CN115679228A - Silicon carbide fiber reinforced aluminum-based composite material and preparation method and application thereof - Google Patents
Silicon carbide fiber reinforced aluminum-based composite material and preparation method and application thereof Download PDFInfo
- Publication number
- CN115679228A CN115679228A CN202211457781.8A CN202211457781A CN115679228A CN 115679228 A CN115679228 A CN 115679228A CN 202211457781 A CN202211457781 A CN 202211457781A CN 115679228 A CN115679228 A CN 115679228A
- Authority
- CN
- China
- Prior art keywords
- silicon carbide
- fiber bundle
- carbide fiber
- composite material
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 116
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 93
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 82
- 239000002131 composite material Substances 0.000 title claims abstract description 76
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000011159 matrix material Substances 0.000 claims abstract description 40
- 238000007731 hot pressing Methods 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 31
- 238000005266 casting Methods 0.000 claims abstract description 29
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 24
- 239000002243 precursor Substances 0.000 claims description 24
- 238000005406 washing Methods 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 6
- 229910001338 liquidmetal Inorganic materials 0.000 claims description 6
- 238000005498 polishing Methods 0.000 claims description 5
- 238000005245 sintering Methods 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 2
- 239000002585 base Substances 0.000 claims 1
- 238000005242 forging Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 10
- 239000000758 substrate Substances 0.000 abstract description 7
- 238000009826 distribution Methods 0.000 abstract description 4
- 238000007747 plating Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 238000009736 wetting Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 238000005452 bending Methods 0.000 description 11
- 239000010410 layer Substances 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 8
- 238000005520 cutting process Methods 0.000 description 8
- 229910017604 nitric acid Inorganic materials 0.000 description 8
- 238000002791 soaking Methods 0.000 description 8
- 238000010030 laminating Methods 0.000 description 6
- 238000005554 pickling Methods 0.000 description 6
- 238000009990 desizing Methods 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 4
- 238000004512 die casting Methods 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 244000137852 Petrea volubilis Species 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000012783 reinforcing fiber Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000009497 press forging Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Images
Landscapes
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
The invention discloses a silicon carbide fiber reinforced aluminum matrix composite material and a preparation method and application thereof. The composite material comprises a silicon carbide fiber bundle and an aluminum alloy matrix, wherein a silicon carbide fiber bundle layer and an aluminum alloy plate layer are overlapped and laid, and the composite material is obtained by vacuum hot pressing and vacuum pressure casting. The composite material is based on the synergistic effect of the components, and the composite material forms tight package between the aluminum matrix and the surface of the silicon carbide fiber bundle, so that the bonding force between the aluminum matrix and the silicon carbide fiber bundle is greatly enhanced. The method adopts vacuum hot pressing and vacuum pressure casting, does not need to perform bundling or chemical plating treatment on the silicon carbide fiber bundle wires, controls the bundling property and the wetting property of the aluminum substrate on the silicon carbide fiber bundle wires by controlling the vacuum degree, the temperature and the pressure, and controls the orientation distribution of the silicon carbide fiber bundle wires, thereby greatly improving the mechanical property of the material.
Description
Technical Field
The invention relates to an aluminum-based composite material, in particular to a silicon carbide fiber bundle reinforced aluminum-based composite material and a preparation method and application thereof, belonging to the technical field of composite materials.
Background
The silicon carbide fiber has the advantages of high tensile strength and elastic modulus, good high-temperature strength and heat resistance, good wettability with metals, small fiber diameter and the like. The larger the volume fraction of the reinforcing SiC fibers in the silicon carbide reinforced aluminum matrix composite material is, the higher the thermal conductivity is, the smaller the thermal expansion coefficient is, and meanwhile, the silicon carbide reinforced aluminum matrix composite material has the advantages of high specific strength and specific stiffness, low density, wear resistance, fatigue resistance and good dimensional stability. The main method for preparing the silicon carbide fiber reinforced aluminum matrix composite material at present comprises the following steps: (1) The melting and infiltrating method is to infiltrate the liquid aluminum and the aluminum alloy into the fiber bundle or to make the fiber bundle pass through a liquid aluminum and aluminum alloy molten pool to make each fiber wetted by the molten metal and then remove the redundant metal surface to obtain the composite wire and then extrude the composite material. The disadvantage is that molten aluminum and aluminum alloys can damage the properties of the fibers when they are easily wetted. (2) Pressure casting method, in which molten aluminum or aluminum alloy is forced into a fixed mold cavity of a preform with a built-in fiber until solidification is completed. The disadvantage is that the casting pressure and the reinforcing fiber content have a great influence on the properties of the aluminium matrix composite. (3) The diffusion bonding method mainly refers to a manufacturing method of aluminum-based composite material obtained by laminating aluminum foil and fiber filaments or composite filaments or single-layer plates which are subjected to surface treatment and then soaked in aluminum liquid according to a specified sequence, and performing high-temperature pressurization diffusion bonding molding under the condition of vacuum or inert gas. In addition, the method also comprises a normal pressure sintering method, a hot pressing method and a high temperature extrusion method. The disadvantage is that the matrix is difficult to impregnate between the fiber tows, and the interfacial bonding is weak. (4) The powder metallurgy method is that the metal aluminum powder is sprayed on the arranged reinforcing fiber by plasma spraying method or is dispersed in acrylic resin (or polystyrene resin) to be coated to prepare a prepreg plate, the prepreg plate is overlapped alternately, and then is pressed and sintered in vacuum or argon at the temperature close to the melting point of aluminum to obtain the fiber reinforced aluminum-based composite material. The disadvantages are large fibre damage, uneven distribution and low content.
Disclosure of Invention
In view of the defects in the prior art, a first object of the present invention is to provide a silicon carbide fiber bundle reinforced aluminum-based composite material, which forms a tight package between an aluminum matrix and the surface of a silicon carbide fiber bundle based on the synergistic effect between the components, so as to greatly enhance the bonding force between the aluminum matrix and the silicon carbide fiber bundle, thereby improving the tensile strength and bending resistance of the material.
The second purpose of the invention is to provide a preparation method of the silicon carbide fiber bundle reinforced aluminum matrix composite, which adopts vacuum hot pressing and vacuum pressure casting, does not need to perform bundling or chemical plating treatment on silicon carbide fiber bundles, controls the bundling property and the wetting property of the aluminum substrate to the silicon carbide fiber bundles by controlling the vacuum degree, the temperature and the pressure, and controls the orientation distribution of the silicon carbide fiber bundles, thereby greatly improving the mechanical property of the material.
The third purpose of the invention is to provide application of the silicon carbide fiber bundle reinforced aluminum-based composite material as an aeroengine compressor component. The material is beneficial to interface combination of fibers and a matrix by adopting a vacuum hot-pressing preparation process, composite materials with different shapes can be designed according to a mould by vacuum pressure casting, excellent bending resistance and pressure resistance are given to the prepared material, and the mechanical requirement of an aircraft engine compressor can be met.
In order to achieve the technical purpose, the invention provides a preparation method of a silicon carbide fiber bundle reinforced aluminum matrix composite, which comprises the following steps: overlapping and laying the aluminum alloy plate layer with the oxide film removed and the silicon carbide fiber bundle layer in a mould, and performing vacuum hot pressing to obtain a composite material precursor; vacuum pressure casting the composite material precursor and the aluminum alloy plate layer with the oxide film removed, and cooling to obtain the composite material; in the composite material, the volume ratio of the composite material precursor to the aluminum alloy plate layer is 3-6.
The preparation method provided by the invention adopts a two-step method, firstly, partial aluminum matrix is promoted to completely wrap the surface of the silicon carbide fiber bundle through vacuum hot pressing and is partially immersed in the silicon carbide fiber yarns, thus not only having the functions of bundling and threshold limiting on the fiber bundle, but also strengthening the bonding strength between the fiber bundle and the aluminum matrix; furthermore, in the vacuum pressure casting process, the aluminum matrix is ensured to be at a liquid-solid phase junction point and to be in a flowing state under the vacuum casting condition, so that the aluminum matrix can be ensured to be tightly combined with the composite material precursor, and meanwhile, the fiber bundle can be further fixed, and the fiber bundle filament is ensured to be unidirectionally and uniformly distributed, thereby greatly improving the tensile strength and the bending resistance of the composite material.
In a preferable scheme, the number of the fiber bundle filaments in the silicon carbide fiber bundle layer is less than or equal to 1K.
Preferably, the monofilament diameter of the fiber bundle is 6 to 10 μm; the tensile strength of the fiber monofilament is 2.5-3.6 GPa.
As a preferred scheme, the vacuum hot-pressing condition is as follows: vacuum degree < 5 x 10 -3 Pa, the hot-pressing sintering temperature is 550-620 ℃, the pressure is 60-100 MPa, and the time is 0.5-3 h. Wherein the degree of vacuum is less than 5 x 10 -3 Pa is beneficial to the interface bonding of the fiber and the aluminum matrix; the hot-pressing sintering temperature is less than 550 ℃, or the pressure is less than 60MPa, or the time is less than 0.5h, so that the hot-pressing sintering is not beneficial to press forming, and the temperature is more than 620 ℃, so that excessive liquid phase is formed, and the subsequent pressure casting is not beneficial; pressures above 100MPa or times longer than 3 hours are detrimental to the integrity of the silicon carbide fibers.
As a preferable scheme, the volume ratio of the silicon carbide fiber bundle layer to the aluminum alloy plate layer in the composite material precursor is 3-6.
Preferably, the composite precursor further comprises removing the oxide layer before vacuum press forging.
Preferably, the oxide layer of the composite material precursor is removed by at least one of polishing, strong alkali washing and strong acid washing.
Preferably, the vacuum pressure casting is performedThe conditions are as follows: vacuum degree < 5 x 10 -3 Pa, the temperature is 660-720 ℃, the pressure is 50-100MPa, the time is 0.5h-1.5h, and the pressure is maintained until the liquid metal is solidified. Wherein the vacuum degree is higher than 5 × 10 -3 Pa, the interface bonding between the fiber and the aluminum matrix is not facilitated; when the casting temperature is lower than 660 ℃, the aluminum matrix can not be completely melted into a liquid state, and when the temperature is higher than 720 ℃, the interface reaction between the aluminum matrix and the fibers is not facilitated, and the performance of the composite material is directly reduced due to the serious interface reaction; casting pressures below 50MPa or times less than 0.5 hours are detrimental to composite formation, while pressures above 100MPa or times longer than 1 hour can damage the silicon carbide fibers.
Preferably, the thickness of the aluminum alloy plate layer is 0.05-0.15 mm, and the aluminum alloy plate layer is at least one of 1 series aluminum alloy, 3 series aluminum alloy and 6 series aluminum alloy.
The invention also provides a silicon carbide fiber bundle reinforced aluminum matrix composite material which is prepared by any one of the preparation methods. The silicon carbide fiber bundle reinforced aluminum-based composite material provided by the invention has excellent mechanical properties, particularly greatly improves the tensile strength and the bending strength of the material, and tests show that the tensile strength of the obtained material can reach 750MPa, and the bending strength can reach 840MPa.
The invention also provides application of the silicon carbide fiber bundle reinforced aluminum-based composite material as an aeroengine compressor component.
Compared with the prior art, the invention has the following technical effects:
1) The composite material provided by the invention is based on the synergistic effect of the components, the compact package is formed between the aluminum matrix and the surface of the silicon carbide fiber bundle, and the bonding force between the aluminum matrix and the silicon carbide fiber bundle is greatly enhanced, so that the tensile strength and the bending resistance of the material are improved.
2) According to the technical scheme provided by the invention, vacuum hot pressing and vacuum pressure casting are adopted, bundling or chemical plating treatment on the silicon carbide fiber bundle wires is not needed, bundling property and wetting property of the aluminum substrate on the silicon carbide fiber bundle wires are controlled by controlling vacuum degree, temperature and pressure, and orientation distribution of the silicon carbide fiber bundle wires is controlled, so that the mechanical property of the material is greatly improved.
3) According to the technical scheme provided by the invention, the porosity of the material can be greatly reduced by adjusting the volume fraction of the silicon carbide fiber bundles and the wettability between the aluminum substrate and the silicon carbide fiber bundles, and tests show that the density of the composite material provided by the invention is 95.5-98.7%, the volume fraction of the silicon carbide fiber is 30-60%, the internal structure is uniform and compact, and the bonding force between the silicon carbide fiber bundles and the aluminum substrate is greatly enhanced.
Drawings
FIG. 1 is a schematic view showing a layering method of vacuum hot-pressed fibers and an aluminum substrate in example 1;
FIG. 2 is a schematic view of a precursor structure in example 1;
FIG. 3 is a schematic view of the layering of a pressure casting precursor and an aluminum substrate in example 1.
Detailed Description
The present invention will be described in detail below with reference to the drawings and embodiments, and the embodiments of the present invention are not to be considered limited to the description. For those skilled in the art to which the invention pertains, several simple deductions or substitutions can be made without departing from the spirit of the invention, and all shall be considered as belonging to the protection scope of the invention.
Example 1
The embodiment provides a preparation method of a silicon carbide fiber bundle reinforced aluminum matrix composite, which comprises the following steps:
the method comprises the following steps: cutting 30 pieces of 6061-Al plates with the length, width and thickness of 79mm × 19mm × 0.1mm, soaking in 40g/LNaOH solution for 30h, then pickling with 30% HNO3 for 3min, washing with water, wiping off water stains, and removing an oxide film on the surface of the aluminum plate;
step two: selecting a silicon carbide fiber bundle with the diameter of 1k and the fiber bundle wire of 9 microns, desizing the silicon carbide fiber bundle at 500 ℃ for 1.5 hours, and then mutually laminating and paving the fiber bundle and an aluminum plate in a vacuum hot-pressing mold;
step three: putting the assembled mould into a vacuum hot-pressing furnace, and putting the mould into the vacuum hot-pressing furnace under the vacuum condition (the vacuum degree is 5 to 10) -3 Pa), the temperature is 580 ℃, the vacuum hot pressing is carried out for 1.5h under the pressure of 80MPa, and carbon is obtainedA silicon fiber reinforced aluminum-based composite plate precursor;
step four: polishing the surface of the obtained silicon carbide fiber reinforced aluminum-based composite material precursor by using sand paper, cutting 60 6061-Al plates with the thickness of 79mm x 19mm x 0.5mm, soaking the 6061-Al plates and the plates in 40g/L NaOH solution for 30min, then carrying out acid washing for 3min by using 30% HNO3, finally washing by using distilled water, and wiping water stains;
step five: putting 30 processed aluminum plates into the bottom of a pressure casting mold, then superposing the processed silicon carbide fiber reinforced aluminum-based composite material precursor, finally superposing the remaining processed 30 aluminum plates, and covering an upper mold;
step six: putting the loaded pressure casting die into a vacuum hot pressing furnace, carrying out die casting for 1h under the vacuum condition (the vacuum degree is 5 x 10-3 Pa), the temperature is 680 ℃ and the pressure is 50MPa, and keeping the pressure until the liquid metal is solidified;
step seven: and taking out the die-cast die, opening the die after cooling, taking out a sample formed by internal pressure casting, machining and grinding off redundant aluminum matrixes at two sides, and finally obtaining the silicon carbide fiber reinforced aluminum matrix composite board with the tensile strength of 720MPa and the bending strength of 814MPa.
Example 2
The embodiment provides a preparation method of a silicon carbide fiber bundle reinforced aluminum matrix composite, which comprises the following steps:
the method comprises the following steps: cutting 30 pieces of 6061-Al plates with the length, width and thickness of 79mm × 19mm × 0.1mm, soaking in 40g/LNaOH solution for 30h, then pickling with 30% HNO3 for 3min, washing with water, wiping off water stains, and removing an oxide film on the surface of the aluminum plate;
step two: selecting 1k silicon carbide fiber bundles with the fiber bundle wire diameter of 9 micrometers, performing desizing treatment at 500 ℃ for 1.5 hours, and then mutually laminating and paving the fiber bundles and an aluminum plate in a vacuum hot-pressing mould;
step three: putting the assembled mould into a vacuum hot-pressing furnace, and putting the mould into the vacuum hot-pressing furnace under the vacuum condition (the vacuum degree is 5 to 10) -3 Pa), the temperature is 600 ℃, and the vacuum hot pressing is carried out for 1.5h under the pressure of 80MPa, thus obtaining the precursor of the silicon carbide fiber reinforced aluminum-based composite board;
step four: polishing the surface of the obtained silicon carbide fiber reinforced aluminum-based composite material precursor by using sand paper, cutting 60 6061-Al plates with the thickness of 79mm x 19mm x 0.5mm, soaking the 6061-Al plates and the plates in 40g/L NaOH solution for 30min, then carrying out acid washing for 3min by using 30% HNO3, finally washing by using distilled water, and wiping water stains;
step five: putting 30 processed aluminum plates into the bottom of a pressure casting mold, then superposing the processed silicon carbide fiber reinforced aluminum-based composite material precursor, finally superposing the rest processed 30 aluminum plates, and covering an upper mold;
step six: putting the loaded pressure casting die into a vacuum hot pressing furnace, carrying out die casting for 1h under the vacuum condition (the vacuum degree is 5 x 10-3 Pa), the temperature is 710 ℃ and the pressure is 50MPa, and keeping the pressure until the liquid metal is solidified;
step seven: and taking out the die-cast die, opening the die after cooling, taking out a sample formed by internal pressure casting, machining and grinding off redundant aluminum matrixes at two sides, and finally obtaining the silicon carbide fiber reinforced aluminum matrix composite board with the tensile strength of 750MPa and the bending strength of 840MPa.
Example 3
The embodiment provides a preparation method of a silicon carbide fiber bundle reinforced aluminum matrix composite, which comprises the following steps:
the method comprises the following steps: cutting 30 pieces of 6061-Al plates with the length, width and thickness of 79mm × 19mm × 0.1mm, soaking in 40g/LNaOH solution for 30h, then pickling with 30% HNO3 for 3min, washing with water, wiping off water stains, and removing an oxide film on the surface of the aluminum plate;
step two: selecting a silicon carbide fiber bundle with the diameter of 1k and the fiber bundle wire of 9 microns, desizing the silicon carbide fiber bundle at 500 ℃ for 1.5 hours, and then mutually laminating and paving the fiber bundle and an aluminum plate in a vacuum hot-pressing mold;
step three: the loaded mold was placed in a vacuum autoclave under vacuum (vacuum 5 x 10) -3 Pa), the temperature is 620 ℃, and the vacuum hot pressing is carried out for 1.5h under the pressure of 60MPa, thus obtaining the precursor of the silicon carbide fiber reinforced aluminum-based composite board;
step four: polishing the surface of the obtained silicon carbide fiber reinforced aluminum-based composite material precursor by using sand paper, cutting 60 pieces of 6061-Al plates with the sizes of 79mm × 19mm × 0.5mm, soaking the 6061-Al plates and the 60 pieces of 6061-Al plates in a 40g/L NaOH solution for 30min, pickling the 60 pieces of 6061-Al plates with 30% of HNO3 for 3min, finally cleaning the plates with distilled water, and wiping water stains;
step five: putting 30 processed aluminum plates into the bottom of a pressure casting mold, then superposing the processed silicon carbide fiber reinforced aluminum-based composite material precursor, finally superposing the remaining processed 30 aluminum plates, and covering an upper mold;
step six: putting the loaded pressure casting die into a vacuum hot pressing furnace, carrying out die casting for 1h under the vacuum condition (the vacuum degree is 5 x 10-3 Pa), the temperature is 710 ℃ and the pressure is 70MPa, and keeping the pressure until the liquid metal is solidified;
step seven: and taking out the die-cast die, opening the die after cooling, taking out a sample formed by internal pressure casting, machining and grinding off redundant aluminum matrixes at two sides, and finally obtaining the silicon carbide fiber reinforced aluminum matrix composite board with the tensile strength of 708MPa and the bending strength of 799MPa.
Comparative example 1
The method comprises the following steps: cutting 30 pieces of 6061-Al plates with the length, width and thickness of 79mm × 19mm × 0.1mm, soaking in 40g/LNaOH solution for 30h, then pickling with 30% HNO3 for 3min, washing with water, wiping off water stains, and removing an oxide film on the surface of the aluminum plate;
step two: selecting a silicon carbide fiber bundle with the diameter of 1k and the fiber bundle wire of 9 microns, desizing the silicon carbide fiber bundle at 500 ℃ for 1.5 hours, and then mutually laminating and paving the fiber bundle and an aluminum plate in a vacuum hot-pressing mold;
step three: putting the assembled mould into a vacuum hot-pressing furnace, and putting the mould into the vacuum hot-pressing furnace under the vacuum condition (the vacuum degree is 5 to 10) -3 Pa), the temperature is 620 ℃, the vacuum hot pressing is carried out for 1.5h under the pressure of 80MPa, and the silicon carbide fiber reinforced aluminum-based composite material is obtained, the tensile strength is 605MPa, and the bending strength is 700MPa;
comparative example 2
The method comprises the following steps: cutting 30 pieces of 6061-Al plates with the length, width and thickness of 79mm × 19mm × 0.1mm, soaking in 40g/LNaOH solution for 30h, then pickling with 30% HNO3 for 3min, washing with water, wiping off water stains, and removing an oxide film on the surface of the aluminum plate;
step two: selecting a silicon carbide fiber bundle with the diameter of 1k and the fiber bundle wire of 9 microns, desizing the silicon carbide fiber bundle at 500 ℃ for 1.5 hours, and then mutually laminating and paving the fiber bundle and an aluminum plate in a vacuum pressure casting mold;
step three: putting the loaded pressure casting die into a vacuum hot pressing furnace, carrying out die casting for 1h under the vacuum condition (the vacuum degree is 5 x 10-3 Pa), the temperature is 700 ℃, and the pressure is 80MPa, and keeping the pressure until the liquid metal is solidified;
step four: and taking out the die-cast die, opening the die after cooling, taking out a sample formed by internal pressure casting, machining and grinding off redundant aluminum matrixes at two sides, and finally obtaining the silicon carbide fiber reinforced aluminum matrix composite board with the tensile strength of 310MPa and the bending strength of 430MPa.
Claims (10)
1. A preparation method of a silicon carbide fiber bundle reinforced aluminum matrix composite is characterized by comprising the following steps: the method comprises the following steps: overlapping and laying the aluminum alloy plate layer with the oxidation film removed and the silicon carbide fiber bundle layer in a mold, and performing vacuum hot pressing to obtain a composite material precursor; vacuum pressure casting the composite material precursor and the aluminum alloy plate layer with the oxide film removed, and cooling to obtain the composite material; in the composite material, the volume ratio of the composite material precursor to the aluminum alloy plate layer is 3-6.
2. The method for preparing the silicon carbide fiber bundle reinforced aluminum-based composite material according to claim 1, wherein the method comprises the following steps: the number of fiber strands in the silicon carbide fiber bundle layer is less than or equal to 1K.
3. The method for preparing the silicon carbide fiber bundle reinforced aluminum matrix composite material according to claim 2, wherein the method comprises the following steps: the monofilament diameter of the fiber bundle is 6-10 mu m; the tensile strength of the fiber monofilament is 2.5-3.6 GPa.
4. Silicon carbide fiber bundle reinforced aluminum according to claim 1The preparation method of the base composite material is characterized by comprising the following steps: the vacuum hot-pressing conditions are as follows: vacuum degree < 5 x 10 -3 Pa, the hot-pressing sintering temperature is 550-620 ℃, the pressure is 60-100 MPa, and the time is 0.5-3 h.
5. The method for preparing the silicon carbide fiber bundle reinforced aluminum matrix composite material according to claim 4, wherein the method comprises the following steps: the volume ratio of the silicon carbide fiber bundle layer to the aluminum alloy plate layer in the composite material precursor is 3-6.
6. The method for preparing the silicon carbide fiber bundle reinforced aluminum matrix composite material according to claim 1, wherein the method comprises the following steps: the composite material precursor also comprises an oxide layer removal step before vacuum pressure forging; the oxide layer of the composite material precursor is removed in a mode of at least one of polishing removal, strong alkali washing removal and strong acid washing removal.
7. The method for preparing the silicon carbide fiber bundle reinforced aluminum matrix composite material according to claim 1, wherein the method comprises the following steps: the vacuum pressure casting conditions are as follows: vacuum degree < 5 x 10 -3 Pa, the temperature is 660-720 ℃, the pressure is 50-100MPa, the time is 0.5h-1.5h, and the pressure is maintained until the liquid metal is solidified.
8. The method for preparing the silicon carbide fiber bundle reinforced aluminum matrix composite according to claims 1 to 7, wherein the method comprises the following steps: the thickness of the aluminum alloy plate layer is 0.05-0.15 mm, and the aluminum alloy plate layer is at least one of 1 series aluminum alloy, 3 series aluminum alloy and 6 series aluminum alloy.
9. A silicon carbide fiber bundle reinforced aluminum matrix composite is characterized in that: the product obtained by the process of any one of claims 1 to 8.
10. The use of a silicon carbide fiber bundle reinforced aluminum matrix composite as claimed in claim 9, wherein: as an aircraft engine compressor component.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202211457781.8A CN115679228B (en) | 2022-11-21 | 2022-11-21 | Silicon carbide fiber reinforced aluminum-based composite material and preparation method and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202211457781.8A CN115679228B (en) | 2022-11-21 | 2022-11-21 | Silicon carbide fiber reinforced aluminum-based composite material and preparation method and application thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN115679228A true CN115679228A (en) | 2023-02-03 |
CN115679228B CN115679228B (en) | 2024-01-26 |
Family
ID=85053650
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202211457781.8A Active CN115679228B (en) | 2022-11-21 | 2022-11-21 | Silicon carbide fiber reinforced aluminum-based composite material and preparation method and application thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN115679228B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116141774A (en) * | 2023-02-16 | 2023-05-23 | 江苏礼德铝业有限公司 | Aluminum plate with ceramic fibers and manufacturing method thereof |
CN116200687A (en) * | 2023-02-23 | 2023-06-02 | 集美大学 | Transverse fiber reinforced armored aluminum alloy and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107513675A (en) * | 2017-07-31 | 2017-12-26 | 西安科技大学 | A kind of preparation method of silicon carbide fibre beam reinforced aluminum matrix composites |
CN110396652A (en) * | 2019-08-28 | 2019-11-01 | 苏州宏久航空防热材料科技有限公司 | A kind of SiC Fiber Reinforced Al Matrix Composites and preparation method thereof |
CN111636040A (en) * | 2020-06-15 | 2020-09-08 | 南昌航空大学 | 3D reinforced aluminum matrix composite material with controllable structure and preparation method thereof |
CN114921734A (en) * | 2022-05-12 | 2022-08-19 | 厦门大学 | Preparation method of continuous ceramic fiber reinforced aluminum matrix composite |
-
2022
- 2022-11-21 CN CN202211457781.8A patent/CN115679228B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107513675A (en) * | 2017-07-31 | 2017-12-26 | 西安科技大学 | A kind of preparation method of silicon carbide fibre beam reinforced aluminum matrix composites |
CN110396652A (en) * | 2019-08-28 | 2019-11-01 | 苏州宏久航空防热材料科技有限公司 | A kind of SiC Fiber Reinforced Al Matrix Composites and preparation method thereof |
CN111636040A (en) * | 2020-06-15 | 2020-09-08 | 南昌航空大学 | 3D reinforced aluminum matrix composite material with controllable structure and preparation method thereof |
CN114921734A (en) * | 2022-05-12 | 2022-08-19 | 厦门大学 | Preparation method of continuous ceramic fiber reinforced aluminum matrix composite |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116141774A (en) * | 2023-02-16 | 2023-05-23 | 江苏礼德铝业有限公司 | Aluminum plate with ceramic fibers and manufacturing method thereof |
CN116200687A (en) * | 2023-02-23 | 2023-06-02 | 集美大学 | Transverse fiber reinforced armored aluminum alloy and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CN115679228B (en) | 2024-01-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2843371C (en) | Heat dissipating component for semiconductor element | |
Kelly et al. | The principles of the fibre reinforcement of metals | |
CN102286709B (en) | Preparation method of continuous fiber reinforcement metal-based composite material section | |
CN110369709A (en) | A kind of magnesium/aluminium multilayer materials and preparation method thereof | |
US20060024490A1 (en) | Metal matrix composites, and methods for making the same | |
CN115679228B (en) | Silicon carbide fiber reinforced aluminum-based composite material and preparation method and application thereof | |
WO2006023069A1 (en) | Metal matrix composites, and methods for making the same | |
US20060021729A1 (en) | Metal matrix composites, and methods for making the same | |
JPS6147891B2 (en) | ||
CN111560572A (en) | Continuous carbon fiber reinforced magnesium-aluminum bimetal-based composite material and preparation method thereof | |
CN111155038A (en) | Preparation method of chopped carbon fiber reinforced magnesium-based composite material | |
CN114921734B (en) | Preparation method of continuous ceramic fiber reinforced aluminum matrix composite | |
CN113953532A (en) | Heterogeneous multi-layer structure preform and additive-equal material composite manufacturing method thereof | |
Ma et al. | Study on defects of 2D-C f/Al composite prepared by liquid-solid extrusion following vacuum infiltration technique | |
CN109112442B (en) | Multi-scale reinforced low/negative thermal expansion magnesium-based composite material and preparation method thereof | |
CN113817933A (en) | Ceramic reinforced titanium-based composite material, preparation method and application thereof | |
Degischer et al. | Properties of continuous fibre reinforced Al-and Mg-matrix composites produced by gas pressure infiltration | |
CN108866457A (en) | A kind of preparation method of continuous carbon fibre reinforced aluminum matrix composites | |
EP0223081A2 (en) | Method for production of fiber-reinforced metal composite material | |
Cheng et al. | Fabrication of carbon fibre-reinforced aluminium composites with hybridization of a small amount of particulates or whiskers of silicon carbide by pressure casting | |
CN101629272B (en) | Method for preparing continuous-fiber partially-reinforced aluminum alloy parts | |
CN108796400B (en) | A kind of preparation method of continuous carbon fibre enhancing nickel-base composite material | |
CN115725913B (en) | Reinforced aluminum-based composite material and preparation method thereof | |
KR20050058342A (en) | Metal matrix composites, and methods for making the same | |
CN112927956A (en) | Electric contact material and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |