia feldspar 48 parts, 20 parts of quartz, 20 parts of barium carbonate, 2 parts of calcined zinc oxide and 10 parts of black mud.
In a preferred embodiment, the inkjet process includes the steps of: the method comprises the steps of presetting an ink-jet pattern in a computer connected with an ink-jet machine, carrying out gridding treatment on the pattern, arranging a plurality of blocks of blanks after glazing procedures in a matrix mode, and printing ink on the arranged blanks in a flash-jet mode through a plurality of groups of spray heads.
In a preferred embodiment, a gap is left between two adjacent blanks.
Detailed Description
In this embodiment, the present invention includes the following steps performed in order:
1) A raw material crushing step of selecting a pug containing less iron and titanium as a raw material of a green body, mixing and crushing the whiter pug with medium-temperature pug, low-temperature pug, natural clay, water glass and the like, and carrying out fineness screening to obtain finer particles;
2) A batching grinding process, wherein a certain amount of zirconium silicate is added into the raw material powder obtained in the raw material grinding process, the prepared powder is conveyed into a ball mill through a batching machine, water is added until the water content of the mixture is about 18% by weight, and the ball mill is started to perform ball milling until the fineness is calibrated;
3) A slurry homogenization procedure, namely placing the slurry with qualified fineness ground by the ball mill into a slurry tank, and stirring raw materials to uniformly mix the crushed raw materials;
4) A spray drying procedure, namely, the slurry mixed uniformly in the slurry pool is conveyed into a drying tower under pressure through a slurry pump, atomized into fine drops by an atomizer, sprayed into a drying cavity in the drying tower, and dried and dehydrated through hot air (400-600 ℃) in the drying tower to form powder particles; after drying for a certain period of time, collecting the dried powder through a discharge hole of a drying tower, collecting the micropowder by a bag-type dust remover from the air with micropowder and water vapor in the drying tower, and then removing dust by a water bath and discharging the micropowder from an exhaust fan so as to prevent the dust from being discharged into the atmosphere to influence the environment;
5) A storage bin aging process, wherein the dried powder enters a storage bin through a conveying system, and the storage bin is placed to further homogenize the moisture of the powder;
6) A pressurizing and forming step, namely placing homogenized powder and conveying the powder to a press, wherein when pressure is applied to the powder in a mould, powder particles are extruded by the pressure and start to move towards each other, so that a blank in the mould is contracted, and air between the powder particles is discharged, and the maximum pressure of the press is 140 bar;
7) And glazing, namely spraying the pre-blended and melted glaze on the surface of the formed green body through a spray gun, wherein the surface glaze comprises the following components in parts by mass: gao Wenjia feldspar 46-56 parts, quartz 19-24 parts, barium carbonate 15-20 parts, calcined zinc oxide 1.5-3 parts and black mud 8-13 parts; the specific gravity of the surface glaze slurry is 1.50g/ml to 1.70g/ml, the surface glaze flow rate is 17s to 19s, and the glazing quantity is 9g/cm 2 To 10g/cm 2 ;
8) And an ink-jet procedure, namely selecting a western oil painting pattern to be printed, and then guiding the pattern into an ink-jet computer to trim the pattern by adjusting the texture, saturation, brightness and hue of the pattern. Finally, carrying out gridding treatment on the pattern, arranging a plurality of blocks of blanks after glazing procedures in a matrix manner, moving the blanks to a station of an ink jet machine, and carrying out flash spraying through a plurality of groups of spray heads so as to print ink on the glazed blanks to form the pattern;
9) And (3) sintering, namely conveying the carrier carrying the green body to a roller kiln under high-temperature oxidizing atmosphere through a roller way to perform sintering after finishing ink jet, wherein the sintering temperature is 1230 ℃, and the sintering period is 50min.
After firing, the inkjet bricks with smooth glaze, no ripple, complete inkjet patterns, good color development and high color saturation are obtained. The oil painting style ink-jet brick can be widely applied to house decoration, and the artistic sense of integral decoration can be improved. In addition, the oil painting patterns are printed on a plurality of mosaic bricks, and then a better visual effect can be presented through random and various combinations.
As shown in table 1, the existing inkjet tile overglaze composition:
table 1 overglaze formulation composition
Raw materials | Albite feldspar | Calcite | Calcined talc | Calcined kaolin | Black mud powder | Alumina oxide | Zinc oxide | Zirconium silicate |
Parts by mass | 51 | 16 | 10 | 4 | 8 | 4 | 2 | 10 |
In the test process, the final product after the overglaze is used can show smooth texture, and the problem of ripple on the glaze can be effectively overcome. In addition, the patterns are bright in color, the used ink quantity is large, the wettability of ink drops on the green body is poor, the ink drops after firing can be excessively spread on the green body, the patterns of the product are fuzzy and distorted, and the yield is low.
As shown in table 2, in this example, the overglaze composition in this application:
surface 2 overglaze formulation (parts)
Raw materials | Gao Wenjia feldspar | Quartz | Barium carbonate | Calcined zinc oxide | Black mud |
Proportioning of | 48 | 20 | 20 | 2 | 10 |
The glaze material of the embodiment has more flux content, and the overglaze is applied to the green body, so that the glaze surface is smooth and flat, and is more stable in the high-temperature sintering process. The surface glaze can be fused with a large amount of ink, and can be compatible with the application of the ink-jet tile for the western oil painting with high saturation. Meanwhile, the fired oil painting ink-jet brick has the characteristics of attractive and elegant appearance, simplicity, softness, good thermal stability and the like. BaO is introduced by adding a certain amount of barium carbonate, and barium microcrystals can be generated by introducing BaO, so that the glaze can have a matt effect. Meanwhile, baO is used as a fluxing agent of the glaze, and the high-temperature viscosity of the glaze melt can be adjusted, so that the defects of glaze flowing, dry glaze, unsmooth glaze and the like are overcome.
In this example, the specific gravity of the glaze slip was 1.60g/ml, the overglaze flow rate was 18s, and the glazing amount was 9.57g/cm 2 。
In this embodiment, 0.35-0.4% of electrolyte, such as sodium tripolyphosphate, is added to the glaze.
In the embodiment, the water content of the blank is 5-5.5% when the ink-jet procedure is carried out, and the water content in the glaze is 10-15%; adding 0.004-0.006ml of dispersing agent, such as ink discharging agent (a water-soluble high polymer organic matter), into each kilogram of glaze; so that the non-polar substances in the ceramic ink can form wetting with the polar ceramic body.
In the embodiment, the ceramic pigment used in the ink can maintain good chemical and physical stability in the solvent, and can not generate chemical reaction change and particle agglomeration and precipitation after long-time storage. The intermediate colorant of the ink has stable and good color development performance and matching performance with the blank glaze after being sintered at the high temperature of 1150-1300 ℃.
The invention is suitable for the research and development production field of the ink-jet bricks with the style of western oil painting.
The above embodiments are only specific embodiments of the present invention, and are not intended to limit the present invention, and any modifications, improvements, etc. within the spirit and principles of the present invention should be within the scope of the present invention.
Claims (7)
1. The manufacturing process of the inkjet brick comprises the steps of raw material crushing, batching and grinding, slurry homogenization, spray drying, bin aging, compression molding, glazing, inkjet and firing, and is characterized in that the glazing comprises the following steps: spraying overglaze on the surface of the green body prepared in the compression molding process, wherein the overglaze is uniformly sprayed in three intervals according to the total amount of overglaze; wherein the overglaze comprises the following components in parts by mass: 46-56 parts of Gao Wenjia feldspar, 19-24 parts of quartz, 15-20 parts of barium carbonate, 1.5-3 parts of calcined zinc oxide and 8-13 parts of black mud.
2. The process for producing an inkjet brick according to claim 1, wherein the specific gravity of the overglaze slip is 1.50g/ml to 1.70g/ml, the overglaze flow rate is 17s to 19s, and the glazing amount is 9g/cm 2 To 10g/cm 2 。
3. The process for producing an inkjet brick according to claim 2, wherein the specific gravity of the overglaze slip is 1.60g/ml, the overglaze flow rate is 18s, and the glazing amount is 9.57g/cm 2 。
4. The process for manufacturing the inkjet brick according to claim 1, wherein the overglaze comprises the following components in parts by mass: gao Wenjia feldspar 48 parts, 20 parts of quartz, 20 parts of barium carbonate, 2 parts of calcined zinc oxide and 10 parts of black mud.
5. The process for manufacturing an inkjet brick according to claim 1, wherein the inkjet process comprises the steps of: the method comprises the steps of presetting an ink-jet pattern in a computer connected with an ink-jet machine, carrying out gridding treatment on the pattern, arranging a plurality of blocks of blanks after glazing procedures in a matrix mode, and printing ink on the arranged blanks in a flash-jet mode through a plurality of groups of spray heads.
6. The process according to claim 5, wherein a gap is left between two adjacent green bodies when the inkjet process is performed.
7. The process for manufacturing the ink-jet brick according to claim 1, wherein the water content of the blank is 5-5.5% in the ink-jet procedure, the water content in the glaze is 10-15%, and 0.004-0.006ml of dispersing agent is added into each kilogram of glaze.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202211469908.8A CN116041044A (en) | 2022-11-23 | 2022-11-23 | Manufacturing process of ink-jet brick |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202211469908.8A CN116041044A (en) | 2022-11-23 | 2022-11-23 | Manufacturing process of ink-jet brick |
Publications (1)
Publication Number | Publication Date |
---|---|
CN116041044A true CN116041044A (en) | 2023-05-02 |
Family
ID=86124461
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202211469908.8A Pending CN116041044A (en) | 2022-11-23 | 2022-11-23 | Manufacturing process of ink-jet brick |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN116041044A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108911701A (en) * | 2018-08-27 | 2018-11-30 | 佛山石湾鹰牌陶瓷有限公司 | Dumb light dry granular glazed tile and preparation method thereof |
CN112340991A (en) * | 2020-11-25 | 2021-02-09 | 珠海市白兔陶瓷有限公司 | Ink-jet brick and production process thereof |
-
2022
- 2022-11-23 CN CN202211469908.8A patent/CN116041044A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108911701A (en) * | 2018-08-27 | 2018-11-30 | 佛山石湾鹰牌陶瓷有限公司 | Dumb light dry granular glazed tile and preparation method thereof |
CN112340991A (en) * | 2020-11-25 | 2021-02-09 | 珠海市白兔陶瓷有限公司 | Ink-jet brick and production process thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107963814B (en) | Composite glaze, composite glaze slip and 4-8 degree soft surface wear-resistant porcelain archaized brick | |
EP3604258B1 (en) | Method for manufacturing a decorated semi-transparent ceramic sheet | |
CN103113135B (en) | A kind of microballon shape dry granular and its preparation method and application | |
CN113461443B (en) | Ceramic plate with matte dry particle texture and preparation method thereof | |
CN111943729B (en) | Manufacturing method of matte marble tile | |
CN105272160B (en) | It is primary to burn microcrystallite glass-ceramic composite brick and its production method | |
CN106986540A (en) | One kind, which is sunk, peels off marble galze making formula | |
CN106431204A (en) | Waste residue ceramic tile, used powder, brick green body, and preparation methods for waste residue ceramic tile, used powder and brick green body | |
CN110790507B (en) | Ground glaze and preparation method thereof, black ink-jet ceramic tile and manufacturing method thereof | |
CN108821588A (en) | High alumina titanate ceramics glaze, ink-jet Ceramic Tiles of the glaze of titanate ceramics containing high alumina and preparation method thereof | |
CN110978221B (en) | Preparation process for solving polishing yellow edge problem of gray glazed brick | |
CN107417303A (en) | The manufacture method of ink-jet pattern permeating tile under a kind of glaze | |
CN105753511A (en) | Longquan celadon celadon-glaze jet ink and preparation method thereof | |
CN107673616B (en) | Ceramic tile containing isolation glaze, manufacturing process and product gray level configuration method | |
CN110683867A (en) | Black ink-jet ceramic tile and manufacturing method thereof | |
CN110304827A (en) | The technique that hydrophilic material water-proof material and application material realization green compact enter the reduction of kiln moisture | |
CN117623808A (en) | Lead-free silver metal glaze and preparation method of product thereof | |
CN116041044A (en) | Manufacturing process of ink-jet brick | |
CN111453994B (en) | White glaze, ceramic tile and preparation method of ceramic tile | |
CN103787693A (en) | Ceramic glazed tile and preparation method thereof | |
CN111039699B (en) | Ultra-large-specification thin porcelain plate with negative ion function and production method thereof | |
CN112429967A (en) | Super-flat glaze for ceramic tiles, ceramic tiles and manufacturing method of ceramic tiles | |
CN115466056B (en) | Color frit dry particles and ceramic tile decorated by same | |
CN1158192C (en) | Making method of stone texture imitating surface of ceramic tile | |
CN106116467A (en) | A kind of method utilizing black earth to prepare low grade fever's glazed tiles |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |