CN106830169A - A kind of capillarity aids in pollution of river thing catalytic degradation device - Google Patents

A kind of capillarity aids in pollution of river thing catalytic degradation device Download PDF

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Publication number
CN106830169A
CN106830169A CN201611224580.8A CN201611224580A CN106830169A CN 106830169 A CN106830169 A CN 106830169A CN 201611224580 A CN201611224580 A CN 201611224580A CN 106830169 A CN106830169 A CN 106830169A
Authority
CN
China
Prior art keywords
water surface
horizontal frame
fibrous braid
capillarity
pollution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611224580.8A
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Chinese (zh)
Inventor
冯婷
马建锋
赵文昌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou University
Original Assignee
Changzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changzhou University filed Critical Changzhou University
Priority to CN201611224580.8A priority Critical patent/CN106830169A/en
Publication of CN106830169A publication Critical patent/CN106830169A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/30—Treatment of water, waste water, or sewage by irradiation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/34—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/38—Organic compounds containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/40—Organic compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007—Contaminated open waterways, rivers, lakes or ponds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/08—Nanoparticles or nanotubes
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/10—Photocatalysts

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  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

The present invention discloses a kind of capillarity auxiliary pollution of river thing catalytic degradation device, it is characterized in that including：One horizontal frame, it is fixed on more than the water surface；Fibrous braid, is covered in the horizontal frame surface, and a line of the fibrous braid hangs down from horizontal frame edge, contacts the water surface, and another a line corresponding thereto also hangs down from horizontal pane edge, close to the water surface without the contact water surface；The fibrous braid surface is also loaded the catalyst with visible light activity.A thin film system for constant flow can be formed without any power, so as to obtain more preferable catalytic effect, and additional means separating catalyst need not be passed through.

Description

A kind of capillarity aids in pollution of river thing catalytic degradation device
Technical field
The present invention relates to a kind of capillarity auxiliary pollution of river thing catalytic degradation device, belong in environmental protection at sewage Reason technical field.
Background technology
Traditional method for treating water efficiency is low, high cost, there are secondary pollution problems, and waste water control always cannot be well Solution.The development and application of nanometer technology are likely to thoroughly solve this problem., A.Fujishima and K.Honda in 1972 In n-type semiconductor TiO2The photoelectrocatalysis decomposition of water, TiO are found that on electrode2Oxidation activity is higher, and chemical stability is good, Harmless to the human body, low cost is pollution-free, has a wide range of application, thus is most paid attention to, and is that current most widely used nanometer light is urged Change material, be also the environmental type catalyst for most developing future.
Research shows, nano-TiO2Various toxic compounds can be processed, can be by the hydro carbons in water, halogenated hydrocarbons, acid, surface Soon complete oxidation is CO for activating agent, dyestuff, itrogenous organic substance, organophosphorus insecticide, timber preservative and fuel oil etc.2、 H2The innocuous substances such as O.But up to the present nano-photo catalytic TiO2Technology is not used widely in terms of wastewater treatment yet, main If because nano particle separates difficulty, without simply applicable processing equipment.
Loaded in carrier surface by nano particle, can solve the problems, such as that particle is separated.But it is loaded with nano particle When carrier is soaked in water, the solution that exciting light must be transmitted through thicker (often more than several centimeters) can just be irradiated to catalysis In agent.And in fact, either in ultraviolet region or visible region, organic solution (especially colored organic wastewater) is all Different degrees of light absorbs are had, this will certainly cause the different degrees of light loss of exciting light, so as to get up to catalyst surface Luminous intensity declines, so that the yield in light induced electron and hole declines, the final degradation efficiency for causing pollutant is reduced.
Patent CN 102515303A disclose a kind of device for photocatalytic abatement of organic pollution of riverway, can obtain preferably Water treatment efficiency, but need the flowing of electric power and water.Equally, several patents such as CN104609571B, CN104609572B are disclosed Method be all that the flowing for needing river can just obtain photocatalysis effect.If the fluid ability of river is not enough to pushing meanss Rotate, then treatment facility may be made to fail.
The content of the invention
The purpose of the present invention is to solve the shortcomings of the prior art, propose a kind of capillarity auxiliary pollution of river thing catalysis Decomposition apparatus, the device is simple, non-power consumption, only utilizes sun light action, you can reach preferable treatment effect.
A kind of capillarity auxiliary pollution of river thing catalytic degradation device disclosed by the invention, including：
One horizontal frame, it is fixed on more than the water surface；
Fibrous braid, is covered in the horizontal frame surface, and the fibrous braid a line from horizontal frame Edge hangs down, and contacts the water surface, and another a line corresponding thereto also hangs down from horizontal pane edge, close to the water surface without contact water Face；
The fibrous braid surface is also loaded the catalyst with visible light activity.
The beneficial effects of the invention are as follows：Using the capillarity of fibrous braid, water is connect from fibrous braid and water Tactile one end capillary is drunk up, and korneforos is instilled from the other end, and relatively thin liquid film is formed on fibrous braid surface, without any dynamic Power can form a thin film system for constant flow, so as to obtain more preferable catalytic effect, and need not pass through additional means Separating catalyst.
Experiment is proved：For the concentration of II containing gold orange in the waste water of 25mg/L, the gold after 12h is persistently processed by the equipment The clearance of orange II is up to 95%.
Brief description of the drawings
Fig. 1 is structural representation of the invention
Specific embodiment
Reference picture, an including horizontal frame 1 is fixed on more than the water surface, and the surface of horizontal frame 1 is coated with fibrous braid 2, the sagging contact water surface in the one end of fibrous braid 2, the other end it is sagging close to the water surface without contact the water surface, the surface of fibrous braid 2 It is loaded with the catalyst with visible light activity.Device is fixed on river course surface during operation, under the irradiation of sunshine Complete organic matter degradation in urban river water.

Claims (1)

1. a kind of capillarity aids in pollution of river thing catalytic degradation device, it is characterized in that including：
One horizontal frame, it is fixed on more than the water surface；
Fibrous braid, is covered in the horizontal frame surface, and the fibrous braid a line from horizontal frame edge Hang down, contact the water surface, another a line corresponding thereto also hangs down from horizontal pane edge, close to the water surface without the contact water surface；
The fibrous braid surface is also loaded the catalyst with visible light activity.
CN201611224580.8A 2016-12-27 2016-12-27 A kind of capillarity aids in pollution of river thing catalytic degradation device Pending CN106830169A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611224580.8A CN106830169A (en) 2016-12-27 2016-12-27 A kind of capillarity aids in pollution of river thing catalytic degradation device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611224580.8A CN106830169A (en) 2016-12-27 2016-12-27 A kind of capillarity aids in pollution of river thing catalytic degradation device

Publications (1)

Publication Number Publication Date
CN106830169A true CN106830169A (en) 2017-06-13

Family

ID=59136488

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611224580.8A Pending CN106830169A (en) 2016-12-27 2016-12-27 A kind of capillarity aids in pollution of river thing catalytic degradation device

Country Status (1)

Country Link
CN (1) CN106830169A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114014405A (en) * 2022-01-05 2022-02-08 济南天邦化工有限公司 Waste water treatment recovery system of smart glufosinate-ammonium solvent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000279820A (en) * 1999-03-29 2000-10-10 Matsushita Electric Ind Co Ltd Photocatalyst
US20130008775A1 (en) * 2011-07-05 2013-01-10 Osman Ahmed Photocatalytic Panel and System for Recovering Output Products Thereof
CN104671458A (en) * 2015-01-26 2015-06-03 常州大学 River pollutant removal device
CN105776410A (en) * 2016-03-28 2016-07-20 朱连文 Flexible bismuth oxybromide-titanium oxide/carbon fiber water-purifying material with capillary water supply and photocatalytic adsorption functions and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000279820A (en) * 1999-03-29 2000-10-10 Matsushita Electric Ind Co Ltd Photocatalyst
US20130008775A1 (en) * 2011-07-05 2013-01-10 Osman Ahmed Photocatalytic Panel and System for Recovering Output Products Thereof
CN104671458A (en) * 2015-01-26 2015-06-03 常州大学 River pollutant removal device
CN105776410A (en) * 2016-03-28 2016-07-20 朱连文 Flexible bismuth oxybromide-titanium oxide/carbon fiber water-purifying material with capillary water supply and photocatalytic adsorption functions and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114014405A (en) * 2022-01-05 2022-02-08 济南天邦化工有限公司 Waste water treatment recovery system of smart glufosinate-ammonium solvent

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Application publication date: 20170613

RJ01 Rejection of invention patent application after publication