CN112007662A - Preparation method and application of metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst - Google Patents
Preparation method and application of metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst Download PDFInfo
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- CN112007662A CN112007662A CN202010639806.0A CN202010639806A CN112007662A CN 112007662 A CN112007662 A CN 112007662A CN 202010639806 A CN202010639806 A CN 202010639806A CN 112007662 A CN112007662 A CN 112007662A
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 229910052982 molybdenum disulfide Inorganic materials 0.000 title claims abstract description 52
- 239000002131 composite material Substances 0.000 title claims abstract description 45
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 33
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 31
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000002071 nanotube Substances 0.000 title claims abstract description 28
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 26
- 239000002184 metal Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 229910052961 molybdenite Inorganic materials 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 230000001699 photocatalysis Effects 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 238000005406 washing Methods 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 8
- 239000000725 suspension Substances 0.000 claims abstract description 8
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 239000012535 impurity Substances 0.000 claims abstract description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004202 carbamide Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 238000001291 vacuum drying Methods 0.000 claims abstract description 5
- 239000004809 Teflon Substances 0.000 claims abstract description 4
- 229920006362 Teflon® Polymers 0.000 claims abstract description 4
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 4
- 229940088710 antibiotic agent Drugs 0.000 claims abstract description 4
- 239000002243 precursor Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 3
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 13
- 229960004989 tetracycline hydrochloride Drugs 0.000 claims description 9
- 230000003115 biocidal effect Effects 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 230000035484 reaction time Effects 0.000 claims description 2
- 239000002351 wastewater Substances 0.000 claims description 2
- YCIHPQHVWDULOY-FMZCEJRJSA-N (4s,4as,5as,6s,12ar)-4-(dimethylamino)-1,6,10,11,12a-pentahydroxy-6-methyl-3,12-dioxo-4,4a,5,5a-tetrahydrotetracene-2-carboxamide;hydrochloride Chemical compound Cl.C1=CC=C2[C@](O)(C)[C@H]3C[C@H]4[C@H](N(C)C)C(=O)C(C(N)=O)=C(O)[C@@]4(O)C(=O)C3=C(O)C2=C1O YCIHPQHVWDULOY-FMZCEJRJSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 abstract description 4
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 abstract description 4
- 238000001027 hydrothermal synthesis Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 11
- 239000000243 solution Substances 0.000 description 9
- XMEVHPAGJVLHIG-FMZCEJRJSA-N chembl454950 Chemical compound [Cl-].C1=CC=C2[C@](O)(C)[C@H]3C[C@H]4[C@H]([NH+](C)C)C(O)=C(C(N)=O)C(=O)[C@@]4(O)C(O)=C3C(=O)C2=C1O XMEVHPAGJVLHIG-FMZCEJRJSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 6
- 238000006731 degradation reaction Methods 0.000 description 6
- 230000006872 improvement Effects 0.000 description 5
- 230000003197 catalytic effect Effects 0.000 description 4
- 230000000593 degrading effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000003426 co-catalyst Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 238000001308 synthesis method Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
- B01J27/051—Molybdenum
-
- B01J35/39—
-
- B01J35/50—
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
Abstract
The invention discloses a preparation method of a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst, which comprises the following steps: firstly, dissolving 18mg of MoO3, 21mg of thioacetamide and 180mg of urea in 80ml of deionized water to obtain a precursor solution of 1T-MoS 2; secondly, adding 40-4000mgTNTs powder into the solution, and stirring for 2 hours to fully mix the materials to obtain suspension; thirdly, transferring the suspension into a high-pressure reaction kettle with a 100mL Teflon liner, and reacting for 12-24h in an oven at 200 ℃; and fourthly, washing the product obtained after the reaction by deionized water and absolute ethyl alcohol to remove impurities, then drying in a vacuum drying oven, and finally grinding to obtain 0.5-5% of 1T-MoS2@ TNTs composite photocatalytic material powder. The metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalytic material is synthesized for the first time by a hydrothermal method with simple operation, and is found to show good capability of decomposing antibiotics in water under visible light.
Description
Technical Field
The invention belongs to the technical field of synthesis of molybdenum disulfide/titanium dioxide composite photocatalysts, and particularly relates to a preparation method and application of a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst.
Background
In recent years, with the increasing severity of water body antibiotic pollution, clean and efficient pollution treatment schemes are increasingly emphasized. Among them, the photocatalytic technology is considered to be an effective way to solve the antibiotic pollution of water body due to the advantages of cleanness, no pollution, low cost and the like. Semiconductor photocatalysts are widely researched in the aspect of degrading organic pollutants, and the search for efficient photocatalysts is always the research focus in the field.
TiO2 is applied to the research of the photocatalysis field for a long time due to the excellent photoelectric property, titanium dioxide nanotubes (TNTs) are a one-dimensional titanium dioxide material, compared with zero-dimensional titanium dioxide nanoparticles, the structure has larger specific surface area, higher utilization rate of sunlight, stronger adsorption effect and larger potential in the photocatalysis field. However, the photocatalytic ability is limited by the characteristics of titanium dioxide such as large forbidden bandwidth, poor response to visible light, high recombination efficiency of photo-generated electrons and holes, and the like, so that a material needs to be introduced for modification. Research shows that the catalytic performance of the catalyst can be effectively improved by loading MoS2 on the surface of TiO 2. The metallic phase molybdenum disulfide (1T-MoS2) possesses higher electron transfer efficiency and more abundant active sites than the semiconducting phase molybdenum disulfide 2H-MoS2, however previous studies have used 2H-MoS2 as a co-catalyst due to 1T-MoS2 instability. The preparation method of the stable 1T-MoS2 is mature at present, but no 1T-MoS2 and TiO2 composite material photocatalyst is reported.
Accordingly, there is a need for improvements in the art.
Disclosure of Invention
The invention aims to provide a preparation method and application of a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst with simple process and low cost.
In order to solve the technical problems, the invention provides a preparation method of a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst, which comprises the following steps: the method comprises the following steps:
step S1: 18mgMoO321mg thioacetamide and 180mg urea in 80ml deionized water to obtain 1T-MoS2In a 1T-MoS2Adding 40-4000mgTNTs powder into the precursor solution, and stirring for 2 hours to fully mix the materials to obtain a suspension;
step S2: transferring the suspension obtained in the step S1 into a 100mL Teflon-lined high-pressure reaction kettle (without pressurization), and reacting in an oven at 200 ℃ for 12-24h to obtain a reaction product;
step S3: washing the reaction product obtained in the step S2 by deionized water and absolute ethyl alcohol to remove impurities, then drying in a vacuum drying oven, and finally grinding to obtain 0.5-5% of 1T-MoS2@ TNTs composite photocatalytic material powder.
The preparation method of the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst is improved as follows:
the TNTs powder in step S1 was 4000 mg.
As a further improvement of the preparation method of the metal phase molybdenum disulfide/titanium dioxide nanotube composite material photocatalyst, the preparation method comprises the following steps:
in the step S2, the drying temperature in the oven is 60 ℃, and the reaction time is 12 h.
As a further improvement of the preparation method of the metal phase molybdenum disulfide/titanium dioxide nanotube composite material photocatalyst, the preparation method comprises the following steps:
in step S3, 0.5% by mass of 1T-MoS is obtained2@ TNTs composite photocatalytic material powder.
As a further improvement of the preparation method of the metal phase molybdenum disulfide/titanium dioxide nanotube composite material photocatalyst, the preparation method comprises the following steps:
the specific steps of removing impurities by washing with deionized water and absolute ethyl alcohol are as follows: washing with deionized water for 3 times, and washing with anhydrous ethanol for 3 times.
The invention also provides an application of the metal phase molybdenum disulfide/titanium dioxide nanotube composite material photocatalyst:
the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst degrades residual antibiotics in wastewater.
As an improvement on the application of the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst of the invention:
the antibiotic is tetracycline hydrochloride.
The preparation method and the application of the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst have the technical advantages that:
the invention synthesizes 1T-MoS for the first time2The @ TNTs composite photocatalytic material is found to show good capability of decomposing antibiotics in water under visible light. The invention is 1T-MoS2The application of the co-catalyst provides a new thought and a preparation method, and has a strong market application prospect.
The invention provides the 1T-MoS with simple process and low cost by adopting an in-situ synthesis method2A preparation method of a @ TNTs composite photocatalyst. MoS in the composite material prepared by the method2Is pure 1T phase, MoS2The nano particles are uniformly distributed on the TiO2 nano tube material and have better antibiotic degradation performance under visible light. Wherein the efficiency of degrading tetracycline hydrochloride by the composite photocatalyst with the mass ratio of 0.5% under visible light reaches 57%.
Drawings
The following describes embodiments of the present invention in further detail with reference to the accompanying drawings.
FIG. 1 is an X-ray diffraction pattern and corresponding XRD standard card for photocatalysts prepared in example 1, comparative example 1 and comparative example 2 of the present invention;
FIG. 2a is a 1T-MoS prepared according to example 1 of the present invention2Scanning Electron Microscopy (SEM) of @ TNTs composite catalyst;
FIG. 2b is a 1T-MoS prepared according to example 1 of the present invention2Transmission Electron Microscopy (TEM) of @ TNTs composite catalyst;
FIG. 3 shows the preparation of photocatalysts prepared in example 1, comparative example 1 and comparative example 2 of the present inventionCatalytic Performance diagram, 1T-MoS2TNTs and 1T-MoS2The degradation rates of the @ TNTs composite catalyst were 0.6%, 22% and 56%, respectively.
Detailed Description
The invention will be further described with reference to specific examples, but the scope of the invention is not limited thereto.
Example 1, a method for preparing a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst, comprising the steps of:
18mgMoO321mg thioacetamide and 180mg urea are dissolved in 80ml deionized water to obtain 1T-MoS24000mgTNTs powder is added into the precursor solution, and the mixture is stirred for 2 hours to fully mix the materials to obtain suspension. The suspension was transferred to a 100mL Teflon lined autoclave and allowed to react in an oven at 200 ℃ for 12 h. Washing the product obtained after the reaction by deionized water and absolute ethyl alcohol to remove impurities, drying in a vacuum drying oven, and finally grinding to obtain 0.5% 1T-MoS2@ TNTs composite photocatalytic material powder.
1T-MoS obtained in example 12The catalytic performance of the @ TNTs composite photocatalytic material powder is tested by degrading tetracycline hydrochloride within the visible light wavelength range (not less than 420 nm). The dosage of the catalyst is 50mg, and the concentration of the tetracycline hydrochloride solution is 20 mg/L. The 1h degradation rate was 57% as measured by UV-visible spectrophotometer.
Embodiment 2, a method for preparing a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst with different proportions, comprising the following steps:
400mg of TNTs powder and the balance of the TNTs powder are the same as those in example 1, and the composite photocatalytic material powder with the mass ratio of 5 percent is prepared, and the degradation rate of the composite photocatalytic material powder is 40 percent
Comparative example 1: 1T-MoS2The synthesis method of the catalyst comprises the following steps:
mixing 96mgMoO3102mg thioacetamide and 0.96g urea were dissolved in 80mL deionized water and stirred for 2h to mix well. The solution was then placed in an autoclave, and the oven was heatedAfter reaching 200 ℃, the reaction kettle is placed in the reaction kettle for reaction for 12 hours. And after the reaction is finished, taking out the reaction kettle, quickly cooling the reaction kettle to room temperature, collecting a solid product, and centrifugally washing the solid product by using deionized water and an ethanol solution. Drying and grinding the sample in a vacuum drying oven to obtain 1T-MoS2A catalyst powder.
Comparative example 2: a method for synthesizing a TNTs catalyst comprises the following steps:
the powder P25 was added to 100mL of a concentrated alkali solution of NaOH having a concentration of 10mol/L and stirred with a magnetic stirrer for 4 hours, and then the solution was transferred to a Teflon liner and charged into a reaction vessel. The reaction kettle is placed into an oven at 150 ℃ for reaction for 12 hours. After the reaction is finished, HNO with the concentration of 0.1mol/L is used3And repeatedly washing the aqueous solution and the deionized water to obtain a white product, drying, and grinding into powder to obtain the TNTs sample.
The TNTs sample of the product obtained in the comparative example 2 degrades tetracycline hydrochloride in the visible wavelength range (not less than 420nm) to test the catalytic performance. The dosage of the catalyst is 50mg, and the concentration of the tetracycline hydrochloride solution is 20 mg/L. The 1h degradation rate is 22% as measured by an ultraviolet-visible spectrophotometer.
Finally, it is also noted that the above-mentioned lists merely illustrate a few specific embodiments of the invention. It is obvious that the invention is not limited to the above embodiments, but that many variations are possible. All modifications which can be derived or suggested by a person skilled in the art from the disclosure of the present invention are to be considered within the scope of the invention.
Claims (8)
1. A preparation method of a metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst is characterized by comprising the following steps: the method comprises the following steps:
step S1: 18mg of MoO321mg of thioacetylThe amine and 180mg urea were dissolved in 80ml deionized water to give 1T-MoS2In a 1T-MoS2Adding 40-4000mgTNTs powder into the precursor solution, and stirring for 2 hours to fully mix the materials to obtain a suspension;
step S2: transferring the suspension obtained in the step S1 to a reaction kettle with a Teflon liner of 100mL, and reacting in an oven at 200 ℃ for 12-24h to obtain a reaction product;
step S3: washing the reaction product obtained in the step S2 by deionized water and absolute ethyl alcohol to remove impurities, drying in a vacuum drying oven, and finally grinding to obtain 1T-MoS2@ TNTs composite photocatalytic material powder.
2. The method for preparing the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst according to claim 1, characterized in that:
1T-MoS21T-MoS in @ TNTs composite photocatalytic material powder2The mass ratio of the TNTs to the TNTs is 0.5-5 percent.
3. The method for preparing the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst according to claim 2, characterized in that:
the TNTs powder in step S1 was 4000 mg.
4. The method for preparing the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst according to claim 3, characterized in that:
in the step S2, the drying temperature in the oven is 60 ℃, and the reaction time is 12 h.
5. The method for preparing the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst according to claim 4, wherein:
in step S3, 0.5% by mass of 1T-MoS is obtained2@ TNTs composite photocatalytic material powder.
6. The method for preparing the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst according to claim 1, characterized in that:
the specific steps of removing impurities by washing with deionized water and absolute ethyl alcohol are as follows: washing with deionized water for 3 times, and washing with anhydrous ethanol for 3 times.
7. The application of the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst as claimed in claim 1, wherein:
the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst degrades residual antibiotics in wastewater.
8. The application of the metal phase molybdenum disulfide/titanium dioxide nanotube composite photocatalyst as claimed in claim 7, wherein:
the antibiotic is tetracycline hydrochloride.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113981484A (en) * | 2021-10-25 | 2022-01-28 | 青海大学 | High-purity metal phase molybdenum disulfide array/carbon fiber cloth composite material and preparation method and application thereof |
| CN114308076A (en) * | 2021-11-30 | 2022-04-12 | 江苏大学 | Composite photocatalyst, preparation method and application |
| CN115212898A (en) * | 2021-04-14 | 2022-10-21 | 中国科学院大连化学物理研究所 | Catalyst for preparing acetic acid by photocatalytic methane conversion and preparation method thereof |
| CN117005190A (en) * | 2023-08-28 | 2023-11-07 | 广州广微环境科技有限公司 | Mildew-proof antibacterial agent for textiles and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108786855A (en) * | 2017-05-04 | 2018-11-13 | 中国计量大学 | A kind of preparation method of mesoporous molybdenum disulfide visible light catalyst material and its application in degradation antibiotic waste water field |
| CN109621943A (en) * | 2018-12-24 | 2019-04-16 | 南昌航空大学 | A kind of preparation method and applications of 1T phase molybdenum disulfide carried titanium dioxide nano-tube array |
-
2020
- 2020-07-06 CN CN202010639806.0A patent/CN112007662A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108786855A (en) * | 2017-05-04 | 2018-11-13 | 中国计量大学 | A kind of preparation method of mesoporous molybdenum disulfide visible light catalyst material and its application in degradation antibiotic waste water field |
| CN109621943A (en) * | 2018-12-24 | 2019-04-16 | 南昌航空大学 | A kind of preparation method and applications of 1T phase molybdenum disulfide carried titanium dioxide nano-tube array |
Non-Patent Citations (1)
| Title |
|---|
| XIUMEI GENG ET AL.，: "Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction", 《NATURE COMMUNICATIONS》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115212898A (en) * | 2021-04-14 | 2022-10-21 | 中国科学院大连化学物理研究所 | Catalyst for preparing acetic acid by photocatalytic methane conversion and preparation method thereof |
| CN115212898B (en) * | 2021-04-14 | 2023-10-20 | 中国科学院大连化学物理研究所 | Catalyst for preparing acetic acid by photocatalytic methane conversion and preparation method thereof |
| CN113981484A (en) * | 2021-10-25 | 2022-01-28 | 青海大学 | High-purity metal phase molybdenum disulfide array/carbon fiber cloth composite material and preparation method and application thereof |
| CN113981484B (en) * | 2021-10-25 | 2023-09-22 | 青海大学 | High-purity metal phase molybdenum disulfide array/carbon fiber cloth composite material and preparation method and application thereof |
| CN114308076A (en) * | 2021-11-30 | 2022-04-12 | 江苏大学 | Composite photocatalyst, preparation method and application |
| CN114308076B (en) * | 2021-11-30 | 2023-10-10 | 江苏大学 | Composite photocatalyst, preparation method and application |
| CN117005190A (en) * | 2023-08-28 | 2023-11-07 | 广州广微环境科技有限公司 | Mildew-proof antibacterial agent for textiles and preparation method thereof |
| CN117005190B (en) * | 2023-08-28 | 2023-12-19 | 广州广微环境科技有限公司 | Mildew-proof antibacterial agent for textiles and preparation method thereof |
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