CN111454780A - Washing machine tank cleaning agent - Google Patents

Washing machine tank cleaning agent Download PDF

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Publication number
CN111454780A
CN111454780A CN202010390140.XA CN202010390140A CN111454780A CN 111454780 A CN111454780 A CN 111454780A CN 202010390140 A CN202010390140 A CN 202010390140A CN 111454780 A CN111454780 A CN 111454780A
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parts
washing machine
machine tank
sodium
sodium percarbonate
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张文琳
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0068Deodorant compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395Bleaching agents
    • C11D3/3951Bleaching agents combined with specific additives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C11D3/485Halophors, e.g. iodophors

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention relates to a washing machine tank cleaning agent, which comprises sodium percarbonate, trichloroisocyanuric acid, biological enzyme, sodium benzenesulfonate, citric acid and sodium carbonate. The sodium percarbonate can react with citric acid to generate a decomposer, and the sodium percarbonate and trichloroisocyanuric acid are compatible for use, so that the sodium percarbonate can realize quick disinfection, sterilization, virus killing and bacteriostasis in a very short time, and the sterilization rate and the bacteriostasis rate of the sodium percarbonate can both reach more than 99 percent; when the detergent for the washing machine tank is put into water for use, the sodium percarbonate, the trichloroisocyanuric acid and the water react to release chlorine, and the effective release time of the chlorine is over 30 minutes, so that the detergent not only can clean, sterilize, kill viruses, inhibit bacteria, bleach, remove dirt and the like for the washing machine tank so as to avoid the problem that the dirt accumulation occurs to generate bacteria and the accumulated dirt blocks the pipeline of the washing machine, but also can prolong the antibacterial time of the washing machine tank cleaned by the detergent, and the antibacterial time of the washing machine tank is over 25 minutes.

Description

Washing machine tank cleaning agent
Technical Field
The invention relates to a washing machine tank cleaning agent.
Background
At present, the sterilizing capability of the detergent for washing machine tanks on the market is still to be improved, for example, the Chinese patent with publication number of CN109468178A and patent name of a detergent for washing machine tanks and a preparation method thereof, the sterilizing rate of the detergent is generally below 99%, the sterilizing rate of the detergent is difficult to reach above 99%, the time for dissolving and soaking the detergent in water is generally long when the detergent reaches the sterilizing rate of nearly 99%, and the soaking time is generally at least 20 minutes. For example, the chinese patent with publication No. CN109554241A and the patent name of the invention is a detergent for washing machine tank, which has antibacterial and descaling functions, but the above two patents and most of the detergents for washing machine tank in the current market do not have bleaching function and function of removing smell or odor of washing machine tank, and the detergent for washing machine tank without bleaching function or poor bleaching effect is liable to cause the pipe blockage due to the accumulation of dirt in the washing machine tank, and cause the washing machine to bring more different strains due to the accumulation of dirt, thereby reducing the sterilization rate.
In addition, the current washing machine tank cleaning agent on the market can not release chlorine after being dissolved in water, or even if chlorine is released, the effective time of chlorine release is short, and the cleaning and bacteriostasis time is short, namely the cleaning and bacteriostasis time is only 1-3 minutes.
Disclosure of Invention
The invention aims to solve the technical problem of providing a washing machine tank cleaning agent, which has the sterilization rate and the bacteriostasis rate of more than 99 percent, can release chlorine after being dissolved in water, has the effective time of chlorine release of 2542 minutes, effectively solves the problem that the prior washing machine tank cleaning agent generally does not release chlorine or has short effective time of chlorine release, and has the functions of bleaching and preventing the problem of pipeline blockage caused by dirt accumulation in a washing machine tank. The invention is realized by the following technical scheme:
a washing machine tank cleaning agent is prepared from the following components in parts by weight: 60-80 parts of sodium percarbonate, 0.5-5 parts of trichloroisocyanuric acid, 1-10 parts of biological enzyme, 1-8 parts of sodium benzenesulfonate, 0.1-3 parts of citric acid and 1-20 parts of sodium carbonate.
Further, the washing machine tank cleaning agent is prepared from the following components in parts by weight: 75 parts of sodium percarbonate, 1 part of trichloroisocyanuric acid, 1 part of biological enzyme, 5 parts of sodium benzenesulfonate, 1 part of citric acid and 17 parts of sodium carbonate.
Further, the washing machine tank cleaning agent is prepared from the following components in parts by weight: 70 parts of sodium percarbonate, 2 parts of trichloroisocyanuric acid, 3 parts of biological enzyme, 8 parts of sodium benzenesulfonate, 2 parts of citric acid and 15 parts of sodium carbonate.
Further, the washing machine tank cleaning agent is prepared from the following components in parts by weight: 66 parts of sodium percarbonate, 5 parts of trichloroisocyanuric acid, 10 parts of biological enzyme, 4 parts of sodium benzenesulfonate, 3 parts of citric acid and 12 parts of sodium carbonate.
Further, the washing machine tank cleaning agent is prepared from the following components in parts by weight: 78 parts of sodium percarbonate, 3 parts of trichloroisocyanuric acid, 5 parts of biological enzyme, 6 parts of sodium benzenesulfonate, 1 part of citric acid and 7 parts of sodium carbonate.
Further, the washing machine tank cleaning agent is prepared from the following components in parts by weight: 73 parts of sodium percarbonate, 4 parts of trichloroisocyanuric acid, 4 parts of biological enzyme, 2 parts of sodium benzenesulfonate, 0.5 part of citric acid and 16.5 parts of sodium carbonate.
The invention relates to a washing machine tank cleaning agent, which comprises sodium percarbonate, trichloroisocyanuric acid, biological enzyme, sodium benzenesulfonate, citric acid and sodium carbonate. The citric acid is added into the components, sodium percarbonate reacts with the citric acid to generate the action of a decomposer, the functions of removing smell and peculiar smell are realized, trichloroisocyanuric acid is added into the components, and when the sodium percarbonate and the trichloroisocyanuric acid are used in a compatible way, the sodium percarbonate and the trichloroisocyanuric acid can be quickly disinfected, sterilized, virucidal and bacteriostatic in a very short time, so that the sodium percarbonate and trichloroisocyanuric acid disinfectant has the advantages of short time for disinfecting, sterilizing and virucidal, high sterilization efficiency, good sterilization effect and good bacteriostatic effect, and the sterilization rate and the bacteriostatic rate of the sodium percarbonate are both more than 99%; when the detergent for the washing machine tank is put into water for use, chlorine can be released by the reaction of sodium percarbonate, trichloroisocyanuric acid and water, the effective release time of the chlorine is over 30 minutes, so that the detergent not only can clean, sterilize, kill viruses, inhibit bacteria, bleach, remove dirt and the like for the washing machine tank so as to avoid the problem that the dirt is accumulated in the washing machine tank to generate bacteria and prevent the accumulated dirt from blocking a pipeline of the washing machine, but also can prolong the antibacterial time of the washing machine tank cleaned by the detergent, so that the antibacterial time of the washing machine tank is over 25 minutes, and the detergent is convenient to obtain materials, low in use cost and very convenient to use.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
A washing machine tank cleaning agent is prepared from the following components in parts by weight:
Figure BDA0002485657080000031
example 1:
a washing machine tank cleaning agent is prepared from the following components in parts by weight:
Figure BDA0002485657080000032
example 2:
a washing machine tank cleaning agent is prepared from the following components in parts by weight:
Figure BDA0002485657080000033
example 3:
a washing machine tank cleaning agent is prepared from the following components in parts by weight:
Figure BDA0002485657080000034
Figure BDA0002485657080000041
example 4:
a washing machine tank cleaning agent is prepared from the following components in parts by weight:
Figure BDA0002485657080000042
example 5:
a washing machine tank cleaning agent is prepared from the following components in parts by weight:
Figure BDA0002485657080000043
in another embodiment, the present invention also provides a method for preparing a detergent for a washing machine tub, comprising: the method comprises the following steps: firstly, preparing the components according to the weight parts, then putting the sodium percarbonate and the citric acid into a stirrer together, setting the stirring speed of the stirrer to be 2500-3500 rpm, and stirring for 0.5-3 hours until the sodium percarbonate and the citric acid are uniformly mixed to prepare the decomposer;
step two: putting trichloroisocyanuric acid and sodium carbonate into a stirrer for preparing a decomposer to mix and stir, and then setting the stirring speed of the stirrer to 2000-3000 r/min for 0.5-3 h until the trichloroisocyanuric acid, the sodium carbonate and other materials are uniformly stirred in the stirrer;
step three: adding the biological enzyme and the sodium benzenesulfonate into a stirrer for mixing and stirring, and then setting the stirring speed of the stirrer to be 2500-3500 rpm until the biological enzyme, the sodium benzenesulfonate and other materials are uniformly stirred in the stirrer to prepare the washing machine tank cleaning agent;
step four: the uniformly stirred detergent for the washing machine tank is put into a granulator, and the granulator is used for preparing the detergent for the washing machine tank into granules, so that the detergent can be quickly dissolved in a very short time (the detergent can be completely dissolved in 2 minutes) in use, the problem that the existing detergent for the washing machine tank needs long time for dissolving and soaking is solved,
step five: and cooling and molding the granular washing machine tank cleaning agent, and then packaging or packaging the cooled and molded granular washing machine tank cleaning agent to obtain a finished product.
In step one, the stirring speed of the stirrer can be set to 2900 revolutions per minute, 3000 revolutions per minute, 3100 revolutions per minute, 3200 revolutions per minute, 3300 revolutions per minute, 3400 revolutions per minute and 3500 revolutions per minute; the stirring time was 3 hours, 2.5 hours, 2 hours, 1.5 hours, 1 hour and 0.5 hour.
In step two, the stirring speed of the stirrer can be set to 2100 rpm, 2300 rpm, 2500 rpm, 2700 rpm, 2800 rpm, 2900 rpm, and 3000 rpm; the stirring time was 3 hours, 2.5 hours, 2 hours, 1.5 hours, 1 hour and 0.5 hour.
In step three, in step one, the stirring speed of the stirrer can be set to 2600 rpm, 2700 rpm, 2800 rpm, 3000 rpm, 3200 rpm, 3300 rpm and 3400 rpm; the stirring time was 3 hours, 2.5 hours, 2 hours, 1.5 hours, 1 hour and 0.5 hour.
The formulations of examples 1 to 5 were compared with the detergent for washing machine tank prepared by the preparation method of the present invention, and the results are shown in the following table:
Figure BDA0002485657080000051
Figure BDA0002485657080000061
TABLE 1
Figure BDA0002485657080000062
TABLE 2
From the above table, the washing machine tank cleaning agent prepared by the formula and the preparation method of the invention has the sterilization rate and the bacteriostasis rate of more than 99% within 3-15 minutes, and compared with the maximum sterilization rate and the bacteriostasis rate of more than 20 minutes of the existing washing machine tank cleaning agent which are soaked and only can reach 98.9% and the sterilization rate and the bacteriostasis rate of the existing washing machine tank cleaning agent which are soaked within the soaking time of less than or equal to 5 minutes are only 55-75%, the invention realizes that the sterilization rate and the bacteriostasis rate of the washing machine tank can reach more than 99% within a short time (3-15 minutes), namely the sterilization time is greatly shortened, and the sterilization efficiency and the sterilization effect are both obviously improved; in addition, the bleaching rate of the bleaching agent in 3-15 minutes reaches more than 95, so that the bleaching agent not only has a bleaching effect, but also realizes a good bleaching effect; in addition, the detergent can release chlorine after being dissolved in water, so that bacteria, viruses and the like can be killed, the effective time of chlorine release is 2542 minutes, the problem that the conventional detergent for the washing machine tank generally does not release chlorine is effectively solved, and the washing machine tank cleaned by the detergent has longer bacteriostatic time; the citric acid is added into the components, and the sodium percarbonate reacts with the citric acid to generate the function of decomposing agent, so that the decomposing agent can disperse dirt accumulated in a washing machine tank and enhance the bleaching function, thereby avoiding the problem that the washing machine tank blocks a washing machine pipeline due to dirt accumulation and realizing the function of removing odor or peculiar smell of the washing machine tank.
The present invention is not limited to the above-mentioned preferred embodiments, and any other products similar or identical to the present invention, which can be obtained by anyone based on the teaching of the present invention, fall within the protection scope of the present invention.

Claims (6)

1. A washing machine tank cleaner characterized by: the composition is prepared from the following components in parts by weight: 60-80 parts of sodium percarbonate, 0.5-5 parts of trichloroisocyanuric acid, 1-10 parts of biological enzyme, 1-8 parts of sodium benzenesulfonate, 0.1-3 parts of citric acid and 1-20 parts of sodium carbonate.
2. A washing machine tub cleaner as claimed in claim 1, characterized in that: the composition is prepared from the following components in parts by weight: 75 parts of sodium percarbonate, 1 part of trichloroisocyanuric acid, 1 part of biological enzyme, 5 parts of sodium benzenesulfonate, 1 part of citric acid and 17 parts of sodium carbonate.
3. A washing machine tub cleaner as claimed in claim 1, characterized in that: the composition is prepared from the following components in parts by weight: 70 parts of sodium percarbonate, 2 parts of trichloroisocyanuric acid, 3 parts of biological enzyme, 8 parts of sodium benzenesulfonate, 2 parts of citric acid and 15 parts of sodium carbonate.
4. A washing machine tub cleaner as claimed in claim 1, characterized in that: the composition is prepared from the following components in parts by weight: 66 parts of sodium percarbonate, 5 parts of trichloroisocyanuric acid, 10 parts of biological enzyme, 4 parts of sodium benzenesulfonate, 3 parts of citric acid and 12 parts of sodium carbonate.
5. A washing machine tub cleaner as claimed in claim 1, characterized in that: the composition is prepared from the following components in parts by weight: 78 parts of sodium percarbonate, 3 parts of trichloroisocyanuric acid, 5 parts of biological enzyme, 6 parts of sodium benzenesulfonate, 1 part of citric acid and 7 parts of sodium carbonate.
6. A washing machine tub cleaner as claimed in claim 1, characterized in that: the composition is prepared from the following components in parts by weight: 73 parts of sodium percarbonate, 4 parts of trichloroisocyanuric acid, 4 parts of biological enzyme, 2 parts of sodium benzenesulfonate, 0.5 part of citric acid and 16.5 parts of sodium carbonate.
CN202010390140.XA 2020-05-11 2020-05-11 Washing machine tank cleaning agent Pending CN111454780A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114525178A (en) * 2022-01-26 2022-05-24 晋江市佐净日用品有限责任公司 Oxygen-increasing phosphorus-free concentrated cleaning solution and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN1066560A (en) * 1992-05-29 1992-12-02 高建胜 Instant disinfectant tablet and preparation method
CN1250806A (en) * 1999-10-21 2000-04-19 薛万政 Disinfecting detergent for washer
CN1600102A (en) * 2003-09-28 2005-03-30 江苏北方氯碱集团有限公司 Bactericin agent of trichloro-isocyanuric acid
CN1631154A (en) * 2004-11-12 2005-06-29 上海利康消毒高科技有限公司 Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof
CN102228058A (en) * 2011-05-25 2011-11-02 山西新源华康化工股份有限公司 Citric acid composite disinfectant
CN102433227A (en) * 2011-10-27 2012-05-02 吴克 Granulated cleaning agent for washing machine slot
CN104388211A (en) * 2014-11-24 2015-03-04 上海净安化工科技有限公司 Antiseptic cleaning agent for washer tank
CN108753490A (en) * 2018-06-21 2018-11-06 无锡市天爱装饰工程有限公司 A kind of washing machine tank purificant
CN109554241A (en) * 2017-09-25 2019-04-02 陈小梅 A kind of Washine-machine chute detergent
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CN1066560A (en) * 1992-05-29 1992-12-02 高建胜 Instant disinfectant tablet and preparation method
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CN1631154A (en) * 2004-11-12 2005-06-29 上海利康消毒高科技有限公司 Disinfection effervescence tablet, granule or powder containing chlorine with low chlorine odor and preparation method thereof
CN102228058A (en) * 2011-05-25 2011-11-02 山西新源华康化工股份有限公司 Citric acid composite disinfectant
CN102433227A (en) * 2011-10-27 2012-05-02 吴克 Granulated cleaning agent for washing machine slot
CN104388211A (en) * 2014-11-24 2015-03-04 上海净安化工科技有限公司 Antiseptic cleaning agent for washer tank
CN109554241A (en) * 2017-09-25 2019-04-02 陈小梅 A kind of Washine-machine chute detergent
CN108753490A (en) * 2018-06-21 2018-11-06 无锡市天爱装饰工程有限公司 A kind of washing machine tank purificant
CN109609291A (en) * 2018-12-28 2019-04-12 北京绿伞化学股份有限公司 A kind of pipeline bad smell removal detergent effervescent tablet and preparation method thereof

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114525178A (en) * 2022-01-26 2022-05-24 晋江市佐净日用品有限责任公司 Oxygen-increasing phosphorus-free concentrated cleaning solution and preparation method thereof
CN114525178B (en) * 2022-01-26 2024-06-07 晋江市佐净日用品有限责任公司 Preparation method of oxygen-enriched phosphorus-free concentrated washing liquid

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Application publication date: 20200728