CN105969539A - Multifunctional condensed cleaning agent - Google Patents

Multifunctional condensed cleaning agent Download PDF

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Publication number
CN105969539A
CN105969539A CN201610303463.4A CN201610303463A CN105969539A CN 105969539 A CN105969539 A CN 105969539A CN 201610303463 A CN201610303463 A CN 201610303463A CN 105969539 A CN105969539 A CN 105969539A
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China
Prior art keywords
parts
butyl alcohol
cleaning agent
dimethyl sulfoxide
hydrogen peroxide
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Granted
Application number
CN201610303463.4A
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Chinese (zh)
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CN105969539B (en
Inventor
严敬华
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Zhejiang shiweikang biomedical materials Co.,Ltd.
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Hangzhou Oxyaction Biotechnology Co Ltd
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Priority to CN201610303463.4A priority Critical patent/CN105969539B/en
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3445—Organic compounds containing sulfur containing sulfino groups, e.g. dimethyl sulfoxide
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3937—Stabilising agents
    • C11D3/394—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a multifunctional condensed cleaning agent. The cleaning agent is prepared by the following raw materials in parts by weight: 35-45 parts of an anionic surfactant sodium lauryl polyoxyethylene ether sulfate; 30-40 parts of a nonionic surfactant fatty alcohol polyoxyethylene ether; 5-15 parts of hydrogen peroxide; 1-3 parts of sodium hydroxide; 40-50 parts of water; 0.7-0.9 parts of stabilizing agents comprising n-butyl alcohol and dimethyl sulfoxide, wherein the ratio in parts by weight of n-butyl alcohol to dimethyl sulfoxide is 6-8:1. The multifunctional condensed cleaning agent has stable properties, hydrogen peroxide is not easy to decompose, which is related to the ratio in parts by weight of n-butyl alcohol to dimethyl sulfoxide in the raw materials, when the ratio in parts by weight of n-butyl alcohol to dimethyl sulfoxide is 6-8:1, the effects are best, and the decomposition and degradation rate of hydrogen peroxide is lowest. The multifunctional condensed cleaning agent contains active oxygen (hydrogen peroxide), dirt is totally removed by spraying and wiping, and irritant smell is not contained, and the multifunctional condensed cleaning agent has good product experience.

Description

A kind of multi-functional concentration cleaning agent
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of multi-functional concentration cleaning agent.
Background technology
Detergent is daily product indispensable during people live.Along with the continuous progress of society, the quality of life of people is day by day Improving, consumer is more and more higher for the requirement of commercial quality.For detergent, articles for washing tends to variation, various Detergent new product continues to bring out.Generally speaking, energy-saving and water-saving, the gentleest, easy to use and meet safety and environmental protection and want Ask, be the main flow direction of current cleaning product development.And concentrated type detergent not only can save in production, transport, storing process The about energy, but also have easy to use, dissolution velocity is fast, usage amount is few, to the gentleer feature of fabric and skin, with Time also there is more green, efficient, the advantage of energy-conserving and environment-protective.Just because of this, concentrated cleaning demonstrates powerful growth potential, Increasingly favored by consumer.
Research and practice for many years are it has been shown that concentrated cleaning is compared to there being many advantages for conventional detergent. For Producer, it is possible to reduce the cost of packaging, it is also possible to reduce the space of goods storage；Consumer is come Saying, the usage amount of concentrated cleaning can be less；Meanwhile, concentrated cleaning dissolution velocity is fast, and dispersibility is good, is possible not only to more Effectively remove spot, do not have alkaline residues matter after laundry, and the injury to skin and fabric can be less；It addition, from For the angle of environmental protection, promoting the discharge capacity that concentrated cleaning can increase the utilization rate reduction chemical substance of active matter, it is right to reduce The pollution of environment, it is also possible to reduce the cost of blowdown pollution treatment.
Summary of the invention
It is an object of the invention to provide a kind of multi-functional concentration cleaning agent.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of multi-functional concentration cleaning agent, is prepared from by the raw material of following weight portion: anion surfactant dodecyl Polyoxyethylenated alcohol sodium sulfate, 35～45 parts；Nonionic surfactant fatty alcohol-polyoxyethylene ether, 30～40 parts；Hydrogen peroxide, 5～15 parts；Sodium hydroxide, 1～3 part；Water, 40～50 parts；Also include stabilizer n-butyl alcohol and dimethyl sulfoxide totally 0.7～0.9 part, The weight ratio of n-butyl alcohol and dimethyl sulfoxide is 6～8:1.
Further, described multi-functional concentration cleaning agent is prepared from by the raw material of following weight portion: anion surface active Agent Brij 35 sodium sulfate, 40 parts；Nonionic surfactant fatty alcohol-polyoxyethylene ether, 35 parts；Dioxygen Water, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and dimethyl sulfoxide totally 0.8 part, positive fourth The weight ratio of alcohol and dimethyl sulfoxide is 7:1.
Further, described multi-functional concentration cleaning agent is prepared from by the raw material of following weight portion: anion surface active Agent Brij 35 sodium sulfate, 35 parts；Nonionic surfactant fatty alcohol-polyoxyethylene ether, 30 parts；Dioxygen Water, 5 parts；Sodium hydroxide, 1 part；Water, 40 parts；Also include stabilizer n-butyl alcohol and dimethyl sulfoxide totally 0.7 part, n-butyl alcohol It is 6:1 with the weight ratio of dimethyl sulfoxide.
Further, described multi-functional concentration cleaning agent is prepared from by the raw material of following weight portion: anion surface active Agent Brij 35 sodium sulfate, 45 parts；Nonionic surfactant fatty alcohol-polyoxyethylene ether, 40 parts；Dioxygen Water, 15 parts；Sodium hydroxide, 3 parts；Water, 50 parts；Also include stabilizer n-butyl alcohol and dimethyl sulfoxide totally 0.9 part, positive fourth The weight ratio of alcohol and dimethyl sulfoxide is 8:1.
The preparation method of above-mentioned multi-functional concentration cleaning agent, comprises the steps:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
Advantages of the present invention:
(1) multi-functional concentration cleaning agent (hydrogen peroxide) Han active oxygen that the present invention provides, a spray one wiping dirt disappears entirely, and stingless Swashing property abnormal smells from the patient, Product Experience is good；
(2) the multi-functional concentration cleaning agent stable in properties that the present invention provides, hydrogen peroxide is not easily decomposed, long shelf-life.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit scope with this.To the greatest extent The present invention is explained in detail by pipe with reference to preferred embodiment, it will be understood by those within the art that, can be to the present invention Technical scheme modify or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of multi-functional concentration cleaning agent
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 40 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 35 parts；Hydrogen peroxide, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.8 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 7:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
Embodiment 2: the preparation of multi-functional concentration cleaning agent
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 35 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 30 parts；Hydrogen peroxide, 5 parts；Sodium hydroxide, 1 part；Water, 40 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.7 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 6:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
Embodiment 3: the preparation of multi-functional concentration cleaning agent
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 45 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 40 parts；Hydrogen peroxide, 15 parts；Sodium hydroxide, 3 parts；Water, 50 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.9 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 8:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
Embodiment 4: the preparation of multi-functional concentration cleaning agent
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 40 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 35 parts；Hydrogen peroxide, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.8 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 6:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
Embodiment 5: the preparation of multi-functional concentration cleaning agent
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 40 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 35 parts；Hydrogen peroxide, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.8 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 8:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
The weight ratio of embodiment 6: comparative example, n-butyl alcohol and dimethyl sulfoxide is 5:1
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 40 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 35 parts；Hydrogen peroxide, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.8 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 5:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
The weight ratio of embodiment 7: comparative example, n-butyl alcohol and dimethyl sulfoxide is 9:1
Parts by weight of raw materials compares:
Anion surfactant Brij 35 sodium sulfate, 40 parts；Nonionic surfactant fatty alcohol polyoxy Vinyl Ether, 35 parts；Hydrogen peroxide, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and dimethyl Sulfoxide totally 0.8 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 9:1.
Preparation method:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
Embodiment 8: effect example
Hydrogen peroxide easily decomposes, and causes Active oxygen release ability to reduce, affects cleaning effect.To this end, test embodiment respectively The storage stability of the multi-functional concentration cleaning agent of 1～7 preparations, 36 months experiment investigation time limits, test temperature 25 ± 5 DEG C, examination Test humidity 50 ± 5%RH.Inspection target: hydrogen peroxide content is relative to the decline percentage ratio (%) of content during harsh output.
Result see table.
The above results shows, the multi-functional concentration cleaning agent stable in properties that the present invention provides, and hydrogen peroxide is not easily decomposed, and this may be with In raw material, n-butyl alcohol is relevant with the weight ratio of dimethyl sulfoxide, and the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 6～8:1 Shi Xiaoguo is best, and decomposing hydrogen dioxide solution degradation rate is minimum.
Multi-functional concentration cleaning agent (hydrogen peroxide) Han active oxygen that the present invention provides, a spray one wiping dirt disappears entirely, and nonirritant gas Taste, Product Experience is good.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit protection scope of the present invention with this. It will be understood by those within the art that, technical scheme can be modified or equivalent, and not take off Essence and protection domain from technical solution of the present invention.

Claims (5)

1. a multi-functional concentration cleaning agent, it is characterised in that be prepared from by the raw material of following weight portion: anionic surface Activating agent Brij 35 sodium sulfate, 35～45 parts；Nonionic surfactant fatty alcohol-polyoxyethylene ether, 30～40 Part；Hydrogen peroxide, 5～15 parts；Sodium hydroxide, 1～3 part；Water, 40～50 parts；Also include that stabilizer n-butyl alcohol and dimethyl are sub- Sulfone totally 0.7～0.9 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 6～8:1.
Multi-functional concentration cleaning agent the most according to claim 1, it is characterised in that prepared by the raw material of following weight portion Form: anion surfactant Brij 35 sodium sulfate, 40 parts；Nonionic surfactant poly alkyl alcohol Oxygen vinyl Ether, 35 parts；Hydrogen peroxide, 10 parts；Sodium hydroxide, 2 parts；Water, 45 parts；Also include stabilizer n-butyl alcohol and diformazan Base sulfoxide totally 0.8 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 7:1.
Multi-functional concentration cleaning agent the most according to claim 1, it is characterised in that prepared by the raw material of following weight portion Form: anion surfactant Brij 35 sodium sulfate, 35 parts；Nonionic surfactant poly alkyl alcohol Oxygen vinyl Ether, 30 parts；Hydrogen peroxide, 5 parts；Sodium hydroxide, 1 part；Water, 40 parts；Also include stabilizer n-butyl alcohol and diformazan Base sulfoxide totally 0.7 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 6:1.
Multi-functional concentration cleaning agent the most according to claim 1, it is characterised in that prepared by the raw material of following weight portion Form: anion surfactant Brij 35 sodium sulfate, 45 parts；Nonionic surfactant poly alkyl alcohol Oxygen vinyl Ether, 40 parts；Hydrogen peroxide, 15 parts；Sodium hydroxide, 3 parts；Water, 50 parts；Also include stabilizer n-butyl alcohol and diformazan Base sulfoxide totally 0.9 part, the weight ratio of n-butyl alcohol and dimethyl sulfoxide is 8:1.
5. the preparation method of the arbitrary described multi-functional concentration cleaning agent of Claims 1 to 4, it is characterised in that comprise the steps:
Step S1, after dissolved hydrogen water sodium oxide, n-butyl alcohol and dimethyl sulfoxide, adds hydrogen peroxide, prepares component A；
Step S2, obtains component B by Brij 35 sodium sulfate and fatty alcohol-polyoxyethylene ether mix homogeneously；
Step S3, while stirring addO-on therapy B in component A, mix homogeneously.
CN201610303463.4A 2016-05-08 2016-05-08 A kind of multi-functional concentration detergent Active CN105969539B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106823627A (en) * 2017-03-29 2017-06-13 吉占年 A kind of gas washing agent
CN114891571A (en) * 2022-04-29 2022-08-12 苏州炽蓝生物科技有限公司 Foamless high-concentration hard surface cleaner

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1575331A (en) * 2001-10-24 2005-02-02 大金工业株式会社 Composition for cleaning
CN103805349A (en) * 2012-11-07 2014-05-21 薛晓萌 Pollution-free stain cleanser
CN105542993A (en) * 2015-12-16 2016-05-04 青岛克立克信息技术有限公司 Eco-friendly concentrated detergent powder

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1575331A (en) * 2001-10-24 2005-02-02 大金工业株式会社 Composition for cleaning
CN103805349A (en) * 2012-11-07 2014-05-21 薛晓萌 Pollution-free stain cleanser
CN105542993A (en) * 2015-12-16 2016-05-04 青岛克立克信息技术有限公司 Eco-friendly concentrated detergent powder

Non-Patent Citations (1)

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Title
朱洪法: "《炼油及石油化工"三剂"手册》", 31 January 2015 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106823627A (en) * 2017-03-29 2017-06-13 吉占年 A kind of gas washing agent
CN114891571A (en) * 2022-04-29 2022-08-12 苏州炽蓝生物科技有限公司 Foamless high-concentration hard surface cleaner
CN114891571B (en) * 2022-04-29 2023-08-08 苏州炽蓝生物科技有限公司 Foamless high concentrated hard surface cleaner

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