CN114713239B - 一种用于油品加氢的催化剂级配方法 - Google Patents
一种用于油品加氢的催化剂级配方法 Download PDFInfo
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- CN114713239B CN114713239B CN202011526433.2A CN202011526433A CN114713239B CN 114713239 B CN114713239 B CN 114713239B CN 202011526433 A CN202011526433 A CN 202011526433A CN 114713239 B CN114713239 B CN 114713239B
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- 239000003054 catalyst Substances 0.000 title claims abstract description 263
- 238000005984 hydrogenation reaction Methods 0.000 title claims abstract description 158
- 238000000034 method Methods 0.000 title claims abstract description 48
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- 239000011800 void material Substances 0.000 claims abstract description 47
- 238000011049 filling Methods 0.000 claims abstract description 29
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- 239000000126 substance Substances 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims description 20
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- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 9
- 238000000151 deposition Methods 0.000 claims description 8
- 238000006477 desulfuration reaction Methods 0.000 claims description 7
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 4
- 239000005977 Ethylene Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
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- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 229910017604 nitric acid Inorganic materials 0.000 description 6
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- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
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- 229910000476 molybdenum oxide Inorganic materials 0.000 description 4
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- 230000000274 adsorptive effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- -1 residuum Substances 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 2
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- 125000003118 aryl group Chemical group 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 2
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- 229910052731 fluorine Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
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- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- 239000004484 Briquette Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
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Classifications
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- B01J37/088—Decomposition of a metal salt
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- C—CHEMISTRY; METALLURGY
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- C—CHEMISTRY; METALLURGY
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- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
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CN202011526433.2A CN114713239B (zh) | 2020-12-22 | 2020-12-22 | 一种用于油品加氢的催化剂级配方法 |
CN202180072421.3A CN116601271A (zh) | 2020-12-22 | 2021-12-15 | 固体颗粒床、固定床和油品加氢方法 |
KR1020237022232A KR20230124939A (ko) | 2020-12-22 | 2021-12-15 | 고체 입자층, 고정층 및 오일 수소화 방법 |
US18/247,773 US20230348797A1 (en) | 2020-12-22 | 2021-12-15 | Solid particle bed, fixed bed, and oil hydrogenation method |
PCT/CN2021/138368 WO2022135235A1 (zh) | 2020-12-22 | 2021-12-15 | 固体颗粒床、固定床和油品加氢方法 |
CA3201684A CA3201684A1 (en) | 2020-12-22 | 2021-12-15 | Solid particle bed, fixed bed, and oil hydrogenation method |
EP21909231.9A EP4268948A1 (en) | 2020-12-22 | 2021-12-15 | Solid particle bed, fixed bed, and oil hydrogenation method |
TW110148054A TW202235151A (zh) | 2020-12-22 | 2021-12-22 | 固體顆粒床、固定床和油品加氫方法 |
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WO1999020384A1 (en) * | 1997-10-21 | 1999-04-29 | Mobil Oil Corporation | Multiple catalyst bed radial flow reactor |
CN103805241A (zh) * | 2012-11-07 | 2014-05-21 | 中国石油化工股份有限公司 | 一种重油加氢处理催化剂级配组合方法 |
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GB9922940D0 (en) * | 1999-09-29 | 1999-12-01 | Ici Plc | Catalytic reactor |
US20100152507A1 (en) * | 2008-12-16 | 2010-06-17 | Gajda Gregory J | Process for Using Layered Sphere Catalysts with High Accessibility Indexes |
US10537867B2 (en) * | 2018-01-04 | 2020-01-21 | Chevron Phillips Chemical Company Lp | Optimized reactor configuration for optimal performance of the aromax catalyst for aromatics synthesis |
EP3983118B1 (en) * | 2019-06-13 | 2023-10-11 | Duke Technologies, LLC | Hydroprocessing reactor to lower pressure drop and extend catalyst life |
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WO1999020384A1 (en) * | 1997-10-21 | 1999-04-29 | Mobil Oil Corporation | Multiple catalyst bed radial flow reactor |
CN103805241A (zh) * | 2012-11-07 | 2014-05-21 | 中国石油化工股份有限公司 | 一种重油加氢处理催化剂级配组合方法 |
GB201406931D0 (en) * | 2013-05-10 | 2014-06-04 | Johnson Matthey Plc | Reactor |
FR3033264A1 (fr) * | 2015-03-05 | 2016-09-09 | Ifp Energies Now | Reacteur radial a lits catalytiques fixes |
CN110732297A (zh) * | 2018-07-19 | 2020-01-31 | 中国石油化工股份有限公司 | 用于向微通道反应器中加载微粒的***和方法 |
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