CN114014405B - Waste water treatment recovery system of smart glufosinate-ammonium solvent - Google Patents
Waste water treatment recovery system of smart glufosinate-ammonium solvent Download PDFInfo
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- CN114014405B CN114014405B CN202210003437.5A CN202210003437A CN114014405B CN 114014405 B CN114014405 B CN 114014405B CN 202210003437 A CN202210003437 A CN 202210003437A CN 114014405 B CN114014405 B CN 114014405B
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- glufosinate
- turnover
- liquid
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- ammonium
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- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000002904 solvent Substances 0.000 title claims abstract description 19
- 238000011084 recovery Methods 0.000 title claims abstract description 15
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 97
- 230000007246 mechanism Effects 0.000 claims abstract description 95
- 239000000835 fiber Substances 0.000 claims abstract description 56
- 238000006731 degradation reaction Methods 0.000 claims abstract description 37
- 230000015556 catabolic process Effects 0.000 claims abstract description 36
- 230000007306 turnover Effects 0.000 claims abstract description 34
- 239000002351 wastewater Substances 0.000 claims abstract description 33
- 239000011941 photocatalyst Substances 0.000 claims abstract description 10
- 238000005086 pumping Methods 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000011858 nanopowder Substances 0.000 claims description 6
- 238000004064 recycling Methods 0.000 claims description 4
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 16
- 238000005286 illumination Methods 0.000 abstract description 12
- 230000008569 process Effects 0.000 abstract description 7
- 230000000593 degrading effect Effects 0.000 abstract description 4
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 238000007146 photocatalysis Methods 0.000 abstract description 3
- 230000001699 photocatalysis Effects 0.000 abstract description 3
- 238000013032 photocatalytic reaction Methods 0.000 abstract description 3
- 230000009471 action Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000010586 diagram Methods 0.000 description 5
- 239000012466 permeate Substances 0.000 description 5
- 238000006073 displacement reaction Methods 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 230000002363 herbicidal effect Effects 0.000 description 4
- 239000004009 herbicide Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 244000025254 Cannabis sativa Species 0.000 description 1
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The application particularly relates to a wastewater treatment and recovery system for a refined glufosinate-ammonium solvent, which belongs to the field of photocatalysis and comprises a degradation mechanism and a turnover mechanism, wherein the degradation mechanism comprises an outer frame and capillary fibers, and a liquid inlet flow channel and a liquid outlet flow channel are arranged in the outer frame; two ends of the capillary fiber are respectively arranged in the liquid inlet flow channel and the liquid outlet flow channel, and the capillary fiber is loaded with a photocatalyst; the turnover mechanism comprises an upright post, a ray tracker and a turnover motor, the turnover motor is arranged on the side face of the upright post, and the output shaft is connected with the outer framework. The precision glufosinate-ammonium wastewater is permeated through capillary fibers loaded with a photocatalyst, the specific surface area of photocatalytic reaction is improved, the light ray tracker tracks the light ray angle, the turnover degradation mechanism of the turnover mechanism is controlled to track the light ray, the irradiation angle of the light ray is parallel to the capillary fiber net of the turnover mechanism as far as possible, the illumination intensity of a unit area is enhanced, the process of degrading the precision glufosinate-ammonium wastewater can be realized through natural illumination, and the energy consumption is reduced.
Description
Technical Field
The application relates to the field of photocatalysis, in particular to a wastewater treatment and recovery system for an accurate glufosinate-ammonium solvent.
Background
The chemical formula of glufosinate-ammonium is C5H15N2O4P, an organic herbicide, has broad herbicidal spectrum, low toxicity, high activity and environmental compatibilityGood and the like; the herbicide has wide herbicide controlling spectrum and good weed control effect on most of annual and perennial weeds in farmlands. The refined glufosinate-ammonium is an L-type isomer of glufosinate-ammonium, is low in toxicity, safe, easy to degrade in soil, safe to crops, small in drift and safe to nearby crops.
In China, a Strecker method is mostly adopted to synthesize glufosinate-ammonium, and the glufosinate-ammonium is converted into L-glufosinate-ammonium through chiral induction, chiral catalysis or chiral splitting and the like, but a large amount of organic wastewater is generated in the production process of the glufosinate-ammonium, the COD of the organic wastewater is as high as 100000mg/L, and the existing method for degrading organic matters in the refined glufosinate-ammonium wastewater is mainly an electrochemical oxidation method, but the method is high in energy consumption.
Disclosure of Invention
The application provides a waste water treatment recovery system of smart glufosinate-ammonium solvent to solve the technical problem that the organic matter power consumption is high in the degradation smart glufosinate-ammonium waste water among the prior art.
A waste water treatment recovery system of refined glufosinate-ammonium solvent comprises:
the degradation mechanism comprises an outer frame and capillary fibers, and a liquid inlet flow channel and a liquid outlet flow channel are arranged in the outer frame; one end of the capillary fiber is arranged in the liquid inlet flow channel, the other end of the capillary fiber is arranged in the liquid outlet flow channel, and the capillary fiber is loaded with a photocatalyst;
tilting mechanism, including stand, ray tracker and upset motor, the upset motor is located the side of stand, the output shaft of upset motor with outer frame attach, ray tracker control the upset motor upset outer frame.
Optionally, the number of the turnover mechanisms is two, the outer frame is a hexagonal frame, and a pair of opposite side edges of the outer frame are respectively connected with the turnover motors of the two turnover mechanisms.
Optionally, a top of the outer frame, which is far away from the two sides connected to the flipping motor, is further provided with a liquid inlet and a liquid outlet, the liquid inlet is communicated with the liquid inlet flow channel, and the liquid outlet is communicated with the liquid outlet flow channel.
Optionally, the apparatus further comprises a rotation mechanism, the rotation mechanism comprising:
an annular base;
the rotary base is annular, an annular groove corresponding to the annular base is formed in the bottom surface of the rotary base, gear teeth are arranged on the peripheral side of the rotary base, and the turnover mechanism is arranged on the top surface of the rotary base;
the driving part, the driving part includes driving motor and drive gear, driving motor's output shaft with drive gear connects, drive gear with the gear teeth meshing, ray tracker control driving motor rotates.
Optionally, the apparatus further comprises:
the feeding groove is arranged above the degradation mechanism;
the discharging groove is arranged below the degradation mechanism and is used for receiving liquid flowing out of the degradation mechanism;
the liquid inlet end of the pumping mechanism is arranged in the discharging groove, and the liquid outlet end of the pumping mechanism is arranged in the feeding groove;
and the liquid inlet end of the liquid guide mechanism is arranged in the feeding groove, and the liquid outlet end of the liquid guide mechanism is communicated with the liquid inlet flow channel.
Optionally, the liquid guiding mechanism includes:
the barb is hung on the top edge of the feeding groove, and an accommodating channel is arranged inside the barb;
the telescopic passage is arranged in the telescopic joint, and one end of the telescopic joint is communicated with the inside of the barb;
the connecting joint is internally provided with a connecting channel, and the other end of the telescopic joint is rotatably connected and communicated with one end of the connecting joint;
the first rotating block is internally provided with a rotating channel, the first rotating block is communicated with the other end of the connecting joint, and the first rotating block is rotatably connected and communicated with the outer frame;
the drain fiber, the fibrous one end of drain is located in the material loading groove, the other end passes through in proper order hold the passageway flexible passageway link channel rotate the passageway with inlet channel with capillary fiber connects.
Optionally, a first opening is formed in the side face of the telescopic joint, a rotary connecting portion is arranged on the outer side of the first opening, a second opening is formed in the side face of the connecting joint, and the rotary connecting portion is arranged in the second opening and is rotatably connected with the second opening, so that the first opening is communicated with the second opening.
Optionally, the inner side wall of the feeding groove is provided with a sliding groove along the length direction, and the outer side wall of the barb is provided with a corresponding sliding strip.
Optionally, the degradation mechanisms are multiple, are arranged in an array along the length direction of the feeding trough, and are connected with the corresponding turnover mechanisms.
Optionally, the photocatalyst is titanium dioxide nanopowder or bismuth tungstate nanopowder.
Compared with the prior art, the technical scheme provided by the embodiment of the application has the following advantages:
the fine glufosinate-ammonium wastewater enters from the liquid inlet flow channel, is absorbed by one end of the capillary fiber, then permeates along the capillary fiber, permeates to the other end of the capillary fiber under the combined action of gravity and capillary effect, finally enters the liquid outlet flow channel, is collected in the liquid outlet flow channel, and drives the degradation mechanism to overturn by the overturning mechanism, so that the degradation mechanism is always opposite to sunlight. Smart glufosinate-ammonium waste water is through permeating along the capillary fibre that is loaded with photocatalyst, the specific surface area of photocatalytic reaction has greatly been promoted, ray tracker pursuit light angle simultaneously, and control tilting mechanism upset degradation mechanism pursuit light, make the illumination angle of light parallel with tilting mechanism's capillary fibre web as far as possible, greatly strengthened unit area's illumination intensity, make the process of degrading smart glufosinate-ammonium waste water realize through natural illumination, reduced the energy consumption.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the invention and together with the description, serve to explain the principles of the invention.
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without inventive exercise.
FIG. 1 is a schematic structural diagram of a degradation mechanism and a turnover mechanism of a wastewater treatment and recovery system for a refined glufosinate-ammonium solvent provided by an embodiment of the present application;
FIG. 2 is a schematic diagram of the internal structure of a degradation mechanism of a wastewater treatment and recovery system for refined glufosinate-ammonium solvent provided in the embodiment of the present application;
fig. 3 is a schematic structural diagram of a rotating mechanism of a wastewater treatment and recovery system for refined glufosinate-ammonium solvent provided in an embodiment of the present application;
FIG. 4 is a schematic diagram of the general structure of a wastewater treatment and recovery system for refined glufosinate-ammonium solvent provided by the embodiment of the present application;
FIG. 5 is a schematic structural diagram of a drainage mechanism of a wastewater treatment and recovery system for refined glufosinate-ammonium solvent provided in an embodiment of the present application;
fig. 6 is an enlarged view of the area a in fig. 4.
Reference numerals:
1-degradation mechanism, 11-outer frame, 111-liquid inlet flow channel, 112-liquid outlet flow channel, 113-liquid inlet, 114-liquid outlet, 115-rotation part, 12-capillary fiber;
2-a turnover mechanism, 21-an upright post and 22-a turnover motor;
3-rotation mechanism, 31-annular base, 32-rotation base, 321-gear teeth, 33-driving part, 331-driving motor and 332-driving gear;
4-feeding trough, 41-chute;
5-feeding trough;
6-a pumping mechanism;
7-a liquid guiding mechanism, 71-a barb, 711-an accommodating channel, 712-a sliding strip, 72-a telescopic joint, 721-a telescopic channel, 722-a rotary connecting part, 73-a connecting joint, 731-a connecting channel, 74-a first rotating block, 741-a rotating channel and 75-liquid guiding fibers;
8-strip-shaped base, 81-sliding groove.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are some embodiments of the present application, but not all embodiments. All other embodiments obtained by a person of ordinary skill in the art based on the embodiments in the present application without making creative efforts shall fall within the protection scope of the present application.
As shown in fig. 1 and 2, a system for treating and recycling wastewater of an refined glufosinate-ammonium solvent comprises:
the degradation mechanism 1 comprises an outer frame 11 and capillary fibers 12, wherein a liquid inlet flow channel 111 and a liquid outlet flow channel 112 are arranged in the outer frame 11; one end of the capillary fiber 12 is arranged in the liquid inlet flow passage 111, the other end of the capillary fiber 12 is arranged in the liquid outlet flow passage 112, a photocatalyst is loaded on the capillary fiber 12, and the photocatalyst is titanium dioxide nanopowder or bismuth tungstate nanopowder;
The refined glufosinate-ammonium wastewater enters from the liquid inlet flow channel 111, is absorbed by one end of the capillary fiber 12, then permeates along the capillary fiber 12, permeates to the other end of the capillary fiber 12 under the combined action of gravity and capillary effect, finally enters the liquid outlet flow channel 112, is collected in the liquid outlet flow channel 112, and the turnover mechanism 2 drives the degradation mechanism 1 to turn over, so that the degradation mechanism 1 always faces the sunlight. Refined glufosinate ammonium waste water is through permeating along the capillary fibre 12 that is loaded with photocatalyst, photocatalytic reaction's specific surface area has greatly been promoted, not only can accept illumination towards the one side of sunlight, the environment illumination also can be accepted at the back, ray tracker traces the light angle simultaneously, and control 2 upset degradation mechanism 1 pursuits light of tilting mechanism, make the illumination angle of light perpendicular with tilting mechanism 2's capillary fibre 12 net as far as possible, unit area's illumination intensity has greatly been strengthened, make the process of degrading refined glufosinate ammonium waste water realize through natural illumination, the energy consumption has been reduced.
In the present embodiment, the capillary fibers 12 may be any substance capable of generating a capillary effect, such as natural fibers, artificial fibers, or capillaries.
As an embodiment of the present application, there are two turnover mechanisms 2, the outer frame 11 is a hexagonal frame, and a pair of opposite sides of the outer frame 11 are respectively connected to two turnover motors 22 of the turnover mechanisms 2. The top point of the side edge of the outer frame 11 far away from the two connecting turning motors 22 is further provided with a liquid inlet 113 and a liquid outlet 114, the liquid inlet 113 is communicated with the liquid inlet flow passage 111, and the liquid outlet 114 is communicated with the liquid outlet flow passage 112.
The liquid inlet 113 is arranged at one vertex of the hexagonal outer frame 11 and serves as the highest point of the whole outer frame 11, after the refined glufosinate ammonium wastewater enters from the liquid inlet 113, the refined glufosinate ammonium wastewater naturally flows towards two sides along the liquid inlet flow channel 111 due to the action of gravity, and similarly, after the refined glufosinate ammonium wastewater passes through the capillary fibers 12, the refined glufosinate ammonium wastewater is separated from the tail ends of the capillary fibers 12 due to the action of gravity and is collected in the liquid outlet flow channel 112, and then is collected and flows out from the lowest point of the hexagonal outer frame 11, namely the liquid outlet 114. Simultaneously for the quadrilateral frame that two summits interval are equal, the width is equal, hexagonal outer frame 11 can be when guaranteeing that liquid can flow naturally, and hexagonal outer frame 11 is longer by the length of the capillary fiber 12 of the opposite side of both sides, and then reduces the length difference of longest capillary fiber 12 and shortest capillary fiber 12 to the infiltration journey of extension grass ammonium phosphine wastewater on capillary fiber 12, extension reaction time promotes the degradation effect.
As shown in fig. 3, as an embodiment of the present application, the apparatus further includes a rotation mechanism 3, and the rotation mechanism 3 includes:
an annular base 31;
the rotary base 32 is annular, an annular groove corresponding to the annular base 31 is formed in the bottom surface of the rotary base 32, gear teeth 321 are arranged on the peripheral side of the rotary base 32, and the turnover mechanism 2 is arranged on the top surface of the rotary base 32;
and the driving part 33, the driving part 33 includes a driving motor 331 and a driving gear 332, an output shaft of the driving motor 331 is connected to the driving gear 332, the driving gear 332 is engaged with the gear teeth 321, and the ray tracker controls the driving motor 331 to rotate.
Due to the different irradiation angles of the sun in different regions, if the sunlight is tracked by turning over only, the method is only suitable for the regions within the return line of south and north, and is most preferable when the sun is only directly projected on the ground, and the mesh formed by the capillary fibers 12 cannot be kept perpendicular to the sunlight at other times and regions. The rotary base 32 is arranged to drive the whole device to horizontally rotate on the top surface of the annular base 31 so as to track the inclination angle of the solar rays, and the device is suitable for any time in any area with solar illumination.
As shown in fig. 4 as an embodiment of the present application, the apparatus further includes:
the feeding groove 4 is arranged above the degradation mechanism 1;
the discharging groove 5 is arranged below the degradation mechanism 1 and is used for receiving liquid flowing out of the degradation mechanism 1;
the liquid inlet end of the pumping mechanism 6 is arranged in the discharging groove 5, and the liquid outlet end of the pumping mechanism 6 is arranged in the feeding groove 4;
and the liquid inlet end of the liquid guiding mechanism 7 is arranged in the feeding groove 4, and the liquid outlet end of the liquid guiding mechanism 7 is communicated with the liquid inlet flow channel 111.
The top surface of the strip-shaped base 8 is provided with a sliding groove 81 along the width direction of the feeding chute 4, the annular base 31 is arranged on the top surface of the strip-shaped base, and the bottom surface of the annular base 31 is provided with a sliding strip corresponding to the sliding groove 81;
the degradation mechanisms 1 are arranged in an array along the length direction of the feeding trough 4, and each degradation mechanism 1 is correspondingly provided with a turnover mechanism 2, an annular base 31, a rotating base 32, a driving part 33 and a liquid guide mechanism 7.
Let in during fine glufosinate ammonium waste water into last silo 4, during liquid guide mechanism 7 introduces the waste water in last silo 4 into feed liquor runner 111, after the photocatalysis degradation organic matter, in the silo 5 under the liquid outlet 114 outflow entering, then go into again by pumping mechanism 6 pump-in last silo 4, so circulate, can degrade fine glufosinate ammonium waste water repeatedly, until organic matter content is up to standard in the waste water. Meanwhile, the degradation mechanisms 1 form a degradation array, wastewater in the feeding trough 4 is simultaneously introduced into the degradation mechanisms 1, and degradation efficiency can be improved exponentially.
In this embodiment, go up silo 4 and can also be made by transparent material such as glass, can reduce to shelter from, promote the illumination intensity on the degradation mechanism 1.
As shown in fig. 5, the liquid guide mechanism 7 includes, as an embodiment of the present application:
the barb 71 is hung on the top edge of the feeding groove 4, and an accommodating channel 711 is arranged inside the barb 71;
the telescopic joint 72 is composed of a plurality of telescopic sleeves, a telescopic channel 721 is arranged inside the telescopic joint 72, one end of the telescopic joint 72 is communicated with the inside of the barb 71, a first opening is arranged on the side surface of the telescopic joint 72, and a rotary connecting part 722 is arranged on the outer side of the first opening;
the connecting joint 73 is internally provided with a connecting channel 731, the side surface of the connecting joint 73 is provided with a second opening, and the rotary connecting part 722 is arranged in the second opening and is rotatably connected with the second opening so as to enable the first opening to be communicated with the second opening;
a first rotating block 74, wherein a rotating channel 741 is arranged inside the first rotating block 74, the first rotating block 74 is communicated with the other end of the connecting joint 73, a spherical rotating part 115 is arranged at the liquid inlet 113 of the outer frame 11, and the first rotating block 74 is connected and communicated with the rotating part 115;
one end of the liquid guiding fiber 75 is disposed in the feeding trough 4, and the other end of the liquid guiding fiber 75 passes through the accommodating channel 711, the telescopic channel 721, the connecting channel 731, the rotating channel 741 and the liquid inlet channel in sequence to be connected with the capillary fiber 12.
The liquid guiding fiber 75 sucks up the fine glufosinate-ammonium wastewater in the feeding trough 4 due to the capillary effect, and the fine glufosinate-ammonium wastewater enters the liquid inlet channel along the liquid guiding fiber 75, is butted with the capillary fiber 12 and permeates into the capillary fiber 12.
When the rotating base 32 rotates, the rotating portion 115 of the outer frame 11 follows the outer frame 11 to rotate, the first rotating block 74 and other components of the liquid guiding mechanism 7 are kept relatively stationary, and since the rotating portion 115 and the first rotating block 74 are connected by a ball, the outer frame 11 rotates relatively around the spherical first rotating block 74 during the rotation. Specifically, the displacement in the longitudinal direction of the upper trough 4 is realized by the barb 71 sliding along the upper trough 4, the displacement in the width direction of the upper trough 4 is realized by the annular base 31 sliding along the sliding groove 81 of the strip base 8 in the width direction of the upper trough 4, and the rotation is realized by the rotation part 115 and the first rotation block 74 being connected by a ball, so that the array type turnover mechanism 2 can also follow the deflection angle of light to perform certain adjustment, and can adapt to the light angle in most areas on the earth.
As shown in fig. 6, as an embodiment of the present application, the inner side wall of the feeding chute 4 is provided with a sliding groove 41 along the length direction thereof, and the outer side wall of the barb 71 is provided with a corresponding sliding strip 712.
The slide bar 712 and the corresponding slide groove 41 are arranged, and the displacement and deflection of the barb 71 in the vertical direction are further limited, so that the barb 71 can only slide along the length direction of the feeding trough 4, the barb 71 is prevented from being jacked up in the rotating process due to the friction force between each section of the telescopic section 72, and the liquid guide fiber 75 is separated from the fine glufosinate ammonium wastewater.
It is noted that, in this document, relational terms such as "first" and "second," and the like, are used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The foregoing are merely exemplary embodiments of the present invention, which enable those skilled in the art to understand or practice the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (8)
1. The utility model provides a waste water treatment recovery system of smart glufosinate-ammonium solvent which characterized in that includes:
the degradation mechanism (1), the degradation mechanism (1) includes outer frame (11) and capillary fiber (12), the outer frame (11) is a hexagonal frame, and a liquid inlet flow channel (111) and a liquid outlet flow channel (112) are arranged in the outer frame (11); one end of the capillary fiber (12) is arranged in the liquid inlet flow channel (111), the other end of the capillary fiber is arranged in the liquid outlet flow channel (112), and a photocatalyst is loaded on the capillary fiber (12);
the turnover mechanism (2) comprises a stand column (21), a ray tracker and a turnover motor (22), wherein the turnover motor (22) is arranged on the side surface of the stand column (21), an output shaft of the turnover motor (22) is connected with the outer frame (11), and the ray tracker controls the turnover motor (22) to turn over the outer frame (11);
the feeding trough (4) is arranged above the degradation mechanism (1);
the discharging groove (5) is arranged below the degradation mechanism (1) and is used for receiving liquid flowing out of the degradation mechanism (1);
the liquid inlet end of the liquid guiding mechanism (7) is arranged in the feeding groove (4), the liquid outlet end of the liquid guiding mechanism (7) is communicated with the liquid inlet flow channel (111), the liquid guiding mechanism (7) comprises liquid guiding fibers (75), one end of each liquid guiding fiber (75) is arranged in the feeding groove (4), and the other end of each liquid guiding fiber is connected with the capillary fibers (12);
the liquid guide mechanism (7) further comprises:
the barb (71), the barb (71) is hung on the top edge of the feeding trough (4), and an accommodating channel (711) is arranged inside the barb (71);
the telescopic joint (72) is internally provided with a telescopic channel (721), and one end of the telescopic joint (72) is communicated with the inside of the barb (71);
the telescopic joint comprises a connecting joint (73), wherein a connecting channel (731) is arranged in the connecting joint (73), and the other end of the telescopic joint (72) is rotatably connected and communicated with one end of the connecting joint (73);
a first rotating block (74), wherein a rotating channel (741) is arranged inside the first rotating block (74), the first rotating block (74) is communicated with the other end of the connecting joint (73), and the first rotating block (74) is rotatably connected and communicated with the outer frame (11);
the liquid guide fiber (75) is connected with the capillary fiber (12) through the containing channel (711), the telescopic channel (721), the connecting channel (731), the rotating channel (741) and the liquid inlet channel (111) in sequence,
the side of telescopic joint (72) is equipped with first opening, the outside of first opening is equipped with swivelling joint portion (722), the side of connecting joint (73) is equipped with the second opening, swivelling joint portion (722) are located in the second opening and with the second opening rotates and is connected, make first opening and second opening communicate with each other.
2. The system for treating and recycling wastewater containing glufosinate-ammonium solvent according to claim 1, wherein the turnover mechanism (2) has two, and one pair of opposite sides of the outer frame (11) is connected to turnover motors (22) of the two turnover mechanisms (2), respectively.
3. The system for treating and recycling wastewater of glufosinate-ammonium solvent as claimed in claim 2, wherein a liquid inlet (113) and a liquid outlet (114) are further provided at the top of the outer frame (11) far away from the two sides connected to the turning motor (22), the liquid inlet (113) is communicated with the liquid inlet channel (111), and the liquid outlet (114) is communicated with the liquid outlet channel (112).
4. A system for wastewater treatment recovery of glufosinate-ammonium solvent according to claim 1, characterized in that the system further comprises a rotation mechanism (3), the rotation mechanism (3) comprising:
an annular base (31);
the rotary base (32) is annular, an annular groove corresponding to the annular base (31) is formed in the bottom surface of the rotary base (32), gear teeth (321) are arranged on the peripheral side of the rotary base (32), and the turnover mechanism (2) is arranged on the top surface of the rotary base (32);
the driving component (33), the driving component (33) includes a driving motor (331) and a driving gear (332), an output shaft of the driving motor (331) is connected with the driving gear (332), the driving gear (332) is engaged with the gear teeth (321), and the ray tracker controls the driving motor (331) to rotate.
5. The system for wastewater treatment and recovery of glufosinate-ammonium solvent according to claim 1, further comprising:
the liquid inlet end of the pumping mechanism (6) is arranged in the discharging groove (5), and the liquid outlet end of the pumping mechanism (6) is arranged in the feeding groove (4).
6. The system for treating and recovering the wastewater of the glufosinate-ammonium solvent according to claim 1, wherein the inner side wall of the feeding trough (4) is provided with a sliding groove (41) along the length direction thereof, and the outer side wall of the barb (71) is provided with a corresponding sliding strip (712).
7. The system for treating and recycling wastewater containing glufosinate-ammonium as claimed in claim 1, wherein the degradation mechanism (1) is provided in a plurality, arrayed along the length direction of the feeding trough (4), and connected with a plurality of corresponding turnover mechanisms (2).
8. The wastewater treatment recovery system for a glufosinate-ammonium-rich solvent according to any one of claims 1 to 7, wherein the photocatalyst is titanium dioxide nanopowder or bismuth tungstate nanopowder.
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| CN115624710B (en) * | 2022-09-30 | 2023-09-15 | 洪湖市一泰科技有限公司 | Method for treating organic phosphine in glufosinate-ammonium waste salt by photocatalytic degradation |
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Denomination of invention: A Wastewater Treatment and Recovery System for Refined Ammonium Glyphosate Solvent Effective date of registration: 20230423 Granted publication date: 20220524 Pledgee: Bank of Beijing Co.,Ltd. Jinan Branch Pledgor: JINAN TIANBANG CHEMICAL Co.,Ltd. Registration number: Y2023370000075 |
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Denomination of invention: A wastewater treatment and recovery system using a refined ammonium phosphine solvent Granted publication date: 20220524 Pledgee: Huaxia Bank Co.,Ltd. Jinan Branch Pledgor: JINAN TIANBANG CHEMICAL Co.,Ltd. Registration number: Y2024980015202 |