CN114929803A - 以压延法制备的具有薄膜的弹性薄膜层压材料 - Google Patents

以压延法制备的具有薄膜的弹性薄膜层压材料 Download PDF

Info

Publication number
CN114929803A
CN114929803A CN202080090411.8A CN202080090411A CN114929803A CN 114929803 A CN114929803 A CN 114929803A CN 202080090411 A CN202080090411 A CN 202080090411A CN 114929803 A CN114929803 A CN 114929803A
Authority
CN
China
Prior art keywords
composition
styrene
elastic film
fabric
equal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202080090411.8A
Other languages
English (en)
Inventor
K·沙阿
C·克鲁兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evant Co
Original Assignee
Evant Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evant Co filed Critical Evant Co
Publication of CN114929803A publication Critical patent/CN114929803A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/156—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is calendered and immediately laminated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10—Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14—Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/06—Interconnection of layers permitting easy separation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B29C43/24—Calendering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/02—2 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/03—3 layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0276—Polyester fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2274/00—Thermoplastic elastomer material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/748—Releasability
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/756—Refurbishable, i.e. marks or scratches can be removed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B32B2437/02—Gloves, shoes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00—Decorative or ornamental articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2479/00—Furniture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2535/00—Medical equipment, e.g. bandage, prostheses, catheter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00—Protective equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

公开了一种通过对组合物(包括聚合物和织物)进行压延来制造弹性薄膜或片材的方法。组合物可以包含聚合物、棉、或两者的组合。压延的组合物可以形成坚韧、柔软的薄膜和片材。薄膜和片材具有使得其适合用作一些PVC薄膜替代品的光学和物理性质。还公开了用于压延的组合物，所述组合物包含织物和聚合物。

Description

以压延法制备的具有薄膜的弹性薄膜层压材料
优先权声明
本申请要求2019年10月27日提交的代理人案卷号为12019014的美国临时专利申请系列号62/926,533的优先权权益，该文通过引用全文纳入本文。
发明领域
本发明涉及以压延法制备的能够与织物层压延的弹性薄膜层压材料。
发明背景
存在对一种材料的需求，所述材料可以替代在窗帘(drapery)或家具织物覆盖物等产品中使用的含聚氯乙烯织物。
发明概述
本发明公开了一种用于压延的组合物，其中，所述组合物具有织物和弹性薄膜组分，所述弹性薄膜组分包含苯乙烯类嵌段共聚物、油和任选的添加剂。在压延加工期间和之后，弹性薄膜与织物相邻。
苯乙烯类嵌段共聚物可以是：苯乙烯-乙烯-丁烯-苯乙烯；苯乙烯-乙烯-丙烯-苯乙烯；苯乙烯-乙烯-乙烯/丙烯-苯乙烯；苯乙烯-异丁烯-苯乙烯；苯乙烯-丁二烯-苯乙烯；苯乙烯-异戊二烯-苯乙烯或其两种或更多种的组合。
组合物的织物可以是棉、聚酯或其两种或更多种的组合。
在一个实施方式中，本发明是由压延的组合物制成的制品。制品可以是服装、鞋袜、家具或家具覆盖物、窗帘或任何其他合适的物体。
本发明还公开了用于制造组合物的方法。
参考以下实施方式，本发明的特征将变得明显。所公开发明的上述各方面所提到的特征存在多种变形。附加特征也可以纳入所公开发明的上述方面中。这些变形和附加特征可单独存在，也可以任何组合的形成存在。例如，本发明所述任一方面所涉及的下文所讨论的各种特征可单独地或以任意组合形式结合到本发明所述的任一方面中。
具体实施方式
发明以下方法以开发并筛选材料，所述材料在压延加工中形成均匀薄膜，具有良好的熔融强度和内聚强度，并转移到织物上而不会在SS辊上发生内聚破坏。
首先，使用薄膜模头(die)在BrabenderTM机器上制备均匀的10密耳(mil)薄膜。然后，将薄膜夹在一侧上的不锈钢板和另一侧上的聚酯或棉织物之间，形成分层组件。接着，分层组件在压制模塑机中在不增加任何压力的情况下预热至300℉60秒，然后在25PSI压力下通过使两个板闭合15秒，在两个板之间进行压制。该方法用于复制压延过程。在一个实施方式中，薄膜可以夹在两个织物层之间，即，织物-薄膜-织物。在一个实施方式中，组合物可以包含在一侧或两侧上具有薄膜的织物。在一个实施方式中，薄膜可以仅在一侧上具有织物。在一个实施方式中，本发明可以用标准压延加工技术制备。
组件随后可以取出，并且在热的时候，通过手拉动织物，以评估弹性薄膜是否从不锈钢板上脱落而没有内聚破坏以及保持与织物的连接，制备良好层压材料。如果薄膜成功地附着在织物上而没有内聚破坏，则意味着薄膜的配方将在压延加工中形成良好的层压材料。该类型实验代表了对弹性薄膜与织物粘合的定性评估，证明了足以防止撕裂的内聚强度。
为了量化上述过程并能够预测其在压延加工中的性能，将组件从压制模塑机中取出后，使组件冷却至室温，然后在InstronTM机中进行90度剥离试验。如果薄膜从不锈钢板上剥离而没有内聚破坏，仍然附着在织物上，并且如果在室温下剥离力低于3lbf，则薄膜材料将在300-400℉的压延过程中与不锈钢辊分离而没有内聚破坏，并在压延加工中形成良好的层压材料。然而，如果剥离力在室温下大于4lbf，则其表示内聚破坏和不良的熔体强度。3至4lbf的剥离力范围似乎是临界情况，根据其他标准，薄膜表现出良好的内聚强度。
测量弹性配方在190℃和230℃下的熔融指数，以确定组件的物理性能。如果190℃的熔融指数低于4克/10分钟，230℃的熔融指数低于35克/10分钟，则弹性配方显示出非常好的内聚强度。另一方面，如果190℃的熔融指数高于5克/10分钟，230℃的熔融指数高于39克/10分钟，则弹性配方显示出不良的熔体强度和内聚强度。
同样，4-5克/10分钟的190℃下的熔融指数范围和35-39克/10分钟的230℃下的熔融指数范围似乎是临界情况。总之，如果弹性薄膜配方190℃下的熔融指数小于190℃下4克/10分钟，230℃的熔融指数小于35克/10分钟，则该配方将制成一种薄膜，所述薄膜显示出在室温下与不锈钢板的剥离力低于3lbf，并将保持与织物的粘合。
另一方面，如果弹性薄膜配方190℃下的熔融指数大于190℃下5克/10分钟，230℃的熔融指数大于39克/10分钟，则该配方将制成一种薄膜，所述薄膜显示出大于4lbf的剥离强度，并将具有不良的内聚强度。190℃下为4-5克/10分钟且230℃下为35-39克/10分钟的熔融指数范围似乎更好一些，此时，由该配方制成的薄膜将显示出3-4lbf的剥离力，并且有时会从不锈钢辊上干净地剥离，有时会因内聚破坏而剥离。
如果薄膜由符合以下标准的弹性配方制成，则薄膜将从300-400℉的不锈钢辊上干净剥离，并干净地转移到织物上，而不会在压延加工中发生内聚破坏：(1)190℃的熔融指数低于4克/10分钟；(2)230℃的熔融指数低于35克/10分钟；和(3)室温下与不锈钢板的剥离力为0-3lbf。
如果薄膜由符合以下标准的弹性配方制成，则薄膜将显示出用300-400℉的不锈钢辊会发生内聚破坏，并不均匀地转移到织物上，并且在压延加工中发生内聚破坏和熔体断裂：(1)190℃的熔融指数高于5克/10分钟；(2)230℃的熔融指数高于39克/10分钟；和(3)室温下与不锈钢板的剥离力大于4lbf。
如果薄膜由符合以下标准的弹性配方制成，则薄膜有时从300-400℉的不锈钢辊上干净剥离，并有时干净地转移到织物上，而不会在压延加工中发生内聚破坏：(1)190℃的熔融指数为4-5克/10分钟；(2)230℃的熔融指数为35-39克/10分钟；和(3)室温下与不锈钢板的剥离力为3-4lbf。
本发明的弹性薄膜部分可以包含聚合物、油和任选的添加剂。
合适的聚合物包括不同于热塑性聚氨酯的热塑性弹性体，例如苯乙烯类嵌段共聚物、热塑性硫化橡胶、聚烯烃弹性体、共聚酯及其组合。
合适的苯乙烯类嵌段共聚物的非限制性示例包括苯乙烯-乙烯/丁烯-苯乙烯(SEBS)、苯乙烯-乙烯/丙烯-苯乙烯(SEPS)、苯乙烯-乙烯/乙烯/丙烯-苯乙烯(SEEPS)、苯乙烯-异丁烯-苯乙烯(SIBS)、苯乙烯-丁二烯-苯乙烯(SBS)、苯乙烯-异戊二烯-苯乙烯(SIS)，及其组合。
合适的共聚物的非限制性示例包括嵌段共聚物，其包括重复的脂肪族聚醚或脂肪族聚酯的软链段和芳族聚酯的硬链段。
聚合物可以任意合适量存在，包括但不限于：约25重量％至约75重量％；约30重量％至约70重量％；约35重量％至约65重量％；约40重量％至约60重量％；和约45重量％至约55重量％。
可以使用任意合适的油，例如，矿物油、植物油、合成油。油组分的具体示例在下文的实施例部分中进行详述。
油可以任意合适量存在，包括但不限于：约20重量％至约35重量％；约25重量％至约30重量％；和约27重量％至约29重量％。
合适的任选的添加剂包括常规或市售可得的塑料添加剂。热塑性配混领域的技术人员无需过多的实验就可以由可获得的参考文件选择合适的添加剂，所述参考文件为例如E.W.Flick，塑料设计库(Plastics Design Library)的《塑料添加剂数据库(PlasticsAdditives Database)》(Elsevier 2004)。
可以足以为组合物的弹性薄膜部分和/或由其模塑的制品提供所需加工特性或性能特性的任意量使用任选的添加剂。该量不应造成添加剂的浪费，也不应对弹性薄膜和/或由其模塑的制品的加工或性能不利。
任选的添加剂的非限制性示例包括：粘合促进剂；抗雾化剂；抗氧化剂；抗静电剂；杀生物剂(抗菌剂、杀真菌剂和防霉剂)；着色剂，包括颜料和染料；分散剂；填料和增量剂；防火剂、阻燃剂和烟雾抑制剂；硬度调节剂；抗冲改性剂；引发剂；润滑剂；云母；脱模剂；油和增塑剂；加工助剂；二次聚合物；硅烷类、钛酸盐/酯和锆酸盐/酯；滑爽剂和抗粘连剂；稳定剂；硬脂酸酯/盐；紫外光吸收剂；粘度调节剂；和蜡。
在一些实施方式中，弹性薄膜还包含如下物质中的一种或多种：抗氧化剂和稳定剂；着色剂；脱模剂；紫外光吸收剂；和它们的组合。
任选的增塑剂
增塑剂可被用于例如调节柔软度和/或改进聚合物配混物的流动性质或者其他性质。
任何常规的能对苯乙烯类嵌段共聚物进行增塑的油(例如矿物油、植物油、合成油等)均能用于本发明。市售的油的实例包括：购自加拿大石油公司(Petro-Canada)的PURETOL 380品牌的油；和购自埃克森美孚公司(ExxonMobil)的PRIMOL 382品牌的油。
制造弹性薄膜组合物的方法和加工
一旦选择了合适的成分，所公开发明的聚合物配混物的制备并不复杂。配混物可以间歇或连续操作的方式进行制备。
以连续工艺进行的混合通常在挤出机中进行，该挤出机的温度升高到足以使聚合物基质熔化的程度，且在进料喉处、或通过下游的注射或侧进料器添加所有的添加剂。挤出机速度范围可为约200至约700转/分钟(rpm)，例如为约250rpm至约350rpm。通常，挤出机的输出物进行造粒，以供稍后加工成热塑性制品。
加工技术见述于可获得的参考文献，例如Dominick V.Rosato等人，《塑料设计手册》(Plastics Design Handbook)(施普林格出版公司(Springer)2013)。
在一些实施方式中，所公开发明的热塑性弹性体配混物通过注塑工艺模塑成热塑性制品。
本发明的其它方面涉及通过压延工艺制备的压延制品。
本发明的实用性
本发明的组合物可用于制造任何类型的织物应用，包括需要抵抗来自食物、饮料、油、污垢、清洁剂和其他相关物品的染色和损坏的织物应用。
所公开发明的压延组合物具有用于多种不同工业领域中的各种应用的潜力，包括但不限于：家居装饰；家具；服装和鞋袜；汽车和运输；消费品；电子设备；保健和医疗；家用电器；和获益于其独特性质组合的其它工业领域或应用。
在一些实施方式中，本发明的组合物尤其可用于制造窗帘、家具、汽车座椅用织物覆盖物以及衣物和鞋袜。
实施例
提供所公开发明的多种实施方式的非限制性实施例。
表1.实施例的配方
Figure BDA0003713192890000061
表2.实施例的配方
Figure BDA0003713192890000062
表3.实施例的配方
Figure BDA0003713192890000071
表4.实施例的配方
Figure BDA0003713192890000072
表5.实施例的配方
Figure BDA0003713192890000081
表6.实施例的配方
Figure BDA0003713192890000082
表7.实施例的配方
Figure BDA0003713192890000091
表8.实施例的配方
Figure BDA0003713192890000092
表9.实施例的配方
Figure BDA0003713192890000101
表10.实施例的配方
Figure BDA0003713192890000102
表11.实施例的配方
Figure BDA0003713192890000111
表12.实施例的配方
Figure BDA0003713192890000112
表13.成分
原料 成分类型
100粘度USP白油 油
380粘度白油 油
Dowlex 2035NT 聚乙烯树脂
Drakeol 34 矿物油
Epolene C10 低密度聚乙烯均聚物
Formolene 1102KR 聚丙烯均聚物
Irgafos 168 加工助剂
Irganox 1010 稳定剂
kemamide E Ultra 润滑剂
Kemamide U粉末 润滑剂
Kraton A1536 SEBS聚合物
Kraton FG1901X-1000-05 SEBS聚合物
Kraton G1650 SEBS聚合物
Kraton G1652 SEBS聚合物
Kraton G1657 SEBS聚合物
PC90083 UV稳定剂
Piccolastic D-125 烃树脂
Pinnacle 5112C3 聚丙烯共聚物
Plastolyn 290 烃树脂
聚苯乙烯EA3400 聚苯乙烯
聚苯乙烯MB3150 聚苯乙烯
Regalrez 1126 烃树脂
Skypel G140D 热塑性聚酯弹性体
UV 62琥珀酸盐 UV吸收剂
表14.剥离测试结果
Figure BDA0003713192890000131
表15.肖氏A硬度
实施例 肖氏A硬度
A 57
B 55
C 47
D 54
E 64
F 54
AA 48
BA 46
CA 58
DA 56
EA 46
FA 42
GA 37
GB 51.67
AC 49.37
BC 49.1
CC 57.45
DC 56.22
EC 52.92
FC 53.77
GC 53.9
AD 34
AE 48.56
BE 48.56
AF 50
CF 50
AG 49.37
无需过多的实验，本领域普通技术人员可以利用包括实施例在内的说明书来制造和使用所公开发明的各个方面。
除非另有说明，否则本发明实施方式中涉及的所有文献通过引用整体结合到本文中。任何文献的引用并不构成承认其是相对所公开发明的现有技术。
虽然说明并描述了所公开发明的具体实施方式，但是对于本领域技术人员显而易见的是，在不偏离本发明的精神和范围下可以进行各种其他变化和修改。所附权利要求书意在覆盖在所公开发明范围内所有这样的改变和修改。

Claims (16)

1.一种用于压延的组合物，所述组合物包括：
(a)弹性薄膜，所述弹性薄膜包括：
苯乙烯类嵌段共聚物；
油；
和
任选的添加剂；
(b)织物；
其中，弹性薄膜定位为与织物相邻。
2.如权利要求1所述的组合物，其中，所述苯乙烯类嵌段共聚物选自下组：苯乙烯-乙烯-丁烯-苯乙烯；苯乙烯-乙烯-丙烯-苯乙烯；苯乙烯-乙烯-乙烯/丙烯-苯乙烯；苯乙烯-异丁烯-苯乙烯；苯乙烯-丁二烯-苯乙烯；苯乙烯-异戊二烯-苯乙烯或它们的组合。
3.如权利要求1-2中任一项所述的组合物，其中，织物选自下组：棉、聚酯或它们的组合。
4.如权利要求1-3中任一项所述的组合物，其中，弹性薄膜还包含大于或等于25重量％且小于或等于75重量％的苯乙烯类嵌段共聚物。
5.如权利要求1-4中任一项所述的组合物，其中，弹性薄膜还包含大于或等于40重量％且小于或等于70重量％的苯乙烯类嵌段共聚物。
6.如权利要求1-5中任一项所述的组合物，其中，弹性薄膜还包含大于或等于20重量％且小于或等于35重量％的油。
7.如权利要求1-6中任一项所述的组合物，其中，弹性薄膜还包含大于或等于25重量％且小于或等于30重量％的油。
8.如权利要求1-7中任一项所述的组合物，其中，弹性薄膜位于第一织物和第二织物之间且与第一织物和第二织物相邻。
9.如权利要求8所述的组合物，其中，第一织物包含第一材料，并且第二织物包含第二材料。
10.如权利要求9所述的组合物，其中，第一材料与第二材料相同。
11.如权利要求9所述的组合物，其中，第一材料不同于第二材料。
12.如权利要求1-11中任一项所述的组合物，其中，弹性薄膜在190℃的熔融指数低于4克/10分钟。
13.如权利要求1-11中任一项所述的组合物，其中，弹性薄膜在230℃的熔融指数为约35-39克/10分钟。
14.如权利要求1-13中任一项所述的组合物，其中，室温下弹性薄膜离开不锈钢板的剥离力为约0-3lbf。
15.一种包含如权利要求1所述的组合物的制品，其中，所述制品选自下组：服装、鞋袜、家具和窗帘。
16.一种用于制造组合物的方法，所述方法包括以下步骤：
制备包含苯乙烯类嵌段共聚物、油和任选的添加剂的弹性薄膜组合物，其中，弹性薄膜具有第一侧和相反的第二侧；
将弹性薄膜组合物夹在第一侧上的第一不锈钢板和第二侧上的织物之间，以产生分层组件；
对分层组件进行预热；
在第一不锈钢板和第二不锈钢板之间压制分层组件；以及
从不锈钢板中取出织物和弹性薄膜组件。
CN202080090411.8A 2019-10-27 2020-10-26 以压延法制备的具有薄膜的弹性薄膜层压材料 Pending CN114929803A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962926533P 2019-10-27 2019-10-27
US62/926,533 2019-10-27
PCT/US2020/057326 WO2021086779A1 (en) 2019-10-27 2020-10-26 Elastic film laminates with film made in a calendaring process

Publications (1)

Publication Number Publication Date
CN114929803A true CN114929803A (zh) 2022-08-19

Family

ID=75716241

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080090411.8A Pending CN114929803A (zh) 2019-10-27 2020-10-26 以压延法制备的具有薄膜的弹性薄膜层压材料

Country Status (4)

Country Link
US (1) US20220379595A1 (zh)
EP (1) EP4048733A4 (zh)
CN (1) CN114929803A (zh)
WO (1) WO2021086779A1 (zh)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050214461A1 (en) * 2004-03-29 2005-09-29 The Procter & Gamble Company Method of gravure printing elastomeric compositions
CN101432356A (zh) * 2004-08-13 2009-05-13 埃克森美孚化学专利公司 聚合物组合物，包括它们的用途和制备方法
US20120238162A1 (en) * 2007-01-25 2012-09-20 Clopay Plastic Products Company, Inc. Elastomeric laminate materials that do not require mechanical activation

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USH2096H1 (en) * 1993-02-03 2004-01-06 Exxon Chemical Patents, I Thermoplastic elastomer copolymer films
CA2161712A1 (en) * 1994-11-03 1996-05-04 Ketan N. Shah Silane modified elastomeric compositions and articles made therefrom
US5882770A (en) * 1996-12-31 1999-03-16 Makansi; Munzer Rainbow and hologram images on fabrics
CN100420713C (zh) * 2003-05-14 2008-09-24 陶氏环球技术公司 嵌段共聚合组成物及以其所制造的透明弹性体
US8182456B2 (en) * 2004-03-29 2012-05-22 The Procter & Gamble Company Disposable absorbent articles with components having both plastic and elastic properties
US7612001B2 (en) * 2004-12-22 2009-11-03 Kimberly-Clark Worldwide, Inc. High performance elastic materials made using styrene block copolymers and mixtures
US20060246804A1 (en) * 2005-04-29 2006-11-02 Thomas Oomman P Elastomeric materials
DE102009014249B4 (de) * 2009-03-20 2012-12-27 Smartrac Ip B.V. Mehrschichtige thermoplastische laminierte Folienanordnung sowie Vorrichtung und Verfahren zum Laminieren
EP2415836B1 (en) * 2009-03-31 2014-08-20 Zeon Corporation Composition for stretchable film
TW201412547A (zh) * 2012-09-11 2014-04-01 Kraton Polymers Us Llc 具有增進散熱的織物及其他基材
EP3615610B1 (en) * 2017-04-25 2022-06-01 Avient Corporation Thermoplastic elastomer compounds exhibiting improved stain resistance
US11512191B2 (en) * 2017-11-10 2022-11-29 Avient Corporation Polyolefin elastomer blends for elastomeric films

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050214461A1 (en) * 2004-03-29 2005-09-29 The Procter & Gamble Company Method of gravure printing elastomeric compositions
CN101432356A (zh) * 2004-08-13 2009-05-13 埃克森美孚化学专利公司 聚合物组合物，包括它们的用途和制备方法
US20120238162A1 (en) * 2007-01-25 2012-09-20 Clopay Plastic Products Company, Inc. Elastomeric laminate materials that do not require mechanical activation

Also Published As

Publication number Publication date
US20220379595A1 (en) 2022-12-01
WO2021086779A1 (en) 2021-05-06
EP4048733A4 (en) 2023-11-15
EP4048733A1 (en) 2022-08-31

Similar Documents

Publication Publication Date Title
EP0347794B1 (en) Thermoplastic resinous composition
US20100331465A1 (en) Tpe composition having good clarity and low hardness and articles formed therefrom
TW408154B (en) Nonflammable polyolefin thermoplastic elastomer composition for use in skins of automotive internal trim and the laminated thin sheet using the same
CN103261288A (zh) 包含可再生的淀粉聚合物的弹性膜
EP2714813B1 (en) Thermoplastic elastomer compounds exhibiting shape memory via thermo-mechanical action
US20110082225A1 (en) Thermoplastic elastomers exhibiting superior abrasion resistance properties
JP5933141B1 (ja) 熱可塑性エラストマー組成物および成形品
CN110573575A (zh) 呈现出透明度的阻尼热塑性弹性体掺混物
JP2006282683A (ja) 伸縮性フィルム
CN114929803A (zh) 以压延法制备的具有薄膜的弹性薄膜层压材料
CN111344347A (zh) 用于弹性薄膜的聚烯烃弹性体掺混物
WO2003089512A1 (fr) Composition elastomere thermoplastique, feuilles et lamines correspondants
JP2017095637A (ja) 変形回復性耐熱構造体用ポリプロピレン系樹脂組成物および変形回復性耐熱構造体
JP3700515B2 (ja) 熱可塑性エラストマー組成物
CN113785011A (zh) 热塑性弹性体凝胶
JP6485140B2 (ja) 変形回復性耐熱構造体用プロピレン系樹脂組成物および変形回復性耐熱構造体
JP2021116380A (ja) 樹脂組成物、成形体及び積層体
JP3851239B2 (ja) 塩化ビニル系重合体組成物
JP4533483B2 (ja) 熱可塑性樹脂組成物
JP2022018570A (ja) シート部材
JP6591921B2 (ja) 熱可塑性エラストマー組成物
JP4075579B2 (ja) スチレン系熱可塑性エラストマー表皮シート
JP6553740B2 (ja) 複合成形体用熱可塑性エラストマー組成物及び複合成形体
JPH04164903A (ja) エチレン酢酸ビニルコポリマー変性物の製造方法
JP4905945B2 (ja) 熱可塑性エラストマー組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination