CN108911701A - Dumb light dry granular glazed tile and preparation method thereof - Google Patents
Dumb light dry granular glazed tile and preparation method thereof Download PDFInfo
- Publication number
- CN108911701A CN108911701A CN201810979553.4A CN201810979553A CN108911701A CN 108911701 A CN108911701 A CN 108911701A CN 201810979553 A CN201810979553 A CN 201810979553A CN 108911701 A CN108911701 A CN 108911701A
- Authority
- CN
- China
- Prior art keywords
- dry
- adobe
- dry granular
- glaze
- time
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
- C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6562—Heating rate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Finishing Walls (AREA)
- Glass Compositions (AREA)
Abstract
The application provides a kind of dumb light dry granular glazed tile and preparation method thereof.A kind of dumb light dry granular glazed tile including adobe and is successively set on the ground coat enamel and dry granular glaze on adobe surface.It the described method comprises the following steps：By the Free water inside drying and removing for the first time, the moisture content controlled in adobe is less than the 0.5% of adobe gross mass for the adobe that press is accomplished fluently；Adobe goes out after dry kiln in its surface atomized water spray；Then ground coat enamel is drenched to billet surface, then uses ink jet printer printing pattern, it is dry through second of dry kiln；Then spray drying grain glaze enters burning kiln after dry kiln third time is dry, fires 60-70min by 1170-1185 DEG C of high temperature and obtain semi-finished product；Semi-finished product carry out soft throwing by edging and with fiber polishing block combiner, are packaged after examining matter as finished product.Dumb light dry granular glazed tile provided by the present application and preparation method thereof, dumb light dry granular glazed tile obtained has stone texture true to nature, while sense of touch is gentle as beautiful, and structural strength is high.
Description
Technical field
The present invention relates to ceramic fields, in particular to a kind of dumb light dry granular glazed tile and preparation method thereof.
Background technique
Modern imitations brick occupation rate of market was higher and higher in recent years, betray come sense of history, sense of nostalgia, natural sense,
Return sense, the Cultural Elements such as personalization and both with fashion landscape gradually obtain more and more concerns and approval.
The soft and moist dry granular glazed tile of dumb light belongs to a kind of upgrading products of modern imitations brick, it not only inherits the unique text of Antique Imitation Tiles itself
Change the superpower hardness of element and polished bricks, and impart the texture of its more lifelike stone, while sense of touch is gentle as beautiful, without
The ice-cold feeling of stone material.The soft and moist dry granular glazed tile of dumb light is that a kind of texture is stronger, sense of touch is more soft and moist, hardness is stronger and antifouling anti-
The sliding better floor tile of effect.Such floor tile is different from the feeling that other floor tiles step on ice-cold to people, stiff, glutinous foot, and dumb light is soft
Profit dry granular glazed tile can allow people feel as snug as a bug in a rug, step on feeling that is steady and sure, warm, loosening, be well suited for advocating recurrence
Natural crowd.
The prior art has the following disadvantages:There is card dirt and soil pick-up in product surface.There are many such currently on the market
Product after being only simply mixed in a certain ratio with dry granular and suspending agent, is uniformly sprayed on product surface with glaze spraying cabinet.It should
Technique is mostly used on brick product modelled after an antique, plays the role of decorative product surface tactile sensation, but since product surface is uneven, dry granular it
Between gap it is either large or small, in product after paving, surface is easy that card is dirty and soil pick-up.
In view of this, the present invention is specifically proposed.
Summary of the invention
The first object of the present invention is a kind of dumb light dry granular glazed tile provided, and product surface anti-pollution is good, modelled after an antique
Ornamental performance is good.
The second object of the present invention is to provide the preparation method of above-mentioned dumb light dry granular glazed tile.
In order to realize above-mentioned purpose of the invention, spy uses following technical scheme：
A kind of dumb light dry granular glazed tile including adobe and is successively set on the ground coat enamel and dry granular glaze on the adobe surface；
The adobe by percentage to the quality, including：Feldspar 25-30%, pyrophillite 18-20%, kaolin 20-25%,
Quartz sand 20-25% and marble 5-10%；
The ground coat enamel by percentage to the quality, including：SiO240-55%, Al2O310-15%, CaO8-10%, MgO5-
8%, ZnO10-15%, K2O4-6%, Na2O1-3%, BaO1-3%；
The dry granular glaze includes 40-50 parts of dry granular, glaze 10-20 parts of protection, 1-3 parts of kaolinite soil paste, burns based on parts by weight
0.5-1.5 parts of talcum slurry, 1-3 parts of additive, 90-110 parts of suspending agent and 0.05-0.1 parts of venting agent；
The dry granular by percentage to the quality, including：Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-
10%, MgO5-12%, BaO4-10%, ZnO2-5%, RuO20.1-0.5%, V2O50.1-0.5%, Bi2O30.1-0.5% and
TiO20.1-0.5%；
The protection glaze include by mass percentage transparent powdered frit 59-65%, sodium carboxymethylcellulose 0.2-0.5%,
Sodium tripolyphosphate 0.2-0.4%, aluminium chloride 1-2%, aluminum sulfate 1-2%, 12 hydrazine aluminum sulfate potassium 1-2%, water 30-36%；
The transparent powdered frit includes Al by percentage to the quality2O310%, SiO252%, CaO15%, K2O8%, MgO5%,
BaO4.5%, ZnO5%, Lu2O30.5%；
The additive is the solution that mass concentration is 3-5%, solute is phenolic resin, solvent is acetone.
The selection of adobe and ground coat enamel ingredient lays the foundation for the integral product effect of dumb light dry granular glazed tile, guarantees simultaneously
The underlying strength of product；The ingredient of dry granular glaze and the selection of dosage, can obtain that performance is more preferable, antique effect more preferably product,
Specifically：The effect for protecting glaze is that effective filing effect is formed between dry granular, so that glaze paint obtains the semicircle of appropriate size
Shape protrusion, improves surface texture, improves anti-fouling effect；Kaolinite soil paste is kaolin and water, can be with while playing peptizaiton
Improve the firing temperature of dry granular glaze；Talcum slurry is burnt to burn talcum and water, primarily serves the effect for reducing the firing temperature of dry granular glaze,
It cooperates with kaolinite soil paste, obtains suitable firing temperature, is conducive to control dry granular and protects shape of the ingredient of glaze when firing
State obtains preferably melting or semi-molten form, so that it is guaranteed that glaze paint microstructure, guarantees anti-pollution.The use of suspending agent
It is in order to guarantee that each component can be preferably dispersed in system to prevent from that part unevenly bring matter occurs in sintering procedure
Measure flaw；The use of venting agent is in order to avoid following situations：Due to grease cannot and it is molten and cause ink-jet printed position and water
Property glaze junction generate water-oil separating, in turn result in ceramic tile firing rear surface and generate contracting glaze, pit and the defects of bubble, seriously
Influence product quality.Venting agent can also greatly improve glaze slip levelling and caking property in addition to it can overcome disadvantages described above, and then improve glaze
Face is smooth and caking ability.The use of additive is the uniformity in order to optimize each component in dry granular glaze system, with dispersing agent one
It rises and reduces quality flaw；Meanwhile the use of additive can also improve the integral strength of product, especially between dry granular glaze and ground coat enamel
Bond strength, and the mobility of dry granular glaze can be improved, promote surface depolluting properties.
Preferably, the granularity of the dry granular is 120-200 mesh.
The control of granularity can make configuration of surface more optimize, and anti-pollution is more preferable.
It is further preferred that the dry granular glaze specific gravity is 1.23-1.27g/ml, fineness is the siccative weight hundred after 200 meshes
Divide than being 0.4%-0.6%.
Controlling specific gravity and tailing over is to obtain better properties of product, and intensity is higher, anti-pollution is more preferable.
Preferably, the suspending agent is sodium carboxymethylcellulose, and the venting agent is polyacrylamide.
Suspending agent and the preferred result of venting agent can make overall performance reach best.
The application also provides a kind of preparation method of dumb light dry granular glazed tile, includes the following steps：
A. by the Free water inside drying and removing for the first time, the moisture controlled in the adobe contains for the adobe that press is accomplished fluently
Amount is less than the 0.5% of the adobe gross mass；Adobe goes out after dry kiln in its surface atomized water spray；
B. ground coat enamel then is drenched to billet surface, then uses ink jet printer printing pattern, it is dry through second of dry kiln；
C. then spray drying grain glaze enters burning kiln after dry kiln third time is dry, fires by 1170-1185 DEG C of high temperature
60-70min obtains semi-finished product；
D. semi-finished product carry out soft throwing by edging and with fiber polishing block combiner, are packaged after examining matter as finished product.
By the content of moisture in control adobe, mainly control adobe interior moisture content, avoid in subsequent sintering procedure
Middle bubbling, leads to product defect；Atomized water spray is to promote intensity in order to which ground coat enamel and adobe can be preferably bonded after brick bat drying；
The control of firing temperature is to reach best to control each ingredient in dry granular glaze when firing and obtain optimal micromorphology
Work in coordination and coat form, to obtain optimal anti-pollution.It is to reduce surface hair using fiber polishing module
Thorn reduces the strong luminous effect in surface, avoids light pollution, while antique effect is more preferable.
Preferably, in step A, the amount of the atomized water spray is 120-140g/m2。
The control of the amount of atomized water spray is but also water spray to be avoided excessively to cause surface moisture to reach and not only meet leaching ground coat enamel demand
The problems such as penetrating into inside, reducing effect dry for the first time, bring blistering.
Preferably, the temperature of the first time drying is 90-110 DEG C, time 60-120min；Described second dry
Temperature be 200-300 DEG C, time 10-20min；The dry temperature of the third time is 150-200 DEG C, time 60-
80min。
The control of first time drying temperature and time but also is avoided caused by too fast drying to not only reach drying purpose
Adobe instability problem；The control of second of drying temperature and time is but also to avoid too fast drying to not only reach drying purpose
Cause pattern unstable, the problem obscured in later period sintering procedure；The control of third time drying temperature and time is in order to both
Reach drying purpose, and avoids drying fastly that dry granular glaze layer internal stress unevenness is caused to cause occur flaw in sintering procedure.Three times
It dries while considering the problem of improving production efficiency under the premise of guaranteeing product quality.
It is further preferred that in step C, the sintering procedure for entering the calcining kiln is：It is dry vertical later through the third time
It is first to be warming up to 1100 DEG C with 10-20min into the calcining kiln, then controlling heating rate is 2 DEG C/min, reaches 1170-
Constant temperature is fired after 1185 DEG C.
When near the fusing point that firing temperature reaches each principle active component, control heating rate can make each at separately winning
Preferably melting or semi-molten state are obtained, be formed with the Inner Constitution for being conducive to improve structural strength after the cooling period and is conducive to improve
The surface texture of antifouling capacity.Too fast heating will lead to inside and be unevenly distributed, and structural strength reduces, while surface microscopic knot
Structure forms local high brightness point and brightness point, so that the whole light effect of product is deteriorated in too fast temperature-rise period.
Preferably, the fiber polishing block combiner is arranged successively：600 mesh nylon fibers polish 1 group of module, 700
Mesh flaxen fiber polishes 2 groups of module and 800 mesh wool fibers polish 3 groups of module.
Using different fiber polishing modules, the burr on brick body surface can be removed；Meanwhile the side for passing through flexible polishing
Formula can control influence of the polishing to the micro-structure on brick body surface, prevent hard breakdown.
It is further preferred that the time of the soft throwing is 10-15min.
The soft throwing time is controlled, is to preferably obtain the optimal product of surface light effect.
Compared with prior art, beneficial effects of the present invention are：
1. by the ingredient of selection dry granular, especially addition RuO2、V2O5、Bi2O3And TiO2, make it after high temperature firing,
It forms the relatively uniform hemi-spherical granule of size and is covered on product surface, it is gentle comfortable to make glaze paint sense of touch, while promoting soil resistance
Energy；
2. protection glaze is added in dry granular glaze, plays and can solve the work that the gap between particle and particle does not block dirt and soil pick-up
With；
3. the integral strength of product can be improved in the use of additive, the especially combination between dry granular glaze and ground coat enamel is strong
Degree, and the mobility of dry granular glaze can be improved, promote surface depolluting properties；
4. preferred firing temperature and sintering procedure form appropriate molten condition in sintering process, obtain after cooling
Optimal surface microstructure improves anti-pollution.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
Embodiment 1
Dumb light dry granular glazed tile is prepared as steps described below：
1, the adobe that press is accomplished fluently is by the Free water inside drying and removing for the first time, and dry temperature is 110 for the first time
DEG C, time 60min makes the moisture of adobe less than 0.5%；Adobe goes out after dry kiln in its surface atomized water spray, the amount of atomized water spray
For 140g/m2, it is formed on its surface water membrane；
Adobe by percentage to the quality, including：Feldspar 25%, pyrophillite 20%, kaolin 25%, quartz sand 25% and big
Fibrous gypsum 5%；
2, ground coat enamel then is drenched to billet surface, glaze amount is 89g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO240%, Al2O315%, CaO10%, MgO8%, ZnO15%, K2O6%, Na2O3%, BaO3%；Then ink jet printer is used
Printing pattern, dry through second of dry kiln, second of dry temperature is 300 DEG C, time 10min；
3, spray drying grain glaze；Dry granular glaze specific gravity is 1.27g/ml, and glaze amount is 65g (pallet of 340*670), and fineness is through 200
Siccative weight percent is 0.4% after mesh；Dry granular glaze includes 40 parts of dry granular, 20 parts of glaze of protection, 1 part of kaolinite soil paste, burns talcum
1.5 parts of slurry, 90 parts of suspending agent, 0.1 part of venting agent and 1 part of additive；
Dry granular includes Al by mass percentage2O315%, SiO240%, CaO18%, K2O5.2%, MgO12%,
BaO4%, ZnO5%, RuO20.1%, V2O50.5% and Bi2O30.1%, TiO20.1%；The granularity of dry granular is 200 mesh；
Protect glaze includes transparent powdered frit 64.8%, sodium carboxymethylcellulose 0.4%, sodium tripolyphosphate by mass percentage
0.2%, aluminium chloride 1%, aluminum sulfate 1.6%, 12 hydrazine aluminum sulfate potassium 2%, water 30%；Transparent powdered frit is by percentage to the quality
Including Al2O315%, SiO255%, CaO10%, K2O5%, MgO5%, BaO4.5%, ZnO5%, Lu2O30.5%；
Additive is the solution that mass concentration is 3%, solute is phenolic resin, solvent is acetone；
Suspending agent is sodium carboxymethylcellulose, and the venting agent is polyacrylamide；
It is jetted through the adobe of dry granular glaze and enters burning kiln after dry kiln third time is dry, drying temperature is 200 DEG C, and the time is
60min；When burning kiln is fired, 1100 DEG C first are warming up to 10min, then controlling heating rate is 2 DEG C/min, reaches 1185
Constant temperature is fired after DEG C, and sintering procedure continues altogether 65min；Then it is cooled to room temperature；
4, semi-finished product polish 2 groups of module with 600 mesh nylon fibers polishing, 1 group of module, 700 mesh flaxen fibers after edging
3 groups of carry out flexible polishings of module are polished with 800 mesh wool fibers, the soft throwing time is 10min；After examining matter, it is packaged and is used as finished product.
Embodiment 2
Dumb light dry granular glazed tile is prepared as steps described below：
1, the adobe that press is accomplished fluently is by the Free water inside drying and removing for the first time, and dry temperature is 90 for the first time
DEG C, time 120min makes the moisture of adobe less than 0.5%；Adobe goes out after dry kiln in its surface atomized water spray, the amount of atomized water spray
For 130g/m2, it is formed on its surface water membrane；
Adobe by percentage to the quality, including：Feldspar 30%, pyrophillite 18%, kaolin 22%, quartz sand 20% and big
Fibrous gypsum 10%；
2, ground coat enamel then is drenched to billet surface, glaze amount is 92g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO255%, Al2O313%, CaO8%, MgO5%, ZnO10%, K2O5%, Na2O2%, BaO2%；Then it is sprayed with ink jet printer
Drawing case, dry through second of dry kiln, second of dry temperature is 200 DEG C, time 20min；
3, spray drying grain glaze；Dry granular glaze specific gravity is 1.23g/ml, and glaze amount is 72g (pallet of 340*670), and fineness is through 200
Siccative weight percent is 0.6% after mesh；Dry granular glaze includes 50 parts of dry granular, 10 parts of glaze of protection, 3 parts of kaolinite soil paste, burns talcum
0.5 part of slurry, 3 parts of additive, 110 parts of suspending agent and 0.05 part of venting agent；
Dry granular includes Al by mass percentage2O35%, SiO249%, CaO17%, K2O5%, MgO11%, BaO8%,
ZnO4%, RuO20.2%, V2O50.15%, Bi2O30.15% and TiO20.5%；The granularity of dry granular is 120 mesh；
Protect glaze includes transparent powdered frit 65%, sodium carboxymethylcellulose 0.2%, sodium tripolyphosphate by mass percentage
0.3%, aluminium chloride 2%, aluminum sulfate 1%, 12 hydrazine aluminum sulfate potassium 1%, water 30.5%；Transparent powdered frit is by percentage to the quality
Including Al2O315%, SiO255%, CaO10%, K2O5%, MgO5%, BaO4.5%, ZnO5%, Lu2O30.5%；
Additive is the solution that mass concentration is 5%, solute is phenolic resin, solvent is acetone；
Suspending agent is sodium carboxymethylcellulose, and venting agent is polyacrylamide；
It is jetted through the adobe of dry granular glaze and enters burning kiln after dry kiln third time is dry, drying temperature is 150 DEG C, and the time is
80min；When burning kiln is fired, 1100 DEG C first are warming up to 20min, then controlling heating rate is 2 DEG C/min, reaches 1170
Constant temperature is fired after DEG C, and sintering procedure continues altogether 70min；Then it is cooled to room temperature；
4, semi-finished product polish 2 groups of module with 600 mesh nylon fibers polishing, 1 group of module, 700 mesh flaxen fibers after edging
3 groups of carry out flexible polishings of module are polished with 800 mesh wool fibers, the soft throwing time is 15min；After examining matter, it is packaged and is used as finished product.
Embodiment 3
Dry granular glazed tile is prepared as steps described below：
1, the adobe that press is accomplished fluently is by the Free water inside drying and removing for the first time, and dry temperature is 100 for the first time
DEG C, time 90min makes the moisture of adobe less than 0.5%；Adobe goes out after dry kiln in its surface atomized water spray, the amount of atomized water spray
For 120g/m2, it is formed on its surface water membrane；
Adobe by percentage to the quality, including：Feldspar 28%, pyrophillite 19%, kaolin 20%, quartz sand 24% and big
Fibrous gypsum 9%；
2, ground coat enamel then is drenched to billet surface, glaze amount is 90g (pallet of 340*670)；Ground coat enamel wraps by mass percentage
Include SiO254%, Al2O310%, CaO9%, MgO7%, ZnO14%, K2O4%, Na2O1%, BaO1%；Then it is sprayed with ink jet printer
Drawing case, dry through second of dry kiln, second of dry temperature is 260 DEG C, time 15min；
3, spray drying grain glaze；Dry granular glaze stream specific gravity is 1.265g/ml, and glaze amount is 70g (pallet of 340*670), and fineness is warp
Siccative weight percent is 0.5% after 200 meshes；Dry granular glaze includes 48 parts of dry granular, 15 parts of glaze of protection, 2 parts of kaolinite soil paste, burns and slide
1 part of stone slurry, 2 parts of additive, 100 parts of suspending agent and 0.08 part of venting agent；
Dry granular includes Al by mass percentage2O36.5%, SiO255%, CaO10%, K2O10%, MgO5%,
BaO10%, ZnO2%, RuO20.5%, V2O50.1%, Bi2O30.5% and TiO20.4%；The granularity of dry granular is 150 mesh；
Protect glaze includes transparent powdered frit 59%, sodium carboxymethylcellulose 0.5%, sodium tripolyphosphate by mass percentage
0.4%, aluminium chloride 1.05%, aluminum sulfate 2%, 12 hydrazine aluminum sulfate potassium 1.05%, water 36%；Transparent powdered frit is with quality percentage
It include Al than meter2O315%, SiO255%, CaO10%, K2O5%, MgO5%, BaO4.5%, ZnO5%, Lu2O30.5%；
Additive is the solution that mass concentration is 4%, solute is phenolic resin, solvent is acetone；
Suspending agent is sodium carboxymethylcellulose, and venting agent is polyacrylamide；
It is jetted through the adobe of dry granular glaze and enters burning kiln after dry kiln third time is dry, drying temperature is 180 DEG C, and the time is
70min；When burning kiln is fired, 1100 DEG C first are warming up to 15min, then controlling heating rate is 2 DEG C/min, reaches 1180
Constant temperature is fired after DEG C, and sintering procedure continues altogether 65min；Then it is cooled to room temperature；
4, semi-finished product polish 2 groups of module with 600 mesh nylon fibers polishing, 1 group of module, 700 mesh flaxen fibers after edging
3 groups of carry out flexible polishings of module are polished with 800 mesh wool fibers, the soft throwing time is 12min；After examining matter, it is packaged and is used as finished product.
Comparative example 1
Compared with Example 1, the difference is that, RuO is not contained in dry granular2、V2O5、Bi2O3And TiO2；
Comparative example 2
Compared with Example 2, the difference is that, protection glaze is not contained in dry granular glaze；
Comparative example 3
Compared with Example 3, the difference is that, suspending agent and venting agent are not contained；
Comparative example 4
Compared with Example 1, the difference is that, additive is not contained；
Comparative example 5
Compared with Example 2, the difference is that, 1200 DEG C of firing temperature；
Comparative example 6
Compared with Example 3, the difference is that, dry 50min, second dry 5min, third time are dry for the first time
30min；
Comparative example 7
Compared with Example 1, the difference is that, not atomized water spray is dried later for the first time；
Comparative example 8
Compared with Example 2, the difference is that, at the uniform velocity heating is fired in burning kiln after third time is dry.
The parameter of testing example 1-3 and comparative example 1-8 resulting product, as a result as shown in table 1 below：
1 test result of table
By upper table 1 it is found that RuO2、V2O5、Bi2O3And TiO2Addition, can effectively improve the glossiness of finished product, change
The strong light that directly reflection generates gives user's bring sense of discomfort, meanwhile, it is capable to effectively improve anti-pollution；It protects glaze, suspend
The use of agent and venting agent is conducive to improve incrustation performance, improves the intensity of product；The use of additive, in certain journey
Decorative effect and structural strength are promoted on degree；The control of firing temperature is conducive to optimizing surface structure, improves anti-pollution and imitates
Ancient effect；The control of drying time, advantageous lift structure intensity；Atomized water spray also contributes to improving the intensity of product；Control heating
Speed, temperature changing speed especially at high operating temperatures are conducive to the surface microstructure for changing product dry granular glaze paint, drop
Low-luster reduces emergency light reflex bring light pollution.
The dumb light dry granular glazed tile being prepared using method provided by the present application, in addition to anti-pollution is good, decorative effect
Except good, resultant effect can also to people's one kind as snug as a bug in a rug, steady and sure, the warm, antique effect that loosens, while structural strength is very
It is high.
For those skilled in the art, various changes and changes are possible in this application.It is all in spirit herein
Within principle, any modification, equivalent replacement, improvement and so on be should be included within the scope of protection of this application.Although
The present invention is illustrate and described with specific embodiment, however will be appreciated that without departing substantially from the spirit and scope of the present invention
In the case of can make many other change and modification.It is, therefore, intended that in the following claims including belonging to this hair
All such changes and modifications in bright range.
Claims (10)
1. a kind of dumb light dry granular glazed tile, which is characterized in that including adobe and be successively set on the ground coat enamel on the adobe surface
With dry granular glaze；
The adobe by percentage to the quality, including：Feldspar 25-30%, pyrophillite 18-20%, kaolin 20-25%, quartz
Sand 20-25% and marble 5-10%；
The ground coat enamel by percentage to the quality, including：SiO240-55%, Al2O310-15%, CaO8-10%, MgO5-8%,
ZnO10-15%, K2O4-6%, Na2O1-3%, BaO1-3%；
The dry granular glaze includes 40-50 parts of dry granular, glaze 10-20 parts of protection, 1-3 parts of kaolinite soil paste, burns talcum based on parts by weight
0.5-1.5 parts of slurry, 1-3 parts of additive, 90-110 parts of suspending agent and 0.05-0.1 parts of venting agent；
The dry granular by percentage to the quality, including：Al2O35-15%, SiO240-55%, CaO10-18%, K2O5-10%,
MgO5-12%, BaO4-10%, ZnO2-5%, RuO20.1-0.5%, V2O50.1-0.5%, Bi2O30.1-0.5% and
TiO20.1-0.5%；
The protection glaze includes transparent powdered frit 59-65%, sodium carboxymethylcellulose 0.2-0.5%, trimerization by mass percentage
Sodium phosphate 0.2-0.4%, aluminium chloride 1-2%, aluminum sulfate 1-2%, 12 hydrazine aluminum sulfate potassium 1-2%, water 30-36%；It is described
Transparent powdered frit includes Al by percentage to the quality2O310%, SiO252%, CaO15%, K2O8%, MgO5%, BaO4.5%,
ZnO5%, Lu2O30.5%；
The additive is the solution that mass concentration is 3-5%, solute is phenolic resin, solvent is acetone.
2. dumb light dry granular glazed tile according to claim 1, which is characterized in that the granularity of the dry granular is 120-200 mesh.
3. dumb light dry granular glazed tile according to claim 1, which is characterized in that the dry granular glaze specific gravity is 1.23-
1.27g/ml, fineness are that siccative weight percent is 0.4%-0.6% after 200 meshes.
4. dumb light dry granular glazed tile according to claim 1, which is characterized in that the suspending agent is carboxymethyl cellulose
Sodium, the venting agent are polyacrylamide.
5. a kind of preparation method of any one of claim 1-4 dumb light dry granular glazed tile, which is characterized in that including following step
Suddenly：
A. by the Free water inside drying and removing for the first time, the moisture content controlled in the adobe is small for the adobe that press is accomplished fluently
In the 0.5% of the adobe gross mass；Adobe goes out after dry kiln in its surface atomized water spray；
B. ground coat enamel then is drenched to billet surface, then uses ink jet printer printing pattern, it is dry through second of dry kiln；
C. then spray drying grain glaze enters burning kiln after dry kiln third time is dry, fires 60- by 1170-1185 DEG C of high temperature
70min obtains semi-finished product；
D. semi-finished product carry out soft throwing by edging and with fiber polishing block combiner, are packaged after examining matter as finished product.
6. preparation method according to claim 5, which is characterized in that in step A, the amount of the atomized water spray is 120-
140g/m2。
7. preparation method according to claim 5, which is characterized in that the temperature of the first time drying is 90-110 DEG C,
Time is 60-120min；Second of dry temperature is 200-300 DEG C, time 10-20min；The third time is dry
Temperature be 150-200 DEG C, time 60-80min.
8. preparation method according to claim 5, which is characterized in that in step C, enter the sintering procedure of the calcining kiln
For：Enter the calcining kiln immediately later through the third time is dry, is first warming up to 1100 DEG C with 10-20min, then control heating
Speed is 2 DEG C/min, and constant temperature is fired after reaching 1170-1185 DEG C.
9. preparation method according to claim 5, which is characterized in that the fiber polishing block combiner is to be arranged successively
's：600 mesh nylon fibers polish 1 group of module, 700 mesh flaxen fibers, 2 groups of module of polishing and 800 mesh wool fibers and polish 3 groups of module.
10. preparation method according to claim 5, which is characterized in that the time of the soft throwing is 10-15min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810979553.4A CN108911701B (en) | 2018-08-27 | 2018-08-27 | Matte dry particle glazed tile and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810979553.4A CN108911701B (en) | 2018-08-27 | 2018-08-27 | Matte dry particle glazed tile and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108911701A true CN108911701A (en) | 2018-11-30 |
| CN108911701B CN108911701B (en) | 2021-04-27 |
Family
ID=64405971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810979553.4A Active CN108911701B (en) | 2018-08-27 | 2018-08-27 | Matte dry particle glazed tile and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108911701B (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110482859A (en) * | 2019-09-17 | 2019-11-22 | 广东新润成陶瓷有限公司 | A kind of starlight glaze Ceramic Tiles and preparation method thereof |
| CN110668792A (en) * | 2019-10-31 | 2020-01-10 | 佛山市东鹏陶瓷有限公司 | Three-dimensional multicolor dry grain polished ceramic large plate and preparation method thereof |
| WO2020042355A1 (en) * | 2018-08-27 | 2020-03-05 | 佛山石湾鹰牌陶瓷有限公司 | Dry granules, dry granular glaze, and dry granular glazed tile |
| CN110981197A (en) * | 2019-12-20 | 2020-04-10 | 佛山欧神诺陶瓷有限公司 | Preparation method of wet-process dry-grain polished crystal brick and polished crystal brick |
| CN111116235A (en) * | 2019-12-30 | 2020-05-08 | 肇庆乐华陶瓷洁具有限公司 | Fine dry particle ceramic tile, preparation method thereof and fine dry particle glaze |
| WO2020177248A1 (en) * | 2019-03-01 | 2020-09-10 | 东莞市唯美陶瓷工业园有限公司 | Ink-jet dry-grain decorative ceramic tile and manufacturing method thereof |
| CN112062608A (en) * | 2020-08-13 | 2020-12-11 | 广东嘉联企业陶瓷有限公司 | Rock plate surface dry grain semi-polishing processing technology |
| CN112079654A (en) * | 2020-08-13 | 2020-12-15 | 广东嘉联企业陶瓷有限公司 | Rock plate surface layer matte surface treatment method |
| CN112592208A (en) * | 2020-12-18 | 2021-04-02 | 佛山市三水新明珠建陶工业有限公司 | Silk glaze ceramic tile and preparation method thereof |
| CN113354285A (en) * | 2021-07-07 | 2021-09-07 | 肇庆市将军陶瓷有限公司 | Dry particle glaze material for replacing digital ink with matt rock plate |
| CN113698190A (en) * | 2021-03-16 | 2021-11-26 | 亚细亚建筑材料股份有限公司 | Preparation process of dry-grain half-polished brick |
| CN113860887A (en) * | 2021-10-22 | 2021-12-31 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
| CN114735935A (en) * | 2022-03-31 | 2022-07-12 | 佛山市阿特贝尔建材有限公司 | 5-degree low-light-level diffuse reflection ceramic rock plate and preparation method thereof |
| CN115448598A (en) * | 2022-09-19 | 2022-12-09 | 江西新明珠建材有限公司 | Dry particle protective glaze, soft marble tile and preparation method thereof |
| CN116041044A (en) * | 2022-11-23 | 2023-05-02 | 珠海市白兔陶瓷有限公司 | Manufacturing process of ink-jet brick |
| CN118005430A (en) * | 2024-04-09 | 2024-05-10 | 佛山市东鹏陶瓷有限公司 | Soft polished tile with uniform luster and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101910086A (en) * | 2007-11-15 | 2010-12-08 | 新泽西州州立大学(拉特格斯) | The hydro-thermal liquid-phase sintering process of stupalith and derived product thereof |
| KR101457614B1 (en) * | 2013-05-31 | 2014-11-10 | 한국세라믹기술원 | Glass composition for solid oxide fuel cell sealant, sealant and the manufacturing method using the same |
| CN105175021A (en) * | 2015-08-27 | 2015-12-23 | 广东博华陶瓷有限公司 | Soft light tile |
| CN107032833A (en) * | 2017-05-17 | 2017-08-11 | 佛山欧神诺陶瓷股份有限公司 | A kind of on-slip brick and preparation method thereof |
| CN107903086A (en) * | 2017-11-06 | 2018-04-13 | 蒙娜丽莎集团股份有限公司 | A kind of ceramic tile that can produce low-light dry granular effect and preparation method thereof |
-
2018
- 2018-08-27 CN CN201810979553.4A patent/CN108911701B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101910086A (en) * | 2007-11-15 | 2010-12-08 | 新泽西州州立大学(拉特格斯) | The hydro-thermal liquid-phase sintering process of stupalith and derived product thereof |
| KR101457614B1 (en) * | 2013-05-31 | 2014-11-10 | 한국세라믹기술원 | Glass composition for solid oxide fuel cell sealant, sealant and the manufacturing method using the same |
| CN105175021A (en) * | 2015-08-27 | 2015-12-23 | 广东博华陶瓷有限公司 | Soft light tile |
| CN107032833A (en) * | 2017-05-17 | 2017-08-11 | 佛山欧神诺陶瓷股份有限公司 | A kind of on-slip brick and preparation method thereof |
| CN107903086A (en) * | 2017-11-06 | 2018-04-13 | 蒙娜丽莎集团股份有限公司 | A kind of ceramic tile that can produce low-light dry granular effect and preparation method thereof |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020042355A1 (en) * | 2018-08-27 | 2020-03-05 | 佛山石湾鹰牌陶瓷有限公司 | Dry granules, dry granular glaze, and dry granular glazed tile |
| WO2020177248A1 (en) * | 2019-03-01 | 2020-09-10 | 东莞市唯美陶瓷工业园有限公司 | Ink-jet dry-grain decorative ceramic tile and manufacturing method thereof |
| CN110482859A (en) * | 2019-09-17 | 2019-11-22 | 广东新润成陶瓷有限公司 | A kind of starlight glaze Ceramic Tiles and preparation method thereof |
| CN110482859B (en) * | 2019-09-17 | 2021-03-30 | 广东新润成陶瓷有限公司 | Starlight glaze ceramic tile and preparation method thereof |
| CN110668792B (en) * | 2019-10-31 | 2021-10-12 | 佛山市东鹏陶瓷有限公司 | Three-dimensional multicolor dry grain polished ceramic large plate and preparation method thereof |
| CN110668792A (en) * | 2019-10-31 | 2020-01-10 | 佛山市东鹏陶瓷有限公司 | Three-dimensional multicolor dry grain polished ceramic large plate and preparation method thereof |
| CN110981197A (en) * | 2019-12-20 | 2020-04-10 | 佛山欧神诺陶瓷有限公司 | Preparation method of wet-process dry-grain polished crystal brick and polished crystal brick |
| CN110981197B (en) * | 2019-12-20 | 2022-05-24 | 佛山欧神诺陶瓷有限公司 | Preparation method of wet-process dry-grain polished crystal brick and polished crystal brick |
| CN111116235A (en) * | 2019-12-30 | 2020-05-08 | 肇庆乐华陶瓷洁具有限公司 | Fine dry particle ceramic tile, preparation method thereof and fine dry particle glaze |
| CN112062608A (en) * | 2020-08-13 | 2020-12-11 | 广东嘉联企业陶瓷有限公司 | Rock plate surface dry grain semi-polishing processing technology |
| CN112079654A (en) * | 2020-08-13 | 2020-12-15 | 广东嘉联企业陶瓷有限公司 | Rock plate surface layer matte surface treatment method |
| CN112592208B (en) * | 2020-12-18 | 2024-01-16 | 佛山市三水新明珠建陶工业有限公司 | Silk glaze ceramic tile and preparation method thereof |
| CN112592208A (en) * | 2020-12-18 | 2021-04-02 | 佛山市三水新明珠建陶工业有限公司 | Silk glaze ceramic tile and preparation method thereof |
| CN113698190A (en) * | 2021-03-16 | 2021-11-26 | 亚细亚建筑材料股份有限公司 | Preparation process of dry-grain half-polished brick |
| CN113354285A (en) * | 2021-07-07 | 2021-09-07 | 肇庆市将军陶瓷有限公司 | Dry particle glaze material for replacing digital ink with matt rock plate |
| CN113860887A (en) * | 2021-10-22 | 2021-12-31 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
| CN113860887B (en) * | 2021-10-22 | 2022-08-30 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
| CN114735935A (en) * | 2022-03-31 | 2022-07-12 | 佛山市阿特贝尔建材有限公司 | 5-degree low-light-level diffuse reflection ceramic rock plate and preparation method thereof |
| CN114735935B (en) * | 2022-03-31 | 2023-09-22 | 佛山市阿特贝尔建材有限公司 | 5-degree low-light diffuse reflection ceramic rock plate and preparation method thereof |
| CN115448598A (en) * | 2022-09-19 | 2022-12-09 | 江西新明珠建材有限公司 | Dry particle protective glaze, soft marble tile and preparation method thereof |
| CN115448598B (en) * | 2022-09-19 | 2023-09-01 | 江西新明珠建材有限公司 | Dry grain protective glaze, soft marble tile and preparation method thereof |
| CN116041044A (en) * | 2022-11-23 | 2023-05-02 | 珠海市白兔陶瓷有限公司 | Manufacturing process of ink-jet brick |
| CN118005430A (en) * | 2024-04-09 | 2024-05-10 | 佛山市东鹏陶瓷有限公司 | Soft polished tile with uniform luster and preparation method thereof |
| CN118005430B (en) * | 2024-04-09 | 2024-06-25 | 佛山市东鹏陶瓷有限公司 | Soft polished tile with uniform luster and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108911701B (en) | 2021-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108911701A (en) | Dumb light dry granular glazed tile and preparation method thereof | |
| CN109053226A (en) | The method for preparing dumb light dry granular glazed tile | |
| CN109052958B (en) | Dry granules, dry granules glaze and dry granules glazed tile | |
| CN103626523B (en) | A kind of ostentatious ceramic tile of dry granular glaze and manufacture method thereof | |
| CN109279918A (en) | A kind of sheen brick and preparation method thereof | |
| CN103435369B (en) | Method for manufacturing wear-resistant antiskid dry-particle ceramic tile | |
| CN109279920A (en) | A kind of wear-resisting antiskid brick and preparation method thereof | |
| WO2019015237A1 (en) | Anti-slip wear-resistant glaze, anti-slip wear-resistant easy-clean ceramic tile, and preparation method therefor | |
| CN107963814A (en) | Compound glaze, the wear-resisting porcelain Antique Imitation Tiles of compound glaze slip and the soft face of 4-8 degree | |
| CN107285737B (en) | The easy clean Ceramic Tiles of anti-skid wearable | |
| CN106278383B (en) | A method of manufacture surface has Z-Correct bump mapping Z-correct Ceramic Tiles | |
| CN109232024A (en) | A kind of preparation method of multi-functional full space of a whole page dark color ceramic tile | |
| CN105461358A (en) | A stone-imitating porcelain tile with three-dimensional decoration effects and a producing method thereof | |
| CN108863298A (en) | A kind of the Shi ceramic tile and its production technology of high rigidity and high water absorbing capacity | |
| CN110482859A (en) | A kind of starlight glaze Ceramic Tiles and preparation method thereof | |
| CN109279919A (en) | A kind of water mill essence stone brick and preparation method thereof | |
| CN108996908A (en) | A kind of printing polishing glaze and preparation method thereof and the application method in tile product | |
| CN109384476A (en) | A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof | |
| CN104892034B (en) | It is a kind of that there are ceramics of group glaze effect and preparation method thereof | |
| CN108752057B (en) | Soft-surface wear-resistant easy-to-clean retro brick with surface glossiness of 4-8 degrees | |
| CN114195386A (en) | Pearlescent dry particles, pearlescent glazed tile and preparation method thereof | |
| CN106007800B (en) | A kind of preparation method of background wall brick and the preparation method of wall | |
| CN107265861A (en) | The preparation method of the easy clean Ceramic Tiles of anti-skid wearable | |
| CN107200554A (en) | A kind of preparation technology of antifouling sheen Dali stone ceramic tile | |
| WO2014071701A1 (en) | Ceramic coating material with 3d effect, and coating method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |