CN111564237B - 一种近红外热修复柔性导电膜的制备方法 - Google Patents

一种近红外热修复柔性导电膜的制备方法 Download PDF

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Publication number: CN111564237B
Authority: CN; China
Prior art keywords: conductive film; silver; feed liquid; composite material; graphene
Prior art date: 2020-05-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

CN202010434712.XA

Other languages

English (en)

Chinese (zh)

Other versions

CN111564237A (zh

Inventor

王悦辉

周志敏

赵玉珍

王可

林凯文

张小宾

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dragon Totem Technology Hefei Co ltd

Original Assignee

University of Electronic Science and Technology of China Zhongshan Institute

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2020-05-21

Filing date

2020-05-21

Publication date

2021-02-02

2020-05-21 Application filed by University of Electronic Science and Technology of China Zhongshan Institute filed Critical University of Electronic Science and Technology of China Zhongshan Institute

2020-05-21 Priority to CN202010434712.XA priority Critical patent/CN111564237B/zh

2020-08-04 Priority to PCT/CN2020/106757 priority patent/WO2021232597A1/fr

2020-08-21 Publication of CN111564237A publication Critical patent/CN111564237A/zh

2021-02-02 Application granted granted Critical

2021-02-02 Publication of CN111564237B publication Critical patent/CN111564237B/zh

Status Active legal-status Critical Current

2040-05-21 Anticipated expiration legal-status Critical

Links

238000002360 preparation method Methods 0.000 title claims abstract description 14
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 124
229910021389 graphene Inorganic materials 0.000 claims abstract description 116
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 92
229910052709 silver Inorganic materials 0.000 claims abstract description 83
239000004332 silver Substances 0.000 claims abstract description 83
239000007788 liquid Substances 0.000 claims abstract description 61
239000002131 composite material Substances 0.000 claims abstract description 60
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims abstract description 60
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 57
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims abstract description 48
239000004433 Thermoplastic polyurethane Substances 0.000 claims abstract description 47
229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 47
238000006243 chemical reaction Methods 0.000 claims abstract description 38
229910001961 silver nitrate Inorganic materials 0.000 claims abstract description 31
229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 28
239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 28
235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 28
230000008439 repair process Effects 0.000 claims abstract description 27
238000002156 mixing Methods 0.000 claims abstract description 26
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 25
238000004729 solvothermal method Methods 0.000 claims abstract description 18
238000001035 drying Methods 0.000 claims abstract description 13
239000011268 mixed slurry Substances 0.000 claims abstract description 11
238000003756 stirring Methods 0.000 claims description 32
238000000034 method Methods 0.000 claims description 30
230000015572 biosynthetic process Effects 0.000 claims description 10
239000012295 chemical reaction liquid Substances 0.000 claims description 9
238000009210 therapy by ultrasound Methods 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 2
239000000463 material Substances 0.000 abstract description 18
230000009471 action Effects 0.000 abstract description 2
-1 silver nitrate ions Chemical class 0.000 description 29
239000000243 solution Substances 0.000 description 27
239000002042 Silver nanowire Substances 0.000 description 24
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 22
239000013078 crystal Substances 0.000 description 22
239000011259 mixed solution Substances 0.000 description 20
238000010438 heat treatment Methods 0.000 description 17
230000008569 process Effects 0.000 description 15
239000002002 slurry Substances 0.000 description 15
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 14
229920001343 polytetrafluoroethylene Polymers 0.000 description 11
239000004810 polytetrafluoroethylene Substances 0.000 description 11
238000005266 casting Methods 0.000 description 9
238000005406 washing Methods 0.000 description 9
239000006185 dispersion Substances 0.000 description 8
238000001816 cooling Methods 0.000 description 7
229910021607 Silver chloride Inorganic materials 0.000 description 6
FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 6
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
239000000084 colloidal system Substances 0.000 description 6
229910052760 oxygen Inorganic materials 0.000 description 6
239000001301 oxygen Substances 0.000 description 6
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 6
238000001291 vacuum drying Methods 0.000 description 6
229920006316 polyvinylpyrrolidine Polymers 0.000 description 5
239000002904 solvent Substances 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
230000000694 effects Effects 0.000 description 4
238000005530 etching Methods 0.000 description 4
238000011161 development Methods 0.000 description 3
238000002604 ultrasonography Methods 0.000 description 3
LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 2
229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000011231 conductive filler Substances 0.000 description 2
238000005034 decoration Methods 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
239000011159 matrix material Substances 0.000 description 2
239000000203 mixture Substances 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000003607 modifier Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
230000001737 promoting effect Effects 0.000 description 2
230000009467 reduction Effects 0.000 description 2
238000010405 reoxidation reaction Methods 0.000 description 2
238000011160 research Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000005299 abrasion Methods 0.000 description 1
238000005452 bending Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
239000012776 electronic material Substances 0.000 description 1
239000010793 electronic waste Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
230000006872 improvement Effects 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
238000012827 research and development Methods 0.000 description 1
231100000241 scar Toxicity 0.000 description 1
238000007790 scraping Methods 0.000 description 1
238000006748 scratching Methods 0.000 description 1
230000002393 scratching effect Effects 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B5/00—Non-insulated conductors or conductive bodies characterised by their form
- H01B5/14—Non-insulated conductors or conductive bodies characterised by their form comprising conductive layers or films on insulating-supports
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables

CN202010434712.XA 2020-05-21 2020-05-21 一种近红外热修复柔性导电膜的制备方法 Active CN111564237B (zh)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
CN202010434712.XA CN111564237B (zh)	2020-05-21	2020-05-21	一种近红外热修复柔性导电膜的制备方法
PCT/CN2020/106757 WO2021232597A1 (fr)	2020-05-21	2020-08-04	Film conducteur flexible de réparation thermique à la lumière du proche infrarouge et procédé de préparation associé

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CN202010434712.XA CN111564237B (zh)	2020-05-21	2020-05-21	一种近红外热修复柔性导电膜的制备方法

Publications (2)

Publication Number	Publication Date
CN111564237A CN111564237A (zh)	2020-08-21
CN111564237B true CN111564237B (zh)	2021-02-02

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CN (1)	CN111564237B (fr)
WO (1)	WO2021232597A1 (fr)

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Publication number	Priority date	Publication date	Assignee	Title
CN113861662A (zh) *	2021-09-30	2021-12-31	南昌航空大学	一种自修复聚氨酯导热复合材料及其制备方法
CN114010844B (zh) *	2021-10-28	2023-08-22	浙江理工大学	一种具有稳定信号传导功能的膜材料、心肌补片及其制备方法
CN114477152B (zh) *	2021-12-30	2023-08-15	杭州电子科技大学	一种银纳米颗粒/多层石墨烯复合材料及制备方法
CN116836421B (zh) *	2023-04-11	2024-02-06	湖北中一科技股份有限公司	一种导电膜及其制备方法

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CN110527120A (zh) *	2019-10-09	2019-12-03	南昌航空大学	一种高强度的柔性导电自修复薄膜的制作方法

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KR20200002700A (ko) *	2018-06-29	2020-01-08	삼성전자주식회사	자가 복원성 복합체 및 이를 포함하는 소자
CN109336091B (zh) *	2018-10-11	2020-08-25	华南协同创新研究院	一种石墨烯原位生长银纳米线杂化导电材料及其制备方法和应用
CN110085349B (zh) *	2019-02-03	2020-10-27	深圳前海皓隆科技有限公司	一种透明石墨烯负载纳米银线防静电膜及其制备方法

2020
- 2020-05-21 CN CN202010434712.XA patent/CN111564237B/zh active Active
- 2020-08-04 WO PCT/CN2020/106757 patent/WO2021232597A1/fr active Application Filing

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CN104607655A (zh) *	2015-03-06	2015-05-13	苏州大学	一种银纳米线的制备方法
CN105623136A (zh) *	2016-03-17	2016-06-01	中国科学院深圳先进技术研究院	一种聚合物导电复合材料及其制备方法
CN106519939A (zh) *	2016-09-29	2017-03-22	广东工业大学	一种基于形状记忆的自修复型导电传感高分子材料
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Publication number	Publication date
WO2021232597A1 (fr)	2021-11-25
CN111564237A (zh)	2020-08-21

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Date	Code	Title	Description
2020-08-21	PB01	Publication
2020-08-21	PB01	Publication
2020-09-15	SE01	Entry into force of request for substantive examination
2020-09-15	SE01	Entry into force of request for substantive examination
2021-02-02	GR01	Patent grant
2021-02-02	GR01	Patent grant
2024-01-12	TR01	Transfer of patent right
2024-01-12	TR01	Transfer of patent right	Effective date of registration: 20231228 Address after: 230000 floor 1, building 2, phase I, e-commerce Park, Jinggang Road, Shushan Economic Development Zone, Hefei City, Anhui Province Patentee after: Dragon totem Technology (Hefei) Co.,Ltd. Address before: 528402, Xueyuan Road, 1, Shiqi District, Guangdong, Zhongshan Patentee before: University OF ELECTRONIC SCIENCE AND TECHNOLOGY OF CHINA, ZHONGSHAN INSTITUTE

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