CN111534182A - 一种水性上光油及其制备方法 - Google Patents

一种水性上光油及其制备方法 Download PDF

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CN111534182A
CN111534182A CN202010385120.3A CN202010385120A CN111534182A CN 111534182 A CN111534182 A CN 111534182A CN 202010385120 A CN202010385120 A CN 202010385120A CN 111534182 A CN111534182 A CN 111534182A
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emulsion
water
styrene
aqueous varnish
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陈梁
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Bauhinia Variegata Ink Zhejiang Co ltd
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Abstract

本发明公开了一种水性上光油，所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液60‑70g、苯乙烯‑丙烯酸酯树脂液5‑12g、防滑蜡乳液10‑15g、助剂6‑8g、水6‑10g。本发明提高了水性上光油的防滑性能，不需要再添加其他交联剂就能达到很好的防滑效果，非常实用，值得以后推广使用。

Description

一种水性上光油及其制备方法
技术领域
本发明涉及光油技术领域，尤其涉及一种水性上光油及其制备方法。
背景技术
由于水性上光油具有无毒、环保、价格低廉等特点，已经越来越多运用在纸品印刷行业，但由于水性上光油在光泽、防水等方面仍有不足，不能很好地满足客户需求，在手挽袋，啤酒箱等要求防潮防水领域应用受到限制，本发明旨在解决这一技术难题。因此，提出了一种水性上光油。
发明内容
本发明的目的在于提供一种水性上光油，以解决上述背景技术中提出的问题。
为了实现上述目的，本发明采用了如下技术方案：
一种水性上光油，所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液60-70g、苯乙烯-丙烯酸酯树脂液5-12g、防滑蜡乳液10-15g、助剂6-8g、水6-10g。
优选的，所述室温交联型聚丙烯酸酯乳液是一种加入功能单体 DAAM(双丙酮丙烯酰胺)和交联剂ADH(己二酰肼)、甲基丙烯酸缩水甘油酯(GMA)的聚丙烯酸乳液。
优选的，所述助剂为消泡剂、滑爽剂、成膜助剂中的一种。
优选的，所述苯乙烯-丙烯酸酯树脂液是碱溶性苯乙烯-丙烯酸树脂。
优选的，所述防滑蜡乳液是固体份为30-40g的特殊防滑蜡乳液。
优选的，所述消泡剂为破泡聚硅氧烷和憎水颗粒在聚乙二醇中的混合物，固含量为95-100g。
优选的，所述滑爽剂为超高分子量聚二甲基硅氧烷的水分散体。
优选的，所述成膜助剂为十二碳醇酯或二丙二醇甲醚。
本发明还提供一种水性上光油的制备方法，包括如下步骤：
常温下，先加入室温交联型丙烯酸酯乳液，然后在800-900转/ 分钟的转速下边搅拌边缓慢地依次加入消泡剂、苯乙烯-丙烯酸酯树脂液、防滑蜡乳液、成膜助剂，25-35分钟后调低转速至350-450转/ 分钟，再分散20-40分钟，使体系的各种原料分散均匀，即得到一种防水水性上光油。
室温交联型丙烯酸乳液的制备，通过乳液聚合的方法，合成了含有双丙酮丙烯酰胺(DAAM)、甲基丙烯酸缩水甘油酯(GMA)功能单体的乳液，后期添加己二酰肼(ADH)，制成乳液，这种乳液为玉色半透明的单组分室温可固化聚丙烯酸酯乳液
乳液配方
Figure RE-GDA0002560002020000021
Figure RE-GDA0002560002020000031
合成工艺:
(1)预乳化
在装有电动搅拌器、温度计、冷凝管及滴液漏斗的500ml四颈瓶中加入第一段用碱溶性树脂，单体，乳化剂以及去离子水，在54±2℃搅拌约10min，得到预乳化液。
(2)种子乳液制备
取1/4预乳化液在四颈瓶中，升温至74±2℃，然后滴加1/4 APS溶液，反应30min，制得种子乳液。
(3)乳液聚合
核乳液制备：将剩余的APS溶液分成四份，保持反应温度不变，加一份APS溶液与反应瓶中，并滴加剩余3/4预乳化液，1h 滴完，其中每隔30min补加一份APS溶液；
壳乳液制备：
方法一：第二段单体不预乳化。将第二段单体溶于去离子水，并一次性加入反应瓶中，补加一份APS溶液，然后滴加第二段单体的混合溶液，1h内滴加完，保温反应2h，其中每隔30min补加一份APS液；
方法二；第二段单体预乳化。将第二段单体、乳化剂、去离子水预乳化，方法同种子用预乳化法，然后慢慢滴加进核乳液中， 1h内滴加完，保温反应2h，其中每隔30min补加一份APS液；
升温至80±1℃，反应2h，降至室温，并缓慢加入10％ADH溶液，用氨水中和至中性。过滤，出料，得到一种呈蓝光的乳白色乳液。
碱溶性苯丙树脂的合成，采用半连续聚合工艺。
合成配方：
Figure RE-GDA0002560002020000032
Figure RE-GDA0002560002020000041
合成工艺：
首先将适量溶剂、分子量调节剂、部分单体溶液(约占总单体溶液的30％)、部分引发剂溶液(占总引发剂溶液的90％)加入反应器，并将剩余的单体溶液加入到恒压分液漏斗中，然后加热到130℃，缓慢搅拌，预热30min后滴加单体溶液，2h滴完，再补加引发剂溶液后保温2h，降温得到聚合物溶液；将聚合物溶液逐渐倾倒入含去离子水的托盘，不断搅拌，直至固体物全部析出成较小颗粒，然后减压抽滤，得到的固体聚合物干燥即为碱溶性苯乙烯-丙烯酸树脂固体粉末。
固体树脂碱化，将一定量的固体树脂和去离子水加入反映器中，升温到70℃，缓慢搅拌，然后缓慢滴加氨水，直至固体树脂完全溶解，调节pH值至8-9。即得碱溶性苯乙烯-丙烯酸树脂液。
本发明提供的一种水性上光油，本发明以室温交联型聚丙烯酸酯乳液、苯乙烯-丙烯酸酯树脂液、防滑蜡乳液、助剂、水为原料，制得的光油在光泽、防水等方面可以很好地满足客户需求，提高了水性上光油的防滑性能，不需要再添加其他交联剂就能达到很好的防滑效果，非常实用，值得以后推广使用。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合具体实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
实施例1
一种水性上光油，所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液60g、苯乙烯-丙烯酸酯树脂液5g、防滑蜡乳液 10g、助剂6g、水6g。
本发明还提供一种水性上光油的制备方法，包括如下步骤：
常温下，先加入室温交联型丙烯酸酯乳液，然后在800转/分钟的转速下边搅拌边缓慢地依次加入消泡剂、苯乙烯-丙烯酸酯树脂液、防滑蜡乳液、成膜助剂，25分钟后调低转速至350转/分钟，再分散20分钟，使体系的各种原料分散均匀，即得到一种防水水性上光油。
实施例2
一种水性上光油，所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液65g、苯乙烯-丙烯酸酯树脂液8g、防滑蜡乳液 10g、助剂6g、水8g。
本发明还提供一种水性上光油的制备方法，包括如下步骤：
常温下，先加入室温交联型丙烯酸酯乳液，然后在850转/分钟的转速下边搅拌边缓慢地依次加入消泡剂、苯乙烯-丙烯酸酯树脂液、防滑蜡乳液、成膜助剂，30分钟后调低转速至400转/分钟，再分散30分钟，使体系的各种原料分散均匀，即得到一种防水水性上光油。
实施例3
一种水性上光油，所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液65g、苯乙烯-丙烯酸酯树脂液10g、防滑蜡乳液 12g、助剂7g、水8g。
本发明还提供一种水性上光油的制备方法，包括如下步骤：
常温下，先加入室温交联型丙烯酸酯乳液，然后在850转/分钟的转速下边搅拌边缓慢地依次加入消泡剂、苯乙烯-丙烯酸酯树脂液、防滑蜡乳液、成膜助剂，30分钟后调低转速至420转/分钟，再分散35分钟，使体系的各种原料分散均匀，即得到一种防水水性上光油。
实施例4
一种水性上光油，所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液70g、苯乙烯-丙烯酸酯树脂液12g、防滑蜡乳液 15g、助剂8g、水10g。
本发明还提供一种水性上光油的制备方法，包括如下步骤：
常温下，先加入室温交联型丙烯酸酯乳液，然后在900转/分钟的转速下边搅拌边缓慢地依次加入消泡剂、苯乙烯-丙烯酸酯树脂液、防滑蜡乳液、成膜助剂，35分钟后调低转速至450转/分钟，再分散40分钟，使体系的各种原料分散均匀，即得到一种防水水性上光油。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (9)

1.一种水性上光油，其特征在于：所述水性上光油按照重量的配方如下：室温交联型聚丙烯酸酯乳液60-70g、苯乙烯-丙烯酸酯树脂液5-12g、防滑蜡乳液10-15g、助剂6-8g、水6-10g。
2.根据权利要求1所述的一种水性上光油，其特征在于：所述室温交联型聚丙烯酸酯乳液是一种加入功能单体DAAM（双丙酮丙烯酰胺）和交联剂ADH（己二酰肼）、甲基丙烯酸缩水甘油酯（GMA）的聚丙烯酸乳液。
3.根据权利要求1所述的一种水性上光油，其特征在于：所述助剂为消泡剂、滑爽剂、成膜助剂中的一种。
4.根据权利要求1所述的一种水性上光油，其特征在于：所述苯乙烯-丙烯酸酯树脂液是碱溶性苯乙烯-丙烯酸树脂。
5.根据权利要求1所述的一种水性上光油，其特征在于：所述防滑蜡乳液是固体份为30-40g的特殊防滑蜡乳液。
6.根据权利要求3所述的一种水性上光油，其特征在于：所述消泡剂为破泡聚硅氧烷和憎水颗粒在聚乙二醇中的混合物，固含量为95-100g。
7.根据权利要求3所述的一种水性上光油，其特征在于：所述滑爽剂为超高分子量聚二甲基硅氧烷的水分散体。
8.根据权利要求3所述的一种水性上光油，其特征在于：所述成膜助剂为十二碳醇酯或二丙二醇甲醚。
9.一种权利要求1所述的水性上光油的制备方法，其特征在于：包括如下步骤：
常温下，先加入室温交联型丙烯酸酯乳液，然后在800-900转/分钟的转速下边搅拌边缓慢地依次加入消泡剂、苯乙烯- 丙烯酸酯树脂液、防滑蜡乳液、成膜助剂，25-35分钟后调低转速至350-450转/分钟，再分散20-40分钟，使体系的各种原料分散均匀，即得到一种防水水性上光油。
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