CN112409832A - Heat-resistant cooling building material and preparation method thereof - Google Patents
Heat-resistant cooling building material and preparation method thereof Download PDFInfo
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- CN112409832A CN112409832A CN202011345138.7A CN202011345138A CN112409832A CN 112409832 A CN112409832 A CN 112409832A CN 202011345138 A CN202011345138 A CN 202011345138A CN 112409832 A CN112409832 A CN 112409832A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
The invention discloses a heat-resistant cooling building material and a preparation method thereof, wherein the heat-resistant cooling building material comprises the following raw materials in parts by weight: the building material has the advantages of being capable of directly being used for building roofs and outer walls, and being capable of achieving indoor cooling after being coated due to excellent heat insulation and heat radiation performance, wherein the building material is composed of, by weight, 150-168 parts of acrylic emulsion, 10-13 parts of silicon carbide fiber, 3-5 parts of hexamethyldisilazane, 22-34 parts of vinyltriethoxysilane, 2-4 parts of sodium alkylsulfonate, 18-30 parts of silicone resin polyether emulsion, 25-26 parts of mica powder, 10-14 parts of iron oxide, 15-20 parts of nano titanium dioxide, 1-3 parts of tetraisopropyl titanate, 3-5 parts of glycidyl methacrylate, 2-4 parts of polyamide wax and 1-3 parts of polyvinylpyrrolidone.
Description
Technical Field
The invention relates to a heat-resistant cooling building material and a preparation method thereof.
Background
Building materials are a general term for materials used in civil engineering and construction. It can be divided into structural material, decorative material and some special materials. The structural materials comprise wood, bamboo, stone, cement, concrete, metal, tiles, ceramics, glass, engineering plastics, composite materials and the like. The decorative material includes various coatings, paints, plating layers, veneers, ceramic tiles with various colors, glass with special effects and the like, and the special material is used for water proofing, moisture proofing, corrosion resistance, fire proofing, flame retardance, sound insulation, heat preservation, sealing and the like.
The heat insulation of houses is particularly important, and houses with good heat insulation effect can keep relatively low temperature and are more comfortable, so that a building material product with excellent heat insulation effect is needed.
Disclosure of Invention
The invention aims to provide a heat-resistant cooling building material and a preparation method thereof, the heat-resistant cooling building material can be directly used for building roofs and outer walls, and indoor cooling can be realized after coating due to excellent heat insulation and heat radiation performance.
In order to solve the problems, the invention adopts the following technical scheme:
the heat-resistant cooling building material comprises the following raw materials in parts by weight: 150-168 parts of acrylic emulsion, 10-13 parts of silicon carbide fiber, 3-5 parts of hexamethyldisilazane, 22-34 parts of vinyl triethoxysilane, 2-4 parts of alkyl sodium sulfonate, 18-30 parts of silicone resin polyether emulsion, 25-26 parts of mica powder, 10-14 parts of iron oxide, 15-20 parts of nano titanium dioxide, 1-3 parts of tetraisopropyl titanate, 3-5 parts of glycidyl methacrylate, 2-4 parts of polyamide wax and 1-3 parts of polyvinylpyrrolidone.
Further, the feed comprises the following raw materials in parts by weight: 150 parts of acrylic emulsion, 10 parts of silicon carbide fiber, 3 parts of hexamethyldisilazane, 22 parts of vinyltriethoxysilane, 2 parts of sodium alkylsulfonate, 18 parts of silicone polyether emulsion, 25 parts of mica powder, 10 parts of ferric oxide, 15 parts of nano titanium dioxide, 1 part of tetraisopropyl titanate, 3 parts of glycidyl methacrylate, 2 parts of polyamide wax and 1 part of polyvinylpyrrolidone.
Further, the feed comprises the following raw materials in parts by weight: 168 parts of acrylic emulsion, 13 parts of silicon carbide fiber, 5 parts of hexamethyldisilazane, 34 parts of vinyl triethoxysilane, 4 parts of sodium alkyl sulfonate, 30 parts of silicone polyether emulsion, 26 parts of mica powder, 14 parts of iron oxide, 20 parts of nano titanium dioxide, 3 parts of tetraisopropyl titanate, 5 parts of glycidyl methacrylate, 4 parts of polyamide wax and 3 parts of polyvinylpyrrolidone.
Further, the feed comprises the following raw materials in parts by weight: 155 parts of acrylic emulsion, 12 parts of silicon carbide fiber, 4 parts of hexamethyldisilazane, 30 parts of vinyl triethoxysilane, 3 parts of sodium alkyl sulfonate, 25 parts of silicone polyether emulsion, 26 parts of mica powder, 13 parts of iron oxide, 18 parts of nano titanium dioxide, 2 parts of tetraisopropyl titanate, 4 parts of glycidyl methacrylate, 3 parts of polyamide wax and 2 parts of polyvinylpyrrolidone.
The invention aims to solve another technical problem of providing a preparation method of the heat-resistant cooling building material, which comprises the following steps:
1) pouring 150-168 parts of acrylic emulsion, 3-5 parts of hexamethyldisilazane, 22-34 parts of vinyl triethoxysilane, 2-4 parts of sodium alkylsulfonate, 18-30 parts of silicone polyether emulsion, 1-3 parts of tetraisopropyl titanate, 3-5 parts of glycidyl methacrylate, 2-4 parts of polyamide wax and 1-3 parts of polyvinylpyrrolidone into a pulping tank for stirring and premixing treatment to prepare a premix for later use;
2) adding 25-26 parts of mica powder, 10-14 parts of ferric oxide, 15-20 parts of nano titanium dioxide and 10-13 parts of silicon carbide fiber into the premix prepared in the step 1), and stirring and mixing the mixture in a pulping tank to uniformly mix the materials to obtain the building material.
The invention has the beneficial effects that: through adding, carborundum fibre, mica powder, iron oxide and nanometer titanium dioxide, can be so that the articles for use after paintings have outstanding heat shielding performance, and coating intensity is high moreover, and mica powder and iron oxide can cause excellent heat radiation effect simultaneously, can launch the heat energy that the membrane face absorbed heat and accumulated with the radiation mode, can effectually reduce the inside temperature of building when hot weather after the use.
The following characteristics or functions of the raw materials of the heat-resistant and temperature-reducing building material are as follows:
the acrylic emulsion is non-toxic, non-irritant, non-harmful to human body, environmentally friendly, non-film-forming high gloss resin, excellent gloss and transparency, and good in anti-blocking performance.
Silicon carbide fiber: the maximum use temperature reaches 1200 ℃, the heat resistance and the oxidation resistance of the composite material are superior to those of carbon fiber, the strength reaches 1960-4410 MPa, the strength retention rate is more than 80% at the maximum use temperature, the modulus is 176.4-294 GPa, and the chemical stability is good. Mainly used as high temperature resistant materials and reinforcing materials, and the high temperature resistant materials comprise heat shielding materials.
Hexamethyldisilazane: a colorless transparent liquid. The silicon carbide fiber is used as an auxiliary agent of the silicon carbide fiber, improves the heat resistance and the strength of the silicon carbide fiber, and is also used as an anti-settling agent of a coating.
Vinyltriethoxysilane: the emulsion is prepared by adding the cross-linking agent into acrylic emulsion and polymerizing, and combines the high temperature resistance, weather resistance, chemical resistance, hydrophobicity, low surface energy and low pollution resistance of organic silicon and the high color retention, flexibility and adhesiveness of acrylic resin.
Sodium alkyl sulfonate: is an antirust additive and an emulsifier.
Silicone polyether emulsion: better compatibility. Antifouling and scratch-resistant, reduces the surface tension of the system, promotes leveling, improves the wettability of the substrate and prevents shrinkage cavity. While enhancing surface smoothness and gloss.
Mica powder: the sericite with ultraviolet and infrared resistance has excellent performance of shielding ultraviolet rays, infrared rays and the like. Can greatly improve the ultraviolet resistance of the paint film, delay the aging of the paint film and simultaneously have good heat insulation effect.
Iron oxide: the covering power and the tinting strength are strong, and the paint has no oil permeability and water permeability. The mica powder is stable in atmosphere and sunlight, resistant to dirty gas, resistant to high temperature and alkali, and capable of causing excellent heat radiation effect by matching with the mica powder, and emitting heat energy absorbed and accumulated by the film surface in a radiation mode.
Nano titanium dioxide: has strong ultraviolet shielding effect, good dispersibility and good weather resistance. Can be used as ultraviolet screening agent for preventing ultraviolet ray invasion.
Tetraisopropyl titanate: when the coating is used in paint, various polymers or resins can play a role in crosslinking, the corrosion resistance of the coating is improved, and the adhesion between the coating and the surface is promoted.
Glycidyl methacrylate: the adhesive force to metal, glass, cement, polyvinyl fluoride and the like can be improved by compounding the acrylic emulsion.
Polyamide wax: is a thixotropic additive. The solvent is effectively activated to form a strong network structure in a paint system, and the paint system has excellent thixotropic property and excellent sagging resistance and sedimentation resistance.
Polyvinylpyrrolidone: improve the luster and the dispersibility of the paint and the pigment, improve the thermal stability, improve the dispersibility of the filler and the like.
Detailed Description
The technical solutions of the present invention are described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and it is obvious for those skilled in the art to obtain other embodiments according to these embodiments without creative efforts.
Example 1:
the heat-resistant cooling building material comprises the following raw materials in parts by weight: 150 parts of acrylic emulsion, 10 parts of silicon carbide fiber, 3 parts of hexamethyldisilazane, 22 parts of vinyltriethoxysilane, 2 parts of sodium alkylsulfonate, 18 parts of silicone polyether emulsion, 25 parts of mica powder, 10 parts of ferric oxide, 15 parts of nano titanium dioxide, 1 part of tetraisopropyl titanate, 3 parts of glycidyl methacrylate, 2 parts of polyamide wax and 1 part of polyvinylpyrrolidone.
The preparation method of the heat-resistant cooling building material comprises the following steps:
1) pouring 150 parts of acrylic emulsion, 3 parts of hexamethyldisilazane, 22 parts of vinyl triethoxysilane, 2 parts of alkyl sodium sulfonate, 18 parts of silicone polyether emulsion, 1 part of tetraisopropyl titanate, 3 parts of glycidyl methacrylate, 2 parts of polyamide wax and 1 part of polyvinylpyrrolidone into a pulping tank for stirring and premixing treatment to prepare a premix for later use;
2) adding 25 parts of mica powder, 10 parts of ferric oxide, 15 parts of nano titanium dioxide and 10 parts of silicon carbide fiber into the pre-mixture prepared in the step 1), and continuously stirring and mixing in a pulping tank to uniformly mix the materials to obtain the building material.
Example 2:
the heat-resistant cooling building material comprises the following raw materials in parts by weight: 168 parts of acrylic emulsion, 13 parts of silicon carbide fiber, 5 parts of hexamethyldisilazane, 34 parts of vinyl triethoxysilane, 4 parts of sodium alkyl sulfonate, 30 parts of silicone polyether emulsion, 26 parts of mica powder, 14 parts of iron oxide, 20 parts of nano titanium dioxide, 3 parts of tetraisopropyl titanate, 5 parts of glycidyl methacrylate, 4 parts of polyamide wax and 3 parts of polyvinylpyrrolidone.
The preparation method of the heat-resistant cooling building material comprises the following steps:
1) 168 parts of acrylic emulsion, 5 parts of hexamethyldisilazane, 34 parts of vinyl triethoxysilane, 4 parts of sodium alkylsulfonate, 30 parts of silicone polyether emulsion, 3 parts of tetraisopropyl titanate, 5 parts of glycidyl methacrylate, 4 parts of polyamide wax and 3 parts of polyvinylpyrrolidone are poured into a pulping tank for stirring and premixing treatment to prepare a premix for later use;
2) adding 26 parts of mica powder, 14 parts of ferric oxide, 20 parts of nano titanium dioxide and 13 parts of silicon carbide fiber into the pre-mixture prepared in the step 1), and continuously stirring and mixing in a pulping tank to uniformly mix the materials to obtain the building material.
Example 3:
the heat-resistant cooling building material comprises the following raw materials in parts by weight: 155 parts of acrylic emulsion, 12 parts of silicon carbide fiber, 4 parts of hexamethyldisilazane, 30 parts of vinyl triethoxysilane, 3 parts of sodium alkyl sulfonate, 25 parts of silicone polyether emulsion, 26 parts of mica powder, 13 parts of iron oxide, 18 parts of nano titanium dioxide, 2 parts of tetraisopropyl titanate, 4 parts of glycidyl methacrylate, 3 parts of polyamide wax and 2 parts of polyvinylpyrrolidone.
The preparation method of the heat-resistant cooling building material comprises the following steps:
1) pouring 155 parts of acrylic emulsion, 4 parts of hexamethyldisilazane, 30 parts of vinyl triethoxysilane, 3 parts of alkyl sodium sulfonate, 25 parts of silicone polyether emulsion, 2 parts of tetraisopropyl titanate, 4 parts of glycidyl methacrylate, 3 parts of polyamide wax and 2 parts of polyvinylpyrrolidone into a pulping tank for stirring and premixing treatment to prepare a premix for later use;
2) adding 26 parts of mica powder, 13 parts of ferric oxide, 18 parts of nano titanium dioxide and 12 parts of silicon carbide fiber into the pre-mixture prepared in the step 1), and continuously stirring and mixing in a pulping tank to uniformly mix the materials to obtain the building material.
Experimental example 1:
the building materials prepared in examples 1, 2 and 3 were coated on three acrylic plates each having a length and a width of 5cm × 5cm, respectively, the coating thicknesses were controlled to be about 100 μm, and the coating layers were dried to form films, which were used as test materials for three experimental groups. And the incident light angle is 8 degrees, and a full-spectrum spectrophotometer is adopted to test the reflectivity of the reflection spectrum and the sub-band. The specific test results are shown in the following table:
it can be seen that the building materials prepared in the examples have excellent reflection effect after film formation.
Experimental example 2:
the test objects for the three experimental groups are flatly placed on an external horizontal cement ground at the external temperature of 30 +/-2 ℃, the test objects are placed for 2 hours, then the surface temperature and the ground temperature of each test object are detected by an outdoor thermal infrared imager, data are recorded by a tail removing method, and specific results are shown in the following table.
It can be seen that the surface of the test objects in the experimental group was at a lower temperature than the ground.
The invention has the beneficial effects that: through adding, carborundum fibre, mica powder, iron oxide and nanometer titanium dioxide, can be so that the articles for use after paintings have outstanding heat shielding performance, and coating intensity is high moreover, and mica powder and iron oxide can cause excellent heat radiation effect simultaneously, can launch the heat energy that the membrane face absorbed heat and accumulated with the radiation mode, can effectually reduce the inside temperature of building when hot weather after the use.
The above description is only an embodiment of the present invention, but the scope of the present invention is not limited thereto, and any changes or substitutions that are not thought of through the inventive work should be included in the scope of the present invention.
Claims (5)
1. The heat-resistant cooling building material is characterized by comprising the following raw materials in parts by weight: 150-168 parts of acrylic emulsion, 10-13 parts of silicon carbide fiber, 3-5 parts of hexamethyldisilazane, 22-34 parts of vinyl triethoxysilane, 2-4 parts of alkyl sodium sulfonate, 18-30 parts of silicone resin polyether emulsion, 25-26 parts of mica powder, 10-14 parts of iron oxide, 15-20 parts of nano titanium dioxide, 1-3 parts of tetraisopropyl titanate, 3-5 parts of glycidyl methacrylate, 2-4 parts of polyamide wax and 1-3 parts of polyvinylpyrrolidone.
2. The heat-resistant cooling building material of claim 1, which is characterized by comprising the following raw materials in parts by weight: 150 parts of acrylic emulsion, 10 parts of silicon carbide fiber, 3 parts of hexamethyldisilazane, 22 parts of vinyltriethoxysilane, 2 parts of sodium alkylsulfonate, 18 parts of silicone polyether emulsion, 25 parts of mica powder, 10 parts of ferric oxide, 15 parts of nano titanium dioxide, 1 part of tetraisopropyl titanate, 3 parts of glycidyl methacrylate, 2 parts of polyamide wax and 1 part of polyvinylpyrrolidone.
3. The heat-resistant cooling building material of claim 1, which is characterized by comprising the following raw materials in parts by weight: 168 parts of acrylic emulsion, 13 parts of silicon carbide fiber, 5 parts of hexamethyldisilazane, 34 parts of vinyl triethoxysilane, 4 parts of sodium alkyl sulfonate, 30 parts of silicone polyether emulsion, 26 parts of mica powder, 14 parts of iron oxide, 20 parts of nano titanium dioxide, 3 parts of tetraisopropyl titanate, 5 parts of glycidyl methacrylate, 4 parts of polyamide wax and 3 parts of polyvinylpyrrolidone.
4. The heat-resistant cooling building material of claim 1, which is characterized by comprising the following raw materials in parts by weight: 155 parts of acrylic emulsion, 12 parts of silicon carbide fiber, 4 parts of hexamethyldisilazane, 30 parts of vinyl triethoxysilane, 3 parts of sodium alkyl sulfonate, 25 parts of silicone polyether emulsion, 26 parts of mica powder, 13 parts of iron oxide, 18 parts of nano titanium dioxide, 2 parts of tetraisopropyl titanate, 4 parts of glycidyl methacrylate, 3 parts of polyamide wax and 2 parts of polyvinylpyrrolidone.
5. The preparation method of the heat-resistant cooling building material is characterized by comprising the following steps of:
1) pouring 150-168 parts of acrylic emulsion, 3-5 parts of hexamethyldisilazane, 22-34 parts of vinyl triethoxysilane, 2-4 parts of sodium alkylsulfonate, 18-30 parts of silicone polyether emulsion, 1-3 parts of tetraisopropyl titanate, 3-5 parts of glycidyl methacrylate, 2-4 parts of polyamide wax and 1-3 parts of polyvinylpyrrolidone into a pulping tank for stirring and premixing treatment to prepare a premix for later use;
2) adding 25-26 parts of mica powder, 10-14 parts of ferric oxide, 15-20 parts of nano titanium dioxide and 10-13 parts of silicon carbide fiber into the premix prepared in the step 1), and stirring and mixing the mixture in a pulping tank to uniformly mix the materials to obtain the building material.
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| CN202011345138.7A CN112409832A (en) | 2020-11-26 | 2020-11-26 | Heat-resistant cooling building material and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371541A (en) * | 2014-11-17 | 2015-02-25 | 株洲市九华新材料涂装实业有限公司 | High-temperature primer for metro wheels and preparation method of high-temperature primer |
| CN106957573A (en) * | 2017-04-06 | 2017-07-18 | 赵婕 | A kind of water nano level heat insulating coatings and preparation method thereof |
| CN108395749A (en) * | 2018-04-05 | 2018-08-14 | 晋佳佳 | A kind of anticorrosive coating and preparation method thereof |
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2020
- 2020-11-26 CN CN202011345138.7A patent/CN112409832A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104371541A (en) * | 2014-11-17 | 2015-02-25 | 株洲市九华新材料涂装实业有限公司 | High-temperature primer for metro wheels and preparation method of high-temperature primer |
| CN106957573A (en) * | 2017-04-06 | 2017-07-18 | 赵婕 | A kind of water nano level heat insulating coatings and preparation method thereof |
| CN108395749A (en) * | 2018-04-05 | 2018-08-14 | 晋佳佳 | A kind of anticorrosive coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 苑鸿兴编: "《碳世界》", 31 December 2011 * |
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Application publication date: 20210226 |