CN114525178A - Oxygen-increasing phosphorus-free concentrated cleaning solution and preparation method thereof - Google Patents
Oxygen-increasing phosphorus-free concentrated cleaning solution and preparation method thereof Download PDFInfo
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- CN114525178A CN114525178A CN202210096359.8A CN202210096359A CN114525178A CN 114525178 A CN114525178 A CN 114525178A CN 202210096359 A CN202210096359 A CN 202210096359A CN 114525178 A CN114525178 A CN 114525178A
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- citric acid
- sodium
- water
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- 238000002360 preparation method Methods 0.000 title abstract description 17
- 238000004140 cleaning Methods 0.000 title abstract description 7
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 100
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims abstract description 72
- 229940045872 sodium percarbonate Drugs 0.000 claims abstract description 72
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910001868 water Inorganic materials 0.000 claims abstract description 61
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 50
- 150000004996 alkyl benzenes Chemical class 0.000 claims abstract description 29
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 28
- 239000011734 sodium Substances 0.000 claims abstract description 28
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 27
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 27
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 24
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229960002303 citric acid monohydrate Drugs 0.000 claims abstract description 19
- 239000013543 active substance Substances 0.000 claims abstract description 16
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 14
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 14
- 238000006213 oxygenation reaction Methods 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 13
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 156
- 238000003756 stirring Methods 0.000 claims description 63
- 229960004106 citric acid Drugs 0.000 claims description 52
- 238000005406 washing Methods 0.000 claims description 38
- 230000001105 regulatory effect Effects 0.000 claims description 24
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 22
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 21
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 21
- 235000011152 sodium sulphate Nutrition 0.000 claims description 21
- 239000007788 liquid Substances 0.000 claims description 18
- 229960001617 ethyl hydroxybenzoate Drugs 0.000 claims description 13
- 239000004403 ethyl p-hydroxybenzoate Substances 0.000 claims description 13
- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims description 13
- NUVBSKCKDOMJSU-UHFFFAOYSA-N ethylparaben Chemical group CCOC(=O)C1=CC=C(O)C=C1 NUVBSKCKDOMJSU-UHFFFAOYSA-N 0.000 claims description 13
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 229940093956 potassium carbonate Drugs 0.000 claims description 12
- 230000003068 static effect Effects 0.000 claims description 12
- 238000005303 weighing Methods 0.000 claims description 12
- 125000004442 acylamino group Chemical group 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 239000002304 perfume Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- 208000027418 Wounds and injury Diseases 0.000 abstract 1
- 230000006378 damage Effects 0.000 abstract 1
- 208000014674 injury Diseases 0.000 abstract 1
- 239000003599 detergent Substances 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 238000005202 decontamination Methods 0.000 description 4
- 230000003588 decontaminative effect Effects 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0094—Process for making liquid detergent compositions, e.g. slurries, pastes or gels
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to an oxygenation phosphorus-free concentrated cleaning solution and a preparation method thereof, wherein the oxygenation phosphorus-free concentrated cleaning solution comprises the following raw materials in parts by weight: 5-7.5 parts of sodium percarbonate, 3-5 parts of potassium carbonate, 2-8 parts of citric acid monohydrate, 30-37 parts of active substances, 0.2-0.3 part of odor removing agent and 0.1-0.2 part of antioxidant, wherein the active substances are prepared from the following components in parts by weight: 10-12 parts of sodium fatty alcohol-polyoxyethylene ether sulfate, 15-17 parts of linear alkyl benzene sulfonate, 3-5 parts of sodium dodecyl sulfate, 2-3 parts of cocoamido and the balance of water, and has the advantages of high production speed, good cleaning effect and no injury to hands.
Description
Technical Field
The invention relates to the technical field of detergents, in particular to an oxygenation phosphorus-free concentrated washing liquid and a preparation method thereof.
Background
Sodium percarbonate (sodium percarbonate or SPC for short) is a compound of soda ash and hydrogen peroxide, and generates oxygen, water and sodium carbonate after decomposition. The sodium percarbonate is very suitable to be added into a detergent as a bleaching auxiliary agent, can be quickly decomposed at normal temperature to release active oxygen, thereby realizing the functions of decontamination, bleaching, disinfection and sterilization, and the washed fabric does not generate peculiar smell even if dried in the shade indoors.
Because the sodium percarbonate has high-efficiency washing capacity, the oxygen-containing detergent added with the sodium percarbonate can greatly improve the active ingredients of the detergent, can effectively remove fruit stains, wine stains, yellow dirt spots and the like which cannot be removed by common washing powder, and can effectively reduce the dosage of the detergent and achieve the effects of saving energy and reducing consumption. The sodium percarbonate is an environment-friendly new material while having excellent functional characteristics, and decomposition products of the sodium percarbonate, namely oxygen, water and sodium carbonate, are naturally-occurring substances and have no adverse effect on the environment. Therefore, sodium percarbonate is an efficient, energy-saving and environment-friendly oxygen bleaching auxiliary agent, accords with the development trend of modern detergents, and is widely applied in the washing industry, but the existing sodium percarbonate is mostly used for solid detergents because the sodium percarbonate is very slow in dissolving speed in water and difficult to add into liquid detergents, carbonate also has strong cleaning capacity, and the carbonate is slow in dissolving speed like sodium percarbonate and cannot adapt to industrial rapid production, and hydrogen peroxide generated by dissolving sodium percarbonate in water is corrosive, so that consumers cannot avoid hurting hands when using the sodium percarbonate.
Disclosure of Invention
In order to overcome the technical defects in the prior art, the invention provides the oxygen-increasing phosphorus-free concentrated cleaning solution and the preparation method thereof, the production speed is high, and the hands are not hurt during washing.
The technical solution adopted by the invention is as follows:
the oxygenation phosphorus-free concentrated washing liquid is characterized by comprising the following raw materials in parts by weight: 5-7.5 parts of sodium percarbonate, 3-5 parts of potassium carbonate, 2-8 parts of citric acid monohydrate, 30-37 parts of active substances, 0.2-0.3 part of odor removing agent, 0.1-0.2 part of antioxidant and the balance of water.
Preferably, the active substance is prepared from the following components in parts by weight: 10-12 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 15-17 parts of linear alkyl benzene sulfonate, 3-5 parts of lauryl sodium sulfate and 2-3 parts of coconut oil acylamino.
Preferably, the odor removing agent is a perfume.
Preferably, the antioxidant is ethylparaben.
Preferably, the special detergent comprises 5 parts of sodium percarbonate, 3 parts of potassium carbonate, 2 parts of citric acid monohydrate, 30 parts of active matters, 0.2 part of odor removing agent, 0.1 part of antioxidant and the balance of water.
Preferably, the deodorant comprises 4 parts of sodium percarbonate, 4 parts of potassium carbonate, 5 parts of citric acid monohydrate, 35 parts of active matter, 0.2 part of odor removing agent, 0.1 part of antioxidant and the balance of water.
Preferably, the special detergent comprises 5 parts of sodium percarbonate, 6 parts of potassium carbonate, 8 parts of citric acid monohydrate, 37 parts of active matter, 0.3 part of odor removing agent, 0.2 part of antioxidant and the balance of water.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 13-15 revolutions per minute, adding 7KG-9KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotating speed to 2-5 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 12-14 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
The invention has the beneficial effects that:
the product executes the national advocated environment-friendly phosphorus-free polyester product, adopts a cold preparation method in the whole production process, does not form heat energy emission, is mild, does not hurt skin and fabrics, enhances the decontamination effect of active substances, concentrates, saves package and transportation, and realizes energy conservation and emission reduction.
Specifically, firstly, potassium carbonate is dissolved in citric acid, the citric acid can effectively accelerate the dissolving speed of the potassium carbonate and can effectively neutralize the alkalinity of the potassium carbonate, so that the concentration of an effective decontamination component, namely carbonate, in the solution is increased rapidly, and the solution has low viscosity at the moment, a large amount of carbon dioxide generated by the reaction of the potassium carbonate and the citric acid can be discharged effectively and rapidly, so that the production speed is further accelerated, and the potassium carbonate has stronger water-soluble capacity than the traditional sodium carbonate, is not easy to separate out crystals when the temperature is reduced, and has stronger frost resistance of the product.
And then adding the sodium percarbonate into the solution containing the citric acid, decomposing the sodium percarbonate to generate a large amount of hydrogen peroxide and oxygen, wherein the solution has low viscosity, part of the oxygen is released in stirring, and the rest of the oxygen becomes active oxygen dissolved in water. So that the dissolution of the sodium percarbonate and the potassium carbonate meets the requirement of industrial rapid production.
Therefore, the solution A is poured into another barrel, and the components such as the fatty alcohol-polyoxyethylene ether sodium sulfate and the like are added into the solution A, so that the surfactant is prevented from being mixed into the barrel for originally preparing the solution A, and if the surfactant is mixed into the barrel for preparing the solution A, bubbles generated during the reaction for preparing the solution A are difficult to quickly discharge in the next round of production, and the solution is quickly overflowed.
The components used in the invention are as follows:
sodium percarbonate: decontamination, disinfection and sterilization.
Potassium carbonate: and (5) descaling and decontaminating.
Citric acid monohydrate, neutralizes alkalinity, shortens the dissolution time and reduces corrosivity.
Sodium fatty alcohol-polyoxyethylene ether sulfate, linear alkyl benzene sulfonate, sodium dodecyl sulfate and cocamide group are used as active substances.
Ethylparaben is an antioxidant.
Essence is added.
The specific gravity of the rest water is adjusted according to the consistency requirements of different products.
Detailed Description
The invention is further illustrated below:
example 1:
the embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 5 parts of sodium percarbonate, 3 parts of potassium carbonate, 2 parts of citric acid monohydrate, 30 parts of active substances, 0.2 part of essence, 0.1 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 10 parts of sodium fatty alcohol-polyoxyethylene ether sulfate, 15 parts of linear alkyl benzene sulfonate, 3 parts of lauryl sodium sulfate and 2 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 13 revolutions per minute, adding 7KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotation speed to 2 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 12 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 2
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 5 parts of sodium percarbonate, 3 parts of potassium carbonate, 3 parts of citric acid monohydrate, 31 parts of active substances, 0.2 part of essence, 0.1 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 10 parts of sodium fatty alcohol-polyoxyethylene ether sulfate, 15 parts of linear alkyl benzene sulfonate, 3 parts of lauryl sodium sulfate and 2 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 13 revolutions per minute, adding 7KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotation speed to 2 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 12 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 3
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 5 parts of sodium percarbonate, 3 parts of potassium carbonate, 4 parts of citric acid monohydrate, 32 parts of active substances, 0.2 part of essence, 0.1 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 10 parts of sodium fatty alcohol-polyoxyethylene ether sulfate, 15 parts of linear alkyl benzene sulfonate, 3 parts of lauryl sodium sulfate and 2 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 13 revolutions per minute, adding 7KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotation speed to 2 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 12 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 4
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 5 parts of sodium percarbonate, 4 parts of potassium carbonate, 5 parts of citric acid monohydrate, 33 parts of active substances, 0.2 part of essence, 0.1 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 10 parts of sodium fatty alcohol-polyoxyethylene ether sulfate, 15 parts of linear alkyl benzene sulfonate, 3 parts of lauryl sodium sulfate and 2 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 13 revolutions per minute, adding 7KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotation speed to 2 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 12 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 5
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 5 parts of sodium percarbonate, 4 parts of potassium carbonate, 5 parts of citric acid monohydrate, 34 parts of active substances, 0.2 part of essence, 0.1 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 11 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 16 parts of linear alkyl benzene sulfonate, 4 parts of lauryl sodium sulfate and 2.5 parts of cocoamido.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 14 revolutions per minute, adding 8KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotation speed to 4 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding the fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 13 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from S5 into linear alkyl benzene sodium sulfonate, and stirring until the solution B is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 6
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 5.5 parts of sodium percarbonate, 5 parts of potassium carbonate, 6 parts of citric acid monohydrate, 35 parts of active substances, 0.2 part of essence, 0.1 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 11 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 16 parts of linear alkyl benzene sulfonate, 4 parts of lauryl sodium sulfate and 2.5 parts of cocoamido.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 14 revolutions per minute, adding 8KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotation speed to 4 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 13 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 7
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 6 parts of sodium percarbonate, 5 parts of potassium carbonate, 7 parts of citric acid monohydrate, 36 parts of active substances, 0.3 part of essence, 0.2 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 12 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 16 parts of linear alkyl benzene sulfonate, 4 parts of lauryl sodium sulfate and 2.5 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 15 revolutions per minute, adding 9KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotating speed to 5 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 14 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from S5 into linear alkyl benzene sodium sulfonate, and stirring until the solution B is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Example 8
The embodiment provides an oxygen-increasing phosphorus-free concentrated washing solution, which comprises the following raw materials in parts by weight: 7.5 parts of sodium percarbonate, 5 parts of potassium carbonate, 8 parts of citric acid monohydrate, 37 parts of active matter, 0.3 part of essence, 0.2 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 12 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 17 parts of linear alkyl benzene sulfonate, 5 parts of lauryl sodium sulfate and 3 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 15 revolutions per minute, adding 9KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotating speed to 5 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 14 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in S7 with the solution C prepared in S6, and stirring to obtain a finished liquid.
Comparative example 1
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 7.5 parts of sodium percarbonate, 5 parts of potassium carbonate, 37 parts of active substances, 0.3 part of essence, 0.2 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 12 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 17 parts of linear alkyl benzene sulfonate, 5 parts of lauryl sodium sulfate and 3 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 15 revolutions per minute, adding 9KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotating speed to 5 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 14 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Comparative example 2
The embodiment provides an oxygenation phosphorus-free concentrated washing solution which comprises the following raw materials in parts by weight: 7.5 parts of sodium percarbonate, 5 parts of potassium carbonate, 20 parts of citric acid monohydrate, 37 parts of active matter, 0.3 part of essence, 0.2 part of ethylparaben and the balance of water.
The active matter is prepared from the following components in parts by weight: 12 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 17 parts of linear alkyl benzene sulfonate, 5 parts of lauryl sodium sulfate and 3 parts of cocamide group.
The preparation method of the oxygen-increasing phosphorus-free concentrated washing solution comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 15 revolutions per minute, adding 9KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotating speed to 5 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 14 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocamide group, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
Total stirring time: the stirring time was recorded until the solution did not generate a large amount of bubbles.
pH value: the test is carried out by using a medium-controlled pH580PH meter.
Coli test standards were determined using the HJ/T347-2007 standard.
The active oxygen is determined by titration in the determination of the active oxygen content of GB/T13176.3-1991.
The finished liquids obtained in examples 1 to 8 and comparative examples 1 and 2 were subjected to the performance test, and the results are shown in the following table
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be understood by those skilled in the art that the invention is not limited by the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents.
Claims (8)
1. The oxygenation phosphorus-free concentrated washing liquid is characterized by comprising the following raw materials in parts by weight: 5-7.5 parts of sodium percarbonate, 3-5 parts of potassium carbonate, 2-8 parts of citric acid monohydrate, 30-37 parts of active substances, 0.2-0.3 part of odor removing agent, 0.1-0.2 part of antioxidant and the balance of water.
2. The oxygen-increasing phosphorus-free concentrated washing solution as claimed in claim 1, wherein the active substances are prepared from the following components in parts by weight: 10-12 parts of fatty alcohol-polyoxyethylene ether sodium sulfate, 15-17 parts of linear alkyl benzene sulfonate, 3-5 parts of lauryl sodium sulfate and 2-3 parts of coconut oil acylamino.
3. The concentrated washing solution of claim 1, wherein the odor-removing agent is a perfume.
4. The concentrated washing liquid as claimed in claim 1, wherein the antioxidant is ethylparaben.
5. The oxygen-increasing phosphorus-free concentrated washing solution as claimed in claim 1, wherein the washing solution comprises 5 parts of sodium percarbonate, 3 parts of potassium carbonate, 2 parts of citric acid monohydrate, 30 parts of active matter, 0.2 part of odor removing agent and 0.1 part of antioxidant, and the balance is water.
6. The oxygen-increasing phosphorus-free concentrated washing solution as claimed in claim 1, wherein the washing solution comprises 4 parts of sodium percarbonate, 4 parts of potassium carbonate, 5 parts of citric acid monohydrate, 35 parts of active matter, 0.2 part of odor removing agent and 0.1 part of antioxidant, and the balance is water.
7. The oxygen-increasing phosphorus-free concentrated washing solution as claimed in claim 1, wherein the washing solution comprises 5 parts of sodium percarbonate, 6 parts of potassium carbonate, 8 parts of citric acid monohydrate, 37 parts of active matter, 0.3 part of odor removing agent and 0.2 part of antioxidant, and the balance is water.
8. The method for preparing the oxygen-enriched phosphorus-free concentrated washing solution as claimed in claim 1, which comprises the following steps:
s1: respectively weighing sodium percarbonate, potassium carbonate, citric acid and water;
s2, turning on the stirrer, regulating the rotation speed to 13-15 revolutions per minute, adding 7KG-9KG water into the stirrer, adding citric acid for dissolving, and stopping stirring after the citric acid is completely dissolved;
s3, slowly adding potassium carbonate into the static citric acid solution at a speed that the solution does not overflow out of the barrel;
s4, starting stirring, regulating the rotating speed to 2-5 revolutions per minute, and continuously adding sodium percarbonate until the sodium percarbonate is completely dissolved to prepare a solution A;
s5, pouring the solution A prepared in the step S4 into another stirring barrel, adding fatty alcohol-polyoxyethylene ether sodium sulfate into the solution A, and adjusting the rotating speed to 12-14 revolutions per minute to prepare a solution B;
s6, adding the solution B prepared from the S5 into linear alkyl benzene sodium sulfonate continuously, and stirring until the linear alkyl benzene sodium sulfonate is completely dissolved to prepare a solution C;
s7, adding water into the sodium dodecyl sulfate, dissolving in another barrel, and sequentially adding the cocoamido, the odor removing agent and the antioxidant to prepare a solution D;
s8, mixing the solution D prepared in the step S7 and the solution C prepared in the step S6, and stirring to prepare a finished product liquid.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114806742A (en) * | 2022-05-25 | 2022-07-29 | 晋江市佐净日用品有限责任公司 | Oxygen-increasing phosphorus-free cleaning paste and preparation method thereof |
| CN115612570A (en) * | 2022-10-20 | 2023-01-17 | 晋江市佐净日用品有限责任公司 | Oxygen-increasing liquid cleaning cream and production method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993786A (en) * | 2009-08-14 | 2011-03-30 | 上海和黄白猫有限公司 | Cleanser essence capable of removing odors of kitchen utensils |
| CN104479888A (en) * | 2014-12-31 | 2015-04-01 | 威莱(广州)日用品有限公司 | Laundry detergent |
| CN105907483A (en) * | 2016-05-08 | 2016-08-31 | 杭州氧泡泡生物科技有限公司 | Oxygen-containing multifunctional detergent composition |
| CN106566684A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient kitchen detergent and preparation method thereof |
| CN107400570A (en) * | 2016-05-20 | 2017-11-28 | 北京佳士力科技有限公司 | Novel low-foaming Multi-enzyme detergent and preparation method thereof |
| CN109825376A (en) * | 2019-03-05 | 2019-05-31 | 菏泽富贵花簇生物科技有限公司 | Dish washing liquid and preparation method thereof |
| CN110511826A (en) * | 2019-08-30 | 2019-11-29 | 广州市拓瑞科技有限公司 | It is a kind of to sterilize nontoxic machine dishwasher detergent and preparation method thereof |
| CN111454780A (en) * | 2020-05-11 | 2020-07-28 | 张文琳 | Washing machine tank cleaning agent |
| CN111548870A (en) * | 2020-05-26 | 2020-08-18 | 浙江美生日化用品有限公司 | Cleaning tablet and preparation process thereof |
| CN112080346A (en) * | 2020-09-02 | 2020-12-15 | 湖北无忧车管家网络科技服务有限公司 | Environment-friendly super-concentrated car washing stock solution with micro water and preparation method thereof |
-
2022
- 2022-01-26 CN CN202210096359.8A patent/CN114525178B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993786A (en) * | 2009-08-14 | 2011-03-30 | 上海和黄白猫有限公司 | Cleanser essence capable of removing odors of kitchen utensils |
| CN104479888A (en) * | 2014-12-31 | 2015-04-01 | 威莱(广州)日用品有限公司 | Laundry detergent |
| CN105907483A (en) * | 2016-05-08 | 2016-08-31 | 杭州氧泡泡生物科技有限公司 | Oxygen-containing multifunctional detergent composition |
| CN107400570A (en) * | 2016-05-20 | 2017-11-28 | 北京佳士力科技有限公司 | Novel low-foaming Multi-enzyme detergent and preparation method thereof |
| CN106566684A (en) * | 2016-10-12 | 2017-04-19 | 重庆市五洁新材料有限公司 | Efficient kitchen detergent and preparation method thereof |
| CN109825376A (en) * | 2019-03-05 | 2019-05-31 | 菏泽富贵花簇生物科技有限公司 | Dish washing liquid and preparation method thereof |
| CN110511826A (en) * | 2019-08-30 | 2019-11-29 | 广州市拓瑞科技有限公司 | It is a kind of to sterilize nontoxic machine dishwasher detergent and preparation method thereof |
| CN111454780A (en) * | 2020-05-11 | 2020-07-28 | 张文琳 | Washing machine tank cleaning agent |
| CN111548870A (en) * | 2020-05-26 | 2020-08-18 | 浙江美生日化用品有限公司 | Cleaning tablet and preparation process thereof |
| CN112080346A (en) * | 2020-09-02 | 2020-12-15 | 湖北无忧车管家网络科技服务有限公司 | Environment-friendly super-concentrated car washing stock solution with micro water and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114806742A (en) * | 2022-05-25 | 2022-07-29 | 晋江市佐净日用品有限责任公司 | Oxygen-increasing phosphorus-free cleaning paste and preparation method thereof |
| CN114806742B (en) * | 2022-05-25 | 2024-06-04 | 晋江市佐净日用品有限责任公司 | Preparation method of oxygen-increasing phosphorus-free cleaning paste |
| CN115612570A (en) * | 2022-10-20 | 2023-01-17 | 晋江市佐净日用品有限责任公司 | Oxygen-increasing liquid cleaning cream and production method thereof |
| CN115612570B (en) * | 2022-10-20 | 2023-12-15 | 晋江市佐净日用品有限责任公司 | Automatic material conveying system |
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|---|---|
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