CN115028907B - 矿用工程轮胎胎面胶及其制备方法 - Google Patents
矿用工程轮胎胎面胶及其制备方法 Download PDFInfo
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- CN115028907B CN115028907B CN202210844115.3A CN202210844115A CN115028907B CN 115028907 B CN115028907 B CN 115028907B CN 202210844115 A CN202210844115 A CN 202210844115A CN 115028907 B CN115028907 B CN 115028907B
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- rubber
- parts
- mining engineering
- tread rubber
- engineering tire
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 67
- 239000005060 rubber Substances 0.000 title claims abstract description 67
- 238000005065 mining Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 238000002156 mixing Methods 0.000 claims description 32
- 239000006229 carbon black Substances 0.000 claims description 21
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 20
- 238000007599 discharging Methods 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 12
- 239000004200 microcrystalline wax Substances 0.000 claims description 12
- 238000003825 pressing Methods 0.000 claims description 11
- 230000003712 anti-aging effect Effects 0.000 claims description 10
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 6
- 235000021355 Stearic acid Nutrition 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 6
- 239000008117 stearic acid Substances 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 238000007670 refining Methods 0.000 claims description 4
- 235000014692 zinc oxide Nutrition 0.000 claims description 4
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 3
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims description 3
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 2
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 claims description 2
- 230000002902 bimodal effect Effects 0.000 claims description 2
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical compound O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 19
- 239000000463 material Substances 0.000 abstract description 11
- 229920003052 natural elastomer Polymers 0.000 abstract description 11
- 229920001194 natural rubber Polymers 0.000 abstract description 11
- 238000005520 cutting process Methods 0.000 abstract description 10
- 238000005516 engineering process Methods 0.000 abstract description 10
- 244000043261 Hevea brasiliensis Species 0.000 abstract description 9
- 239000000377 silicon dioxide Substances 0.000 abstract description 7
- 239000002131 composite material Substances 0.000 abstract description 5
- 230000004048 modification Effects 0.000 abstract description 5
- 238000012986 modification Methods 0.000 abstract description 5
- 230000000704 physical effect Effects 0.000 abstract description 5
- 239000000835 fiber Substances 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 229910052814 silicon oxide Inorganic materials 0.000 abstract description 4
- 229920006173 natural rubber latex Polymers 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 19
- 230000020169 heat generation Effects 0.000 description 11
- 230000035882 stress Effects 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- 239000000945 filler Substances 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000010058 rubber compounding Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000004636 vulcanized rubber Substances 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical group C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- ZZMVLMVFYMGSMY-UHFFFAOYSA-N 4-n-(4-methylpentan-2-yl)-1-n-phenylbenzene-1,4-diamine Chemical compound C1=CC(NC(C)CC(C)C)=CC=C1NC1=CC=CC=C1 ZZMVLMVFYMGSMY-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- PBRIXADXGMHVMW-UHFFFAOYSA-N formaldehyde;4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound O=C.CC(C)(C)CC(C)(C)C1=CC=C(O)C=C1 PBRIXADXGMHVMW-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000007777 multifunctional material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
- Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Abstract
Description
物性测试项目 | 实施例1 | 对比例1 | 对比例2 |
拉伸强度/MPa | 28.9 | 23.7 | 26.1 |
100%定伸应力/MPa | 3.2 | 2.4 | 2.7 |
300%定伸应力/MPa | 13.5 | 11.4 | 12.7 |
扯断伸长率/% | 558 | 589 | 577 |
邵氏硬度A/度 | 69 | 66 | 66 |
撕裂强度KN/m | 96 | 82 | 87 |
磨耗/cm3/1.61km | 0.058 | 0.061 | 0.070 |
切割减量/g | 0.075 | 0.074 | 0.083 |
最终疲劳温升/℃ | 32 | 44 | 34 |
60℃Tanδ | 0.1348 | 0.1423 | 0.1353 |
物性测试项目 | 实施例2 | 实施例3 | 对比例3 | 对比例4 |
拉伸强度/MPa | 28.7 | 28.4 | 26.7 | 28.4 |
100%定伸应力/MPa | 2.8 | 3.1 | 2.6 | 2.8 |
300%定伸应力/MPa | 13.2 | 13.3 | 12.8 | 12.5 |
扯断伸长率/% | 563 | 544 | 576 | 582 |
邵氏硬度A/度 | 68 | 69 | 66 | 68 |
撕裂强度KN/m | 94 | 96 | 89 | 90 |
磨耗/cm3/1.61km | 0.057 | 0.050 | 0.066 | 0.072 |
切割减量/g | 0.077 | 0.072 | 0.079 | 0.094 |
最终疲劳温升/℃ | 32 | 30 | 31 | 36 |
60℃Tanδ | 0.1346 | 0.1327 | 0.1351 | 0.1366 |
Claims (8)
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CN202210844115.3A CN115028907B (zh) | 2022-07-18 | 2022-07-18 | 矿用工程轮胎胎面胶及其制备方法 |
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CN202210844115.3A CN115028907B (zh) | 2022-07-18 | 2022-07-18 | 矿用工程轮胎胎面胶及其制备方法 |
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CN115028907A CN115028907A (zh) | 2022-09-09 |
CN115028907B true CN115028907B (zh) | 2023-07-14 |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109054123A (zh) * | 2018-09-26 | 2018-12-21 | 兖矿集团唐村实业有限公司 | 阻燃输送带及其制备方法 |
CN111479865A (zh) * | 2017-12-15 | 2020-07-31 | 株式会社普利司通 | 橡胶组合物、硫化橡胶以及轮胎 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101735492A (zh) * | 2010-01-22 | 2010-06-16 | 中国化工橡胶桂林有限公司 | 工程轮胎胎面胶 |
CN103254472A (zh) * | 2012-02-21 | 2013-08-21 | 北京橡胶工业研究设计院 | 一种全钢载重子午线轮胎胎面胶及使用该胎面胶的轮胎 |
CN102775654B (zh) * | 2012-08-09 | 2014-07-30 | 杭州中策橡胶有限公司 | 液相搅拌混合白炭黑和天然胶的制备方法 |
CN102807689B (zh) * | 2012-08-09 | 2014-09-03 | 杭州中策橡胶有限公司 | 含液相分散白炭黑胶乳混合物的矿山胎胎面胶胶料及其制备方法和应用 |
CN104356444A (zh) * | 2014-11-28 | 2015-02-18 | 山东阳谷华泰化工股份有限公司 | 一种用于轮胎的高耐磨补强材料及其制备方法 |
CN112048110A (zh) * | 2020-09-11 | 2020-12-08 | 青岛联康油脂制品有限公司 | 一种混练胶及其制备方法 |
CN114316401B (zh) * | 2022-01-14 | 2023-09-22 | 泰凯英(青岛)专用轮胎技术研究开发有限公司 | 抗切割低生热的矿用工程轮胎胎面胶及其制备方法 |
CN114605720A (zh) * | 2022-03-10 | 2022-06-10 | 泰凯英(青岛)专用轮胎技术研究开发有限公司 | 矿用工程轮胎胎面胶及其制备方法 |
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- 2022-07-18 CN CN202210844115.3A patent/CN115028907B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111479865A (zh) * | 2017-12-15 | 2020-07-31 | 株式会社普利司通 | 橡胶组合物、硫化橡胶以及轮胎 |
CN109054123A (zh) * | 2018-09-26 | 2018-12-21 | 兖矿集团唐村实业有限公司 | 阻燃输送带及其制备方法 |
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Address after: 266061, 9th and 10th floors, Building 2, No. 6 Keyuan Jingsan Road, Laoshan District, Qingdao City, Shandong Province Patentee after: Taikaiying (Qingdao) special tire technology research and Development Co.,Ltd. Country or region after: China Address before: 266000 room 1901, building 2, Tianbao international business center, 61 Haier Road, Laoshan District, Qingdao City, Shandong Province Patentee before: Taikaiying (Qingdao) special tire technology research and Development Co.,Ltd. Country or region before: China |