CN112680012B - 一种含玄武岩纤维及鳞片粉和金属铜粉的可降解防污涂层及其制备工艺 - Google Patents
一种含玄武岩纤维及鳞片粉和金属铜粉的可降解防污涂层及其制备工艺 Download PDFInfo
- Publication number
- CN112680012B CN112680012B CN202011554151.3A CN202011554151A CN112680012B CN 112680012 B CN112680012 B CN 112680012B CN 202011554151 A CN202011554151 A CN 202011554151A CN 112680012 B CN112680012 B CN 112680012B
- Authority
- CN
- China
- Prior art keywords
- parts
- powder
- degradable
- basalt
- antifouling coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000843 powder Substances 0.000 title claims abstract description 115
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 74
- 238000000576 coating method Methods 0.000 title claims abstract description 68
- 239000011248 coating agent Substances 0.000 title claims abstract description 66
- 229920002748 Basalt fiber Polymers 0.000 title claims abstract description 33
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 24
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 22
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 22
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 20
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 29
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000006185 dispersion Substances 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000003085 diluting agent Substances 0.000 claims description 12
- 239000004925 Acrylic resin Substances 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002048 multi walled nanotube Substances 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- -1 polysiloxane Polymers 0.000 claims description 6
- 239000002109 single walled nanotube Substances 0.000 claims description 6
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229920000180 alkyd Polymers 0.000 claims description 5
- 239000011490 mineral wool Substances 0.000 claims description 5
- 229920005749 polyurethane resin Polymers 0.000 claims description 5
- SHKUUQIDMUMQQK-UHFFFAOYSA-N 2-[4-(oxiran-2-ylmethoxy)butoxymethyl]oxirane Chemical compound C1OC1COCCCCOCC1CO1 SHKUUQIDMUMQQK-UHFFFAOYSA-N 0.000 claims description 4
- JJDGTGGQXAAVQX-UHFFFAOYSA-N 6-methyl-1-(6-methylheptoxy)heptane Chemical compound CC(C)CCCCCOCCCCCC(C)C JJDGTGGQXAAVQX-UHFFFAOYSA-N 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000007822 coupling agent Substances 0.000 claims description 4
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000003672 processing method Methods 0.000 claims description 4
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 claims description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 3
- QXONIHMUSQFKJU-UHFFFAOYSA-N 2-(prop-1-enoxymethyl)oxirane Chemical compound CC=COCC1CO1 QXONIHMUSQFKJU-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 claims description 3
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 235000010445 lecithin Nutrition 0.000 claims description 3
- 239000000787 lecithin Substances 0.000 claims description 3
- 229940067606 lecithin Drugs 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229940008099 dimethicone Drugs 0.000 claims 1
- 239000004205 dimethyl polysiloxane Substances 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 12
- 230000010069 protein adhesion Effects 0.000 abstract description 8
- 241000233866 Fungi Species 0.000 abstract description 4
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 241000195493 Cryptophyta Species 0.000 description 10
- 235000019441 ethanol Nutrition 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- 229910000077 silane Inorganic materials 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 230000008878 coupling Effects 0.000 description 4
- 238000010168 coupling process Methods 0.000 description 4
- 238000005859 coupling reaction Methods 0.000 description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 230000010065 bacterial adhesion Effects 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- 239000004641 Diallyl-phthalate Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000052 vinegar Substances 0.000 description 2
- 235000021419 vinegar Nutrition 0.000 description 2
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 2
- 238000002679 ablation Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229920006167 biodegradable resin Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 1
- 229940112669 cuprous oxide Drugs 0.000 description 1
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 229940083037 simethicone Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011554151.3A CN112680012B (zh) | 2020-12-24 | 2020-12-24 | 一种含玄武岩纤维及鳞片粉和金属铜粉的可降解防污涂层及其制备工艺 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011554151.3A CN112680012B (zh) | 2020-12-24 | 2020-12-24 | 一种含玄武岩纤维及鳞片粉和金属铜粉的可降解防污涂层及其制备工艺 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112680012A CN112680012A (zh) | 2021-04-20 |
CN112680012B true CN112680012B (zh) | 2022-12-27 |
Family
ID=75452966
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011554151.3A Active CN112680012B (zh) | 2020-12-24 | 2020-12-24 | 一种含玄武岩纤维及鳞片粉和金属铜粉的可降解防污涂层及其制备工艺 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112680012B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115012093A (zh) * | 2022-07-05 | 2022-09-06 | 晋江康邦拓新材料科技有限公司 | 一种抗菌防泼水面料及其加工方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE502004009764D1 (de) * | 2003-11-13 | 2009-08-27 | Unternehmen Fuer Spezialfasern | Biozidfreie antifouling-beschichtung enthaltend ein auf basaltfasern basierendes flächengebilde |
CN110964406A (zh) * | 2019-11-12 | 2020-04-07 | 无锡华东锌盾科技有限公司 | 一种水性环氧低表面处理防腐涂料及其制备方法和用途 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106986969B (zh) * | 2017-04-28 | 2022-02-11 | 华南理工大学 | 一种主链降解型聚丙烯酸铜树脂及其制备方法与应用 |
CN110691824B (zh) * | 2017-06-01 | 2021-05-25 | 日东化成株式会社 | 防污涂料组合物、在表面具有利用该组合物形成的防污涂膜的涂装物 |
CN108250941B (zh) * | 2018-01-22 | 2020-05-08 | 黑龙江省科学院高技术研究院 | 一种具有微纳米沟槽结构的低表面能材料及其制备方法 |
CN108441083A (zh) * | 2018-04-28 | 2018-08-24 | 北京航空航天大学 | 一种玄武岩鳞片无溶剂重防腐涂料及其制备方法 |
CN109294402A (zh) * | 2018-10-26 | 2019-02-01 | 达科(泰州)新材料有限公司 | 一种湿表面固化无溶剂重防腐涂料及制备工艺 |
CN110499095A (zh) * | 2019-08-14 | 2019-11-26 | 四川暄洋新材料科技有限公司 | 一种防污损的安全性涂料及其制备工艺与应用 |
CN112062921A (zh) * | 2020-08-24 | 2020-12-11 | 无锡市耀得信化工产品有限公司 | 含锌盐的丙烯酸聚氨酯树脂及其制备方法和应用 |
-
2020
- 2020-12-24 CN CN202011554151.3A patent/CN112680012B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE502004009764D1 (de) * | 2003-11-13 | 2009-08-27 | Unternehmen Fuer Spezialfasern | Biozidfreie antifouling-beschichtung enthaltend ein auf basaltfasern basierendes flächengebilde |
CN110964406A (zh) * | 2019-11-12 | 2020-04-07 | 无锡华东锌盾科技有限公司 | 一种水性环氧低表面处理防腐涂料及其制备方法和用途 |
Also Published As
Publication number | Publication date |
---|---|
CN112680012A (zh) | 2021-04-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101967316B (zh) | 一种用于海洋船舶与设施的无毒防污涂料及其制备方法 | |
CN107400421B (zh) | 一种耐腐蚀的金属涂层材料及其制备方法 | |
CN101230224A (zh) | 氟硅橡胶纳米复合合金三防涂料及其生产方法 | |
CN1106433C (zh) | 钛纳米聚合物涂料 | |
CN108997889A (zh) | 一种海洋舰船用石墨烯重防腐底漆及其制备方法 | |
CN1927968A (zh) | 基于有机硅丙烯酸环氧酯水分散体的水性工业涂料及其制备方法 | |
CN109517516B (zh) | 一种铈化膨润土改性水性聚氨酯涂料及其制备方法 | |
CN113736364B (zh) | 水下高粘结力有机硅海洋防污涂料及其固化涂层和制备方法 | |
CN112680012B (zh) | 一种含玄武岩纤维及鳞片粉和金属铜粉的可降解防污涂层及其制备工艺 | |
CN110684467A (zh) | 一种基于氧化石墨烯的水基防腐涂料及其制备方法 | |
CN115044279B (zh) | 二维聚多巴胺增强水性环氧复合防腐涂料及其制法与应用 | |
CN104387922B (zh) | 水性导静电涂料及其制备 | |
CN112694833A (zh) | 一种含玄武岩纤维粉及鳞片粉的复合低表面能防污涂料及其制备方法 | |
CN105062314A (zh) | 一种耐高低温uv塑胶涂料及其制备方法 | |
CN113683939B (zh) | 一种氧化石墨烯水性环氧涂料及其制备方法 | |
CN107337983A (zh) | 一种双组分阴极电泳涂料 | |
CN108610892A (zh) | 一种海洋钢结构防腐防污水性涂料及其制备方法 | |
CN108250906A (zh) | 一种水性石墨烯涂料及其制备方法 | |
KR20110089762A (ko) | 1액형 상온건조형 수용성 상도 도료 조성물 | |
CN114539885B (zh) | 混凝土专用高渗入型潮湿固化封闭底漆及其制法与应用 | |
CN109233532A (zh) | 一种海洋装备用高固厚膜耐蚀防污环保型涂料 | |
CN110105834A (zh) | 一种水性丙烯酸沥青防腐涂料及其制备工艺 | |
CN104673059A (zh) | 一种水性环氧丙烯酸树脂防腐涂料及其制备方法 | |
CN114181593A (zh) | 水性涂镀锌树脂化合物及其制备方法、应用 | |
CN109517463B (zh) | 一种防污可剥离涂料组合物及其制备方法和用途 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240517 Address after: 570228 Hainan University, 58 Renmin Avenue, Hainan, Haikou Patentee after: HAINAN University Country or region after: China Patentee after: Sichuan Qianyi Composite Material Co.,Ltd. Patentee after: Sichuan Helian Basalt Fiber Technology Co.,Ltd. Address before: 570228 Hainan University, 58 Renmin Avenue, Hainan, Haikou Patentee before: HAINAN University Country or region before: China Patentee before: Sichuan Qianyi Composite Material Co.,Ltd. |