CN114392208A - Peelable nail polish gel for high-precision ink-jet nail printing and preparation method thereof - Google Patents
Peelable nail polish gel for high-precision ink-jet nail printing and preparation method thereof Download PDFInfo
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- CN114392208A CN114392208A CN202111574507.4A CN202111574507A CN114392208A CN 114392208 A CN114392208 A CN 114392208A CN 202111574507 A CN202111574507 A CN 202111574507A CN 114392208 A CN114392208 A CN 114392208A
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- nail
- nail polish
- acrylate
- peelable
- polish gel
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- 238000002360 preparation method Methods 0.000 title abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 40
- 239000000178 monomer Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 claims abstract description 12
- 239000004814 polyurethane Substances 0.000 claims abstract description 12
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- -1 acrylate ester Chemical class 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 3
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 3
- FTALTLPZDVFJSS-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl prop-2-enoate Chemical compound CCOCCOCCOC(=O)C=C FTALTLPZDVFJSS-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- JRWNODXPDGNUPO-UHFFFAOYSA-N oxolane;prop-2-enoic acid Chemical compound C1CCOC1.OC(=O)C=C JRWNODXPDGNUPO-UHFFFAOYSA-N 0.000 claims description 3
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- WSTWYNKMJDORDL-UHFFFAOYSA-N P(OCC)(OC1=C(C=CC=C1)C(C1=C(C=C(C=C1C)C)C)=O)=O Chemical compound P(OCC)(OC1=C(C=CC=C1)C(C1=C(C=C(C=C1C)C)C)=O)=O WSTWYNKMJDORDL-UHFFFAOYSA-N 0.000 claims 1
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 239000000499 gel Substances 0.000 description 45
- 230000000052 comparative effect Effects 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000001514 detection method Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- YMCOIFVFCYKISC-UHFFFAOYSA-N ethoxy-[2-(2,4,6-trimethylbenzoyl)phenyl]phosphinic acid Chemical compound CCOP(O)(=O)c1ccccc1C(=O)c1c(C)cc(C)cc1C YMCOIFVFCYKISC-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
- C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to the technical field of cosmetics and discloses a peelable nail polish gel for high-precision ink-jet nail printing and a preparation method thereof. The nail polish gel provided by the invention comprises the following components in parts by mass: 10-30 parts of a polyurethane acrylate oligomer; 65-75 parts of an acrylate monomer; 1-10 parts of a photoinitiator; 0.1-0.5 part of a leveling agent; 0.1-0.5 part of defoaming agent; the viscosity of the polyurethane acrylate oligomer is 10-120 CPs, and the viscosity of the acrylate monomer is 2-15 CPs. The nail polish gel provided by the invention not only can be used for high-precision nail printing, but also has a strippable characteristic.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to a peelable nail polish gel for high-precision ink-jet nail print and a preparation method thereof.
Background
As the nail market expands year by year, more and more consumers spend a great deal of time on nail art. The traditional manual nail painting method needs long-time operation, and the skill of an operator can influence the nail painting quality.
The nail art is beautified through nail art printer both can shorten first beautiful time, still can reduce the uncertain factor of artifical first beautiful operation, guarantees first beautiful quality. However, the current nail print solutions are common: and manually brushing a layer of nail polish gel, after the nail polish gel is cured, putting a finger into a nail beautifying machine for pattern printing, and then manually brushing a layer of nail polish gel. As can be seen from the above steps, the current nail print embodiments do not completely solve the problems of uncertain quality and long time of manual painting.
The reason for this is that the materials used in high precision nail art printers must have low viscosity, and the nail polish gel products on the market generally have viscosity higher than 1000CPs, and cannot be used in high precision printers. And if the nail polish gel is diluted to low viscosity by a diluent and then printed on the nail surface, the nail polish gel is not strippable. Most of the nail polish gel diluents are organic solvents such as acetone and plasticizers, and have high toxicity; the low-viscosity material obtained by diluting nail polish gel with a diluent has poor curing performance, and the using effect is influenced.
Disclosure of Invention
The invention aims to provide a strippable nail polish gel material for high-precision printing and a preparation method thereof.
In order to solve the above technical problems, a first aspect of the present invention provides a peelable nail polish gel for high-precision inkjet nail printing, comprising, in parts by mass: urethane acrylate oligomer: 10-30 parts; acrylate ester monomer: 65-75 parts of a solvent; photoinitiator (2): 1-10 parts; leveling agent: 0.1-0.5 part; defoaming agent: 0.1-0.5 part; essence: 0.1-0.5 part; the viscosity of the polyurethane acrylate oligomer is 10-120 CPs, and the viscosity of the acrylate monomer is 2-15 CPs.
Preferably, in the peelable nail polish gel for high-precision ink-jet nail polish printing provided by the invention, the viscosity of the polyurethane acrylate oligomer is 50-80 CPs, and the viscosity of the acrylate monomer is 6-10 CPs.
Preferably, in the peelable nail polish gel for high-precision inkjet nail polish printing provided by the invention, the urethane acrylate oligomer is selected from at least one of a urethane acrylate oligomer and a silicone-modified urethane acrylate oligomer.
Preferably, in the peelable nail polish gel for high-precision ink-jet nail polish printing provided by the invention, the acrylate monomer is selected from a monofunctional acrylate monomer, a multifunctional acrylate monomer or a mixture thereof. More preferably, the acrylate monomer is selected from one or more of ethoxyethoxyethyl acrylate, tetrahydrofuran acrylate, isobornyl acrylate, cyclotrimethylolpropane formal acrylate, trimethylolpropane triacrylate, and propoxylated neopentyl diacrylate.
Preferably, in the peelable nail polish gel for high-precision inkjet nail polish printing provided by the invention, the photoinitiator is at least one selected from 1-hydroxycyclohexyl phenyl ketone, 2,4, 6-trimethyl benzoyl phenyl phosphonic acid ethyl ester and 2,4, 6-trimethyl benzophenone.
Preferably, in the peelable nail polish gel for high-precision ink-jet nail polish printing provided by the invention, the leveling agent is selected from at least one of an organic silicon leveling agent, a polyether-modified organic silicon leveling agent and a fluorocarbon-modified acrylate polymer; preferably, the leveling agent is a modified polydioxysiloxane.
Preferably, in the peelable nail polish gel for high-precision inkjet nail polish printing provided by the present invention, the defoaming agent is at least one selected from polyether defoaming agents and silicone defoaming agents.
Preferably, in the peelable nail polish gel for high-precision ink-jet nail polish printing provided by the invention, the viscosity of the peelable nail polish gel is 3-20 CPS.
The second aspect of the present invention also provides a method for preparing the peelable nail polish gel for the high-precision inkjet nail polish printing of the first aspect, comprising the steps of: and (2) uniformly mixing the acrylate monomer and the photoinitiator in a reaction kettle, adding the polyurethane acrylate oligomer, stirring while adding the leveling agent, the defoaming agent and the essence, and stirring uniformly to obtain the methyl-acrylate adhesive.
Compared with the prior art, the nail polish gel has the advantages that the nail polish gel composition formula is adjusted, the raw materials with proper viscosity and performance are selected, the proportion of the active monomers is increased on the basis of ensuring the use performance, the final product has low viscosity and strippability, the nail polish gel can be used for high-precision nail polish printing, and nails do not need to be polished or harmful acetone and other nail polish removing water is not used during nail polish removing. The nail polish gel provided by the invention has extremely low viscosity, the viscosity is 3-20 CPs, and the nail polish gel can be perfectly suitable for high-precision nail printing; the material is composed of strippable components, and the product has strippable performance after being printed on a nail by a high-precision printer and is convenient to strip. Compared with the traditional nail polish gel nail polish removing method which needs to be treated by organic solvents such as acetone, the nail polish gel has the remarkable advantages of long retention time, health, environmental protection, easiness in stripping and the like.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, embodiments of the present invention will be described in detail below. However, it will be appreciated by those of ordinary skill in the art that numerous technical details are set forth in order to provide a better understanding of the present application in various embodiments of the present invention. However, the technical solution claimed in the present application can be implemented without these technical details and various changes and modifications based on the following embodiments.
The embodiment of the invention provides a peelable nail polish gel for high-precision ink-jet nail printing, which comprises the following components in parts by mass: urethane acrylate oligomer: 10-30 parts; acrylate ester monomer: 65-75 parts of a solvent; photoinitiator (2): 1-10 parts; leveling agent: 0.1-0.5 part; defoaming agent: 0.1-0.5 part; essence: 0.1-0.5 part; the viscosity of the polyurethane acrylate oligomer is 10-120 CPs, and the viscosity of the acrylate monomer is 2-15 CPs.
In some embodiments of the present invention, the urethane acrylate oligomer has a viscosity of 50 to 80CPs, and the acrylate monomer has a viscosity of 6 to 10 CPs.
In some embodiments of the invention, the urethane acrylate oligomer is selected from at least one of a urethane acrylate oligomer and a silicone-modified urethane acrylate oligomer.
In some embodiments of the present invention, the acrylate monomer is selected from a monofunctional acrylate monomer, a multifunctional acrylate monomer, or a mixture thereof. More preferably, the acrylate monomer is selected from one or more of ethoxyethoxyethyl acrylate, tetrahydrofuran acrylate, isobornyl acrylate, cyclotrimethylolpropane formal acrylate, trimethylolpropane triacrylate, and propoxylated neopentyl diacrylate.
In some embodiments of the invention, the photoinitiator is selected from at least one of 1-hydroxycyclohexyl phenyl ketone, ethyl 2,4, 6-trimethylbenzoylphenylphosphonate, and 2,4, 6-trimethylbenzophenone.
In some embodiments of the present invention, the leveling agent is selected from at least one of an organosilicon leveling agent, a polyether-modified organosilicon leveling agent, and a fluorocarbon-modified acrylate polymer; preferably, the leveling agent is a modified polydioxysiloxane.
In some embodiments of the invention, the defoamer is selected from at least one of polyether-based defoamers and silicone-based defoamers.
In some embodiments of the invention, the viscosity of the peelable nail polish gel is 3 to 20 CPS.
Some embodiments of the present invention further provide a method for preparing a peelable nail polish gel for high-precision inkjet nail printing, including the steps of: and (2) uniformly mixing the acrylate monomer and the photoinitiator in a reaction kettle, adding the polyurethane acrylate oligomer, stirring while adding the leveling agent, the defoaming agent and the essence, and stirring uniformly to obtain the methyl-acrylate adhesive.
The nail printing method by using the nail polish gel provided by the invention comprises the following steps: the nail polish gel is placed in a light-proof ink box of a nail art printer, after a printing instruction is sent, a nail polish gel product can flow through an ink path pipeline and is printed on a nail through a spray head, and the operation is simple; after UV curing, the nail polish gel can be easily peeled off from the nail.
According to the invention, by adjusting the composition formula of nail polish gel and selecting raw materials with appropriate viscosity and performance, the proportion of active monomers is increased on the basis of ensuring the service performance, so that the final product has low viscosity and strippability, can be used for high-precision nail printing, and does not need to polish nails or use harmful nail polish remover such as acetone during nail polish removing. The nail polish gel provided by the invention has extremely low viscosity, the viscosity is 3-20 CPs, and the nail polish gel can be perfectly suitable for high-precision nail printing; the material is composed of strippable components, and the product has strippable performance after being printed on a nail by a high-precision printer and is convenient to strip. Compared with the traditional nail polish gel nail polish removing method which needs to be treated by organic solvents such as acetone, the nail polish gel has the remarkable advantages of long retention time, health, environmental protection, easiness in stripping and the like. The following examples 1 to 4 and comparative examples illustrate the effect of the formulation of the nail polish gel of the present invention on the viscosity and strippability of the nail polish gel.
Experimental examples 1 to 5 and comparative examples 1 to 6
Uniformly mixing an acrylate monomer (ethoxy ethyl acrylate) and a photoinitiator (1-hydroxycyclohexyl phenyl ketone) in a reaction kettle, adding a polyurethane acrylate oligomer (polyurethane acrylate oligomer), stirring while adding a leveling agent (modified poly-dioxysiloxane), a defoaming agent (non-silicon organic polymer defoaming agent) and essence, and uniformly stirring to obtain the methyl-gasoline adhesive.
The raw material parameters of examples 1 to 5 and comparative examples 1 to 6 are shown in Table 1:
TABLE 1
The methyl oil glues prepared in examples 1 to 5 and comparative examples 1 to 6 were subjected to viscosity detection and strippability detection according to the following methods:
(1) the viscosity detection method comprises the following steps:
the viscosity was measured by using a digital rotational viscometer NDJ-9S. The specific experimental method is as follows:
1. the instrument is adjusted so that the instrument is horizontal.
2. The sample to be tested is poured into a round flat-bottom container with the diameter not less than 70mm (a special container is used in the test of a No. 0 rotor), and the container is placed in a constant temperature environment, and the temperature is controlled to be 25 ℃.
3. The appropriate rotor is selected and screwed onto the spindle coupling of the machine.
4. The height of the instrument is adjusted, the rotor is immersed into the sample, and the liquid level scale line is kept level with the measured liquid level.
5. And opening an instrument switch, selecting a proper rotor and a proper rotating speed to enable the torque value to be 10% -90%, and reading the viscosity value after the viscosity value displayed by the instrument is stable.
(2) The method for detecting the strippability comprises the following steps:
1. pouring the tested sample into a sample bottle of a nail beautifying machine, starting the nail beautifying machine, and printing the tested sample on the nail.
2. The finger was moved under an ultraviolet curing lamp to cure the sample coating.
3. After the coating is completely cured, the coating is peeled off from the nail by hand, and the peeling performance of the coating is divided into the following steps according to the peeling difficulty of the coating: easy peel and monolithic peel 1, easy peel but not monolithic peel 2, peel 3, difficult peel 4, not peel 5.
The results of the viscosity test and the peelability test of the nail polish glues in examples 1 to 5 and comparative examples 1 to 6 are shown in table 2:
TABLE 2
| Viscosity of the oil | Whether nail art printing is possible | Peelability of | |
| Example 1 | 7.35 | Is that | 2 |
| Example 2 | 13.27 | Is that | 1 |
| Example 3 | 17.29 | Is that | 1 |
| Example 4 | 4.51 | Is that | 3 |
| Example 5 | 11.2 | Is that | 1 |
| Comparative example 1 | 14.91 | Is that | 4 |
| Comparative example 2 | 9.38 | Is that | 4 |
| Comparative example 3 | 23.17 | Whether or not | / |
| Comparative example 4 | 6.9 | Is that | 5 |
| Comparative example 5 | 25.34 | Whether or not | / |
| Comparative example 6 | 35.78 | Whether or not | / |
As can be seen from the detection data in Table 2, the nail polish gel prepared in the embodiments 1-5 has extremely low viscosity, and can be perfectly suitable for high-precision nail printing; the product has strippable performance after being printed on a nail surface by a high-precision printer, and is convenient to strip. Moreover, the mass part ratio of the components in the nail polish gel, the viscosity of the polyurethane acrylate oligomer and the viscosity of the acrylate monomer have important influence on the technical effect of the invention, and the nail polish gels of comparative examples 1 to 6 are obviously inferior to examples 1 to 5 in the aspects of adaptability and strippability of high-precision nail polish printing.
It will be understood by those of ordinary skill in the art that the foregoing embodiments are specific examples for carrying out the invention, and that various changes in form and details may be made therein without departing from the spirit and scope of the invention in practice.
Claims (10)
1. A peelable nail polish gel for high-precision ink-jet nail printing is characterized by comprising the following components in parts by mass:
urethane acrylate oligomer: 10-30 parts;
acrylate ester monomer: 65-75 parts of a solvent;
photoinitiator (2): 1-10 parts;
leveling agent: 0.1-0.5 part;
defoaming agent: 0.1-0.5 part;
essence: 0.1-0.5 part;
the viscosity of the polyurethane acrylate oligomer is 10-120 CPs, and the viscosity of the acrylate monomer is 2-15 CPs.
2. The peelable nail polish gel for high precision ink jet nail printing according to claim 1, wherein the urethane acrylate oligomer has a viscosity of 50 to 80CPs and the acrylate monomer has a viscosity of 6 to 10 CPs.
3. The peelable nail polish gel for high precision inkjet nail printing according to claim 1, wherein the urethane acrylate oligomer is selected from at least one of a urethane acrylate oligomer and a silicone-modified urethane acrylate oligomer.
4. The peelable nail polish gel for high precision ink jet nail printing according to claim 1, wherein the acrylate monomer is selected from a monofunctional acrylate monomer, a multifunctional acrylate monomer or a mixture thereof.
5. The peelable nail polish gel for high precision inkjet nail printing according to claim 4, wherein the acrylate monomer is selected from one or more of ethoxyethoxyethyl acrylate, tetrahydrofuran acrylate, isobornyl acrylate, cyclotrimethylolpropane formal acrylate, trimethylolpropane triacrylate and propoxylated neopentyl diacrylate.
6. The peelable nail polish gel for high precision ink jet nail printing according to claim 1, wherein the photoinitiator is selected from at least one of 1-hydroxycyclohexyl phenyl ketone, ethyl 2,4, 6-trimethylbenzoylphenyl phosphonate and 2,4, 6-trimethylbenzophenone.
7. The nail-peelable oil glue for high-precision inkjet nail printing according to claim 1, wherein the leveling agent is selected from at least one of a silicone leveling agent, a polyether-modified silicone leveling agent, and a fluorocarbon-modified acrylate polymer; preferably, the leveling agent is a modified polydioxysiloxane.
8. The nail polish remover for high-precision ink-jet nail printing according to claim 1, wherein the defoaming agent is at least one selected from polyether defoaming agents and silicone defoaming agents.
9. The peelable nail polish gel for high-precision inkjet nail printing according to claim 1, wherein the viscosity of the peelable nail polish gel is 3 to 20 CPS.
10. The method for preparing the peelable nail polish gel for high-precision ink-jet nail polish printing according to any one of claims 1 to 9, comprising the following steps:
and (2) uniformly mixing the acrylate monomer and the photoinitiator in a reaction kettle, adding the polyurethane acrylate oligomer, stirring while adding the leveling agent, the defoaming agent and the essence, and stirring uniformly to obtain the methyl-acrylate adhesive.
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| CN202111574507.4A CN114392208B (en) | 2021-12-21 | 2021-12-21 | Strippable nail polish gel for high-precision ink-jet nail-beautifying printing and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115011236A (en) * | 2022-06-24 | 2022-09-06 | 中山森伯马工艺品有限公司 | Matte resin composition, preparation method thereof, matte film and artificial nail |
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|---|---|---|---|---|
| AU2013203042A1 (en) * | 2009-07-21 | 2013-05-02 | Danny Lee Haile | Compositions for removable gel applications for nails and methods of their use |
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| US20170151148A1 (en) * | 2015-12-01 | 2017-06-01 | Shanghai O'Nine Technologies Ltd. | Nail gel polish and its manufacturing method |
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| CN114392208B (en) | 2024-05-03 |
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