CN112937194A - Method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain - Google Patents
Method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain Download PDFInfo
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- CN112937194A CN112937194A CN202110198306.2A CN202110198306A CN112937194A CN 112937194 A CN112937194 A CN 112937194A CN 202110198306 A CN202110198306 A CN 202110198306A CN 112937194 A CN112937194 A CN 112937194A
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- Prior art keywords
- sculpture
- metal
- manufacturing
- glaze
- transmutation
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 42
- 239000002184 metal Substances 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 22
- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 22
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 239000010931 gold Substances 0.000 title claims abstract description 16
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 16
- 238000009377 nuclear transmutation Methods 0.000 title claims abstract description 14
- 239000002131 composite material Substances 0.000 title claims description 10
- 238000010304 firing Methods 0.000 claims abstract description 19
- 238000005058 metal casting Methods 0.000 claims abstract description 4
- 210000003298 dental enamel Anatomy 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 238000005266 casting Methods 0.000 claims description 12
- 239000000047 product Substances 0.000 claims description 12
- 238000005507 spraying Methods 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 9
- 239000003086 colorant Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 239000004927 clay Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000011152 fibreglass Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910001338 liquidmetal Inorganic materials 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- 230000001413 cellular effect Effects 0.000 claims description 3
- 229910000428 cobalt oxide Inorganic materials 0.000 claims description 3
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims description 3
- 238000013329 compounding Methods 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 3
- 238000004534 enameling Methods 0.000 claims description 3
- 229910052602 gypsum Inorganic materials 0.000 claims description 3
- 239000010440 gypsum Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 229910000480 nickel oxide Inorganic materials 0.000 claims description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 3
- 238000005554 pickling Methods 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 238000007639 printing Methods 0.000 claims description 3
- 238000005488 sandblasting Methods 0.000 claims description 3
- 238000009966 trimming Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000003466 welding Methods 0.000 claims description 3
- 239000012466 permeate Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000029052 metamorphosis Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C9/00—Moulds or cores; Moulding processes
- B22C9/02—Sand moulds or like moulds for shaped castings
- B22C9/04—Use of lost patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/04—Modelling plastic materials, e.g. clay
- B44C3/046—Modelling plastic materials, e.g. clay using a modelling surface, e.g. plate
- B44C3/048—Modelling plastic materials, e.g. clay using a modelling surface, e.g. plate applying an additional decorative element, e.g. picture
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D11/00—Continuous processes; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D13/00—After-treatment of the enamelled articles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23D—ENAMELLING OF, OR APPLYING A VITREOUS LAYER TO, METALS
- C23D5/00—Coating with enamels or vitreous layers
- C23D5/02—Coating with enamels or vitreous layers by wet methods
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Adornments (AREA)
Abstract
The invention discloses a method for manufacturing indoor and outdoor metal sculpture transmutation complex color gold porcelain, which comprises the following steps: (1) the method comprises the following steps of drawing design, (2) sculpture mud shape manufacturing, (3) mould copying, (4) metal casting, (5) blank body processing, (6) multi-color porcelain glaze, (7) firing in a furnace, and (8) finished product finishing.
Description
Technical Field
The invention relates to the field of complex color gold porcelain, in particular to a manufacturing method of indoor and outdoor metal sculpture transmutation complex color gold porcelain.
Background
The ceramic product is wonderful in the special beautiful effect, the traditional enamel products including industrial enamel and artistic enamel are flat and unknobby in visual effect, the colorful enamel is limited to be various in color and tends to be flat without the change of mutual permeation among the colors, the visual expression effect is always limited, the concave-convex space is difficult to be shown, the color is changeable, and the artistic effect of thousands of meteorology is realized.
Disclosure of Invention
In order to solve the technical problems, the technical scheme provided by the invention is as follows: a method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain comprises the following steps:
(1) designing a drawing: drawing a work drawing, and designing the layout of each part, including space unevenness, color change, a glaze flowing mechanism, glazing thickness, picture and white leaving, and subject style drop printing;
(2) manufacturing a sculpture mud shape: manufacturing initial clay draft sculpture works with concave-convex space change by using sculpture mud according to a design drawing;
(3) copying a mould: copying a glass fiber reinforced plastic resin work through a gypsum mold, copying a silica gel outer film again according to the glass fiber reinforced plastic resin work, copying a wax pattern with the same ratio as the original clay draft according to the silica gel outer film, trimming the wax pattern, and copying and casting a required hollow mold by using a lost wax method;
(4) metal casting: selecting a casting metal to be melted into liquid metal at high temperature, casting the hollow mould after removing impurities from the liquid metal, wherein the casting area is not too large so as to prevent the metal wall from being cellular, opening the mould after the cast metal part is cooled, and performing gas welding and splicing after simple cleaning to form a blank;
(5) treating a blank body: carrying out surface pickling cleaning on the cast metal sculpture, carrying out surface sand blasting after drying, washing and drying to prepare glaze color;
(6) compounding color porcelain glaze: placing the treated metal sculpture green body in a dust-free room for overglaze color restoration, firstly coating a layer of under glaze, spraying a layer of clear water after the under glaze is slightly dried, then repeatedly coating enamel overglaze layer by layer according to a design drawing, combining water to enable colors to mutually permeate and fuse, and finally spraying a layer of transparent glaze according to picture requirements; after ensuring that no flaw exists, airing and then firing in a furnace;
(7) firing in a furnace: placing the product in a kiln at an inclination angle of 30 ℃ according to the size of the product, controlling the temperature of the kiln, firing for 40-90 minutes, and performing secondary firing when necessary;
(8) finishing a finished product: and carefully checking whether the composite color gold porcelain works have damage or flaws for finishing after firing.
Preferably, the metal sculpture comprises a circular carving or a relief.
Preferably, the cast metal comprises iron, copper, aluminum, stainless steel.
Preferably, during firing, the temperature of the furnace is controlled according to the melting point of the metal bottom blank; wherein when iron is used, the furnace temperature is controlled to be 800-860 ℃; when copper is used, the furnace temperature is controlled to be 800-820 ℃; when aluminum is used, the furnace temperature is controlled to be 570-580 ℃; when stainless steel is used, the furnace temperature is controlled at 570-820 ℃.
Preferably, the selection of the ground glaze comprises cobalt oxide, nickel oxide and copper oxide.
Preferably, the enameling method includes a dipping method, a coating method, a spraying method, a powder spraying method.
After the scheme is adopted, the invention has the following advantages:
the large, medium and small metal sculptures (circular engravings and reliefs) manufactured by the method have the transmutation effect, are complex color golden porcelain (enamel) artistic works, have three-dimensional space and changeable colors, are firm and durable, meet the requirements of people on decoration or collection of high-end artistic valuables, and fill the blank of enamel art manufacturing modes and expression forms.
Detailed Description
Examples
A method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain comprises the following steps:
(1) designing a drawing: drawing a work drawing, and designing the layout of each part, including space unevenness, color change, a glaze flowing mechanism, glazing thickness, picture and white leaving, and subject style drop printing;
(2) manufacturing a sculpture mud shape: manufacturing initial clay draft sculpture works with concave-convex space change by using sculpture mud according to a design drawing; the representation can be classified as either written or real, pictorial or abstract. The subject contents can be various such as mountains and waters, characters, animals and the like;
(3) copying a mould: copying a glass fiber reinforced plastic resin work through a gypsum mold, copying a silica gel outer film again according to the glass fiber reinforced plastic resin work, copying a wax pattern with the same ratio as the original clay draft according to the silica gel outer film, trimming the wax pattern, and copying and casting a required hollow mold by using a lost wax method;
(4) metal casting: selecting a casting metal to be melted into liquid metal (various metals can be used) at high temperature, casting the hollow mould after removing impurities from the liquid metal, wherein the casting area is not too large so as to prevent the metal wall from being cellular, opening the mould after the cast metal part is cooled, and performing gas welding and splicing after simple cleaning to form a blank;
(5) treating a blank body: carrying out surface pickling cleaning on the cast metal sculpture, carrying out surface sand blasting after drying, washing and drying to prepare glaze color;
(6) compounding color porcelain glaze: placing the treated metal sculpture blank body in a dust-free room for overglaze color restoration, firstly coating a layer of under glaze, spraying a layer of clear water after the under glaze is slightly dried, then repeatedly coating the enamel overglaze layer by layer according to a design drawing, combining water to enable colors to be mutually permeated and fused, and finally spraying a layer of transparent glaze according to picture requirements; the works are inclined by individual parts, naturally flow downwards in the glazing process to form a glaze flowing effect, and then a layer of transparent glaze is sprayed according to the picture requirement; the manufacturing process is completed by the cooperation of experienced technicians; when the glaze color is coated, a metal ground color is properly reserved according to the picture requirement, namely white, basically the same as the writing Chinese painting principle, the writing is performed at a proper position, and the glaze color is dried and fired after ensuring no flaw;
(7) firing in a furnace: placing the product in a kiln at an inclination angle of 30 ℃ according to the size of the product, controlling the temperature of the kiln, firing for 40-90 minutes, generating wonderful change among glaze colors in the high-temperature firing process to form a magic kiln change effect, and performing secondary firing when necessary;
(8) finishing a finished product: and carefully checking whether the composite color gold porcelain works have damage or flaws for finishing after firing.
As a preferred embodiment of this embodiment, the metal sculpture includes a circular carving or a relief.
As a preferred embodiment of this embodiment, the cast metal includes iron, copper, aluminum, stainless steel.
In a preferred embodiment of this example, the temperature of the furnace is controlled according to the melting point of the metal blank; wherein when iron is used, the furnace temperature is controlled to be 800-860 ℃; when copper is used, the furnace temperature is controlled to be 800-820 ℃; when aluminum is used, the furnace temperature is controlled to be 570-580 ℃; when stainless steel is used, the furnace temperature is controlled at 570-820 ℃.
As a preferred embodiment of this embodiment, the selection of the ground coat includes cobalt oxide, nickel oxide, and copper oxide.
As a preferred embodiment of this example, the enameling method includes a dipping method, a coating method, a spraying method, and a powder spraying method.
The invention combines various colors of enamel glaze and water to be repeatedly superposed and sprayed on the ground glaze in a plurality of layers, the enamel glaze is mutually permeated and melted and naturally flows to form the picture effect of the Chinese painting and writing according to the pre-designed effect, the enamel glaze is firmly attached to the metal sculpture (circular carving/embossment) by the manufacturing method of industrial enamel, and is sintered at high temperature in a kiln (a tunnel furnace and a box furnace), and the glaze colors can generate wonderful change to form the furnace transmutation effect of metamorphosis during the high-temperature firing process; the enamel and the metal are mutually permeated and firmly combined, the whole product has the supporting strength of the metal, and the surface has the special furnace-changing effects of corrosion resistance, concave-convex space, color change and the like of the compound color enamel, so that the invention becomes a brand new artistic form, namely the compound color gold porcelain.
The present invention and the embodiments thereof have been described above without limitation, and it should be understood by those skilled in the art that the present invention is not limited thereto, and that the present invention is not limited to the embodiments and the embodiments without inventive design without departing from the spirit of the present invention.
Claims (6)
1. A method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain is characterized by comprising the following steps:
(1) designing a drawing: drawing a work drawing, and designing the layout of each part, including space unevenness, color change, a glaze flowing mechanism, glazing thickness, picture and white leaving, and subject style drop printing;
(2) manufacturing a sculpture mud shape: manufacturing initial clay draft sculpture works with concave-convex space change by using sculpture mud according to a design drawing;
(3) copying a mould: copying a glass fiber reinforced plastic resin work through a gypsum mold, copying a silica gel outer film again according to the glass fiber reinforced plastic resin work, copying a wax pattern with the same ratio as the original clay draft according to the silica gel outer film, trimming the wax pattern, and copying and casting a required hollow mold by using a lost wax method;
(4) metal casting: selecting a casting metal to be melted into liquid metal at high temperature, casting the hollow mould after removing impurities from the liquid metal, wherein the casting area is not too large so as to prevent the metal wall from being cellular, opening the mould after the cast metal part is cooled, and performing gas welding and splicing after simple cleaning to form a blank;
(5) treating a blank body: carrying out surface pickling cleaning on the cast metal sculpture, carrying out surface sand blasting after drying, washing and drying to prepare glaze color;
(6) compounding color porcelain glaze: placing the treated metal sculpture green body in a dust-free room for overglaze color restoration, firstly coating a layer of under glaze, spraying a layer of clear water after the under glaze is slightly dry, then repeatedly coating enamel overglaze layer by layer according to a design drawing, combining water to enable the overglaze colors to mutually permeate and fuse, and finally spraying a layer of transparent glaze according to picture requirements; after ensuring that no flaw exists, airing and then firing in a furnace;
(7) firing in a furnace: placing the product in a kiln at an inclination angle of 30 ℃ according to the size of the product, controlling the temperature of the kiln, firing for 40-90 minutes, and performing secondary firing when necessary;
(8) finishing a finished product: and carefully checking whether the composite color gold porcelain works have damage or flaws for finishing after firing.
2. The method for manufacturing the outdoor and indoor metal sculpture transmutation complex color gold porcelain according to claim 1, wherein the metal sculpture comprises a circular sculpture or a relief sculpture.
3. The method for manufacturing the outdoor and indoor metal sculpture transmutation complex color golden porcelain according to claim 1, wherein the cast metal comprises iron, copper, aluminum and stainless steel.
4. The method for manufacturing the outdoor and indoor metal sculpture transmutation complex color gold porcelain according to claim 1, wherein the temperature of a furnace is controlled according to the melting point of a metal bottom blank during firing; wherein when iron is used, the furnace temperature is controlled to be 800-860 ℃; when copper is used, the furnace temperature is controlled to be 800-820 ℃; when aluminum is used, the furnace temperature is controlled to be 570-580 ℃; when stainless steel is used, the furnace temperature is controlled at 570-820 ℃.
5. The method for manufacturing the outdoor and indoor metal sculpture transmutation composite color gold porcelain according to claim 1, wherein the selection of the ground glaze comprises cobalt oxide, nickel oxide and copper oxide.
6. The method for manufacturing the composite color gold porcelain for indoor and outdoor metal sculpture transmutations according to claim 1, wherein the enameling method comprises a dipping method, a coating method, a spraying method and a powder spraying method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110198306.2A CN112937194B (en) | 2021-02-22 | 2021-02-22 | Method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110198306.2A CN112937194B (en) | 2021-02-22 | 2021-02-22 | Method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN112937194A true CN112937194A (en) | 2021-06-11 |
| CN112937194B CN112937194B (en) | 2022-08-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110198306.2A Expired - Fee Related CN112937194B (en) | 2021-02-22 | 2021-02-22 | Method for manufacturing indoor and outdoor metal sculpture transmutation composite color gold porcelain |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112937194B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115556502A (en) * | 2022-11-09 | 2023-01-03 | 金华市神雕雕塑工艺有限公司 | Metal natural controllable forming method and application thereof in artware |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5067548A (en) * | 1991-03-19 | 1991-11-26 | Certech Incorporated | Method of forming a ceramic mold for metal casting |
| CN1799873A (en) * | 2006-01-10 | 2006-07-12 | 张维 | Process for preparing metallic enamel embossment |
| CN102616075A (en) * | 2011-01-27 | 2012-08-01 | 陈毅谦 | Making method of metal painted sculpture and painted craftwork |
| CN103601471A (en) * | 2013-11-05 | 2014-02-26 | 郑艳芳 | Production process of underglaze five-color ceramics with fine brushwork traditional Chinese painting carving |
| CN112174527A (en) * | 2020-10-19 | 2021-01-05 | 青岛裕晋精搪涂层有限公司 | Low-temperature sintering process method for enamel |
-
2021
- 2021-02-22 CN CN202110198306.2A patent/CN112937194B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5067548A (en) * | 1991-03-19 | 1991-11-26 | Certech Incorporated | Method of forming a ceramic mold for metal casting |
| CN1799873A (en) * | 2006-01-10 | 2006-07-12 | 张维 | Process for preparing metallic enamel embossment |
| CN102616075A (en) * | 2011-01-27 | 2012-08-01 | 陈毅谦 | Making method of metal painted sculpture and painted craftwork |
| CN103601471A (en) * | 2013-11-05 | 2014-02-26 | 郑艳芳 | Production process of underglaze five-color ceramics with fine brushwork traditional Chinese painting carving |
| CN112174527A (en) * | 2020-10-19 | 2021-01-05 | 青岛裕晋精搪涂层有限公司 | Low-temperature sintering process method for enamel |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115556502A (en) * | 2022-11-09 | 2023-01-03 | 金华市神雕雕塑工艺有限公司 | Metal natural controllable forming method and application thereof in artware |
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| CN112937194B (en) | 2022-08-05 |
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Granted publication date: 20220805 |