CN112191109A - 氢气提纯的Pd基/CeO2/多孔支撑体复合膜的制备方法 - Google Patents
氢气提纯的Pd基/CeO2/多孔支撑体复合膜的制备方法 Download PDFInfo
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- CN112191109A CN112191109A CN202011079948.2A CN202011079948A CN112191109A CN 112191109 A CN112191109 A CN 112191109A CN 202011079948 A CN202011079948 A CN 202011079948A CN 112191109 A CN112191109 A CN 112191109A
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- 239000012528 membrane Substances 0.000 title claims abstract description 45
- 239000002131 composite material Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 22
- 239000001257 hydrogen Substances 0.000 title claims abstract description 20
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 43
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 31
- 238000012986 modification Methods 0.000 claims abstract description 28
- 230000004048 modification Effects 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- 238000007747 plating Methods 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 49
- 238000002360 preparation method Methods 0.000 claims description 18
- 239000000919 ceramic Substances 0.000 claims description 12
- 239000011148 porous material Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 229910052763 palladium Inorganic materials 0.000 claims description 8
- 239000005373 porous glass Substances 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 206010070834 Sensitisation Diseases 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 6
- 230000002572 peristaltic effect Effects 0.000 claims description 6
- 238000007789 sealing Methods 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- 239000010935 stainless steel Substances 0.000 claims description 6
- 229910001220 stainless steel Inorganic materials 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 3
- 229910021124 PdAg Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 229910001325 element alloy Inorganic materials 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 230000007246 mechanism Effects 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims 1
- 229910001868 water Inorganic materials 0.000 abstract description 11
- 229910045601 alloy Inorganic materials 0.000 abstract description 7
- 239000000956 alloy Substances 0.000 abstract description 7
- 238000000746 purification Methods 0.000 abstract description 7
- 238000002715 modification method Methods 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000007772 electroless plating Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000001878 scanning electron micrograph Methods 0.000 description 3
- 241000282414 Homo sapiens Species 0.000 description 2
- 229910002666 PdCl2 Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical group O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000008313 sensitization Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/022—Metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
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CN202011079948.2A CN112191109A (zh) | 2020-10-10 | 2020-10-10 | 氢气提纯的Pd基/CeO2/多孔支撑体复合膜的制备方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN113368701A (zh) * | 2021-06-16 | 2021-09-10 | 曾祥燕 | 一种Pd复合膜的制备方法 |
Citations (10)
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CN1640530A (zh) * | 2004-01-09 | 2005-07-20 | 中国科学院大连化学物理研究所 | 一种复合金属钯膜或合金钯膜及其制备方法 |
CN101670245A (zh) * | 2008-09-10 | 2010-03-17 | 徐恒泳 | 一种高透氢选择性金属钯复合膜的制备方法 |
WO2011122250A1 (ja) * | 2010-03-29 | 2011-10-06 | 独立行政法人産業技術総合研究所 | 無欠陥化水素分離膜、無欠陥化水素分離膜の製造方法及び水素分離方法 |
CN102698615A (zh) * | 2012-06-28 | 2012-10-03 | 中国科学院大连化学物理研究所 | 一种制备钯膜及其复合膜的方法 |
CN103182249A (zh) * | 2011-12-30 | 2013-07-03 | 财团法人工业技术研究院 | 多孔基材的修饰方法及经修饰的多孔基材 |
US20150027307A1 (en) * | 2013-07-25 | 2015-01-29 | Korea Institute Of Energy Research | Method for preparing hydrogen separation membrane and device for prepariing hydrogen separation membrane |
CN105233701A (zh) * | 2015-09-19 | 2016-01-13 | 辽宁工业大学 | 一种大孔载体表面制备钯膜的方法 |
CN105792918A (zh) * | 2013-12-05 | 2016-07-20 | 株式会社明电舍 | 陶瓷过滤器 |
CN107376661A (zh) * | 2017-08-31 | 2017-11-24 | 廊坊师范学院 | 一种钯基复合膜的制备方法 |
US20180272288A1 (en) * | 2017-03-24 | 2018-09-27 | Korea University Research And Business Foundation | Method of preparing perm-selective porous membrane and method of separating gases using porous membrane prepared thereby |
-
2020
- 2020-10-10 CN CN202011079948.2A patent/CN112191109A/zh active Pending
Patent Citations (10)
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CN1640530A (zh) * | 2004-01-09 | 2005-07-20 | 中国科学院大连化学物理研究所 | 一种复合金属钯膜或合金钯膜及其制备方法 |
CN101670245A (zh) * | 2008-09-10 | 2010-03-17 | 徐恒泳 | 一种高透氢选择性金属钯复合膜的制备方法 |
WO2011122250A1 (ja) * | 2010-03-29 | 2011-10-06 | 独立行政法人産業技術総合研究所 | 無欠陥化水素分離膜、無欠陥化水素分離膜の製造方法及び水素分離方法 |
CN103182249A (zh) * | 2011-12-30 | 2013-07-03 | 财团法人工业技术研究院 | 多孔基材的修饰方法及经修饰的多孔基材 |
CN102698615A (zh) * | 2012-06-28 | 2012-10-03 | 中国科学院大连化学物理研究所 | 一种制备钯膜及其复合膜的方法 |
US20150027307A1 (en) * | 2013-07-25 | 2015-01-29 | Korea Institute Of Energy Research | Method for preparing hydrogen separation membrane and device for prepariing hydrogen separation membrane |
CN105792918A (zh) * | 2013-12-05 | 2016-07-20 | 株式会社明电舍 | 陶瓷过滤器 |
CN105233701A (zh) * | 2015-09-19 | 2016-01-13 | 辽宁工业大学 | 一种大孔载体表面制备钯膜的方法 |
US20180272288A1 (en) * | 2017-03-24 | 2018-09-27 | Korea University Research And Business Foundation | Method of preparing perm-selective porous membrane and method of separating gases using porous membrane prepared thereby |
CN107376661A (zh) * | 2017-08-31 | 2017-11-24 | 廊坊师范学院 | 一种钯基复合膜的制备方法 |
Non-Patent Citations (2)
Title |
---|
D.MARTINEZ-DIAZ,ET AL: "H2 permeation increase of electroless pore-plated Pd/PSS membranes with CeO2 intermediate barriers", 《SEPARATION AND PURIFICATION TECHNOLOGY》 * |
D.MARTINEZ-DIAZ,ET AL: "Pd-thickness reduction in electroless pore-plated membranes by using doped-ceria as interlayer", 《INTERNATIONAL JOURNAL OF HYDROGEN ENERGY》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113368701A (zh) * | 2021-06-16 | 2021-09-10 | 曾祥燕 | 一种Pd复合膜的制备方法 |
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Inventor after: Li Xinzhong Inventor after: Yang Yuxin Inventor after: Li Xinhua Inventor before: Li Xinzhong Inventor before: Yang Yuxin Inventor before: Li Xinhua |
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Effective date of registration: 20220207 Address after: 241000 No. 4, Jinye Road, Sanshan Economic Development Zone, Wuhu City, Anhui Province Applicant after: Wuhu China hydrogen New Energy Technology Co.,Ltd. Address before: 130 Flourishing Street, Nangang District, Harbin City, Heilongjiang Province Applicant before: Li Xinzhong |
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Application publication date: 20210108 |