CN102517176B - Special tub lotion for washing machine - Google Patents

Special tub lotion for washing machine Download PDF

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CN102517176B
CN102517176B CN 201110394669 CN201110394669A CN102517176B CN 102517176 B CN102517176 B CN 102517176B CN 201110394669 CN201110394669 CN 201110394669 CN 201110394669 A CN201110394669 A CN 201110394669A CN 102517176 B CN102517176 B CN 102517176B
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washing machine
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component
weight part
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CN102517176A (en
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甄志超
刘萌
王广峰
李朝顺
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China Science Pioneer Engineering Plastics National Engineering Research Center Co., Ltd.
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HKH NATIONAL ENGINEERING RESEARCH CENTER OF PLASTICS Co Ltd
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Abstract

The invention relates to cleaning materials, in particular to a cleaning material with the functions of descaling and sterilization for a washing machine. The invention provides a special tub lotion for the washing machine. The special tub lotion is formed by mixing ingredients A, B, C and D, wherein the ingredient A is one or more of hypochlorite, percarbonate and perborate, the ingredient B is one or more of calcium oxide, sodium hydroxide, potassium oxide and sodium oxide, the ingredient C is one or more of the OP series, the TX series and the AEO series of a nonionic surfactant, and the ingredient D is one or more of sodium silicate, stearic acid, dextrin and pregelatinized starch. The special tub lotion for the washing machine has the advantages of more thoroughness in descaling, non-toxicity and harmlessness and environment-friendliness, and the scale can be effectively removed at the same time while the effective sterilization is achieved.

Description

Washing machine special barrel lotion
Technical field
The present invention relates to a kind of cleaning material, particularly relate to a kind of for cleaning material washing machine, that have scale removal and sterilizing function.
Background technology
Washing machine originally is convenient for people to cleaning clothes, but through using for a long time, the interlayer of washing machine has just become " secondary pollution source ".The urceolus of opening washing machine can be seen life-time service and can adhere to the solid yellow of one deck or black dirt on the inner tank of washing machine outer wall do not cleared up.Because not only the existence of these dirts can not can also threaten people's health to germ on the clothing band with the clothing wash clean, washing machine interlayer reality becomes source of pollution just as water drain thus, to such an extent as to make clothes wash dirtier and dirtier.
Detect us by analysis and recognize that the dirt in the washing machine interlayer mainly is made up of five class rubbish: 1, the incrustation scale formed of the calcium ion in the tap water and calcium carbonate; 2, the educt of scouring agent (soap powder); 3, the Mierocrystalline cellulose of clothing; 4, the organic substance of human body; 5, grey thing and bacterium and other material brought into of clothing.More than these hodgepodges firmly be attached to (inner tank of washing machine outer wall outer tube inner wall) in the washing machine interlayer, breeding in normal temperature, fermentation can bring human body by pollution clothes during laundry.Washing machine is more long duration of service, and the dirt of accumulation and germ are just more many, is necessary so use the washing machine tank scavenger specially regularly washing machine to be cleared up.
Chinese invention patent application specification CN1796521A discloses a kind of purificant dedicated to barrel type washing machine, made by following raw material: (a) oxygen is sanitising agent, antiseptic-germicide 50-99 weight part, (b) alkaline, inorganic salts class material 0-50 weight part, (c) nonionogenic tenside 0.1-25 weight part; Its 1% aqueous ph value is greater than 8.Though this washing composition can effectively be removed spot and bacterium that the inside and outside bucket of current laundry machine adheres to, accumulates, eliminate the root of washing machine cross infection, have antibiotic rate preferably, its descale effect is not so good.
Chinese invention patent application specification CN101591589A discloses a kind of removing agent for cleaning interlayer of inner tank of washing machine, has following prescription (component and weight percent % thereof): higher alcohols sulfuric acid 10-12; Glycerol fatty acid ester 10-15; Alkyl dimethyl Bian ammonium chloride 5-10; Clorox 2-3; SPC-D 10-15; Water glass 8-10; Biological enzyme formulation 2-3; Water-softening agent 2-3; Soil-suspending agent 2-3; International essence is an amount of; Purify waste water to 100.Though this prescription has antibiotic, soil-removing action, formula constituent more complicated.
Summary of the invention
The present invention is primarily aimed at above technical problem to be solved a kind of new cleaning material is provided, and can effectively remove the dirt on the washing machine drum wall, and kills the bacterium that adheres on barrel wall and make the washing machine interlayer clean, and cleaning get up convenient.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of washing machine special barrel lotion is mixed by component A, B, C, D; Wherein component A is selected from one or more in hypochlorite, percarbonate, the perborate; Component B is selected from one or more in calcium oxide, sodium hydroxide, potassium oxide, the sodium oxide; Component C is selected from one or more in nonionogenic tenside OP series, TX series, the AEO series; Component D is selected from one or more in water glass, stearic acid, dextrin, the pregelatinized Starch.
As a further improvement on the present invention, the shared weight part of component A is 60 parts~95 parts, and the shared weight part of component B is 3 parts~30 parts, and the shared weight part of component C is 1 part~8 parts, and the shared weight part of component D is 1 part~10 parts.
As a further improvement on the present invention, the shared weight part of component A is 70 parts~90 parts, and the shared weight part of component B is 10 parts~22 parts, and the shared weight part of component C is 1 part~5 parts, and the shared weight part of component D is 1 part~6 parts.
As a further improvement on the present invention, the preferred clorox of component A, or SPC-D, or Sodium peroxoborate; The preferred sodium hydroxide of component B; The preferred AEO-7 of component C; The preferred dextrin of component D.
As a further improvement on the present invention, component A is SPC-D, and shared weight part is 60 parts~95 parts; Component B is sodium hydroxide, and shared weight part is 3 parts~30 parts; Component C is AEO~7, and shared weight part is 1 part~8 parts; Component D is dextrin, and shared weight part is 1 part~10 parts.
As a further improvement on the present invention, the purity of component A is oxygen level 9%~16%; The purity of component B is 80%~99%; The purity of component D is 80%~99%.
As a further improvement on the present invention, a kind of washing machine special barrel cleaning block of making according to above-mentioned arbitrary prescription.
As a further improvement on the present invention, washing machine special barrel cleaning block is spheroid, perhaps is rule or irregular n face body (n 〉=2).
As a further improvement on the present invention, the overall dimension of washing machine special barrel cleaning block is 1mm~10mm.
Washing machine special barrel lotion of the present invention has been owing to adopted novel active oxygen decontamination formulation, so it is more thorough, nontoxic to have a decontamination, eco-friendly advantage effectively can effectively removed dirt in the sterilization.In addition, the washing machine tank cleaning block that the prescription of washing machine special barrel lotion is made according to the present invention because it has definite shape, can play dirt is carried out physical shock, the slowly effect of release dissolving, and can not stop up pipe washer, reach sterilization preferably, descale effect.
Embodiment:
Specify embodiments of the present invention below:
A kind of washing machine special barrel lotion is mixed by component A, component B, component C and component D, and component A is inorganic salts; Component B is exothermic agent, and component C is nonionogenic tenside, and component D is shaping assistant.
Component A is inorganic salts, decomposites active oxygen after water-soluble, has bleaching and sterilizing functions.Its weight part in mixture is 60~95 parts, is preferably 70~90 parts; Can be selected from hypochlorite, percarbonate, the perborate one or more, concrete, hypochlorite can be clorox, potassium hypochlorite etc., and percarbonate can be SPC-D, antihypo etc., and perborate can be Sodium peroxoborate, potassium per(oxy)borate etc.; Component A is preferably SPC-D, and SPC-D is tasteless, nontoxic, soluble in water and can decompose and emit active oxygen, so it has very strong bleaching, washability, is a kind of novel alkaline SYNTHETIC OPTICAL WHITNER; Component A is preferred clorox also, or preferred Sodium peroxoborate; Component A purity is oxygen level 9%~16%.
Component B is exothermic agent, can emit heat behind the chance water, and water temperature is raise, and can accelerate the decomposition of component A, makes the easier barrel wall of peeling off of dirt, and is pollution-free.Its weight part in mixture is 3~30 parts, is preferably 10-22 part; Can be selected from calcium oxide, sodium hydroxide, potassium oxide, the sodium oxide one or more, be preferably sodium hydroxide; Component B purity is 80%~99%.
Component C is tensio-active agent, because the dirt in the interlayer mainly is the stupid dirt of anti-anion surfactant, so the present invention selects nonionogenic tenside, by the emulsification of tensio-active agent, wetting, dissemination, reduce the sticking power of dirt and bucket wall, make that dirt is easier to be peeled off.Its weight part in mixture is 1-8 part, is preferably 1-5 part; Can be selected from nonionogenic tenside OP series, TX series, the AEO series one or more, concrete, OP series can be OP-30, OP-10, OP-4, OP-9 etc., and TX series can be TX-10, TX-6, TX-4 etc., and AEO series can be AEO-3, AEO-7, AEO-9 etc.; Component C is preferably the AEO-7 in the AEO series.
Component D is shaping assistant, and its weight part in mixture is 1-10 part, is preferably 1-6 part; Can be selected from water glass, stearic acid, dextrin, the pregelatinized Starch one or more, be preferably dextrin; Purity is 80%~99%.
For the explanation of being more convenient for, adopt the form of form that embodiments of the invention are described in detail in detail below, for the ease of expression, its code name implication is as follows:
---clorox, A2---SPC-D, A3---Sodium peroxoborate, A4---antihypo among the component A: A1;
---calcium oxide, B2---sodium hydroxide, B3---potassium oxide, B4---sodium oxide among the component B: B1;
---OP-30, C2---OP-9, C3---TX-10, C4---TX-4, C5---AEO-3, C6---AEO-7 in the component C: C1;
---water glass, D2---stearic acid, D3---dextrin, D4---pregelatinized Starch among the component D: D1.
Above component A and component C not limit list its included kind, all can meet the demands as long as satisfy salt and the series of the present invention's regulation.Be example with component A, component B, component C and four kinds of materials of component D totally 100 grams of adding up below, the effect of and scale removal antibiotic to washing machine tank under the difference composition be described.
Wherein, the detection of antibiotic rate detects by GB21551.1-2008 " antibiotic, the degerming of household electrical appliances and similar applications electrical equipment, purification function general rule " and JIS Z 2801:2000 " detection of antimicrobial prod anti-microbial property and evaluation " specified test
The testing method of descaling rate is: the inner tank of washing machine that (1) will be stained with dirt cuts into 10 * 10(cm) sheet, chooses two tinsels that dirt is more, is labeled as No. 1, No. 2, records the area of its dirt respectively.(2) two metal sheets is fixed on the electric blender, is immersed in the 2.5L clear water for No. 1, be immersed in the 2.5L water that has added 20g sample (making according to embodiment) for No. 2, water temperature is 25 degree.(3) behind the 40min, the two all stirs 40min with the rotating speed rotation of 200r/min.After stirring is finished two metal sheets is taken off, measure the dirt area, and record data calculate.(4) descaling rate=(No. 2 sheet dirt area/No. 1 sheet dirt areas) * 100%.
Table 1:
Figure 319755DEST_PATH_IMAGE002
Need to prove, the enforceable mode of the present invention that provides of limit not among the embodiment of table 1, for the present invention, component A is selected from any in hypochlorite, percarbonate, the perborate; Component B is selected from any in calcium oxide, sodium hydroxide, potassium oxide, the sodium oxide; Component C is selected from any in nonionogenic tenside OP series, TX series, the AEO series; Component D is selected from any in water glass, stearic acid, dextrin, the pregelatinized Starch.The selection of its concrete material grams can be optional, needs only its umber scope in the composition range that the present invention provides, and its effect that is combined into all can reach purpose of the present invention.
Table 2:
Figure 204534DEST_PATH_IMAGE004
Need to prove, the enforceable mode of the present invention that provides of limit not among the embodiment of table 2, for the present invention, materials A can be a kind of in hypochlorite, percarbonate, the perborate or two kinds or three kinds until or the mixing of multiple material; Material B can be the mixing of a kind of or two kinds or three kinds or the four kinds materials in calcium oxide, sodium hydroxide, potassium oxide, the sodium oxide; Material C can be a kind of in nonionogenic tenside OP series, TX series, the AEO series or two kinds or three kinds until or the mixing of multiple material.The selection of its concrete material grams can be optional, as long as its scope is in the composition range that the present invention provides after constituting every kind of component, its effect that is combined into all can reach purpose of the present invention.
Table 3:
Figure 201110394669X100002DEST_PATH_IMAGE005
Need to prove, the not selection of concrete material grams during the providing the present invention three kinds of constituent materialss are all mixed of limit among the embodiment of table 3, its grams can be selected arbitrarily, as long as its scope is in the composition range that the present invention provides after constituting every kind of component, its effect that is combined into all can reach purpose of the present invention.
Further, a kind of washing machine special barrel cleaning block of making according to the above-mentioned arbitrary prescription of the present invention.This cleaning block is spheroid, perhaps is rule or irregular n face body (n 〉=2), and the overall dimension of cleaning block is 1mm~10mm.During use, an amount of washing machine special barrel cleaning block is put into washing machine, high-water is carried out the purpose that washing-rinsing flow process once can reach washing machine self-cleaning, sterilization, scale removal, easy and simple to handle, with low cost, can not cause damage to washing machine and obligation, the discharge after the washing does not have destruction to environment.

Claims (8)

1. a washing machine special barrel lotion is characterized in that: mixed by component A, B, C, D; Described component A is selected from one or more in hypochlorite, percarbonate, the perborate, and shared weight part is 60 parts~95 parts; Described component B is selected from one or more in calcium oxide, sodium hydroxide, potassium oxide, the sodium oxide, and shared weight part is 3 parts~30 parts; Described component C is selected from one or more in nonionogenic tenside OP series, TX series, the AEO series, and shared weight part is 1 part~8 parts; Described component D is selected from one or more in water glass, stearic acid, dextrin, the pregelatinized Starch, and shared weight part is 1 part~10 parts.
2. a kind of washing machine special barrel lotion according to claim 1, it is characterized in that: the shared weight part of described component A is 70 parts~90 parts, the shared weight part of described component B is 10 parts~22 parts, the shared weight part of described component C is 1 part~5 parts, and the shared weight part of described component D is 1 part~6 parts.
3. a kind of washing machine special barrel lotion according to claim 1 is characterized in that: the preferred clorox of described component A, or SPC-D, or Sodium peroxoborate; The preferred sodium hydroxide of described component B; The preferred AEO-7 of described component C; The preferred dextrin of described component D.
4. a kind of washing machine special barrel lotion according to claim 1, it is characterized in that: described component A is SPC-D, shared weight part is 60 parts~95 parts; Described component B is sodium hydroxide, and shared weight part is 3 parts~30 parts; Described component C is AEO-7, and shared weight part is 1 part~8 parts; Described component D is dextrin, and shared weight part is 1 part~10 parts.
5. according to each described a kind of washing machine special barrel lotion in the claim 1 to 4, it is characterized in that: the purity of described component A is oxygen level 9%~16%; The purity of described component B is 80%~99%; The purity of described component D is 80%~99%.
6. a kind of washing machine special barrel cleaning block of making according to each claim in the claim 1 to 5.
7. a kind of washing machine special barrel cleaning block according to claim 7, it is characterized in that: described washing machine special barrel cleaning block is spheroid, perhaps is rule or irregular n face body.
8. a kind of washing machine special barrel cleaning block according to claim 7, it is characterized in that: the overall dimension of described washing machine special barrel cleaning block is 1mm~10mm.
CN 201110394669 2011-12-02 2011-12-02 Special tub lotion for washing machine Active CN102517176B (en)

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CN102643723B (en) * 2012-03-26 2015-07-29 成都西油联合石油天然气工程技术有限公司 High pressure valve pocket clean-out system and its preparation method and application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796520A (en) * 2004-12-20 2006-07-05 张捷 Purificant dedicated to washing machine
CN1796521A (en) * 2004-12-28 2006-07-05 海尔科化工程塑料国家工程研究中心股份有限公司 Purificant dedicated to barrel type washing machine
CN101760344A (en) * 2008-11-07 2010-06-30 南通芯迎设计服务有限公司 Washing detergent of washing machine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796520A (en) * 2004-12-20 2006-07-05 张捷 Purificant dedicated to washing machine
CN1796521A (en) * 2004-12-28 2006-07-05 海尔科化工程塑料国家工程研究中心股份有限公司 Purificant dedicated to barrel type washing machine
CN101760344A (en) * 2008-11-07 2010-06-30 南通芯迎设计服务有限公司 Washing detergent of washing machine

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Address after: 100080 Beijing Haidian District Zhongguancun North No. 2

Patentee after: China Science Pioneer Engineering Plastics National Engineering Research Center Co., Ltd.

Address before: 100080 Beijing Haidian District Zhongguancun North No. 2

Patentee before: HKH National Engineering Research Center of Plastics Co., Ltd.