CN113089312A - 一种高强阻燃弹性面料及其制备方法 - Google Patents
一种高强阻燃弹性面料及其制备方法 Download PDFInfo
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- CN113089312A CN113089312A CN202110234896.XA CN202110234896A CN113089312A CN 113089312 A CN113089312 A CN 113089312A CN 202110234896 A CN202110234896 A CN 202110234896A CN 113089312 A CN113089312 A CN 113089312A
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- flame
- retardant
- red phosphorus
- epoxy resin
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- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 201
- 239000003063 flame retardant Substances 0.000 title claims abstract description 198
- 239000004744 fabric Substances 0.000 title claims abstract description 79
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 118
- 239000003822 epoxy resin Substances 0.000 claims abstract description 86
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 86
- 239000000835 fiber Substances 0.000 claims abstract description 77
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 26
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 26
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 26
- 229920000728 polyester Polymers 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 21
- 239000004814 polyurethane Substances 0.000 claims abstract description 19
- 229920002635 polyurethane Polymers 0.000 claims abstract description 19
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 16
- 239000003085 diluting agent Substances 0.000 claims abstract description 16
- 229920000297 Rayon Polymers 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 35
- 238000001816 cooling Methods 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 25
- 238000005520 cutting process Methods 0.000 claims description 20
- 235000011837 pasties Nutrition 0.000 claims description 20
- 238000010008 shearing Methods 0.000 claims description 20
- 238000010438 heat treatment Methods 0.000 claims description 19
- 239000000853 adhesive Substances 0.000 claims description 15
- 230000001070 adhesive effect Effects 0.000 claims description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 10
- 239000007822 coupling agent Substances 0.000 claims description 10
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000005011 phenolic resin Substances 0.000 claims description 10
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- 239000000395 magnesium oxide Substances 0.000 claims description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 230000001954 sterilising effect Effects 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- 238000007605 air drying Methods 0.000 claims description 5
- 238000009960 carding Methods 0.000 claims description 5
- 239000012459 cleaning agent Substances 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 230000003014 reinforcing effect Effects 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 238000009987 spinning Methods 0.000 claims description 5
- 238000004659 sterilization and disinfection Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 238000009941 weaving Methods 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 239000010457 zeolite Substances 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 14
- 239000011574 phosphorus Substances 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 12
- 230000009477 glass transition Effects 0.000 abstract description 6
- 230000009471 action Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 24
- 238000002485 combustion reaction Methods 0.000 description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 150000008064 anhydrides Chemical class 0.000 description 6
- 238000003763 carbonization Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000012024 dehydrating agents Substances 0.000 description 4
- 230000018044 dehydration Effects 0.000 description 4
- 238000006297 dehydration reaction Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 125000003700 epoxy group Chemical group 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- 239000007790 solid phase Substances 0.000 description 4
- 238000005979 thermal decomposition reaction Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/69—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with phosphorus; with halides or oxyhalides of phosphorus; with chlorophosphonic acid or its salts
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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- D10B2201/20—Cellulose-derived artificial fibres
- D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Engineering & Computer Science (AREA)
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Mechanical Engineering (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Abstract
本发明公开了一种高强阻燃弹性面料及其制备方法,属于面料技术领域,一种高强阻燃弹性面料,主要包括以下原料:红磷阻燃母料;其中,所述红磷阻燃母粒主要包括红磷、氢氧化镁、氢氧化铝;环氧树脂阻燃剂;其中,所述环氧树脂阻燃剂包括环氧树脂、阻燃性固化剂、活性阻燃稀释剂;聚氨酯;植物纤维;粘胶纤维;中空涤纶纤维;抗菌剂;本发明通过加入了红磷阻燃母粒,能够提高面料的阻燃效果,配合环氧树脂,含磷阻燃环氧树脂固化物具有较高的玻璃化转变温度,良好的热稳定性和阻燃性,同时氢氧化镁受热时产生的水分在疏水性良好的聚氨酯的作用下,能够面料的表面形成水膜,进一步提高阻燃效果。
Description
技术领域
本发明涉及面料技术领域,尤其涉及一种高强阻燃弹性面料及其制备方法。
背景技术
面料是用来制作服装的材料,优质、高档的面料,大都具有穿著舒适、吸汗透气、悬垂挺括、视觉高贵、触觉柔美等特点,随着科学技术的不断进步,人们的生活水平得到大幅提高,人们对服装面料的性能要求也越来越高,除了注重服装的颜色、款式外,越来越注重服装的舒适、安全等功能。
现有的面料在使用时,容易接触到明火,导致面料易燃,进而影响使用,存在安全隐患,因此本发明提供了一种高强阻燃弹性面料。
发明内容
本发明的目的是为了解决现有的面料在使用时,容易接触到明火,导致面料易燃,进而影响使用,存在安全隐患的问题,而提出的一种高强阻燃弹性面料及其制备方法。
为了实现上述目的,本发明采用了如下技术方案:
一种高强阻燃弹性面料,主要包括以下原料:红磷阻燃母料;其中,所述红磷阻燃母粒主要包括红磷、氢氧化镁、氢氧化铝;环氧树脂阻燃剂;其中,所述环氧树脂阻燃剂包括环氧树脂、阻燃性固化剂、活性阻燃稀释剂;聚氨酯;植物纤维;粘胶纤维;中空涤纶纤维;抗菌剂。
优选的,各原料组分比为:红磷阻燃母料10-15份;环氧树脂阻燃剂12-18份;聚氨酯5-10份;植物纤维15-25份;粘胶纤维15-25份;中空涤纶纤维10-15份;抗菌剂2-10份。
优选的,所述红磷阻燃母粒中各原料组分比为:红磷70-100份、氢氧化镁5-10份、氢氧化铝5-10份。
优选的,所述红磷阻燃母粒还包括硅酮粉、POE、EVA、偶联剂、滑石粉、苯酚树脂。
优选的,所述环氧树脂阻燃剂各组分原料比为环氧树脂150-200份、阻燃性固化剂20-25份、活性阻燃稀释剂10-17份。
优选的,所述抗菌剂包括二氧化钛纳米粒子、氧化镁纳米粒子、纳米银、沸石、邻羟基苯甲酸酯。
一种高强阻燃弹性面料制备方法,主要包括以下步骤:
S1、制备所述红磷阻燃母粒、备用;
S2、制备所述环氧树脂阻燃剂、备用;
S3、将所述红磷阻燃母粒、环氧树脂阻燃剂、聚氨酯加热至熔融状态呈混合物料,并将植物纤维、胶黏纤维、中空涤纶纤维均添加至混合物料中,使得混合物料能够对植物纤维、胶黏纤维、中空涤纶纤维的表面进行包覆,后冷却;将包覆红磷阻燃母粒、环氧树脂阻燃剂的植物纤维、胶黏纤维、中空涤纶纤维,在温度为20℃-26℃,湿度为61%-65%的条件下,经过梳棉、并条、粗纱、细纱、加捻五道工艺制成纱线;将制成的纱线进行织造,并在经向和纬向每间隔0.4cm处各增加三根纱线,形成加强格形状,得到基础面料;将织造完成的基础面料在温度为95℃-100℃的具有清洗剂的水中清洗8-10遍,然后在40℃-60℃的水中清洗3-4遍,最后经过烘干、拉幅、定型得到面料。
优选的,步骤S1中制备所述红磷阻燃母粒主要包括以下步骤:
A、将POE、EVA、偶联剂称重加入混料机预混处理;
B、将所述混料机混合完成的混合物加入螺杆挤出机混合、加热、挤出,制成载体剂;
C、红磷原料加入球磨机,球磨机转动加工研磨红磷,加入水淹没红磷,红磷颗粒大小研磨细度为200目到1000目之间,球磨机过滤排出红磷和水到收集装置,在收集装置加入乳化剂,搅拌混合,过滤出红磷颗粒风干;
D、将红磷70-100份、氢氧化镁5-10份、氢氧化铝5-10份、硅酮分、载体剂、滑石粉和苯酚树脂加入混料机混合均匀;
E、混合均匀后的混合物加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物;
F、将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成红磷阻燃母粒。
优选的,制备所述环氧树脂阻燃剂主要包括以下步骤:将环氧树脂加热至熔融状态,并将熔融状态的环氧树脂加入三维混合机中,同时加入阻燃性固化剂、活性阻燃稀释剂进行混合,充分混合后加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物,再将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成环氧树脂阻燃剂母粒。
优选的,在步骤S3后,将制得的面料浸渍在抗菌剂中进行杀菌。
与现有技术相比,本发明提供了一种高强阻燃弹性面料及其制备方法,具备以下有益效果:
1、该高强阻燃弹性面料及其制备方法,通过加入的红磷能够形成磷酸配作为脱水剂,并促进成炭,炭的生成降低了从火焰到凝聚相的热传导;且磷酸可吸热,它阻止了CO氧化为CO2,降低了加热过程;对凝聚相形成一层薄薄的液态保护层,因此降低了氧气扩散和气相与固相之间的热量和质量传递,抑制了炭氧化过程,降低了含磷阻燃剂受热分解发生如下变化:磷系阻燃剂、磷酸偏、磷酸、聚偏磷酸,聚偏磷酸是不易挥发的稳定化合物,具有强脱水性,在聚合物表合物与空气隔绝;脱出的水气吸收大量的热,使聚合物表面阻燃剂受热分解释放出挥发性磷化物,达到阻燃的效果;而氢氧化镁在受热时发生分解吸收燃烧物表面热量起到阻燃作用,同时释放出大量水分稀释燃物表面的氧气,分解生成的活性氧化镁附着于可燃物表面又进一步阻止了燃烧的进行,配合聚氨酯,聚氨酯具有良好的疏水性,在氢氧化镁受热分解时,释放水分时,水分会离开面料,在面料的表面形成水膜,进一步提高阻燃效果;
2、该高强阻燃弹性面料及其制备方法,环氧树脂中的环氧基团可以位于高分子聚合物的分子链的末端、中间或者呈环状结构,具有良好的热稳定性,配合红磷的使用,含磷阻燃环氧树脂固化物具有较高的玻璃化转变温度,良好的热稳定性和阻燃性。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。
实施例1:
一种高强阻燃弹性面料,主要包括以下原料:
红磷阻燃母料;其中,所述红磷阻燃母粒主要包括红磷、氢氧化镁、氢氧化铝,通过加入的红磷能够形成磷酸配作为脱水剂,并促进成炭,炭的生成降低了从火焰到凝聚相的热传导;且磷酸可吸热,它阻止了CO氧化为CO2,降低了加热过程;对凝聚相形成一层薄薄的液态保护层,因此降低了氧气扩散和气相与固相之间的热量和质量传递,抑制了炭氧化过程,降低了含磷阻燃剂受热分解发生如下变化:磷系阻燃剂、磷酸偏、磷酸、聚偏磷酸,聚偏磷酸是不易挥发的稳定化合物,具有强脱水性,在聚合物表合物与空气隔绝;脱出的水气吸收大量的热,使聚合物表面阻燃剂受热分解释放出挥发性磷化物,达到阻燃的效果;而氢氧化镁在受热时发生分解吸收燃烧物表面热量起到阻燃作用,同时释放出大量水分稀释燃物表面的氧气,分解生成的活性氧化镁附着于可燃物表面又进一步阻止了燃烧的进行;
环氧树脂阻燃剂,环氧树脂中的环氧基团可以位于高分子聚合物的分子链的末端、中间或者呈环状结构,具有良好的热稳定性,配合红磷的使用,含磷阻燃环氧树脂固化物具有较高的玻璃化转变温度,良好的热稳定性和阻燃性;
其中,所述环氧树脂阻燃剂包括环氧树脂、阻燃性固化剂、活性阻燃稀释剂,通过加入阻燃性固化剂如80酸酐,固化后的环氧树脂分子中具含有阻燃结构,且80酸酐可在室温下雨环氧树脂混合,阻燃性能佳;
聚氨酯,具有良好的疏水性,在氢氧化镁受热分解时,释放水分时,水分会离开面料,在面料的表面形成水膜,进一步提高阻燃效果;
植物纤维;
粘胶纤维;
中空涤纶纤维;
抗菌剂,用于在面料制备后,对面料进行杀菌。
各原料组分比为:红磷阻燃母料10份;环氧树脂阻燃剂12份;聚氨酯5份;植物纤维15份;粘胶纤维15份;中空涤纶纤维10份;抗菌剂2份。
所述红磷阻燃母粒中各原料组分比为:红磷70份、氢氧化镁5份、氢氧化铝5份。
所述红磷阻燃母粒还包括硅酮粉、POE、EVA、偶联剂、滑石粉、苯酚树脂。
所述环氧树脂阻燃剂各组分原料比为环氧树脂150份、阻燃性固化剂20份、活性阻燃稀释剂10份。
所述抗菌剂包括二氧化钛纳米粒子、氧化镁纳米粒子、纳米银、沸石、邻羟基苯甲酸酯。
一种高强阻燃弹性面料制备方法,主要包括以下步骤:
先制备所述红磷阻燃母粒、备用:
将POE、EVA、偶联剂称重加入混料机预混处理;
将所述混料机混合完成的混合物加入螺杆挤出机混合、加热、挤出,制成载体剂;
红磷原料加入球磨机,球磨机转动加工研磨红磷,加入水淹没红磷,红磷颗粒大小研磨细度为500目之间,球磨机过滤排出红磷和水到收集装置,在收集装置加入乳化剂,搅拌混合,过滤出红磷颗粒风干;
将红磷70份、氢氧化镁5份、氢氧化铝5份、硅酮分、载体剂、滑石粉和苯酚树脂加入混料机混合均匀;
混合均匀后的混合物加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物;
将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成红磷阻燃母粒;
再制备所述环氧树脂阻燃剂、备用:
将环氧树脂加热至熔融状态,并将熔融状态的环氧树脂加入三维混合机中,同时加入阻燃性固化剂、活性阻燃稀释剂进行混合,充分混合后加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物,再将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成环氧树脂阻燃剂母粒;
然后将所述红磷阻燃母粒、环氧树脂阻燃剂、聚氨酯加热至熔融状态呈混合物料,并将植物纤维、胶黏纤维、中空涤纶纤维均添加至混合物料中,使得混合物料能够对植物纤维、胶黏纤维、中空涤纶纤维的表面进行包覆,后冷却;将包覆红磷阻燃母粒、环氧树脂阻燃剂的植物纤维、胶黏纤维、中空涤纶纤维,在温度为20℃-26℃,湿度为61%-65%的条件下,经过梳棉、并条、粗纱、细纱、加捻五道工艺制成纱线;将制成的纱线进行织造,并在经向和纬向每间隔0.4cm处各增加三根纱线,形成加强格形状,得到基础面料;将织造完成的基础面料在温度为95℃-100℃的具有清洗剂的水中清洗8-10遍,然后在40℃-60℃的水中清洗3-4遍,最后经过烘干、拉幅、定型得到面料。
最后将制得的面料浸渍在抗菌剂中进行杀菌。
实施例2:
一种高强阻燃弹性面料,主要包括以下原料:
红磷阻燃母料;其中,所述红磷阻燃母粒主要包括红磷、氢氧化镁、氢氧化铝,通过加入的红磷能够形成磷酸配作为脱水剂,并促进成炭,炭的生成降低了从火焰到凝聚相的热传导;且磷酸可吸热,它阻止了CO氧化为CO2,降低了加热过程;对凝聚相形成一层薄薄的液态保护层,因此降低了氧气扩散和气相与固相之间的热量和质量传递,抑制了炭氧化过程,降低了含磷阻燃剂受热分解发生如下变化:磷系阻燃剂、磷酸偏、磷酸、聚偏磷酸,聚偏磷酸是不易挥发的稳定化合物,具有强脱水性,在聚合物表合物与空气隔绝;脱出的水气吸收大量的热,使聚合物表面阻燃剂受热分解释放出挥发性磷化物,达到阻燃的效果;而氢氧化镁在受热时发生分解吸收燃烧物表面热量起到阻燃作用,同时释放出大量水分稀释燃物表面的氧气,分解生成的活性氧化镁附着于可燃物表面又进一步阻止了燃烧的进行;
环氧树脂阻燃剂,环氧树脂中的环氧基团可以位于高分子聚合物的分子链的末端、中间或者呈环状结构,具有良好的热稳定性,配合红磷的使用,含磷阻燃环氧树脂固化物具有较高的玻璃化转变温度,良好的热稳定性和阻燃性;
其中,所述环氧树脂阻燃剂包括环氧树脂、阻燃性固化剂、活性阻燃稀释剂,通过加入阻燃性固化剂如80酸酐,固化后的环氧树脂分子中具含有阻燃结构,且80酸酐可在室温下雨环氧树脂混合,阻燃性能佳;
聚氨酯,具有良好的疏水性,在氢氧化镁受热分解时,释放水分时,水分会离开面料,在面料的表面形成水膜,进一步提高阻燃效果;
植物纤维;
粘胶纤维;
中空涤纶纤维;
抗菌剂,用于在面料制备后,对面料进行杀菌。
各原料组分比为:红磷阻燃母料12.5份;环氧树脂阻燃剂15份;聚氨酯7.5份;植物纤维20份;粘胶纤维20份;中空涤纶纤维12.5份;抗菌剂8份。
所述红磷阻燃母粒中各原料组分比为:红磷85份、氢氧化镁7.5份、氢氧化铝7.5份。
所述红磷阻燃母粒还包括硅酮粉、POE、EVA、偶联剂、滑石粉、苯酚树脂。
所述环氧树脂阻燃剂各组分原料比为环氧树脂175份、阻燃性固化22.5份、活性阻燃稀释剂14份。
所述抗菌剂包括二氧化钛纳米粒子、氧化镁纳米粒子、纳米银、沸石、邻羟基苯甲酸酯。
一种高强阻燃弹性面料制备方法,主要包括以下步骤:
先制备所述红磷阻燃母粒、备用:
将POE、EVA、偶联剂称重加入混料机预混处理;
将所述混料机混合完成的混合物加入螺杆挤出机混合、加热、挤出,制成载体剂;
红磷原料加入球磨机,球磨机转动加工研磨红磷,加入水淹没红磷,红磷颗粒大小研磨细度为600目之间,球磨机过滤排出红磷和水到收集装置,在收集装置加入乳化剂,搅拌混合,过滤出红磷颗粒风干;
将红磷85份、氢氧化镁7.5份、氢氧化铝7.5份、硅酮分、载体剂、滑石粉和苯酚树脂加入混料机混合均匀;
混合均匀后的混合物加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物;
将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成红磷阻燃母粒;
再制备所述环氧树脂阻燃剂、备用:
将环氧树脂加热至熔融状态,并将熔融状态的环氧树脂加入三维混合机中,同时加入阻燃性固化剂、活性阻燃稀释剂进行混合,充分混合后加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物,再将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成环氧树脂阻燃剂母粒;
然后将所述红磷阻燃母粒、环氧树脂阻燃剂、聚氨酯加热至熔融状态呈混合物料,并将植物纤维、胶黏纤维、中空涤纶纤维均添加至混合物料中,使得混合物料能够对植物纤维、胶黏纤维、中空涤纶纤维的表面进行包覆,后冷却;将包覆红磷阻燃母粒、环氧树脂阻燃剂的植物纤维、胶黏纤维、中空涤纶纤维,在温度为20℃-26℃,湿度为61%-65%的条件下,经过梳棉、并条、粗纱、细纱、加捻五道工艺制成纱线;将制成的纱线进行织造,并在经向和纬向每间隔0.4cm处各增加三根纱线,形成加强格形状,得到基础面料;将织造完成的基础面料在温度为95℃-100℃的具有清洗剂的水中清洗8-10遍,然后在40℃-60℃的水中清洗3-4遍,最后经过烘干、拉幅、定型得到面料。
最后将制得的面料浸渍在抗菌剂中进行杀菌。
实施例3:
一种高强阻燃弹性面料,主要包括以下原料:
红磷阻燃母料;其中,所述红磷阻燃母粒主要包括红磷、氢氧化镁、氢氧化铝,通过加入的红磷能够形成磷酸配作为脱水剂,并促进成炭,炭的生成降低了从火焰到凝聚相的热传导;且磷酸可吸热,它阻止了CO氧化为CO2,降低了加热过程;对凝聚相形成一层薄薄的液态保护层,因此降低了氧气扩散和气相与固相之间的热量和质量传递,抑制了炭氧化过程,降低了含磷阻燃剂受热分解发生如下变化:磷系阻燃剂、磷酸偏、磷酸、聚偏磷酸,聚偏磷酸是不易挥发的稳定化合物,具有强脱水性,在聚合物表合物与空气隔绝;脱出的水气吸收大量的热,使聚合物表面阻燃剂受热分解释放出挥发性磷化物,达到阻燃的效果;而氢氧化镁在受热时发生分解吸收燃烧物表面热量起到阻燃作用,同时释放出大量水分稀释燃物表面的氧气,分解生成的活性氧化镁附着于可燃物表面又进一步阻止了燃烧的进行;
环氧树脂阻燃剂,环氧树脂中的环氧基团可以位于高分子聚合物的分子链的末端、中间或者呈环状结构,具有良好的热稳定性,配合红磷的使用,含磷阻燃环氧树脂固化物具有较高的玻璃化转变温度,良好的热稳定性和阻燃性;
其中,所述环氧树脂阻燃剂包括环氧树脂、阻燃性固化剂、活性阻燃稀释剂,通过加入阻燃性固化剂如80酸酐,固化后的环氧树脂分子中具含有阻燃结构,且80酸酐可在室温下雨环氧树脂混合,阻燃性能佳;
聚氨酯,具有良好的疏水性,在氢氧化镁受热分解时,释放水分时,水分会离开面料,在面料的表面形成水膜,进一步提高阻燃效果;
植物纤维;
粘胶纤维;
中空涤纶纤维;
抗菌剂,用于在面料制备后,对面料进行杀菌。
各原料组分比为:红磷阻燃母料15份;环氧树脂阻燃剂18份;聚氨酯10份;植物纤维25份;粘胶纤维25份;中空涤纶纤维15份;抗菌剂10份。
所述红磷阻燃母粒中各原料组分比为:红磷100份、氢氧化镁10份、氢氧化铝10份。
所述红磷阻燃母粒还包括硅酮粉、POE、EVA、偶联剂、滑石粉、苯酚树脂。
所述环氧树脂阻燃剂各组分原料比为环氧树脂200份、阻燃性固化剂20-25份、活性阻燃稀释剂17份。
所述抗菌剂包括二氧化钛纳米粒子、氧化镁纳米粒子、纳米银、沸石、邻羟基苯甲酸酯。
一种高强阻燃弹性面料制备方法,主要包括以下步骤:
先制备所述红磷阻燃母粒、备用:
将POE、EVA、偶联剂称重加入混料机预混处理;
将所述混料机混合完成的混合物加入螺杆挤出机混合、加热、挤出,制成载体剂;
红磷原料加入球磨机,球磨机转动加工研磨红磷,加入水淹没红磷,红磷颗粒大小研磨细度为600目之间,球磨机过滤排出红磷和水到收集装置,在收集装置加入乳化剂,搅拌混合,过滤出红磷颗粒风干;
将红磷100份、氢氧化镁10份、氢氧化铝10份、硅酮分、载体剂、滑石粉和苯酚树脂加入混料机混合均匀;
混合均匀后的混合物加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物;
将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成红磷阻燃母粒;
再制备所述环氧树脂阻燃剂、备用:
将环氧树脂加热至熔融状态,并将熔融状态的环氧树脂加入三维混合机中,同时加入阻燃性固化剂、活性阻燃稀释剂进行混合,充分混合后加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物,再将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成环氧树脂阻燃剂母粒;
然后将所述红磷阻燃母粒、环氧树脂阻燃剂、聚氨酯加热至熔融状态呈混合物料,并将植物纤维、胶黏纤维、中空涤纶纤维均添加至混合物料中,使得混合物料能够对植物纤维、胶黏纤维、中空涤纶纤维的表面进行包覆,后冷却;将包覆红磷阻燃母粒、环氧树脂阻燃剂的植物纤维、胶黏纤维、中空涤纶纤维,在温度为20℃-26℃,湿度为61%-65%的条件下,经过梳棉、并条、粗纱、细纱、加捻五道工艺制成纱线;将制成的纱线进行织造,并在经向和纬向每间隔0.4cm处各增加三根纱线,形成加强格形状,得到基础面料;将织造完成的基础面料在温度为95℃-100℃的具有清洗剂的水中清洗8-10遍,然后在40℃-60℃的水中清洗3-4遍,最后经过烘干、拉幅、定型得到面料。
最后将制得的面料浸渍在抗菌剂中进行杀菌。
本发明通过加入了红磷阻燃母粒,能够提高面料的阻燃效果,配合环氧树脂,含磷阻燃环氧树脂固化物具有较高的玻璃化转变温度,良好的热稳定性和阻燃性,同时氢氧化镁受热时产生的水分在疏水性良好的聚氨酯的作用下,能够面料的表面形成水膜,进一步提高阻燃效果。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (10)
1.一种高强阻燃弹性面料,其特征在于,主要包括以下原料:
红磷阻燃母料;
其中,所述红磷阻燃母粒主要包括红磷、氢氧化镁、氢氧化铝;
环氧树脂阻燃剂;
其中,所述环氧树脂阻燃剂包括环氧树脂、阻燃性固化剂、活性阻燃稀释剂;
聚氨酯;
植物纤维;
粘胶纤维;
中空涤纶纤维;
抗菌剂。
2.根据权利要求1所述的高强阻燃弹性面料,其特征在于,各原料组分比为:
红磷阻燃母料10-15份;
环氧树脂阻燃剂12-18份;
聚氨酯5-10份;
植物纤维15-25份;
粘胶纤维15-25份;
中空涤纶纤维10-15份;
抗菌剂2-10份。
3.根据权利要求1所述的高强阻燃弹性面料,其特征在于,所述红磷阻燃母粒中各原料组分比为:红磷70-100份、氢氧化镁5-10份、氢氧化铝5-10份。
4.根据权利要求3所述的高强阻燃弹性面料,其特征在于,所述红磷阻燃母粒还包括硅酮粉、POE、EVA、偶联剂、滑石粉、苯酚树脂。
5.根据权利要求1所述的高强阻燃弹性面料,其特征在于,所述环氧树脂阻燃剂各组分原料比为环氧树脂150-200份、阻燃性固化剂20-25份、活性阻燃稀释剂10-17份。
6.根据权利要求1所述的高强阻燃弹性面料,其特征在于,所述抗菌剂包括二氧化钛纳米粒子、氧化镁纳米粒子、纳米银、沸石、邻羟基苯甲酸酯。
7.一种高强阻燃弹性面料制备方法,包括权利要求1-6任一项所述的高强阻燃弹性面秒,其特征在于,主要包括以下步骤:
S1、制备所述红磷阻燃母粒、备用;
S2、制备所述环氧树脂阻燃剂、备用;
S3、将所述红磷阻燃母粒、环氧树脂阻燃剂、聚氨酯加热至熔融状态呈混合物料,并将植物纤维、胶黏纤维、中空涤纶纤维均添加至混合物料中,使得混合物料能够对植物纤维、胶黏纤维、中空涤纶纤维的表面进行包覆,后冷却;
将包覆红磷阻燃母粒、环氧树脂阻燃剂的植物纤维、胶黏纤维、中空涤纶纤维,在温度为20℃-26℃,湿度为61%-65%的条件下,经过梳棉、并条、粗纱、细纱、加捻五道工艺制成纱线;
将制成的纱线进行织造,并在经向和纬向每间隔0.4cm处各增加三根纱线,形成加强格形状,得到基础面料;
将织造完成的基础面料在温度为95℃-100℃的具有清洗剂的水中清洗8-10遍,然后在40℃-60℃的水中清洗3-4遍,最后经过烘干、拉幅、定型得到面料。
8.根据权利要求7所述的高强阻燃弹性面料制备方法,其特征在于,步骤S1中制备所述红磷阻燃母粒主要包括以下步骤:
A、将POE、EVA、偶联剂称重加入混料机预混处理;
B、将所述混料机混合完成的混合物加入螺杆挤出机混合、加热、挤出,制成载体剂;
C、红磷原料加入球磨机,球磨机转动加工研磨红磷,加入水淹没红磷,红磷颗粒大小研磨细度为200目到1000目之间,球磨机过滤排出红磷和水到收集装置,在收集装置加入乳化剂,搅拌混合,过滤出红磷颗粒风干;
D、将红磷70-100份、氢氧化镁5-10份、氢氧化铝5-10份、硅酮分、载体剂、滑石粉和苯酚树脂加入混料机混合均匀;
E、混合均匀后的混合物加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物;
F、将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成红磷阻燃母粒。
9.根据权利要求7所述的高强阻燃弹性面料制备方法,其特征在于,制备所述环氧树脂阻燃剂主要包括以下步骤:将环氧树脂加热至熔融状态,并将熔融状态的环氧树脂加入三维混合机中,同时加入阻燃性固化剂、活性阻燃稀释剂进行混合,充分混合后加入到螺杆挤出机,塑化、输送、混炼、捏合、剪切、再混炼、反旋、再剪切、再输送、挤出为糊状混合物,再将所述糊状混合物加入到螺杆挤出机,输送、挤出,并在所述螺杆挤出机出料口连接热切风冷造粒机对挤出物料热切、甩出、风冷、造粒,制成环氧树脂阻燃剂母粒。
10.根据权利要求7所述的高强阻燃弹性面料制备方法,其特征在于,在步骤S3后,将制得的面料浸渍在抗菌剂中进行杀菌。
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