CN113937188B - Manufacturing method of zigzag grid line - Google Patents
Manufacturing method of zigzag grid line Download PDFInfo
- Publication number
- CN113937188B CN113937188B CN202111141047.6A CN202111141047A CN113937188B CN 113937188 B CN113937188 B CN 113937188B CN 202111141047 A CN202111141047 A CN 202111141047A CN 113937188 B CN113937188 B CN 113937188B
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- grid line
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- battery piece
- zigzag
- manufacturing
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 238000005520 cutting process Methods 0.000 claims abstract description 34
- 238000007639 printing Methods 0.000 claims abstract description 33
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000000465 moulding Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000007493 shaping process Methods 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 4
- 241000561734 Celosia cristata Species 0.000 description 2
- 210000001520 comb Anatomy 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
- H01L31/022433—Particular geometry of the grid contacts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention discloses a manufacturing method of a serrated grating, which comprises the following steps: and paving a forming layer on the battery piece, forming a grid line printing groove by the forming layer, injecting conductive silver paste into the grid line printing groove, drying the conductive silver paste in the grid line printing groove to form a conductive strip, removing the forming layer, and cutting and forming the conductive strip into a zigzag grid line by a cutting device. The manufacturing method of the serrated grid line has the advantages of high production efficiency and good forming effect.
Description
Technical Field
The invention relates to the technical field of photovoltaic equipment, in particular to a manufacturing method of a zigzag grid line.
Background
With the growing shortage of global energy, solar cells are widely valued in countries around the world, and numerous large companies have been put into the development and production of solar cells internationally. In crystalline silicon solar cells, the positive electrode grid line on the silicon wafer is an essential component for collecting the current emitted by the solar cell, and the performance of the positive electrode grid line directly influences the energy conversion efficiency of the cell. Photoelectric conversion efficiency is an important performance index of a solar cell, and higher photoelectric conversion efficiency is always a target for cell research and development. The resistance of the electrode grid line influences the transmission of electrons, the larger the resistance of the electrode grid line is, the larger the current internal consumption of the battery piece is, the contact area of the upper edge and the lower edge of the electrode grid line is increased to reduce the connection resistance, the forming of the electrode grid line is constrained by the fluidity of conductive silver paste, the processing technology and the like, and the conductive silver paste has certain fluidity, so that the paste collapses to two sides of the grid line in the process to cause the phenomenon of burrs, the width of the grid line is obviously increased, and the efficiency of the battery piece is not improved.
Disclosure of Invention
The present invention aims to solve at least one of the technical problems in the related art to some extent.
Therefore, the embodiment of the invention provides a manufacturing method of the zigzag grating, which has the advantages of high production efficiency and good forming effect.
According to the manufacturing method of the serrated grid line, the manufacturing method comprises the steps of paving a forming layer on a battery piece, forming a grid line printing groove by the forming layer, injecting conductive silver paste into the grid line printing groove, drying the conductive silver paste in the grid line printing groove to form a conductive strip, removing the forming layer, and cutting the conductive strip into the serrated grid line by a cutting device.
According to the manufacturing method of the serrated grid line, the forming layer is arranged, so that the grid line printing groove is formed at the set position of the battery piece, further, the conductive silver paste poured in the grid line printing groove can be solidified and formed into the conductive strip with moderate aspect ratio, and the serrated grid line positioned at the set position of the battery piece can be obtained after cutting is completed. Therefore, the forming of the serrated grid line is accurate and quick, and the production efficiency is high.
In some embodiments, the depth of the grid line forming groove is 30um to 100um, and the width of the grid line forming groove is 20um to 60um.
In some embodiments, the grid line forming grooves are multiple and are distributed on the printed surface of the battery piece at intervals along the width direction of the battery piece, and two grid line forming grooves at edge positions are respectively positioned at two edges of the printed surface in the width direction.
In some embodiments, the molding layer includes a plurality of molding films, the plurality of molding films being spaced apart in a width direction of the battery sheet, the printed grid line being formed between any adjacent molding films.
In some embodiments, two of the formed films at the edge are attached to the side surfaces of the battery sheet and at least partially protrude from the printed surface, and the remaining formed films are attached to the printed surface.
In some embodiments, the molding layer includes a molding sheet having a plurality of the grid line molding grooves thereon.
In some embodiments, the shaped sheet is made of a hard material.
In some embodiments, the cutting device includes a laser modulator spaced apart from the battery cell, and a laser beam emitted from the laser modulator is opposite to the conductive bar in a thickness direction of the battery cell.
In some embodiments, the number of laser beams is equal to the number of biting slopes of the serrated gate lines, the laser beams being used to cut and shape the respective biting slopes.
In some embodiments, the cutting device further comprises a bracket, a cutting platform slidably connected to the bracket and configured to secure the battery piece, and a positioner configured to position the serrated grid line, the laser modulator being mounted to the bracket and spaced apart from the cutting platform in a sliding direction.
In some embodiments, the zigzag gridline fabrication method further includes recycling debris cut from the conductive strip.
Drawings
Fig. 1 is a schematic diagram of a grid line printed groove of a battery plate edge according to an embodiment of the present invention.
Fig. 2 is a schematic diagram of a grid line printed groove of a battery plate printed surface according to an embodiment of the present invention.
Fig. 3 is a schematic view illustrating the operation of the cutting device according to the embodiment of the present invention.
Reference numerals: 1. a gate line printing groove; 2. forming a film; 3. a conductive strip; 4. a battery sheet; 5. a cutting device; 51. a laser modulator; 52. a bracket; 53. a cutting platform; 6. a laser beam.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings. The embodiments described below by referring to the drawings are illustrative and intended to explain the present invention and should not be construed as limiting the invention.
According to the manufacturing method of the zigzag grid line, the manufacturing method comprises the steps of paving a forming layer on a battery piece 4, forming a grid line printing groove 1 by the forming layer, injecting conductive silver paste into the grid line printing groove 1, drying the conductive silver paste in the grid line printing groove 1 to form a conductive strip 3, removing the forming layer, and cutting the conductive strip 3 into the zigzag grid line through a cutting device 5.
According to the manufacturing method of the serrated grid line, the forming layer is arranged, so that the grid line printing groove 1 is formed at the set position of the battery piece 4, the conductive silver paste poured in the grid line printing groove 1 is enabled to be solidified and formed into the conductive strip 3 with the moderate aspect ratio, and the serrated grid line positioned at the set position of the battery piece 4 can be obtained after cutting is completed. Therefore, the forming of the serrated grid line is accurate and quick, and the production efficiency is high.
In some embodiments, the gate line formation groove has a depth of 30um to 100um and a width of 20um to 60um.
As shown in fig. 1, taking an example in which the length direction of the prefabricated serrated gate lines coincides with the length direction of the battery piece 4, the length direction of the battery piece 4 is the a direction, the height of the serrated gate lines means the dimension of the serrated gate lines in the thickness direction of the battery piece 4, i.e., the B direction, and the thickness of the serrated gate lines means the dimension of the serrated gate lines in the width direction of the battery piece 4. At this time, the height of the serrated grating line is equal to the depth of the grating line forming groove, and the thickness of the serrated grating line is equal to the width of the grating line forming groove. Therefore, the width and the height of the solidified conductive strip 3 are guaranteed to be consistent with those of the prefabricated serrated grid line, and then the bevel is only needed to be cut in the subsequent cutting process, so that the production efficiency of the serrated grid line is improved.
In some embodiments, the grid line forming grooves are multiple and are distributed on the printed surface of the battery piece 4 at intervals along the width direction of the battery piece 4, and two grid line forming grooves at edge positions are respectively positioned at two edges of the printed surface in the width direction.
Specifically, the plurality of grid line forming grooves are used to form a plurality of saw-tooth grid lines on the surface of the battery piece 4, and the saw-tooth grid lines are parallel to each other. The border position is the edge of battery piece 4 tip, in battery piece 4 width direction, the grid line shaping groove that is located the tip outwards side and battery piece 4's corresponding terminal surface coplane, from this guarantee two cockscomb structure bars line that are located the border position respectively with battery piece 4 in width direction's both ends face parallel and level, and then reduce the shielding to battery piece 4 behind the stack of two battery pieces 4, increase the effective area of battery piece 4, battery piece 4 photoelectric conversion efficiency improves.
In some embodiments, the shaping layer includes a plurality of shaping films 2, the plurality of shaping films 2 being spaced apart in the width direction of the battery sheet 4, and the printing grid line being formed between any adjacent shaping films 2.
Specifically, the molding film 2 is made of a material which is good in thermoplasticity and has a melting point higher than the solidification temperature of the conductive silver paste, so that the molding film 2 is ensured not to be deformed basically in the process of heating and solidifying the conductive silver paste, and the dimensional accuracy of the molded conductive strip 3 is improved. In addition, after the conductive silver paste is solidified to form the conductive strip 3, the formed film 2 can be torn off for reuse, so that the production cost of the serrated grid line is effectively reduced. Alternatively, the molded film 2 may be a water-soluble molded film 2, and the molded film 2 may be dissolved after the conductive strip 3 is produced.
In some embodiments, two of the formed films 2 at the edge are attached to the side surfaces of the battery piece 4 and at least partially protrude from the printed surface, and the remaining formed films 2 are attached to the printed surface.
The plurality of molding films 2 are adhered to the printing surface of the battery piece 4 in parallel, and the zigzag grid lines formed between the adjacent molding films 2 and the zigzag grid lines formed between the molding film 2 adhered to the side surface of the battery piece 4 and the adjacent molding film 2 adhered to the printing surface are used for forming the zigzag grid lines of the battery piece 4. In the subsequent process, the battery pieces 4 are divided to form a plurality of battery pieces 4, the printing surface of each battery piece 4 is provided with a zigzag grid line, and the zigzag grid lines are positioned at the edge of the printing surface.
In some embodiments, the shaping layer comprises a shaping sheet with a plurality of grid line shaping grooves thereon.
Specifically, the area of the molding piece is slightly larger than that of the battery piece 4, so that grid line molding grooves are formed at the edge of the battery piece 4. For shaping membrane 2, a shaping piece bonds with battery piece 4 and can once only shaping all conducting strips 3, and because the grid line shaping groove fixed in position on the shaping piece, the position between each conducting strip 3 is more accurate, from this the wiring efficiency in grid line shaping groove is high, and the production efficiency of cockscomb structure grid line is higher. Moreover, the forming sheet also avoids the precision error existing in the lamination of a plurality of forming films 2, and the manufactured conductive strip 3 has more accurate position and more accurate size.
In some embodiments, the shaping sheet is made of a hard material. The forming sheet is made of hard materials, the constraint capacity of the forming sheet on the conductive silver paste is enhanced, the rigidity of the hard materials is high, and the forming sheet is beneficial to obtaining the grid line with neat edges.
In some embodiments, the cutting device 5 includes a laser modulator 51, the laser modulator 51 being spaced apart from the battery cell 4, and the laser beam emitted from the laser modulator 51 being opposite to the conductive strip 3 in the thickness direction of the battery cell 4.
Thereby, the cutting device 5 can modulate a line of triangular saw-tooth shaped laser beam by the laser modulator 51, and the laser beam cuts the rectangular conductive strip 3 to form a saw-tooth shaped grid line. The laser beam modulated by the laser modulator 51 can be triangular saw teeth with any micron-sized aspect ratio, and the shape of the triangular saw teeth is adjusted according to actual production requirements. The laser beam is perpendicular to the printing surface of the battery piece 4 to cut the conductive strip 3, so that damage to the surface of the battery piece 4 caused by the laser beam is effectively avoided.
In some embodiments, the number of laser beams is equal to the number of biting slopes of the serrated gate lines, and the laser beams are used to cut and shape the corresponding biting slopes.
Thus, one laser beam cuts the conductive strip 3 to form one snap bevel, and two staggered laser beams cut the conductive strip 3 to form two collinear snap bevels, i.e., serrations. The meshing inclined plane of laser beam cutting department is smooth neat, is convenient for two zigzag bars line meshing, and every sawtooth of a zigzag bar line has two meshing inclined planes, needs two laser beam processing, through setting up all meshing inclined planes on the one shot forming zigzag bar line of laser beam crowd, has further improved zigzag bar line's production efficiency.
In some embodiments, the cutting device 5 further comprises a support 52, a cutting deck 53, and a locator. The cutting stage 53 is slidably connected to the bracket 52 and serves to fix the battery piece 4, and a locator serves to locate the saw-tooth grid line, and the laser modulator 51 is mounted to the bracket 52 and spaced apart from the cutting stage 53 in the sliding direction.
Specifically, the laser modulator 51 may be a ribbon shape, and may modulate light beams obliquely emitted at different angles, and the width of the light beams is the same as the width of the grid line of the battery piece 4. The battery piece 4 is placed on the cutting platform 53, and the cutting platform 53 can move up and down along the support 52 to cut saw-tooth grid lines with different patterns and sizes. The battery piece 4 and the cutting platform 53 are fixed together, so that dislocation cutting of the laser beam caused by movement of the battery piece 4 is avoided, and the locator assists the laser beam in locating the grid line position, so that the laser beam is facilitated to stably and accurately cut the grid line. When the laser beam cuts the grating, the position of the grating is aligned through the positioner, and after the laser beam is focused, the grating is cut to form a zigzag grating.
In some embodiments, the zigzag gridline fabrication method further includes recycling the chips cut from the conductive strips 3.
The scraps cut from the conductive strips 3 contain silver, and the scraps can be recovered to reduce the loss of silver, thereby contributing to the reduction of the manufacturing cost of the battery piece 4.
In the description of the present invention, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer", "clockwise", "counterclockwise", "axial", "radial", "circumferential", etc. indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings are merely for convenience in describing the present invention and simplifying the description, and do not indicate or imply that the device or element being referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the present invention.
Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include at least one such feature. In the description of the present invention, the meaning of "plurality" means at least two, for example, two, three, etc., unless specifically defined otherwise.
In the present invention, unless explicitly specified and limited otherwise, the terms "mounted," "connected," "secured," and the like are to be construed broadly, and may be, for example, fixedly connected, detachably connected, or integrally formed; may be mechanically connected, may be electrically connected or may be in communication with each other; either directly or indirectly, through intermediaries, or both, may be in communication with each other or in interaction with each other, unless expressly defined otherwise. The specific meaning of the above terms in the present invention can be understood by those of ordinary skill in the art according to the specific circumstances.
In the present invention, unless expressly stated or limited otherwise, a first feature "up" or "down" a second feature may be the first and second features in direct contact, or the first and second features in indirect contact via an intervening medium. Moreover, a first feature being "above," "over" and "on" a second feature may be a first feature being directly above or obliquely above the second feature, or simply indicating that the first feature is level higher than the second feature. The first feature being "under", "below" and "beneath" the second feature may be the first feature being directly under or obliquely below the second feature, or simply indicating that the first feature is less level than the second feature.
For purposes of this disclosure, the terms "one embodiment," "some embodiments," "example," "a particular example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, the different embodiments or examples described in this specification and the features of the different embodiments or examples may be combined and combined by those skilled in the art without contradiction.
While embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are illustrative and not to be construed as limiting the invention, and that variations, modifications, alternatives and variations may be made to the above embodiments by one of ordinary skill in the art within the scope of the invention.
Claims (9)
1. The manufacturing method of the serrated grid line is characterized by comprising the following steps of:
paving a forming layer on the battery piece, wherein the forming layer forms a grid line printing groove, and injecting conductive silver paste into the grid line printing groove;
drying the conductive silver paste in the grid line printing groove to form a conductive strip, and removing the forming layer;
cutting and forming the conductive strips into zigzag grid lines through a cutting device;
the forming layer comprises a plurality of forming films, the forming films are distributed at intervals in the width direction of the battery piece, and the zigzag grid lines are formed between any adjacent forming films;
the forming film is made of a material with the melting point higher than the solidification temperature of the conductive silver paste, so that the forming film is prevented from deforming in the process of heating and solidifying the conductive silver paste;
the forming films are mutually parallel and adhered to the printing surface of the battery piece, and after the conductive silver paste is solidified to form the conductive strip, the forming films can be torn off for reuse;
and the two forming films at the edge are attached to the side surfaces of the battery piece, at least part of the forming films protrude out of the printing surface, and the rest of the forming films are attached to the printing surface.
2. The method for manufacturing the zigzag gate line according to claim 1, wherein the depth of the gate line printing groove is 30 um-100 um, and the width of the gate line printing groove is 20 um-60 um.
3. The method for manufacturing a zigzag grid line according to claim 1, wherein the plurality of grid line printing grooves are distributed on the printing surface of the battery piece at intervals along the width direction of the battery piece, and two grid line printing grooves at edge positions are respectively positioned at two edges of the printing surface in the width direction.
4. The method for manufacturing a zigzag grating according to claim 1, wherein the molding layer comprises a molding sheet, and the molding sheet is provided with a plurality of grating printing grooves.
5. The method of forming a zigzag grating according to claim 4, wherein the molding sheet is made of a hard material.
6. The method of claim 1, wherein the cutting device comprises a laser modulator, the laser modulator is spaced apart from the battery piece, and a laser beam emitted from the laser modulator is opposite to the conductive strip in a thickness direction of the battery piece.
7. The method for manufacturing a zigzag grating according to claim 6, wherein the number of the laser beams is equal to the number of the engagement slopes of the zigzag grating, and the laser beams are used for cutting and forming the corresponding engagement slopes.
8. The method of claim 6 or 7, wherein the cutting device further comprises a bracket, a cutting platform slidably coupled to the bracket for securing the battery cells, and a positioner for positioning the saw-tooth grid, and wherein the laser modulator is mounted to the bracket and spaced apart from the cutting platform in a sliding direction.
9. The method of claim 1, further comprising recycling the chips cut from the conductive strip.
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CN202111141047.6A CN113937188B (en) | 2021-09-28 | 2021-09-28 | Manufacturing method of zigzag grid line |
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CN202473938U (en) * | 2011-11-21 | 2012-10-03 | 浙江正国太阳能科技有限公司 | Positive silver grid line figure used for selective emitter solar cell |
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