CN113388847A - 普鲁士蓝类似物衍生的金属硫化物/氮掺杂碳电催化剂及其制备方法和应用 - Google Patents
普鲁士蓝类似物衍生的金属硫化物/氮掺杂碳电催化剂及其制备方法和应用 Download PDFInfo
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- CN113388847A CN113388847A CN202110764437.2A CN202110764437A CN113388847A CN 113388847 A CN113388847 A CN 113388847A CN 202110764437 A CN202110764437 A CN 202110764437A CN 113388847 A CN113388847 A CN 113388847A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000010411 electrocatalyst Substances 0.000 title claims abstract description 22
- 229910052976 metal sulfide Inorganic materials 0.000 title claims abstract description 17
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical class [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 title claims abstract description 12
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- -1 cobalt iron Prussian blue analogue Chemical class 0.000 claims abstract description 27
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
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- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(IV) oxide Inorganic materials O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- NJFMNPFATSYWHB-UHFFFAOYSA-N ac1l9hgr Chemical compound [Fe].[Fe] NJFMNPFATSYWHB-UHFFFAOYSA-N 0.000 description 4
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- 230000009286 beneficial effect Effects 0.000 description 3
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- 229910052757 nitrogen Inorganic materials 0.000 description 3
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- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
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- 238000005868 electrolysis reaction Methods 0.000 description 2
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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- 238000004502 linear sweep voltammetry Methods 0.000 description 2
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- 229960003351 prussian blue Drugs 0.000 description 2
- 239000013225 prussian blue Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
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- 238000013112 stability test Methods 0.000 description 2
- 238000012353 t test Methods 0.000 description 2
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- 229910017108 Fe—Fe Inorganic materials 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
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- 229910052796 boron Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- HTXDPTMKBJXEOW-UHFFFAOYSA-N iridium(IV) oxide Inorganic materials O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 1
- 239000002905 metal composite material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
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- 239000000203 mixture Substances 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000013354 porous framework Substances 0.000 description 1
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- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 238000004832 voltammetry Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/054—Electrodes comprising electrocatalysts supported on a carrier
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/069—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of at least one single element and at least one compound; consisting of two or more compounds
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114836768A (zh) * | 2022-06-08 | 2022-08-02 | 中国石油大学(华东) | 一种三相过渡金属氧化物电催化剂的制备及其应用 |
CN114870862A (zh) * | 2022-05-06 | 2022-08-09 | 中国海洋大学 | 一种用作汽车尾气净化的复合氧化物催化剂及其制备方法 |
CN115634698A (zh) * | 2022-11-08 | 2023-01-24 | 江南大学 | 一种微/纳分级花状直接z型异质结可见光催化剂及其制备方法 |
CN115652360A (zh) * | 2022-10-14 | 2023-01-31 | 成都先进金属材料产业技术研究院股份有限公司 | 一种钴铁基硼氮共掺杂碳纳米复合材料及其制备方法 |
CN117509675A (zh) * | 2023-11-08 | 2024-02-06 | 武汉中科先进材料科技有限公司 | 一种低结晶水含量的铁基普鲁士蓝及其制备方法和应用 |
Citations (6)
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CN108706639A (zh) * | 2018-05-31 | 2018-10-26 | 淮海工学院 | 一种yolk-shell结构金属硫化物及其合成方法 |
CN108736028A (zh) * | 2018-05-31 | 2018-11-02 | 深圳大学 | 一种多孔氮掺杂碳负载钴纳米材料、制备方法及其应用 |
US20200261893A1 (en) * | 2019-02-19 | 2020-08-20 | Uchicago Argonne, Llc | Prussian blue derived catalysts |
CN111569907A (zh) * | 2020-04-29 | 2020-08-25 | 国电新能源技术研究院有限公司 | 双金属复合材料及其制备方法和应用 |
CN111715248A (zh) * | 2020-06-22 | 2020-09-29 | 陕西科技大学 | 一种中空纳米电解水用阴极催化剂及其制备方法 |
CN111889128A (zh) * | 2020-07-29 | 2020-11-06 | 淮安新能源材料技术研究院 | 一种笼状镍铁双金属磷化物负载氮掺杂多孔碳材料的制备方法 |
-
2021
- 2021-07-06 CN CN202110764437.2A patent/CN113388847B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108706639A (zh) * | 2018-05-31 | 2018-10-26 | 淮海工学院 | 一种yolk-shell结构金属硫化物及其合成方法 |
CN108736028A (zh) * | 2018-05-31 | 2018-11-02 | 深圳大学 | 一种多孔氮掺杂碳负载钴纳米材料、制备方法及其应用 |
US20200261893A1 (en) * | 2019-02-19 | 2020-08-20 | Uchicago Argonne, Llc | Prussian blue derived catalysts |
CN111569907A (zh) * | 2020-04-29 | 2020-08-25 | 国电新能源技术研究院有限公司 | 双金属复合材料及其制备方法和应用 |
CN111715248A (zh) * | 2020-06-22 | 2020-09-29 | 陕西科技大学 | 一种中空纳米电解水用阴极催化剂及其制备方法 |
CN111889128A (zh) * | 2020-07-29 | 2020-11-06 | 淮安新能源材料技术研究院 | 一种笼状镍铁双金属磷化物负载氮掺杂多孔碳材料的制备方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114870862A (zh) * | 2022-05-06 | 2022-08-09 | 中国海洋大学 | 一种用作汽车尾气净化的复合氧化物催化剂及其制备方法 |
CN114836768A (zh) * | 2022-06-08 | 2022-08-02 | 中国石油大学(华东) | 一种三相过渡金属氧化物电催化剂的制备及其应用 |
CN115652360A (zh) * | 2022-10-14 | 2023-01-31 | 成都先进金属材料产业技术研究院股份有限公司 | 一种钴铁基硼氮共掺杂碳纳米复合材料及其制备方法 |
CN115634698A (zh) * | 2022-11-08 | 2023-01-24 | 江南大学 | 一种微/纳分级花状直接z型异质结可见光催化剂及其制备方法 |
CN115634698B (zh) * | 2022-11-08 | 2024-03-01 | 江南大学 | 一种微/纳分级花状直接z型异质结可见光催化剂及其制备方法 |
CN117509675A (zh) * | 2023-11-08 | 2024-02-06 | 武汉中科先进材料科技有限公司 | 一种低结晶水含量的铁基普鲁士蓝及其制备方法和应用 |
CN117509675B (zh) * | 2023-11-08 | 2024-04-30 | 武汉中科先进材料科技有限公司 | 一种低结晶水含量的铁基普鲁士蓝及其制备方法和应用 |
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