CN114258427A - 压花的洗涤剂固体 - Google Patents

压花的洗涤剂固体 Download PDF

Info

Publication number: CN114258427A
Authority: CN; China
Prior art keywords: acid; solid; weight; detergent; embossed
Prior art date: 2019-08-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

CN202080058725.XA

Other languages

English (en)

Chinese (zh)

Inventor

L·E·戴维斯

A·F·布克斯德卡松

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever IP Holdings BV

Original Assignee

Unilever IP Holdings BV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2019-08-21

Filing date

2020-08-20

Publication date

2022-03-29

2020-08-20 Application filed by Unilever IP Holdings BV filed Critical Unilever IP Holdings BV

2022-03-29 Publication of CN114258427A publication Critical patent/CN114258427A/zh

Status Pending legal-status Critical Current

Links

239000007787 solid Substances 0.000 title claims abstract description 173
239000003599 detergent Substances 0.000 title claims abstract description 112
239000002253 acid Substances 0.000 claims abstract description 64
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
150000007524 organic acids Chemical class 0.000 claims abstract description 35
239000000203 mixture Substances 0.000 claims description 41
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 34
238000004049 embossing Methods 0.000 claims description 33
229920000642 polymer Polymers 0.000 claims description 30
238000000034 method Methods 0.000 claims description 21
239000007864 aqueous solution Substances 0.000 claims description 19
230000008569 process Effects 0.000 claims description 16
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
230000005540 biological transmission Effects 0.000 claims description 15
239000007788 liquid Substances 0.000 claims description 15
150000003839 salts Chemical class 0.000 claims description 14
238000000149 argon plasma sintering Methods 0.000 claims description 13
CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 12
238000004519 manufacturing process Methods 0.000 claims description 11
235000015165 citric acid Nutrition 0.000 claims description 10
229920005646 polycarboxylate Polymers 0.000 claims description 10
239000008247 solid mixture Substances 0.000 claims description 10
VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 claims description 8
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 8
239000011363 dried mixture Substances 0.000 claims description 7
150000007513 acids Chemical class 0.000 claims description 6
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 6
235000011054 acetic acid Nutrition 0.000 claims description 5
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 4
238000001704 evaporation Methods 0.000 claims description 4
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235000013922 glutamic acid Nutrition 0.000 claims description 4
239000004220 glutamic acid Substances 0.000 claims description 4
239000004310 lactic acid Substances 0.000 claims description 4
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229910052757 nitrogen Inorganic materials 0.000 claims description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 3
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
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JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 3
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238000002834 transmittance Methods 0.000 claims description 3
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 2
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239000000047 product Substances 0.000 description 92
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HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
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239000003086 colorant Substances 0.000 description 6
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NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
239000010452 phosphate Substances 0.000 description 6
239000003760 tallow Substances 0.000 description 6
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
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OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
229910000288 alkali metal carbonate Inorganic materials 0.000 description 4
150000008041 alkali metal carbonates Chemical class 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
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PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 description 3
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CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 3
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
239000012190 activator Substances 0.000 description 3
239000003513 alkali Substances 0.000 description 3
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OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 3
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150000002191 fatty alcohols Chemical class 0.000 description 3
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239000002243 precursor Substances 0.000 description 3
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XMWLVXXYIYBETQ-UHFFFAOYSA-N 2-hydroxy-3-(2-methylprop-2-enoylamino)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)NCC(O)CS(O)(=O)=O XMWLVXXYIYBETQ-UHFFFAOYSA-N 0.000 description 2
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VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
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Images

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0091—Dishwashing tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Emergency Medicine (AREA)
Detergent Compositions (AREA)
Polysaccharides And Polysaccharide Derivatives (AREA)

CN202080058725.XA 2019-08-21 2020-08-20 压花的洗涤剂固体 Pending CN114258427A (zh)

Applications Claiming Priority (13)

Application Number	Priority Date	Filing Date	Title
EP19192831.6		2019-08-21
EP19192834.0		2019-08-21
EP19192833		2019-08-21
EP19192833.2		2019-08-21
EP19192836.5		2019-08-21
EP19192827		2019-08-21
EP19192836		2019-08-21
EP19192834		2019-08-21
EP19192828.2		2019-08-21
EP19192831		2019-08-21
EP19192827.4		2019-08-21
EP19192828		2019-08-21
PCT/EP2020/073278 WO2021032815A1 (en)	2019-08-21	2020-08-20	An embossed detergent solid

Publications (1)

Publication Number	Publication Date
CN114258427A true CN114258427A (zh)	2022-03-29

Family

ID=72086878

Family Applications (6)

Application Number	Title	Priority Date	Filing Date
CN202080058492.3A Pending CN114269889A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058749.5A Pending CN114341325A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058583.7A Pending CN114302947A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058726.4A Pending CN114341330A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058501.9A Pending CN114286854A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058725.XA Pending CN114258427A (zh)	2019-08-21	2020-08-20	压花的洗涤剂固体

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Application Number	Title	Priority Date	Filing Date
CN202080058492.3A Pending CN114269889A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058749.5A Pending CN114341325A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058583.7A Pending CN114302947A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058726.4A Pending CN114341330A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物
CN202080058501.9A Pending CN114286854A (zh)	2019-08-21	2020-08-20	洗涤剂固体组合物

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CN (6)	CN114269889A (es)
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GB202109205D0 (en) *	2021-06-25	2021-08-11	Innospec Ltd	Compositions

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EP4017955A1 (en)	2022-06-29
EP4017952B1 (en)	2023-03-22
CN114286854A (zh)	2022-04-05
EP4017953A1 (en)	2022-06-29
CN114302947A (zh)	2022-04-08
EP4017952A1 (en)	2022-06-29
EP4017956A1 (en)	2022-06-29
WO2021032817A1 (en)	2021-02-25
EP4017954B1 (en)	2023-04-05
EP4017954A1 (en)	2022-06-29
ES2942916T3 (es)	2023-06-07
EP4017953B1 (en)	2023-04-12
ES2944450T3 (es)	2023-06-21
WO2021032818A1 (en)	2021-02-25
CN114269889A (zh)	2022-04-01
ES2944952T3 (es)	2023-06-27
CN114341325A (zh)	2022-04-12
EP4017955B1 (en)	2023-03-22
CN114341330A (zh)	2022-04-12
ES2943127T3 (es)	2023-06-09
WO2021032834A1 (en)	2021-02-25
EP4017957B1 (en)	2023-03-29
ES2943558T3 (es)	2023-06-14
WO2021032816A1 (en)	2021-02-25
EP4017957A1 (en)	2022-06-29
EP4017956B1 (en)	2023-03-15
ES2945459T3 (es)	2023-07-03
WO2021032815A1 (en)	2021-02-25
WO2021032833A1 (en)	2021-02-25

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Publication	Publication Date	Title
CN111788293B (zh)	2021-10-26	包含氨基多羧酸盐和有机酸的洗涤剂固体组合物
CN114258427A (zh)	2022-03-29	压花的洗涤剂固体
US20210040417A1 (en)	2021-02-11	Detergent solid composition comprising aminopolycarboxylate and organic acid