CN103113135B - A kind of microballon shape dry granular and its preparation method and application - Google Patents
A kind of microballon shape dry granular and its preparation method and application Download PDFInfo
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- CN103113135B CN103113135B CN201310043412.9A CN201310043412A CN103113135B CN 103113135 B CN103113135 B CN 103113135B CN 201310043412 A CN201310043412 A CN 201310043412A CN 103113135 B CN103113135 B CN 103113135B
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Abstract
The invention belongs to execute and form glaze paint material in billet surface, be specifically related to a kind of microballon shape dry granular and its preparation method and application.The surface of described microballon shape dry granular is closed surface.Described preparation method refers to common dry granular or frit for raw material, is obtained by the processing of flame floating method.Described dry granular vitreous brick is the glaze slip be made into by above-mentioned microballon shape dry granular, fires acquisition after imposing on the surface of base substrate.Microballon shape dry granular provided by the invention greatly can improve the proportion of the dry granular in glaze, glaze good fluidity, and greatly reduce in the past random crystal dry granular to the loss of equipment.Make glaze spraying, drench glaze, screen painting and glue roller printing and all can be used for the production process of dry granular glaze cloth.The decorative cover of dry granular vitreous brick produced has diffusion effect, artistic expression more by force, abundanter.
Description
Technical field
The invention belongs to execute and form glaze paint material in billet surface, be specifically related to a kind of microballon shape dry granular and its preparation method and application.
Background technology
Dry granular glaze is the ceramic tile decoration new variety of R&D and production, and the glaze of dry granular glaze is dry granular.This vitreous brick pattern texture levels are rich, has the effect of sub-light, wear-resisting, anti-skidding, anti-soil, is the new era of having started ceramic tile production technology by reputation.
Ceramic glaze generally can by drenching the method clothes such as glaze, glaze spraying, screen printing or rubber roll stamp.
Described pouring glaze refers to glaze slip suction high level tank, by the shock absorption of glaze groove and screen cloth lattice, makes glaze slip as waterfall, evenly cover the surface of base substrate, described pouring glaze glaze slip
Described glaze spraying refers to and makes glaze slip be atomized the surface being sprayed onto base substrate glaze slip spray gun or atomizer.
Described screen painting and glue roller printing refer to the pattern according to designing in advance, by transfer printing flower net or engraving rubber roll, are transferred on glazed body by the pore of glaze slip through mesh or rubber roll.
In prior art, the preparation method of common dry granular is as follows: be mixed with compound by proportioning raw materials, then mix with blender, again the compound fully mixed is added high-temperature calcination melting in Cinker clew furnace, the molten slurry of melting flows in cold water and just becomes frit after shrend, its pulverizing, screening combination treatment etc. are become common dry granular with pulverizer after drying by frit, and production craft step is: batching-mixing-melting-shrend-oven dry-pulverizing-screening-mixing.The common dry granular that this kind pulverizer is pulverized, screening combination treatment obtains, observe with 40 times of magnifying glasses, as shown in Figure 1, the common dry granular surface that can find 95% is section crushed particles, the glaze slip poor fluidity that common dry granular is configured to, therefore all not satisfactory by above any one mode cloth.If to wear and tear slip shower by drenching glaze cloth, and have a large amount of bubble in billet surface after having drenched, there is damage to the pouring glaze edge of a knife; If by glaze spraying cloth, can Severe blockage spray gun or spraying gas; If adopt screen painting cloth, need a large amount of stamp-pad ink to improve liquidity in formula, and dry granular easy network blocking hole is larger to half tone equipment loss; If adopt glue roller printing cloth, to rubber roll serious wear.In order to improve glaze slip mobility, glaze content in glaze slip need be reduced, repeatedly can complete cloth just need apply, reduce working efficiency.
Therefore, the cloth of current common dry granular is equipped with stationary liquid again mainly through dry granular broadcast application and completes.But the dry granular glaze pattern color that this method is formed is single, and pattern stereoeffect is poor, and the uneven surface finish of cloth is undesirable, easily produces surface imperfection.
Summary of the invention
Technical problem to be solved by this invention is dry granular poor fluidity in prior art, and working method is single, and glazing effect is undesirable, in order to overcome above deficiency, provides a kind of microballon shape dry granular and its preparation method and application.
In order to solve the problems of the technologies described above, technical scheme of the present invention is: the surface of described microballon shape dry granular is closed surface.
Further, the surface of described microballon shape dry granular is sphere.
Further, the granularity of described microballon shape dry granular is 60 ~ 200 orders.
Present invention also offers the preparation method of above-mentioned microballon shape dry granular: described preparation method refers to common dry granular or frit for raw material, obtained by the processing of flame floating method.
Described flame floating method refers to that the particles float of certain particle size is in flame, the process of softening under the effect of flame and air-flow, melting, pearlization and cooling curing.
Further, described common dry granular or frit are made up of the component of following weight proportion:
The per-cent sum of each component is 100% above.
Further, Al in component
2o
3content be 5 ~ 15wt%, ensure the high temperature viscosity that dry granular is suitable, improve row yielding.
Further, the granularity of described common dry granular is 60 ~ 200 orders.
Further, described flame floating method Flame temperature controls at 800 ~ 1000 DEG C.
Present invention also offers a kind of dry granular vitreous brick, described dry granular vitreous brick is the glaze slip be made into by above-mentioned microballon shape dry granular, fires acquisition after imposing on the surface of base substrate.
Further, described microballon shape dry granular imposes on the surface of base substrate by drenching glaze, glaze spraying, screen painting or glue roller printing method.
Further, the glaze slip of described pouring glaze comprises the component of following weight proportion:
Microballon shape dry granular 30 ~ 40 parts
Water-soluble copolymer adhesive 15 ~ 25 parts
15 ~ 25 parts, water,
The viscosity of described water-soluble copolymer adhesive is 800 ~ 1200mPas.
Further, the glaze slip of described glaze spraying comprises the component of following weight proportion:
Microballon shape dry granular 20 ~ 40 parts
2 ~ 4 parts, Walocel MT 20.000PV tackiness agent
100 parts, water,
The viscosity of described Walocel MT 20.000PV tackiness agent is 30 ~ 100mPas.
Further, the glaze slip of described screen painting comprises the component of following weight proportion:
Lithographic plate stamp-pad ink 100 parts
Microballon shape dry granular 250 ~ 300 parts.
If in glaze be common dry granular, then in 100 parts of dull and stereotyped stamp-pad ink, the addition of common dry granular can not more than 200 parts, and solid content declines, and needs repeatedly to print the cloth that just can complete dry granular glaze.
Microballon shape dry granular provided by the invention greatly can improve the proportion of the dry granular in glaze, glaze good fluidity, and greatly reduce in the past random crystal dry granular to the loss of equipment.Make glaze spraying, drench glaze, screen painting and glue roller printing and all can be used for the production process of dry granular glaze cloth.The decorative cover of dry granular vitreous brick produced has diffusion effect, artistic expression more by force, abundanter.
Accompanying drawing explanation
Fig. 1 is that in prior art, common dry granular amplifies the photo after 40 times;
Fig. 2 is that microballon shape dry granular of the present invention amplifies the photo after 40 times.
Embodiment
The preparation of embodiment 1 microballon shape dry granular
By quartz, potassium felspar sand, albite, rhombspar, coarse whiting, talcum, zircon, borax, zinc oxide and cerium oxide, be milled to 200 orders respectively, mixing, fires 1.5 ~ 2 hours for 1530 ~ 1540 DEG C, obtain frit through shrend, frit is made up of the component of following weight proportion:
Frit makes microballon shape dry granular A through flame floating method in glass microsphere manufacturing installation, and flame temperature controls at about 900 DEG C, and the size range of microballon shape dry granular A is 60 ~ 170 orders, and row yielding is 70%, and as shown in Figure 2, the surface of microballon shape dry granular A is sphere.
The preparation of embodiment 2 microballon shape dry granular
By quartz, potassium felspar sand, albite, rhombspar, coarse whiting, zircon, boric acid, zinc oxide, be milled to 200 orders respectively, mixing, fire 1.5 ~ 2 hours for 1530 ~ 1540 DEG C, frit is obtained through shrend, then be crushed to 100-200 order through oven dry, i.e. common dry granular, common dry granular is made up of the component of following weight proportion:
Common dry granular makes microballon shape dry granular B through flame floating method in glass microsphere manufacturing installation, and flame temperature controls at about 860 DEG C, and the granularity of microballon shape dry granular B is 100-200 order, and row yielding is 95%, and as shown in Figure 2, the surface of microballon shape dry granular B is sphere.
Embodiment 3 screen painting prepares dry granular vitreous brick
Be printed on ornamental brick with the 32T half tone being provided with pattern by the glaze slip of the screen painting prepared, then fire and obtain dry granular vitreous brick, decorative pattern is three-dimensional, and effect is rich and varied.
The glaze slip of screen painting comprises the component of following weight proportion:
Lithographic plate stamp-pad ink 100 parts
Microballon shape dry granular B 260 parts.
Embodiment 4 is drenched glaze and is prepared dry granular vitreous brick
Adopt straight line slip shower to impose on brick face by the glaze slip drenching glaze, glaze slip proportion is 1.45 ± 5g/ml, and flow velocity is 40 ± 10sec, and not bubbles and glaze steady flow is good in the glaze slip drenching glaze, the stable not jag of glaze curtain, drenches and do not producing pin hole and pit on brick face.The glaze paint flat smooth of the dry granular vitreous brick fired does not have defect.
The glaze slip drenching glaze comprises the component of following weight proportion:
Microballon shape dry granular 40 parts
GRANICER7010 24 parts
16 parts, water,
The viscosity of GRANICER7010 is about 1000mPas, is purchased from Si Mahuagong (Foshan) company limited.
Dry granular vitreous brick is prepared in embodiment 5 glaze spraying
Water-cutting type glaze spraying device is adopted to impose on brick face by the glaze slip of glaze spraying, glaze slip proportion is 1.25 ± 0.05g/ml, flow velocity is 10 ± 2sec, and the glaze slip mobility of glaze spraying is very good, and the glaze paint flat smooth that the glaze slip of glaze spraying is sprayed on dry granular vitreous brick brick face being fired acquisition does not have defect.
The glaze slip of glaze spraying comprises the component of following weight proportion:
Microballon shape dry granular 25 parts
The sticky CMC 3.5 parts of C50G height
100 parts, water,
The viscosity of the sticky CMC of C50G height is 30 ~ 100mPas, is purchased from the happy many chemical industry in Chancheng District of Foshan City.
Claims (10)
1. a microballon shape dry granular; it is characterized in that; dry granular surface is sphere; the granularity of described microballon shape dry granular is 60 ~ 170 orders; the glaze slip that described microballon shape dry granular is made into by the surface drenching glaze, glaze spraying, screen painting or glue roller printing method impose on base substrate, for the preparation of dry granular vitreous brick, described microballon shape dry granular with common dry granular or frit for raw material; obtained by the processing of flame floating method, described common dry granular or frit are made up of the component of following weight proportion:
2. the preparation method of microballon shape dry granular according to claim 1, is characterized in that, with common dry granular or frit for raw material, is obtained by the processing of flame floating method.
3. the preparation method of microballon shape dry granular according to claim 2, is characterized in that, Al in component
2o
3content be 5 ~ 15wt%.
4. the preparation method of microballon shape dry granular according to claim 2, it is characterized in that, the granularity of described common dry granular is 60 ~ 200 orders.
5. the preparation method of microballon shape dry granular according to claim 2, it is characterized in that, described flame floating method Flame temperature controls at 800 ~ 1000 DEG C.
6. a dry granular vitreous brick, is characterized in that, described dry granular vitreous brick is the glaze slip be made into by microballon shape dry granular described in claim 1, fires acquisition after imposing on the surface of base substrate.
7. a kind of dry granular vitreous brick according to claim 6, is characterized in that, the glaze slip that described microballon shape dry granular is made into imposes on the surface of base substrate by drenching glaze, glaze spraying, screen painting or glue roller printing method.
8. a kind of dry granular vitreous brick according to claim 7, it is characterized in that, the glaze slip of described pouring glaze comprises the component of following weight proportion:
Microballon shape dry granular 30 ~ 40 parts
Water-soluble copolymer adhesive 15 ~ 25 parts
15 ~ 25 parts, water,
The viscosity of described water-soluble copolymer adhesive is 800 ~ 1200mPas.
9. a kind of dry granular vitreous brick according to claim 7, it is characterized in that, the glaze slip of described glaze spraying comprises the component of following weight proportion:
Microballon shape dry granular 20 ~ 40 parts
2 ~ 4 parts, Walocel MT 20.000PV tackiness agent
100 parts, water,
The viscosity of described Walocel MT 20.000PV tackiness agent is 30 ~ 100mPas.
10. a kind of dry granular vitreous brick according to claim 7, it is characterized in that, the glaze slip of described screen painting comprises the component of following weight proportion:
Lithographic plate stamp-pad ink 100 parts
Microballon shape dry granular 250 ~ 300 parts.
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|---|---|---|---|
| CN201310043412.9A CN103113135B (en) | 2013-01-31 | 2013-01-31 | A kind of microballon shape dry granular and its preparation method and application |
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| CN201310043412.9A CN103113135B (en) | 2013-01-31 | 2013-01-31 | A kind of microballon shape dry granular and its preparation method and application |
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| CN103113135B true CN103113135B (en) | 2015-08-05 |
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| CN105016780B (en) * | 2014-04-28 | 2017-02-08 | 佛山市纳来建材有限公司 | Dry particle glaze rock simulated ceramic tile production process |
| CN105060932A (en) * | 2015-07-17 | 2015-11-18 | 星谊精密陶瓷科技（昆山）有限公司 | Low-viscosity ink for dry granules and application |
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| CN105622168B (en) * | 2015-12-23 | 2018-07-24 | 佛山市唯格瓷砖有限责任公司 | A kind of anti-skid wearable dry granular and its application in anti-skid wearable ceramic tile |
| CN105776872B (en) * | 2016-03-17 | 2018-09-07 | 鹰牌陶瓷实业（河源）有限公司 | A kind of coloured high transparency frit and preparation method thereof |
| CN108191242A (en) * | 2018-01-25 | 2018-06-22 | 广东金牌陶瓷有限公司 | A kind of big plate glued surfaces of ceramics protect color glaze and preparation method thereof |
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| CN109354413B (en) * | 2018-12-12 | 2020-04-14 | 泰州市津专知识产权服务有限公司 | Dry-grain glaze ceramic tile and preparation method thereof |
| CN109849163B (en) * | 2019-03-28 | 2021-03-02 | 东莞市唯美陶瓷工业园有限公司 | Stereoscopic glazed brick prepared from edge scraping waste and manufacturing method thereof |
| CN110304828A (en) * | 2019-07-31 | 2019-10-08 | 佛山欧神诺陶瓷有限公司 | A kind of preparation method and ceramic tile without overglaze ceramic tile with concave-convex discoloration metal effect |
| CN110845126B (en) * | 2019-11-04 | 2022-03-22 | Oppo广东移动通信有限公司 | Method for preparing electronic equipment shell, electronic equipment shell and electronic equipment |
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| CN113735443B (en) * | 2021-10-22 | 2023-05-23 | 新明珠集团股份有限公司 | Ball dry particle and preparation method thereof |
| CN113860887B (en) * | 2021-10-22 | 2022-08-30 | 新明珠集团股份有限公司 | Ceramic plate and preparation method thereof |
| CN113860739B (en) * | 2021-10-22 | 2023-04-18 | 蒙娜丽莎集团股份有限公司 | Modified ball dry particle ultra-flat thin ceramic plate and preparation method thereof |
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